Atmospheric disturbance on the gas explosion in closed fire zone

In order to avoid serious safety accidents caused by closed fire zone, based on the continuous monitoring of atmospheric pressure at different monitoring points in multiple mines, the atmospheric pressure fluctuation model and the air leakage model were established and analyzed. The change law with time of oxygen concentration and gas concentration in the fire zone were obtained due to atmospheric disturbances under the influence of different pressure difference, volume and size of fire area, wind resistance, gas emission, sealing moments, etc. so as to evaluate the explosion risk of a closed fire zone. Research showed that the mine atmosphere fluctuates with the atmosphere of ground, and the pressure difference between the inner and outer sides of the enclosed fire zone is affected by the periodic fluctuation of atmosphere, which has about 16-h cosine fluctuation and approximate 8-h fixed value. Compared with the fire zone with poor sealing quality, good sealing fire zone has better resistance to atmospheric disturbance. The reduction of oxygen concentration in the inner side of a well-sealed fire zone mainly depends on the dilution of methane, which is more likely to accumulate and rise rapidly. And the fire zone with poor sealing quality is easy to be interfered. The inner oxygen concentration and gas concentration are easily affected by the absolute gas emission and the air leakage in the fire zone. Fire zone with small wind resistance and small volume is especially obvious. At the initial stage of the closed fire zone it's very possible to happen explosion. The time duration of explosion danger varies under different conditions, and the atmospheric disturbance may lead to repeated explosions in some cases. It's suggested to take some methods to avoid explosions according to the real-time situation, closure time, oxygen concentration and gas concentration of fire zone.


Introduction
The atmospheric pressure on the ground changes with season, temperature, morning and evening. Then the changes in the surface atmospheric pressure will be quickly transmitted to coal mine, causing the atmospheric pressure at various points in the coal mine to fluctuate with fluctuations. This phenomenon is called mine breathing effect. Relevant research showed that the mine breathing effect has a significant impact on the underground air pressure (Zhou 2002). Some experts and scholars have also carried out corresponding studies. According to the concept of breathing phenomenon in goaf, Li (2012a) analyzed the causes and general rules of this phenomenon, and on this basis, he proposed technical measures to prevent this phenomenon. Guo (2016) studied the relationship between atmospheric pressure changes and gas anomalies caused by changes in seasons and alternation of day and night, and adopted ventilation control of the roadway to resist the abnormal gushing of gas. Through the detection technology of tracer gas, Li (2012b) found that there is a close relationship between the breathing phenomenon in the goaf and the atmospheric pressure change on the ground, which easily causes spontaneous combustion of the remaining coal in the goaf. Zhou (2018) established an experimental platform to monitor and study the combustion state in the fire closed zone of coal mine, and inferred the danger after the fire zone was closed. Therefore, if the fluctuation of pressure that is caused by the breathing effect is not considered, or if it is not considered well, it will bring hidden dangers to safe production of the mine, which may lead to major accidents such as gas accumulation and gas explosion in the closed fire zone. It may bring hidden dangers to the closed and unsealing work of the fire zone (Zhu et al. 2008;Niu et al. 2013;Zhai and Lai 2016;Shi et al. 2017;Zhang et al. 1999). However, the different sealing sequence of fire zone of the coal mine will cause different air flow and gas accumulation in the fire zone, resulting in different hazards in the fire zone (Niu et al. 2016). So, safety issues during the closure of coal mines must be addressed through sound management measures (Adam and Alicja 2018;Arif et al. 2015). How to formulate a set of safety management measures for closed fire zones of mine based on atmospheric changes is very important according to the law of ground atmosphere change.
2 Analysis on the influence of surface atmospheric pressure on underground pressure in different locations Based on the comprehensive detector of mine ventilation parameter, the barometer method is used to measure the difference of absolute static pressure between different points in the well and the ground base point. The variation law of ground and underground atmospheric pressure obtained through monitoring around the clock can be used as an important basic parameter for closing, unsealing and determining the risk of gas explosion in the fire zone. Figure 1 showed the variation of atmospheric pressure at three measuring points. It can be seen that the atmospheric pressure changes of three monitoring points are similar, and the atmospheric pressure is obviously affected by the ground pressure, but there is a weak time difference.
Ground pressure changes happened about 30 min before the underground station, about 40 min before the fire sealing zone, and the phase difference was approximately 7.5°and 10°, respectively, while the phase difference between the enclosed fire zone and the outside is only 2.5°. In general, wave transmission is carried out from top to bottom and from near to far. Therefore, it can be approximately considered that the atmospheric pressure outside the closed fire zone changes in a cosine period with the change of the ground atmosphere, which can be expressed by the mathematical formula as follows: where, P out is the air pressure outside the enclosed zone; P average is the average pressure; t is the time; Dt is the cycle period, and DP out is the amplitude of pressure change. Based on Eq.
(1), the periodic variation law of pressure with time at three different monitoring points as shown in Fig. 2 is calculated. Comparing Fig. 1 with Fig. 2, it can be seen that Fig. 2 and Fig. 1 have a high degree of repeatability. In Fig. 2 Fig. 2 Analysis on pressure cycle changes of three different monitoring points in a mine Atmospheric disturbance on the gas explosion in closed fire zone 753 8:00 a.m. to 24:00 p.m., with a period of about 16 h, which is close to the curve from 8:00 a.m. to 24:00 p.m. in Fig. 1 in terms of trend and value. The atmospheric pressure changes between 24:00 p.m. and 8:00 a.m. is approximately a linear relationship of small fluctuations, which can be expressed as follows: P out;initial is the atmospheric pressure at the end of cosine fluctuations, and k is a constant coefficient. When the value of k is small, it can be approximated that the slope is extremely small during linear change. P out % P out;initial . All the above studies have shown that changes in ground atmospheric pressure have a great impact on underground pressure. Therefore, it is necessary to study how atmospheric pressure changes leading to the temporal and spatial changes of gas flow and components in the closed fire zone, so as to analyze the gas explosion risk in the fire zone under the corresponding state and propose corresponding measures.
3 Analysis on the influence of ground atmospheric pressure change on air leakage in the closed fire zone Although there are different degrees of air leakage in the closed fire zone of mine due to various reasons, the air leakage is generally not substantial. Therefore, it can be assumed that the air in the closed fire zone is laminar flow, and the direction of air leakage is flowing into the fire zone.
where q air leakage is the air leakage volume, P closed is the air pressure in the enclosed zone, P out is the air pressure outside the closed zone, and R is the total air resistance of air leakage passage and firewall. The change of the air pressure in the closed fire zone from the initial value P outside;initial reaches P closed after the time t is expressed as: Due to t ¼ 0, P closed ¼ P closed;initial , The above formula can be solved to get: Put Eq. (5) into the Eq. (3): where P closed;initial is the initial air pressure in the closed zone, and t is the time. From Eq. (6), it can be seen that the air leakage volume q air leakage is affected by the air pressure outside the closed zone P out , the air pressure inside the closed zone P closed , and the air leakage channel and total wind resistance R of the fire wall. The air pressure P out outside the closed zone has been analyzed and studied, which is a periodic variable. The total wind resistance R of the air leakage passage and the firewall represents the shape parameter of the air leakage passage on the closed wall. For the closed fire area of fixed research object, it can be assumed to be a fixed value. The air pressure P closed in the enclosed area is affected by both P out and R. According to Eq. (6), Dt can be inferred from measured data and empirical data. The air leakage amount q air leakage can be calculated by real-time air pressure outside the closed zone P out , by total wind resistance of the air leakage channel R, and by initial air pressure in the closed zone P closed;initial . When the outside pressure is greater than the inside, airflow leaks into the fire area from the outside of the closed fire zone. On the contrary, the airflow in the closed fire zone flows from the return air side to the outside.
It is assumed that the combustion reaction consumption, gas generation, oxygen consumption, adsorption and other comprehensive phenomena in the inner side of the fire zone will not lead to a significant change to air pressure in the fire zone. The pressure change in the fire zone is mainly caused by the external air leakage and internal gas outflow is caused by the pressure difference between the inside and outside. Therefore, it can be considered that the initial pressure inside the fire zone is the same as the pressure outside the fire area because of the moment of complete closure. However, due to many factors such as coal seam cracks and unbalanced sealing quality, it is impossible to realize the real separation between inside and outside the fire zone. There is a relationship between the pressure changes, but there is a certain phase difference. The fluctuation ranges of inside and outside are not the same (When the sealing quality is good and the wind resistance is large, the internal and external pressure difference is large; on the contrary, when the sealing quality is poor and the wind resistance is small, the internal and external linkage is obvious, and the pressure difference is small). According to the quality of closed wall in the fire zone, the values of the total wind resistance R of the air leakage channel are set as follows: 0.5, 1, 2, 3, 4, 5 9 10 4 N s/m 5 , respectively. At the same time, according to Figs. 1 and 2, as well as relevant survey data, considering the measurement error, it is assumed that the pressure difference inside the closed fire area maintains the amplitude of about 600 Pa and shows cosine fluctuation (Zhou 2002;Guo 2016;Zhou 2018). In combination with formula (6), the relation between air leakage volume and time in the period of cosine cycle variation is shown in Fig. 3. In Fig. 3, according to the actual situation, under different wind resistance settings, the gas exchange between the inner and outer side of fire zone in the changing period caused by the change of pressure difference between the inner and outer side of the closed fire zone is cosine change in the external atmospheric pressure. When the wind resistance is 0.5 9 10 4 N s/m 5 , then the maximum air leakage q max ¼ 4:8 m 3 /min, which are obtained at both ends of the cosine curve respectively. The air leakage in the middle part is small in symmetry. There was no fresh air flowing into the fire zone from 13:00 pm to 19:00 pm. The gas inside part of the fire zone flows back from the return air side to the fire zone. The better the airtightness, the larger the wind resistance. When the wind resistance is 5 9 10 4 N s/m 5 , the maximum air leakage q max ¼ 0:48 m 3 /min. In summary, the more closed the wall, the better the quality, the greater the wind resistance, the smaller the total amount of air leakage into the inner side of the fire zone. The increase of wind resistance has a significant impact on the leakage air volume.
According to Figs. 1, 2, 3 and the above analyses, the period of air leakage from the outside of the fire zone into the inside is from about 8:00 am to 13:00 pm, and from about 19:00 pm to 24:00 pm. The duration of each period is about 6 h. And an approximate linear change phase lasts about 8 h from about 24 pm to 8 am. From about 13:00 pm to 19:00 pm, since the outside atmospheric pressure is lower than the inside pressure, almost no fresh airflow enters, and the inner gas escapes from the return air side.
4 Analysis on explosion risk in the closed fire area with periodic fluctuation of air pressure Explosion in a closed fire zone must meet the necessary and sufficient conditions for the explosion, which means the oxygen concentration is above 12%, the gas concentration is between 5% and 15%, and the superposition can be generated in time and space. For this reason, it is assumed that oxygen and gas in the closed fire zone are in the same space at every moment. This paper starts with the change trend of oxygen concentration and gas concentration in the closed space with time. Analyses and calculations in this paper are made by establishing a mathematical model. This paper also analyzes the size and coincidence degree of knife and fork of the two in time, so as to determine the gas explosion risk in the closed fire zone. Before solving, it is assumed that all kinds of gases in the air of closed fire zone have been uniformly mixed and there is no chemical reaction, gas adsorption and absorption phenomena. The change in concentration of each gas component in the air of enclosed fire zone can be expressed as follows: where C is the concentration of an air component in the closed zone, q i is the component flow into a confined fire area affected by real-time air leakage volume), and q e is the mixed gas flow out of the closed fire zone. Assuming that the boundary condition is t ¼ 0, C ¼ C 0 , the above differential equation can be solved: The oxygen concentration in the fire zone will reduce by dilution of other gases or oxidation reaction, adsorption and absorption consumption, which of these two types of influences dominate the type of mine fire, after the reduction of the supply of wind, the fire zone spreads and the flow of gas dilutes the air in the fire zone. For small fires in the coal mine with small fire belt (quantity) and large air volume, dilution has a greater impact on the air oxygen concentration than oxygen consumption. Comparing the data of oxygen consumption with that of dilution and consumption, it is found that the influence of oxygen consumption on oxygen concentration can be ignored in most fires with small ignition belts and large air volume (Zhou 2002). Therefore, if only the influences of the double dilution effect of the gas emission from the fire zone and the atmosphere pressure outside the fire zone on the methane and oxygen concentration are considered, then, q i ¼ q a C a can be put into Eq. (7) to get: q a is the air flow into the fire zone (different values in different situations), and C a is the oxygen concentration in q a that is 21%. According to the boundary conditions t ¼ 0, C ¼ C a0 , and the equation is solved, then the corresponding methane and oxygen concentration at a certain time t after the fire zone is closed can be expressed as follows: If the sealing quality is good and there are no cracks in the fire zone, then no air can penetrate the fire zone.q a ¼ 0, the methane and oxygen concentration C ¼ C a0 exp Àt q e v À Á . Relevant parameters should be set before calculating the methane and oxygen concentration inside the enclosed fire zone. Combined with the actual situation, it is assumed that C a0 ¼ 0:5% (initial gas concentration when calculating gas concentration), C a0 ¼ 21% (initial oxygen concentration when calculating oxygen concentration), C a ¼ 21%, q e ¼ q CH 4 þ q a . q a is calculated based on Eq. (6), and q CH 4 is the absolute gas emission. 10 m 3 /min and 1 m 3 /min are adopted respectively according to high and low gas mines.

Analysis on the influence of air pressure fluctuation on oxygen concentration in the closed fire zone
According to Eq. (10), the oxygen concentration inside the fire zone can be calculated at different times with different volume sizes under the circumstance of closed fire zone (in this paper, taking V = 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 , respectively). According to Figs. 1, 2 and 3, 13:00 pm, 19:00 pm and 24:00 pm are selected as the closed time for analysis (Zhou 2002;Deng et al. 2004;Zhou et al. 2013Zhou et al. , 2015Wang et al. 2014;Jiao et al. 2012;Duan et al. 2010;Deng et al. 2004;Wang et al. 2003). Figure 4 shows the change of oxygen concentration in the fire zone from 24:00 at midnight to 13:00 pm of next day. In this interval, as the pressure difference outside the closed fire zone gradually decreases, the air leakage decreases. It can be seen from Fig. 4a that when the absolute gas emission amount in the fire zone is large, the oxygen concentration in the closed fire region with a relatively small volume rapidly decreases, and the larger fire zone decreases slowly. Among them, 500 m 3 fire zone needs about 33 min, 1000 m 3 fire zone needs about 65 min, 2000 m 3 fire zone needs about 130 min, 5000 m 3 fire zone needs about 240 min, 10,000 m 3 fire zone needs about 380 min, 50,000 m 3 fire zone needs about 680 min to reduce the oxygen concentration in the fire zone to the relatively safe limit of 12%. Except in the case of 50,000 m 3 , the oxygen concentration in the rest volume of the fire zone will decrease to nearly 0. Except the 50,000 m 3 super large fire zone, the oxygen concentration in the fire zone can be reduced to 2% in all other cases within about 12 h.
It can be seen from Fig. 4b that when the absolute gas emission amount in the fire zone is small, the change trend of the oxygen concentration inside the fire zone is similar to the case where the absolute gas emission amount is large. However, it has been estimated that in all cases, the oxygen concentration in the fire zone cannot reduce to less than 12% in a short period of time. If it considers the oxidation and oxygen consumption of the fire zone, it will take more than 360 min or even more to reduce the oxygen concentration in the fire zone to a safe limit. For safety reasons, inert gas injection is recommended. Figure 5 is the change of oxygen concentration inside the fire zone from the assumption that the fire zone is completely closed from 19:00 pm to 8:00 am of next day. In this zone, with the passage of time, the pressure difference between the inside and outside of the closed fire zone gradually increased, and the air leakage gradually increased. As seen from Fig. 5a, when the absolute gas emission in the fire zone is large, the oxygen concentration in the relatively small closed fire zone decreases rapidly, while that in the large fire area decreases slowly 500 m 3 fire zone needs about 25 min, 1000 m 3 fire zone needs about 55 min, 2000 m 3 fire area needs about 100 min, 5000 m 3 fire zone needs about 230 min, 10,000 m 3 fire zone needs about 350 min to reduce the oxygen concentration. In the 50,000 m 3 fire zone, it takes about 660 min to reduce the oxygen concentration in the fire zone to the relatively safe limit of 12%. In all cases, the oxygen concentration in the fire zone cannot reduce to less than 2%.
It can be seen from Fig. 5b that when the absolute gas emission amount in the fire zone is small, the change trend of the oxygen concentration inside the fire zone is similar to the case where the absolute gas emission amount is large, and the difference is that the required time is different. Moreover, the oxygen concentration in all cases in the figure cannot reduce to less than 12%. If the oxygen concentration in the fire zone reduces to a safe limit in a short time, it is estimated that the volume of the fire zone is less than 200 m 3 to satisfy the condition. In the actual conditions, the fire zone is relatively large. Because of the oxidation relationship, there are generally different degrees of oxygen consumption. Therefore, for the 500 m 3 situation in Fig. 8b, it is possible to drop oxygen concentration to less than 12% in about 180 min, and it is possible for 1000 m 3 situation to drop oxygen concentration to 12% in 360 min. It is possible for the situation of below 2000 m 3 to drop oxygen concentration to below 12% after 480 min, and the rest of the larger fire zone will take more than 600 min to realize it. But for the 50,000 m 3 fire zone, it's impossible to realize it. The situation shown in Fig. 8b is only effective in small fire zone. If the oxygen concentration inside the fire zone is completely lower than 12%, the safeguard measure is usually to inject inert gas into the fire zone. Figure 6 showed the change of oxygen concentration inside the fire zone from the time that the fire zone was completely closed, which is 13:00 to 8:00 of next morning. As it can be seen from Fig. 6a, when the absolute amount of gas gushing out of the fire zone is very large, the oxygen concentration trend in the 50,000 m 3 super-large fire zone always reduces to a certain level and maintains stable, and the oxygen concentration trend in other types of fire zones first decreases and then recovers to a certain level and maintains stable. It only took 28 min for oxygen concentration of 500 m 3 fire zone reducing to 12%. The capacity of oxygen concentration diluted to 0% in 180 min. As for 1000 m 3 fire zone, it took about 55 min reducing to 12%, and the capacity of oxygen concentration completely diluted in 360 min. Likewise, it took about 110 min for 2000 m 3 fire zone needs reducing to 12%, and 420 min for complete dilution. It took about 220 min for 5000 m 3 fire zone reducing to 12%, and 540 min for dilution to 2.4%. It took about 320 min for 10,000 m 3 fire zone reducing to 12%, and 600 min for dilution to 4.7%. Finally, the oxygen concentration inside the above-mentioned several types of fire zone will temporarily stabilize at around 6.8%. The oxygen concentration in the oversized fire zone of 50,000 m 3 needs to reduce to about 12% within 680 min, and temporarily stabilized at about 7.9%. The oxygen concentration in the smaller fire zone can reduce to less than 2% between 3 and 6 h. It can be seen from Fig. 6b that when the absolute gas emission in the fire zone is very small, the oxygen concentration change inside the fire zone first decreases to lower than 12%, and then quickly rises to higher than 12%, which both have experienced two dangerous areas. The oxygen concentration of 500 m 3 in the fire zone dropped to 12% about within 220 min, and then it dropped as low as 3.7%. After about 6 h, it returned to higher than 12% again and temporarily stabilized around 17.4%. The oxygen concentration in the 1000 m 3 fire zone decreased to 12% about within 320 min, and thereafter it was as low as 4.2%. After about 4 h, it returned to higher than 12% again and temporarily stabilized at around 17.4%. The oxygen concentration in the 2000 m 3 fire zone decreased to 12% about within 560 min, and then decreased to the lowest 4.4%. After about 1.5 h, it returned to higher than 12% again and temporarily stabilized at around 17.4%. The oxygen concentration in the 5000 m 3 fire zone decreased to 12% about within 570 min, and thereafter it decreased to as low as 6.8%. After about 1 h, it returned to higher than 12% again and temporarily stabilized at around 17.4%. The oxygen concentration in the 10,000 m 3 fire zone decreased to 12% about within 580 min, and then decreased to the lowest 10.8%. After about 1 h, it returned to higher than 12% again and temporarily stabilized at around 17.4%. The oxygen concentration in the 50,000 m 3 fire zone temporarily stabilized after it reduced to 17.7%.
In the same way, three different moments were taken to study the change law of oxygen concentration in the initial stage of fire zone closure under the condition of wind resistance is 5 9 10 4 N s/m 5 , as shown in Figs. 7,8,9. Comparative analysis brings the following three conclusions: (1) For the same sealing effect (the same as the wind resistance), the oxygen concentration in the fire zone with a large amount of gas emission has better resistance to external atmospheric disturbance than that with a small amount of gas emission. The fluctuation range is smaller, and the oxygen concentration in the fire zone reduced to a lower range more quickly.
(2) For the outer closed case at the same time, the oxygen concentration in the fire zone with a large amount of gas emission is stronger and more stable than that in the fire zone with a small amount of gas emission, and the value is more stable. When the amount of gas emission in the fire zone is small, the external atmosphere has a strong interference to the oxygen concentration in the fire zone, which is likely to cause a repeated over-limit of 12% of the oxygen concentration in the fire zone. When the gas emission in the fire area is large, although it is also subject to fluctuations in the external atmosphere, the fluctuation range is relatively small, and there is basically no possibility of repeating again to higher than 12%. This is especially true for the completion of closure at 13:00. (3) For the same gas emission amount, the oxygen concentration in the fire zone reduced to a lower value in the case of greater wind resistance than that in the case of smaller wind resistance, and the rebound amplitude was small. Oxygen volume concentration in closed fire zone/% 500m 3 1000m 3 2000m 3 5000m 3 10000m 3 50000m 3 Fig. 6 The relationship between the gas emissions in different fire zone, the volume of different fire zone, and the small wind resistance is presented. The oxygen concentration in the fire zone changes with time after the completion of closure at 13:00 4.2 Analysis on the influence of pressure fluctuation on gas concentration in the closed fire zone Figure 10 showed the changes of gas concentration inside the fire zone for a period of time after the fire zone is completely closed from 24 o'clock in the middle of the night. It can be seen from Fig. 10a that when the absolute gas emission amount in the fire zone is large, the gas concentration in the closed fire zone with relatively small volume rises rapidly, and the larger fire zone rises relatively slowly. 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 fire zones reach the lower limit of 5% explosion time about in 2.5, 5, 10, 25, 45, 180 min, respectively. The time to reach the maximum explosion concentration of 15% was about 8, 16, 32, 80, 110 and 580 min, respectively. The duration of explosion risk concentration was about 5.5, 11, 22, 55, 65 and 400 min, respectively. In Fig. 10b, 500, 1000, 2000, 5000, 10,000, and 50,000 m 3 fire zones reach the lower limit of 5% explosion time was about in 30, 55, 100, 210, 480, 720 min, respectively. The time to reach the maximum explosion concentration of 15% was about 120, 280, 560, 630, 700, 1440 min, respectively. The duration of explosion risk concentration was about 90, 225, 450, 420, 320, and 720 min, respectively. It can be seen that the smaller the volume of the closed fire zone is, the earlier the concentration limit of gas explosion will reach, but the duration is relatively short. In Atmospheric disturbance on the gas explosion in closed fire zone 759 the fire zone with a large amount of gas emission, the gas concentration rises much faster than that in the fire area with a small amount of gas emission. The time to reach the explosion limit is shorter, the lasting time of explosion is shorter, and the danger is relatively smaller. Figure 11 is the change of gas concentration in the fire zone within a period of time after the complete closure of the fire zone was assumed from 19:00. It can be seen from Fig. 11a, 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 fire zones reach the lower limit of 5% explosion time about in 2. 5, 4.5, 9.5, 23, 45, 140 min, respectively. The time to reach the maximum explosion concentration of 15% was about 7.5, 15.5, 31.5, 78.5, 100, and 280 min, respectively. The duration of explosion risk concentration was about 5, 11, 22, 55, 55, 140 min, respectively. In Fig. 11b, 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 fire zones reach the lower limit of 5% explosion time about in 23, 48, 95, 130, 210, 870 min, respectively. The time to reach the maximum explosion concentration of 15% was about 80,115,200,660,920, and 1520 min, respectively. The duration of explosion risk concentration was about 57, 67, 105, 450, 710, 650 min, respectively. After about 30 h, the concentration of all types fluctuates again to 17%-18%. In case of damage caused by poor quality of airtight wall or other reasons, the leakage of fresh air may cause to reach the upper limit of explosion. Figure 12 showed the variation of gas concentration inside the fire zone for a period of time after the fire zone is Methane volume concentration in the enclosed fire zone/% 500m 3 1000m 3 2000m 3 5000m 3 10000m 3 50000m 3 Fig. 10 The changes of different gas emission, different fire zone volume, and small wind resistance, the gas concentration in the fire zone with time after the completion of closing at 24:00 midnight completely closed at 13:00. It can be seen from the Fig. 12, 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 fire zones reach the lower limit of 5% explosion time about 2.5, 4.5, 9.5, 23, 45, 180 min, respectively. The time to reach the maximum explosion concentration of 15% was about 8, 16, 31.5, 78.5, 150, and 390 min, respectively. The duration of explosion risk concentration was about 5.5, 11.5, 22, 55.5, 105, 210 min, respectively. In the Fig. 12b, 500, 1000, 2000, 5000, 10,000 and 50,000 m 3 , respectively, fire zones reach the lower limit of 5% explosion time about at 25, 50, 100, 190, 280, 430 min, respectively. The time to reach the maximum explosion concentration of 15% was about 82, 110, 260, 390, 440, and 450 min, respectively. The duration of explosion risk concentration was about 57, 60, 160, 200, 160, 20 min, respectively. Similarly, three different moments were taken to study the variation law of gas concentration in the initial stage of fire closure under the circumstance of 5 9 10 4 N s/m 5 fire zone wind resistance, as shown in Figs. 13, 14 and 15. Through comparative analysis, it can be seen that the fire zone with good sealing quality (large wind resistance) has better resistance to disturbance of atmospheric pressure fluctuation than the fire zone with poor sealing quality (small wind resistance). The fluctuation range is relatively small (within 30%), and all of them are in non-explosive Methane volume concentration in the enclosed fire zone/% 500m 3 1000m 3 2000m 3 5000m 3 10000m 3 50000m 3 Fig. 12 The gas concentration in different fire zones, the volume of different fire zones, and the small wind resistance. The changes of gas concentration in the fire zone with time after the completion of sealing at 13:00 Atmospheric disturbance on the gas explosion in closed fire zone 761 area. The rise of gas concentration in the inner side of wellsealed fire area mainly depends on the agglomeration of gas gushing out. The gas concentration in a small volume fire area will rapidly rise to the explosion limit range, quickly pass through and reach the non-explosive area, while the gas concentration in a large volume fire area will reach the explosion range after a long period of time, and maintain for a long time. The gas concentration in a small volume fire zone will rapidly rise to the explosion limit range, quickly pass through and reach the non-explosive area, while the gas concentration in a large volume fire zone will reach the explosion range after a long period of time, and maintain for a long time. Comparatively speaking, the rising rate of gas concentration in the fire zone with a large amount of gas emission is much faster than that in the fire zone with a small amount of gas emission. The explosion limit is satisfied earlier, the explosion time period is shorter, and the danger is relatively smaller.
4.3 Analysis on the influence of pressure fluctuation on gas explosion risk in the closed fire zone As it can be seen from Figs. 4, 5 and 6, in the initial stage of sealing, when the sealing quality of the closed wall is good and the absolute gas emission is high, the oxygen concentration will rapidly decrease to lower than 12%, although there is a rebound without exceeding the limit. When the absolute gas emission was low, the oxygen concentration rebounded to higher than 12%. For the poor sealing quality of the closed wall, no matter the absolute gas emission quantity is high or low, the oxygen concentration is higher than 12%. The gas and oxygen concentration were analyzed with the cross analysis method at three different closed time points, as shown in Fig. 16. Figure 16 is a cross analysis diagram of oxygen concentration and gas concentration according to the above analyses, with the maximum and minimum values respectively, representing the two extremes of the analysis type, and the rest are right in somewhere of the middle. It can be seen from the figure that the explosion risk interval corresponding to the case where the wind resistance represented by Fig. 16a is small, the absolute amount of gas emission is large, and the wind resistance represented by Fig. 16c is large and the absolute gas emission amount is relatively small. The duration of the gas explosion in the closed fire zone is less affected by atmospheric fluctuations in the several minutes to 2 or 3 h. The situations of small wind resistance and small absolute gas emission represented in Fig. 16b and the situations of large wind resistance and small absolute gas emission represented in Fig. 16d corresponded to relatively large gas explosion risk interval, which lasted for more than 10 h and was relatively affected by atmospheric fluctuations. Among them, the situation in Fig. 16b is particularly affected by fluctuations, mainly because the gas concentration will be affected by atmospheric fluctuations in the period of 17%-8%, and the upper limit of the gas explosion is very close. If the external conditions are abrupt, it is highly probable that there is an explosion in an instant. Zhou (2002) suggested that after the fire zone is closed, the internal oxygen concentration will gradually decrease and the gas concentration will gradually increase. After a certain period of time, these two will form an area with explosive risk inside the fire area. The difference from the research results is that the size of the enclosed fire zone and the quality of the closed fire zone are different. The time required to reach the explosion area is longer and the duration of the explosion is different. The studies of Niu et al. (2016) showed that different sealing sequences have a certain effect on the gas concentration inside the fire zone. It also creates explosive danger areas inside the fire zone. Zhai and Lai (2016) studied that after the fire area is closed, there is indeed a danger zone leading to explosion. What is different from the research results is that the rise and fall rate of gas and oxygen concentration are much faster, which means the conditions for gas explosion appear much earlier. However, its potential explosion duration is relatively short. At the same time, on-site verification has been carried out in this paper in combination with engineering projects. The engineering background are two mines. The first one is a mine which the air pressure was measured in Fig. 1. The absolute gas emission of this mine is 12.8 m 3 /min, and volume of fire zone is about 2500 m 3 , and the completion of sealing at about 24:00. The oxygen concentration of fire zone was measured about 40 h after sealing completed.

Analysis and verification
The results shows that the oxygen concentration fluctuates between 3% and 7%, it's very close to our researches.
The other one is a mine of a large coal industry group in northern China with an approved production capacity of 1.5 million tons/year. The absolute outflow of the mine is 103.8 m 3 /min, and the relative gushing amount is 21.9 m 3 / t. The mine has a high gas capacity. Rectangular section is adopted in the roadway of this mine, with a net width of 5.0 m, a net height of 3.6 m, and a length of about 715 m. The mining face volume is 12,870 m 3 , including the goaf volume. The fire area volume is larger than goaf volume, which belongs to the situation of the large fire zone. After the coal seam is self-ignited, the relevant technical department uses polyurethane foaming materials to seal the fire zone and close the fire zone at 12:00 on a certain day. After the completion of the sealing, the original monitoring sensor, beam tube and other means were used for gas sampling and chromatographic analysis of different positions inside the fire zone. The results showed that the polyurethane sealing quality is good, and the air leakage in the fire zone is very small, which can be regarded as the case of high wind resistance. After on-site observation, about 8 h after the closure was implemented, a gas explosion occurred in the closed fire zone. This showed that after 8 h, the oxygen concentration and gas concentration inside the fire zone meet the necessary and sufficient conditions for the explosion. There is a high temperature area, which in turn causes a gas explosion. As it belongs to the large fire zone and closed at noon, it can be seen from the comparison of gas concentration 1 and oxygen concentration 1 in Fig. 16c that the oxygen concentration is higher than 12% and the gas concentration is between 5% and 15% in the 8 h interval after the closed zone is completed. There is a complete possibility of explosion. This indirectly proves the field value of the research results. Therefore, the closed time, the closed quality, etc. are critical to the steady state after the fire zone is closed.
All the above research results showed that the research results in this paper are similar with the results mentioned above to a certain extent, and have been verified by engineering projects, which have important guiding significance for the safe implementation of closed operation in coal mine fire zone.

Conclusion
(1) The fluctuations in the atmospheric pressure of the mine, the quality of the closed wall in the fire zone, and the amount of gas in the fire zone have an important influence on the gas concentration and oxygen concentration inside the closed fire zone.
(2) Compared with the fire zone with poor airtight quality (high wind resistance), the fire zone with good airtight quality (low wind resistance) has better resistance to the disturbance of atmospheric pressure fluctuation with relatively small fluctuation range and is located in the non-explosive area. The increase of gas concentration and the decrease of oxygen concentration, inside of the closed fire zone with good quality, mainly depend on the accumulation of gas emission. (3) The gas concentration inside the fire zone with poor airtight quality (small wind resistance) is easy to be disturbed by the external atmosphere, and the relative fluctuation is large. There are situations in which the conditions of the explosion are repeatedly reached or approached. (4) The completion time of the fire zone closure has an important influence on the variation law and fluctuation of the inner gas concentration after the fire zone is closed. Especially, attention should be paid to the fire zone with poor airtight quality. (5) The research results of this paper are highly similar with the results of relevant scholars according to the comparison. After the site verification, it showed that there is a good field practical value, which can effectively guide the safe development of closure work in the coal mine fire area. ck2017zkyb001) and Open Cooperative Innovation Fund of Xi'an Institute of Modern Chemistry (No. 204-J-2019-0387). Thanks.
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