Cooperative Chloride Hydrogel Electrolytes Enabling Ultralow-Temperature Aqueous Zinc Ion Batteries by the Hofmeister Effect

Highlights The electrochemical windows of the chloride hydrogel electrolytes are enlarged by >1 V under cryogenic conditions. The cells based on electrolytes with high Cl− concentrations can work in more severe environments. Based on the Hofmeister effect, the hydrogen-bond network of the electrolytes can be strongly interrupted by the addition of Li+. The full cell with the optimized hydrogel electrolyte presents impressive electrochemical performance at –50 °C. Supplementary Information The online version contains supplementary material available at 10.1007/s40820-022-00836-2.


Introduction
The rapid development of the electronic (E) era has put forward more stringent requirements for energy storage devices [1,2]. Aqueous batteries that employ water as the electrolyte solvent fundamentally solve the intrinsic challenges caused by flammable organic electrolytes, such as safety concerns, strict manufacturing conditions and expensive electrolyte costs [3,4]. Moreover, aqueous electrolytes serve as fast ion conductors, thereby improving the power characteristics of battery systems; thus, their use has attracted considerable attention worldwide [5].
Unfortunately, compared with low-melting organic electrolytes such as ethyl acetate [6], 1,3-dioxolane [7], and methyl propionate [8], aqueous electrolytes often suffer from congelation at ultralow temperatures due to the inherent freezing point (0 °C) of water molecules; this results in a decrease in battery capacity and limits the number of operating cycles of electronic devices [9,10]. High-concentration aqueous electrolytes have recently been proposed, which have lower freezing point temperatures by preventing the formation of a hydrogen-bond (H-bond) network between the water molecules [11][12][13][14]. These aqueous electrolytes can inhibit the thermodynamic reactivity of water by adjusting the number of water molecules in the ionic solvation sheath, which further overcomes the parasitic interfacial reactions and delivers high low-temperature resistance [15]. In addition, high-concentration aqueous electrolytes play a decisive role in widening the electrochemical window and achieving an ultralong cycle life [16][17][18]. As shown in Fig. 1a, the concentrations of the KOTf (KCF 3 SO 3 ) and LiTFSI (LiN(CF 3 SO 2 ) 2 ) organic salts and the ZnCl 2 , LiCl, and NaClO 4 inorganic salts all exceed 10 m (molality, mol kg −1 ). However, the prices of the above inorganic and organic salts are quite different (Fig. 1b). For instance, the price of LiCl is only $69 per kg, which is approximately 1/9 that of LiTFSI, while ZnCl 2 is only $15 per kg, which is approximately 1/40 that of LiTFSI. Therefore, from a cost perspective, it would be highly beneficial to develop highly concentrated aqueous electrolytes utilizing the water-soluble chloride salts ZnCl 2 and LiCl.
In terms of aqueous zinc ion batteries, cooperative hydrated ion electrolytes have shown impressive low-temperature electrochemical performances in previous reports. For instance, a 2 M (molality, mol L −1 ) ZnSO 4 + 4 M LiCl hydrogel electrolyte with high zinc reversibility enables the battery to achieve an ~ 100% capacity retention at −20 °C [19]. However, ZnSO 4 is not preferred in cold climates of < −20 °C due to its low solubility at lower temperatures. It is worth noting that a highly cooperative aqueous chloride electrolyte (7.6 M ZnCl 2 + 0.05 M SnCl 2 ) successfully completed low-temperature operation for 200 cycles at −50 °C, during which zinc dendrite growth was suppressed [20]. Additionally, gel electrolytes have attracted considerable attention for their competitive ion conductivity, good flexibility, low interfacial impedance, and high integration with electrodes; thus, they have been regarded as potential replacements for liquid and all-solid-state electrolytes [21][22][23][24][25]. In the typical Hofmeister series, different types of cations will affect the size of ice particles after recrystallization and the crystalline state (nongelation and gelation) of poly(vinyl alcohol) (PVA) hydrogels, which led to various degrees of damage to the H-bond structure [26,27]. As shown in Fig. 1c, the H-bond destruction in ice crystals and PVA chains by different cations but with the same Cl − anion follows the order Li + > Na + > K + . The bacterial cellulose (BC) hydrogel, containing a large amount of hydroxyl groups and water molecules, is similar to the PVA hydrogel. Thus, the use of BC hydrogel as the electrolyte matrix should produce an analogous order of destruction of H-bonds by Li + , Na + , and K + , as shown in Fig. 1d. In principle, compared to that in the amorphous region, ion transport is much slower in the crystalline regions of BC and the ice crystal regions (where H-bonds exist), which means that fast ion transport is more likely to occur in the ion-interrupted regions of the ice crystals and the amorphous part of BC at low temperatures [28,29]. For example, Hu et al. found that the amorphous regions of cellulose nanofibrils opened by Cu 2+ were capable of quickly transporting ions, resulting in the high ionic conductivity and a high transference number [30]. The increase in the viscosity of electrolytes at low temperatures will lead to a sharp drop in ionic conductivity [31,32], which may be compensated by the way the ions open more channels in the crystalline regions of the gel electrolyte. Therefore, it is rational to hypothesize that the cooperative ZnCl 2 -LiCl, ZnCl 2 -NaCl, and ZnCl 2 -KCl BC hydrogel electrolytes will exhibit unique low-temperature electrochemical performance in aqueous zinc ion batteries, and this stirred our interest. Furthermore, chlorides have been reported to potentially result in unstable electrolyte/ 1 3 electrode interfaces [33,34], thereby causing the narrow electrochemical windows. However, this instability has not yet been thoroughly investigated.
Herein, we systematically studied the electrochemical window stability of BC hydrogel electrolytes composed of chlorides and other salts, and focused on the low-temperature electrochemical behaviour of highly concentrated and cooperative ZnCl 2 -LiCl, ZnCl 2 -NaCl, and ZnCl 2 -KCl hydrogel electrolytes. The low-temperature Raman spectroscopy and linear scanning voltammetry (LSV) results indicate that chloride hydrogel electrolytes (CHEs) with stainless steel as the working electrode have widened electrochemical windows of > 1 V at low temperatures because of the significant increases in the H-bond ratios of the electrolytes. The widened electrochemical windows promote the ultralow-temperature application of aqueous electrolytes in zinc batteries. Compared with other cooperative systems, 3 M ZnCl 2 + 6 M LiCl shows stronger H-bond destruction in the hydrogel electrolyte, exposing more amorphous regions and lowering the viscosity; thus, a high ionic conductivity (σ) of 1.14 mS cm −1 and a low activation energy (E a ) of 0.21 eV at −50 °C are obtained. This phenomenon is consistent with the Hofmeister effect. Integrating the expanded electrochemical window and the fast reaction kinetics of the cooperative chloride electrolytes, a polyaniline (PANI)/Zn battery system delivers a superior capacity of 96.5 mAh g −1 and a stable cycle life of 2000 cycles at −50 °C.

Preparation of the Hydrogel Electrolytes
The frozen-thawed BC hydrogels were prepared according to our previous report [35]. The hydrogel electrolytes were prepared by immersing the frozen-thawed BC hydrogels in aqueous solutions of different salts for 24 h to reach the final equilibrium state.

Materials Characterization
The freezing point of hydrogel electrolytes was measured by differential scanning calorimetry (DSC) through a MET-TLER TOLEDO DSC3 from −60 to 20 °C. The Raman spectroscopic studies were recorded at the 532 nm excitation wavelength with a confocal microscope (LabRAM HR Evolution). FTIR spectroscopy were collected using a Nicolet iS50 spectrometer. The 1 H NMR experiments were carried out on an AVANCE NEO 600 M. XPS was performed on a spectrometer (ESCALAB Xi + ) with Al Kα source. The surface morphologies were identified using field emission scanning electron microscopy (FESEM, HITACHI S-4700). The electrolytes' crystalline patterns were collected on a PANalytical, Aereis X-ray diffractometer using Cu Kα radiation at room temperature. Tensile curves were acquired with an electronic universal testing machine (MDTC-EQ-M12-01) with a stretching rate of 10 mm/min.

Electrochemical Tests
PANI was obtained by oxidizing aniline monomer with ammonium persulfate in hydrochloric acid aqueous solution followed by its in situ polymerization on carbon cloth [36]. The mass loading of PANI was about 1 mg cm −2 . For the LiFePO 4 cathode, in a typical process, the active material was mixed with acetylene black and polyvinylidene fluoride at an 8:1:1 weight ratio. The mass loading of the above active material was approximately 1-2 mg cm −2 . Cells were assembled in an air atmosphere using Zn foil as the anode in CR2032-type coin cells. Galvanostatic cycling studies were conducted using a Neware battery charge/discharge system (China). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were performed by employing an electrochemical workstation (Wuhan CorrTest, CS310H). The CV curves were measured at a scan rate of 2 mV s −1 from 0.6 to 1.6 V. EIS spectra were recorded with an electrochemical workstation in the temperature range of −50-25 °C and a frequency range of 0.01 to 10 6 Hz. The electrochemical window of the hydrogel electrolytes at different temperatures was investigated with a three-electrode configuration, where stainless steel (SS) foil, Ti foil, Ni foil, Al foil, Cu foil, Pt sheet and carbon cloth (CC) were used as working electrodes and the Zn foil was used as the reference and counter electrode.

Calculation Details
The hydrogel electrolytes were sandwiched between two stainless steel sheets, and the ionic conductivity (σ) at different temperatures is calculated by Eq. 1: where d, R, and S are the thickness, the bulk resistance, and the contact area with electrode, respectively.
The cation transfer numbers (t + ) are calculated by Eq. 2: where I s and I 0 are the steady-state and initial currents, respectively, and R s and R 0 are the corresponding steadystate and initial resistances, and ∆V is the potential applied across the symmetric Zn/Zn cell. The activation energy (E a ) of the hydrogel electrolytes is estimated by the fitting of Arrhenius equation (Eq. 3): where R is the molar gas constant, A is a constant, and T is the absolute temperature.
The crystallinity of BC hydrogel electrolytes is obtained by Eq. 4: where I 002 is the maximum intensity at about 22.5°, and I am is amorphous scattering intensity at 18.0°.

Electrochemical Window Study
We adopted frozen-thawed BC hydrogel as the electrolyte matrix (Fig. S1a). The translucent nature indicated their porous structure, which provided channels for the fast transport of ions (Fig. S1b). Moreover, the BC hydrogel had excellent crystallinity (73.26%) and was thin (Fig. S1c-d), which helped to suppress the growth of zinc dendrites and improved the battery energy density. Four chloride salts (ZnCl 2 , LiCl, NaCl, and KCl) were chosen to prepare aqueous solutions at a concentration of 3 M (Fig. 2a). Among them, the 3 M ZnCl 2 aqueous solution did not freeze at −20 °C, while the other three chloride aqueous solutions all froze at −20 °C. Notably, the large number of hydroxyl groups in BC would break the inherent H-bonds between water molecules, resulting the BC hydrogel having a freezing point of −11.3 °C [35]. Therefore, the corresponding CHEs all had a solid-liquid transition temperature below −20 °C (Fig. 2b) [37]. For the above hydrogel electrolyte systems, the electrochemical windows at 25 and −20 °C were determined by the three-electrode configuration (stainless steel sheet as the working electrode and Zn foil as the reference electrode and counter electrode) in Fig. S1, and the test results are shown in Fig. 2c (Fig. S3). In addition, the electrochemical windows of the hydrogel electrolytes with other halogens (F − , Br − , and I − ) as anions were also inspected (Fig. S4). It was clear that the electrolytes with F − , Br − , and I − all exhibited a small electrochemical window expansion at −20 °C, illustrating that the enlargement of the electrochemical windows by > 1 V at −20 °C was a unique property of Cl − . The above results demonstrated that a low-temperature environment facilitated widening the electrochemical windows of CHEs with stainless steel as the working electrode, thereby promoting the feasibility of using the CHEs in low-temperature button batteries. As a control experiment, the electrochemical windows of 3 M ZnCl 2 and 3 M LiCl hydrogel electrolytes with other working electrodes (Al foil, Cu foil, Ni foil, Pt sheet, carbon cloth (CC) and Ti foil) were tested. Figure S5 and Table S1 indicate that the electrochemical windows of CHEs with non-stainless steel working electrodes are all hardly sensitive to temperature changes. Furthermore, the threeelectrode configuration based on the stainless steel working electrode was tested in narrower temperature ranges by storing the electrolytes in an ice-water mixture (0 °C), refrigerator (5 °C) and freezer (-5 °C) (Fig. S6a). Figure  S6b shows that the 3 M ZnCl 2 , 3 M LiCl, 3 M NaCl, and 3 M KCl hydrogel electrolytes all have a widened electrochemical window with a critical point of 0 °C. Since 0 °C is the freezing point of water molecules, the widening of the electrochemical windows of the CHEs at low temperatures should be closely related to the changes in the structure of the hydrogels, which was caused by Cl − .

Evolution of H-bonds at Low Temperatures
Water molecules in ice crystals are completely connected by H-bonds [38,39]. The large number of hydrated ions generated by the addition of salts will break part of the H-bond network between water molecules, which is also the reason for lowering the freezing point of the hydrogel electrolytes [14,35]. Hence, the behaviour of the CHEs at low temperatures were intimately associated with the H-bond structure. To deeply investigate the mechanism of widening the electrochemical windows of the CHEs at low temperatures, the H-bond structures in the CHEs (3 M ZnCl 2 and 3 M LiCl) and non-CHEs (3 M LiTFSI and 3 M Li 2 SO 4 ) at various temperatures were determined by Raman spectroscopy (Fig. 3a-d). Compared with that at 25 °C, the characteristic peaks of electrolytes were strengthened at 0 and −20 °C, which should be attributed to the stronger interaction between ions and water. Additionally, it was observed that the electrolytes did not show a new characteristic peak with decreasing temperature. Figure 3e-h clearly exhibits fitted peaks at 2800-4000 cm −1 , which are the typical O-H stretching vibration bands of hydrogel electrolytes, and the peaks located at ~ 3240, ~ 3410, and ~ 3580 cm −1 correspond to strong, weak and non-H-bonds, respectively [11,19]. For the 3 M ZnCl 2 hydrogel electrolyte, the H-bond network was mainly composed of strong and weak H-bonds, while strong, weak, and non-H-bonds were observed with the 3 M LiCl, 3 M LiTFSI, and 3 M Li 2 SO 4 counterparts. In addition, compared with the non-CHEs, the stretching vibration peaks of the strong H-bonds in the CHEs showed a notable redshift (to a lower wavenumber) as the temperature gradually decreased, implying increased H-bond interaction [40].
To further quantify the influence of temperature on the H-bonds, the increase ratios of H-bonds were calculated by integrating the fitting peak areas (Fig. 3i-l). It is worth mentioning that when the temperature was lowered from 0 to −20 °C, the increase ratio of the strong H-bonds in the 3 M ZnCl 2 hydrogel electrolyte increased from 1.7% to 13.5% (Δ = 11.8%), and that of the 3 M LiCl electrolyte increased from 14.2% to 21.5% (Δ = 7.3%). In contrast, for the 3 M LiTFSI and 3 M Li 2 SO 4 hydrogel electrolytes, the increase ratios of the strong H-bonds at 0 and −20 °C were similar (Δ = 0.8% and 1.0%, respectively). Raman spectroscopy confirmed that lower temperatures promoted the formation of H-bonds in the CHEs, which agreed with the LSV curves. Thus, the expanded electrochemical windows of the CHEs at low temperatures were believed to be due to the formation of more H-bonds, which could be explained by the stronger inhibition of the water activity kinetics. Moreover, the H-bond strength in different anionic electrolytes (Cl − , SO 4 2− , and TFSI − ) was further examined through FTIR, Raman, and 1 H NMR spectroscopies to reveal whether there was a close connection between chlorine and H-bonds. As shown in Fig. 3m, n, the intensity of the strong H-bond peak located at 3240 cm −1 followed the order SO 4 [41], which greatly promoted the increase in the H-bond ratio.

Matching of a High Cl − Concentration with Harsh Conditions
Based on the expanded electrochemical windows of the CHEs and exceptional performance of the stainless steel working electrode at low temperatures, the cycling stability of LiFePO 4 /Zn button battery was studied (Fig. 4a-d). Li + and Zn 2+ were introduced into each electrolyte as the working mechanism of the LiFePO 4 /Zn battery converted from the single-ion transport of a "rocking chair" battery into double-ion transport. Moreover, to study the relationship between the concentration of Cl − and temperature adaptability, other anions were introduced to adjust the concentration  S9a-c). Note that the similar micro-short circuit and cycling stability (discharge specific capacity of ~ 65 mAh g −1 and capacity retention of ~ 100%) of the batteries occurred at room temperature and low temperature, respectively. Meanwhile, the capacity at low temperatures is mainly limited by the LiFePO 4 electrode. At −20 °C (Fig. S10a), the Zn/Zn symmetric battery using 3 M ZnCl 2 hydrogel electrolyte displayed stable Zn plating/ stripping for over 210 h at 0.2 mA cm −2 , and the overpotential was only 30 mV. However, at 25 °C, the symmetric Zn/ Zn battery showed a significant increase in thickness after cycling, and the overpotential increased from 30 to 130 mV after only 4.6 h, which was accompanied by the generation of cuboid by-products on the corresponding spring ( Fig.  S10b-d). Additionally, compared with the morphology of the bare Zn foil, we observed that although the corresponding Zn anode had a similar metallic lustre after 7.5 h of stripping/plating cycles, there was still obvious zinc dendrite growth (Fig. S10e-f). The above results strongly demonstrated that the CHEs had better low-temperature stability. Taking into account the solubility and cost of chloride salts, the 3 M ZnCl 2 + 6 M LiCl electrolyte with a high concentration of Cl − (12 M) was employed in a LiFePO 4 /Zn button battery (Fig. 4e). The same cycling process was repeated at different temperatures. The cut-off voltages of the full battery for sudden failure at 25 and −10 °C were 1.27 and 1.36 V, respectively. Note that the corresponding battery did not immediately fail to work at −20 and −30 °C but stopped working after 7 and 38 h of the charging/discharging process, respectively. Therefore, batteries based on electrolytes with high Cl − concentrations were capable of working in more severe environments (such as those in electric vehicles, aerospace, and military applications), including operations at lower temperatures and higher current densities.

Reaction Kinetics at Low Temperatures Based on the Hofmeister Effect
Inorganic materials generally store energy through ion insertion/extraction. However, lower temperatures will greatly reduce the diffusion coefficient of ions in the electrode materials or even hinder ion insertion, leading to rapid capacity decay. For example, the battery assembled with a commercial LiCoO 2 cathode only maintained approximately 10% of its room-temperature capacity when operating at < −30 °C [42]. In contrast, the charge storage of organic cathode materials is mainly by the coordination of ions and redox active groups on molecular chains, resulting in faster reaction kinetics; thus, it is easier to obtain a higher capacity at low temperatures [43]. The electrochemical performance of the 6 M ZnCl 2 and 3 M ZnCl 2 + 6 M LiCl hydrogel electrolytes (denoted as 6ZC and 3ZC6LC, respectively), both of which had the same charge concentration of anions/cations, were studied in PANI/Zn button cells at ultralow temperatures. Compared with pure CC (Fig. S11a), the PANI distributed on the surface of CC was dark green, featuring a stamen-like nanostructure (Fig. S11b).
The ion storage mechanism of the PANI/Zn battery is shown in Fig. 5a. During the discharge process, the Zn 2+ /Li + cations interacted with the negatively charged C-N − of the reduced PANI, and during the charging process, the Cl − anions interacted with the positively charged C-N + of the oxidized PANI [36]. The cyclic voltammetry (CV) curves of PANI/Zn cells were obtained at rates from 0.1 to 2.0 mV s −1 (Fig. 5d, e). The two pairs of redox peaks in the CV curves of batteries with 6ZC and 3ZC6LC remained the same. The current responses at various sweep rates are analysed by Eq. 5 [44,45]: For a semi-infinite diffusion-controlled redox process, the peak current i varies with v 0.5 (b = 0.5); in contrast for a surface-controlled capacitive process, it varies with v (b = 1.0). Figure 5f shows the relationship between log (i) and log (v). The b values obtained by the slopes of the fitted curves were approximately 1.0, implying that the redox reaction kinetics were mainly dominated by surface-controlled ion intercalation behaviour. The detailed capacitive contributions (the magenta area) at 1 mV s −1 are shown in Fig.  S12. Thus, the impact of ion transport and charge transfer (ion desolvation) in the electrolytes on the reaction kinetics of the full battery was considered (Fig. 5b). The radii of Li + and its hydrate ions were smaller than those of Zn 2+ and its corresponding hydrate ions (Fig. 5c), which might lead to faster diffusion kinetics in the hydrogel electrolytes [46]. Figure 5g shows the σ of electrolytes at low temperatures, which were calculated based on the Nyquist curves of Fig.  S13. At −30 °C, both 6ZC and 3ZC6LC achieved high σ values of 1.84 and 2.52 mS cm −1 , respectively. Due to the drop in temperature, the σ of 6ZC decreased to 0.23 mS cm −1 at −50 °C, while 3ZC6LC retained a high σ of 1.14 mS cm −1 , which was much higher than the reported aqueous electrolyte using dimethyl sulfoxide as an additive (0.11 mS cm −1 at −50 °C) [47]. In addition, compared to 6ZC (0.44 eV), 3ZC6LC exhibited a lower E a of 0.21 eV at −50 °C, signifying stronger ion desolvation and faster interfacial charge transfer (Fig. 5h). Compared with 6ZC, because 3ZC6LC showed a higher pH value and no freezing point above −60 °C (Fig. S14), it was believed that the higher σ of 3ZC6LC at −50 °C was not contributed by H + motion and the solid-liquid transition temperature. Furthermore, the σ values of hydrogel electrolytes with the same charge concentrations and different molar mass ratios of ZnCl 2 /LiCl at −50 °C were analysed (Fig. S15). The experimental results collectively implied that a high concentration of LiCl was beneficial for improving the σ of electrolytes at ultralow temperatures, probably due to the small ionic radius of Li + .
To uncover whether the ionic radius was the critical factor affecting σ at ultralow temperatures, the σ values of the 3 M ZnCl 2 + 6 M NaCl and 3 M ZnCl 2 + 6 M KCl hydrogel electrolytes (denoted 3ZC6NC and 3ZC6KC, respectively) were further evaluated. Na + has the same valence state as Li + in aqueous solution, and their hydrated ion radius is also close (3.82 [46]. Figure 5g, i implies that 3ZC6NC has a σ of 0.25 mS cm −1 and an E a of 0.42 eV, which indicates that the ionic radius is not the dominant factor for σ at ultralow temperatures. Additionally, the σ of 3ZC6KC at −50 °C was 0.007 mS cm −1 , and the corresponding E a was 0.79 eV. Figure S16 and Table S2 show the cation transference number (t + ) measured with symmetric Zn/Zn cell. Compared with 3ZC6NC and 3ZC6KC, higher values of approximately 0.85 (at −30 °C) and 0.79 (at −50 °C) were obtained for 3ZC6LC, which indicated that 3ZC6LC had lower ion transfer resistance at low temperatures. Notably, the results above were consistent with the sequence of H-bond destruction of water molecules and BC chains based on the Hofmeister effect, Li + > Na + > K + , collectively certifying Li + as a superior cooperative cation for the electrolytes of zinc batteries. Additionally, σ could be further reflected by combining the Nernst-Einstein equation and the Stokes-Einstein equation [48,49], and the rearranged equation is shown in Eq. 6: where η is the viscosity of the electrolyte, r is the Stokes radius of the ions, n is the ion concentration, and q is the ion charge. Equation (6) shows that the rapid kinetics of the ion are determined by the ionic radius and electrolyte viscosity in the case of the same ion charge concentration. In this regard, the ions of ZnCl 2 -LiCl effectively broke the crystalline regions of both water and cellulose (Fig. S17), thereby reducing the η of the electrolyte to strengthen the ion kinetics at ultralow temperatures. Moreover, Fig. S18a shows the stress-strain curves of the hydrogel electrolytes (3ZC6LC, 3ZC6NC, and 3ZC6KC) to demonstrate the destruction of the BC crystalline region by ions. As expected, the hydrogel electrolytes had similar tensile strengths (~ 13 MPa) that were lower than that of the BC hydrogel matrix (~ 15 MPa). Note that 3ZC6LC exhibits a greater elongation due to the more H-bonds being broken by ions in the hydrogel. Most pores were in the range of 50-160 nm and had analogous shapes in the hydrogel electrolytes (Fig. S18b). No significant differences in the mechanical properties and morphology were observed between the hydrogel electrolytes, implying that the H-bond disruption order of the electrolytes based on the Hofmeister effect only became more obvious at low temperatures.

Ultralow Temperature Aqueous PANI/Zn Battery Constructed with the ZnCl 2 -LiCl Hydrogel Electrolyte
The expanded electrochemical window and excellent reaction kinetics of 3ZC6LC discussed above encouraged us to systematically evaluate the electrochemical performance of a PANI/Zn button cell. In the CV curves at −30 °C (Fig. 6a), the batteries with 3ZC6LC and 6ZC both showed favourable reversible oxidation and reduction peaks, in accordance with their outstanding rate performance and resilience capabilities (Fig. 6c). In terms of the more rigorous working condition of −50 °C, the dynamics of the full cell with 6ZC dramatically decreased (Fig. 6b), while 3ZC6LC still retained a better rate performance and specific discharge capacity (Fig. 6d).
The charge-discharge curves in Fig. 6e, f further prove that 3ZC6LC has high redox reversibility and low temperature tolerance. EIS spectra were obtained to probe the chargetransfer resistance (R ct ) of the symmetric Zn/Zn batteries and full batteries at low temperatures (Fig.S19). At −30 and −50 °C, the higher slope and smaller semicircle diameter of the EIS curves of the batteries indicated a low R ct (< 10 Ω), which further demonstrated the good interfacial compatibility between 3ZC6LC and the electrode. As expected, the PANI/Zn button battery with an electrolyte having a high Cl − concentration also underwent a micro-short circuit after running at −30 °C for 30 h (3ZC6LC)/120 h (6ZC) at a low current density of 0.2 A g −1 (Fig. S20), which was similar to the results of the LiFePO 4 /Zn battery.
To verify the previous hypothesis, cycling performance tests were conducted under more severe conditions (0.5 A g −1 at −30/−50 °C), which would be essential for the practical application of low-temperature batteries. Figure 6h shows the ultralong steady cycling of the battery (0.5 A g −1 at −30 °C), exhibiting a discharge specific capacity of 132.4 mAh g −1 , a high capacity retention of > 95% and a coulombic efficiency of 100% after 1000 cycles. When the temperature was decreased to −50 °C, the capacity of the battery with 6ZC decreased rapidly in the first 30 cycles and remained 48.6 mAh g −1 after 2000 cycles. Notably, the battery based on 3ZC6LC had an obvious activation process in the initial cycles and then exhibited durable the cycling performance of a capacity of 96.5 mAh g −1 for over 2000 cycles (approximately 30 days) at 0.5 A g −1 (Fig. 6i). Even at a high mass loading of ~ 3 mg cm −2 , the PANI/Zn battery still exhibited a high rate capability and prominent cycling stability at −30 °C (capacity of 97.9 mAh g −1 and capacity retention of ~ 100% after 1000 cycles), which benefitted from the excellent ion transport of 3ZC6LC (Fig. S21). From the self-discharge curves in Fig. S22a, it could be observed that the PANI/Zn battery with 6ZC had a more significant voltage drop at the initial stage of standing. After a natural month, the batteries with 6ZC and 3ZC6LC could still maintain a stable open-circuit voltage above 1.28 V at −50 °C. Moreover, three button cells in series could successfully power LEDs and alarm clocks at −50 °C (Fig. 6g). In addition, the corresponding polarization curves (Fig. S22b) also showed no obvious irreversible fluctuation in overpotential within a month of operation at an extremely low temperature of −50 °C, confirming that the electrochemical performance of this system was preserved. Hence, all the experimental results demonstrated that the cooperative hydrated ions of 3ZC6LC resulted in a promising electrolyte solution for use in high-performance PANI/Zn batteries, allowing for their normal, long-term operation at ultralow temperatures (Table S2).

Conclusion
The low-temperature electrochemical behaviour of a series of CHEs was systematically probed in this work. The experimental analysis validates the mechanism that electrochemical windows of the CHEs widen by > 1 V, namely there are significant increases in the H-bond ratios at lower temperatures. Based on the Hofmeister effect, Li + has a stronger ability to break the H-bonds within water molecules and cellulose chains than Na + and K + ; thus, the addition of Li + results in the electrolyte having a lower viscosity at low temperatures. Thus, among the highly concentrated cooperative ZnCl 2 -LiCl, ZnCl 2 -NaCl, and ZnCl 2 -KCl systems, the cooperative 3 M ZnCl 2 + 6 M LiCl hydrogel electrolyte achieves the most sufficient σ of 1.14 mS cm −1 and lowest E a of 0.21 eV at −50 °C. Benefiting from the expanded electrochemical window and superior reaction kinetics, an assembled PANI/Zn button battery exhibits an impressive discharge capacity of 96.5 mAh g −1 at 0.5 A g −1 and ultralong cycling stability with a high-capacity retention of ~ 100% after 2000 cycles at −50 °C. This work provides new ideas and pathways for designing high-performance, low-temperature aqueous batteries by using cost-effective cooperative chloride hydrogels as electrolytes.
Funding Open access funding provided by Shanghai Jiao Tong University.
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