Physico-chemical and elemental investigation of aqueous leaching of high sulfur coal and mine overburden from Ledo coalfield of Northeast India

Acid mine drainage (AMD) is one of the major problems in high sulfur coal mining areas generating acidic water. The acidic mine water generated contain hazardous elements in varying concentrations. The Northeastern Indian coalfield produces considerable amounts of AMD. The AMD and metal leaching from coal and mine over burden (OB) are the two important naturally occurring processes. In order to know the AMD potential, the aqueous leaching experiment of a few coal and OB samples from the Ledo colliery of the Northeastern coalfield, Mergherita (India), at different time periods (1, 3, 5, and 8 h) and at different temperatures (25, 45, 65, and 90 °C) were performed in the laboratory. The physico-chemical analysis of the aqueous leachates shows the pH, electrical conductivity (EC), and total dissolved solid (TDS) in the range of 1.62–3.52, 106–2006 µs/cm, and 106–1003 ppm for the raw coal samples respectively. The OB samples produced pH, EC, and TDS in the range of 3.68–6.92, 48.6–480 µs/cm, and 69.5–240 ppm respectively. From the study, it was revealed that the concentrations of major (Si, Al, K, Na, Fe, Ca, Mg), minor (Mn) and trace/hazardous elements (As, Ba, Cd, Co, Cr, Cu, Hg, Ni, Pb, Se, Zn) considerably change with leaching time as well as with leaching temperature. Out of these elements As, Cd, Hg, Pb, Cr, and Se are of greater environmental importance. Alteration of the physico-chemical structure of the coal and OB samples resulting from leaching was also studied by field emission scanning electron microscope- energy-dispersive X-ray spectroscopy method. The release of the potentially hazardous elements from the raw coal and OB during leaching time periods to the leachates was detected by inductively coupled plasma-atomic emission spectroscopy and ion-chromatographic analyses. The major minerals found in coal and OB are quartz (SiO2), pyrite (FeS2), hematite, marcasite, and kaolinite. The association of different functional groups in minerals and their mode of association were studied by Fourier-transform infrared spectroscopy and X-ray diffraction analytical techniques. The present laboratory study will be useful in relating the characteristics of aqueous leaching from coal and mine OB with the natural weathering condition at the coal mine area.


Introduction
Coal is a heterogeneous mixture of different organic and inorganic materials. Majority of inorganic materials are occurred in mineral forms. The minerals present in coal consist of several metals and nonmetals especially Si, S, Ca, Mg, Fe, Al etc. (Tomeczec and Palugniok 2002;Mukherjee and Borthakur 2003). The common minerals found in coal and associated mine rejects (OB) are quartz (SiO 2 ), pyrite (FeS 2 ), hematite, marcasite, and kaolinite. Coal is composed of different elements, metals, and nonmetals as a long biological and physical alteration process taken place during the formation of the coal (Swine 1990;Singh and Singh 1995). Before mining these elements are in an immobile state, but during and after mining they have a tendency to disperse into the surrounding areas (Equeenuddin 2015).
Most of these elements are found in trace amount which are toxic in nature beyond their threshold limit. Trace elements are those whose concentrations are lower than 0.1% in the coal (Swaine 2000;Singh et al. 2012a). The study of these trace elements is very important due to their complex changes, inability to decompose in natural processes like weathering and high toxicity to the environment followed by their release and dispersal to the atmosphere, soil and water through the pathways of leaching and weathering (Zhou et al. 2014;Querol et al. 2008;Dai et al. 2005;Chen et al. 2013). Leaching is one of the primary pathways for trace elements to enter into the ecosystem (Yang et al. 2016, Baruah et al. 2004). Swaine (2000) proposed the possibility of the presence of twenty six trace elements in coal that have potential environmental impacts, including As, Cr, Cd, Hg, Pb, Se, B, Mn, Ni, Cu, V, Zn, Co, Sn, Cl, F, Br, Mo, P, Th, U, Ba, Ra, Sb and Tl. Out of these elements As, Cd, Hg, Pb, Cr and Se are of greater environmental importance (Swaine 2000;Prachiti et al. 2011;Singh et al. 2015a, b). Most of the Se in coal is associated with organic constituents; however, some of the Se is also associated with the sulfide minerals of coal, mainly pyrite (Swaine 1990). In coal, Cd is predominantly associated with Sphalerite (ZnS) (Alper et al. 2008). Lead (Pb) occurs in coal mainly as the sulfide mineral galena (PbS) which is the most common form of lead in coal (Finkelman 1994;Swaine 1990). These trace elements present in coal and its mine rejects/overburden enter into the environment through different processes including leaching of coal and oxidation of pyrite (Equeenuddin 2015). Coal dumps are also an important factor in the environmental degradation because the potentially toxic elements are directly released to the environment through the leaching and oxidation of pyrite. To understand the release of potential hazardous elements (PHE's) from coal and coal mine rejects in potential environmental and ecological conditions, the leaching behavior of coal and mine rejects in open cast coal mining is important. During the coal mining activities, the pyrite present in coal is exposed and comes into contact with the atmospheric oxygen, moisture or rain water. This weathering process leads to the generation of AMD. AMD generation and metal leaching processes from coal and mine OB are natural processes. These processes are accelerated by intensification of mining operations (Banerjee 2014). Such mining activities have a detrimental effect on the local environment as well as on the ecology (Kimmel 1983;Johnson 1987;Kaeser and Sharpe 2001).
Due to the formation of sulfuric acid by exposing pyrite to atmospheric oxygen and water, acid mine drainage is generated in coal mining areas. The metals in coal and coal wastes, which are minerals associated with the inorganic part of the coal structure are easily dissolved in highly acidic AMD. Thus, the AMD (pH 2.0-3.0) (Baruah et al. 2006;Dowarah et al. 2009) has a strong leaching potential for releasing a large number of potentially PHE's into the aquatic environment. In addition to the AMD formation, under different atmospheric conditions, pyrite (FeS 2 ) in coal is often found in association with the hazardous elements such as As, Cd, Cu, Co, Pb, Hg, and Zn (Monterroso and Macias 1998;Singh et al. 2016). The formation of elemental sulfur takes place during depyritization of coal by leaching of coal wastes (Schippers et al. 1996). The leachates generated from OB dumps are rich in heavy metals, especially Fe, Cu, Mn and Ni (Tiwari 2001). The leaching property of different elements depends on several factors like specific element solubility and availability or release potential (Moyo et al. 2012). Also the other factors that enhance the metal leaching include swiftly weathering metal containing minerals and the mine drainage conditions that can increase the solubility and flow rates through the contaminated minerals (Banerjee 2014).
The sulfur present in Northeastern (NER) Indian coal is mainly in three forms-sulfate sulfur, pyritic sulfur, and organic sulfur (Baruah and Gogoi 1998). The major part of the inorganic sulfur present in coal is in pyrite (FeS 2 ). The Northeastern Indian coals are rich in sulfur (2%-11%) (Chabukdhara and Singh 2016;Singh et al. 2012bSingh et al. , 2013. The sulfate formed from pyritic sulfur in coal by atmospheric oxygen is not only responsible factor for AMD generation but the oxidation of Fe(II) ion to Fe(III) ion during the process of weathering of pyrite can produce a noticeable amount of AMD (Baruah et al. 2006). Equeenuddin (2015) reported that coal dumps cause environmental degradation due to the release of potentially hazardous elements through the process of leaching of pyrite. The amount of impact of waste and coal containing contaminants in a form of toxic elements on the environment depend not only on the type and concentrations of these elements, but mainly on their mobility. The mobility of pollutants contained in the waste is expressed as the potentiality of them to leach in water (Kalembkiewicz and Palczak 2015). Leaching methods are classified into two types depending upon whether the leaching liquid is added at a single instance (static) or it is renewed (dynamic) (Moyo et al. 2011). The potential to produce acidity of drainage from mine water and mine wastes can be predicted by both geochemical methods in static and kinetic leaching processes (Ferguson and Erickson 1998). The static methods are further classified into two classes, batch leaching where a specific amount of sample is placed in a given amount of leachant solution (US DOE 2005;Hesbach et al. 2005;Kim et al. 2003) and column leaching.
Thus, the quality of surface and ground water in the streams, drains, well, contaminated with AMD water and leachates of coal and overburden was also analyzed to study the possible impact of coal mining on the nearby water resources. During leaching, the elements present in coal and OB dissolve or undergo some chemical and physical reactions and as a result they transfer into the leaching solution (Fotoupoulou et al. 2010;Wang et al. 1999). In the present work, the static aqueous leaching experiments are mainly carried out to evaluate the potential of release of selected metals. The aqueous leaching experiments of different coal and overburden samples, from the Ledo colliery are carried out and the results are also compared with those of field data.

Study area
The Makum coalfield is the largest coalfield among all the coalfields of the Northeastern region (NER) of India. The coalfield is located in the Tinsukia district of Assam and includes five working collieries namely Ledo, Baragolai, Tirap, Tikak, and Tipong. Among them, Ledo is the most recent and active colliery where open cast mining activities are operational. The mining area in Ledo-Margherita range is located within 27°15 0 -27°25 0 N latitudes and 95°40 0 -95°50 0 E longitudes which includes the probable mine affected area. In this study, the nearby areas influenced by the Ledo open cast mining activities have also been chosen. The chosen area extends from Ledo mining area to the Tirap mining area including the Tirap River, Ledopani River, and Kachanalla River. The areas near the Kachanalla and Tirap rivers are large agricultural areas with a tea garden, rural habitation area, and a colony of mining workers. A number of streams and ponds are also found which come across the mine area. The major sources for drinking water for the people of these areas are tube-wells and dig-wells. A location map of the study areas is shown in the Fig. 1. 100 g of each finely ground sample was mixed with distilled water (300 ml) for 1, 3, 5, and 8 h at 25, 45, 65, and 90°C respectively. Then the mixture was mechanically stirred in an electronic shaker (VELP, Scintifica JLT6) for the time periods 1, 3, 5, and 8 h at a stirring rate of 250 rpm. The supernatant liquid was filtered from the solid phase with a Whatmann-1 filter paper. The filtrate was collected and used for different physical, chemical, and elemental analyses. The residues of the leached samples were also subjected to selected chemical analyses as mentioned in later part.

Physico-chemical analysis of aqueous leachates
The aqueous leachates of the coal and overburden (OB) samples obtained were subjected to pH, TDS (total Physico-chemical and elemental investigation of aqueous leaching of high sulfur coal… 267 dissolved solid), and EC (electrical conductivity) analysis by using a EUTECH PC700 pH/EC/TDS meter.

Ion-chromatographic analysis
Ion-chromatographic (IC) analysis of the aqueous leachates of coal and overburden samples at different time and temperatures were subjected to IC analysis to determine the concentrations of different cations and anions (in ppm) by using an ion chromatography system-Metrohm 882 Compact IC Plus using standards purchased from Merck and Sigma Aldrich. Before analysis, the liquid samples were filtered through 0.22 lm Millipore filter paper. The anions were analyzed using 4 mm 9 250 mm Metrosep A Supp 5 analytical column with the chemical suppression sulfuric acid and Metrosep RP2 3.5 guard column. Similarly, the cations were analyzed using a 4 mm 9 150 mm Metrosep C-4 analytical column and Metrosep RP2 3.5 guard column.

Inductively coupled plasma optical emission spectrometry (ICP-OES) and atomic absorption spectrometry (AAS)
The trace elements were determined by using an inductively coupled plasma optical emission spectrometry (ICP-OES). In this process 0.2 g from reference material for digestion was used. Wet digestion of samples was performed using 5 ml mixtures of acids: HNO 3 :HClO 4 (3:1). Each sample was heated up to 180°C for 3.0 h (sample should be transparent) on the heating digestion block. Then the acid digest sample was allowed to cool and filtered into a 25 mL volumetric flask, using Whatmann filter paper and made up to mark with de-ionised water. The blank digests sample was similarly processed. The digested samples were followed by ICP-OES, (Perkin Elmer, Optima 5300 V).Calibration curves for elements were created from mixtures of high-purity element standard solutions (Merck, Germany) in a 4% (v/v) HNO 3 matrix. Atomic absorption spectrometry (AAS), flame atomic absorption spectrometry (FAAS), and graphite furnace atomic absorption spectrometry (GFAAS) analytical methods were used to detect different elements. GAAS is based on the same principles as FAAS with the main difference in the atomization of the samples. Instead of the flame in FAAS, the GFAAS uses an electro thermal atomizer (a small graphite tube). The samples were prepared for both analyses by digesting the samples with HNO 3 -H 2 O 2 in a ratio of 4:1 using microwave assisted acid digestion process. For FAAS analytical method, different standard solutions were used like Fe [(p/n 8003-0906), Zn (p/n 8003-0942)], Cu (p/n 5190-8280). In GFAAS analytical method, stock standard solutions are prepared from analytical reagent grade high purity metals, oxides, or nonhygroscopic salts using reagent water and redistilled HNO 3 or HCl.

X-ray diffraction analysis
X-ray diffraction analysis (XRD) of the samples were carried out in an X-ray diffractometer, model JDXII PZA, JEOL, Japan, using Cu Ka Fe-filtered X-ray radiation (k = 1.5426 Å ) to study the presence of different minerals in the leached samples. Operating parameters were as follows: start angle: 5.0, target: Cu (Fe-filtered), stop angle: 80.0, measuring time: 0.5 and step angle: 0.03, data processing conditions included: smoothing points, Goniometer radius (R): 240 mm, equatorial angle subtended at the specimen by the detector slit (b): 1°.

Fourier transform infrared spectroscopy analysis
The Fourier transform infrared spectroscopy (FTIR) analyses of the leached samples were done by using Perkin-Elmer system 2000, model 640B with KBr pellet. The detector used was deuterated triglycine sulphate (DTGS). The total number of scans was 50 with the spectral resolution of 4 cm -1 during the recording of the spectra. The samples were subjected to FTIR analyses to determine the presence of different functional groups, including sulfur containing groups.

Field emission-scanning electron microscopic analysis
Field emission-scanning electron microscopy (FESEM) provides elemental information at magnifications of 109-300,0009 with virtually unlimited depth of field. Compared with convention scanning electron microscopy (SEM), field emission SEM provides clearer, less electrostatically distorted images with spatial resolution down to 11/2 nm-three to six times better. Field emission scanning electron microscopy (FESEM) images were obtained from a Carl Zeiss Sigma FESEM instrument. Energy dispersive X-ray spectroscopy (EDS) pattern and elemental mapping analysis was recorded on Oxford X Max 20 equipment.

Physico-chemical characteristics of aqueous leachates
The physico-chemical parameters including pH, EC, and TDS were determined for the aqueous leachates obtained at increasing time intervals and temperatures. Table 1 shows that the pH values of the leachates of the samples decreased gradually from 1 h of leaching to 5 h of leaching time at room temperature. The pH of the leachates however increased slightly at 8 h of leaching time. The leaching at 45°C for 1, 3, 5 and 8 h respectively demonstrate a gradual increase in pH values. The electrical conductivity (EC) of the aqueous leachates of the samples at room temperature (25°C) gradually increased from 1 to 8 h of leaching. Similarly, the TDS values were found to increase gradually with increase in time period of leaching and with increase in leaching temperature (from room temperature to 45°C). Various physico-chemical properties of the aqueous leachates of coal and OB samples are given subsequently. The pH of the leachates (leached in different time periods at different temperature) from the Ledo coal is highly acidic (pH 2.5) while other OB samples release a nearly neutral discharge (4-7.4). In the cases of leaching at a temperature higher than room temperature (45°C), the pH increased up to 9.40.

Ions present in the aqueous leachates of coals and overburdens
The Ion-Chromatographic analyses were carried out for aqueous leachates of coal and overburden samples after leaching for 1, 3, 5, and 8 h at 25, 45 and 65°C respectively. The concentration of cations like Na ? , Mg 2? , Ca 2? , NH 4 ? and Li ? in the leachates of coal and overburden decreased with an increase in leaching temperature (Figs. 3,4,5,6,7,8,9,10). The leaching of Li ? ion in aqueous solution is found to be decreased with leaching time from 1 to 8 h as shown in Table S5 (see in supplementary information).
From Figs. 11, 12, 13 and 14, it can be observed that the concentrations of F -, Cland SO 4 2ions from the leachates of coal and overburden samples of Ledo colliery increased with an increase in the leaching time at room temperature. With the increase in leaching temperature Physico-chemical and elemental investigation of aqueous leaching of high sulfur coal… 269  from 25 to 45°C however, the concentration of F -, Clbecame lower (Figs. 15, 16, 17, 18). The leaching of SO 4 2ion from coal and overburden was increased with leaching temperature from 25 to 65°C and time (see Figs. 15,16,17,18,19,20,21,22). Hg, Ni and Zn as well as the minerals in coal can vary from coal to coal and according to their association in coal, the concentration of various elements in aqueous leachates can be detected. In most of the coals, the metals occur as mineral matters, or as discrete minerals, or as free or embedded in organic matter (Swain and Goodarzi 1995 Tables S29 and S30 (see in supplementary information). In the case of Fe, the concentration is higher in leachates than in raw samples (the maximum Fe concentration in raw coal was 43.1 and 2320 ppm in the leachates of the coal samples).

Field-emission-scanning-electron microscopic analysis
In the FE-SEM analysis of raw coal samples of the Ledo coal ( Fig. 35) it was found that barite (BaSO 4 ) and galena (PbS) were associated with pyrite (FeS 2 ) which is not shown by EDS analysis of leached coal (Fig. 36). From the FE-SEM/EDS analysis of both the raw and leached samples, it was found that the atomic percentage of Fe in raw coal and overburden sample (LC-20A, LOB-15A) were 18.33% and 8.43% whereas in leached coal it was 7.84%

Physico-chemical characteristics of aqueous leachates
From the Table 1 it is found that the leaching at 45°C for 1, 3, 5 and 8 h respectively demonstrate a gradual increase in pH values The gradual increase in pH (decrease in acidity) values implies that the continuous rainfall at normal temperature for 5 h can generate AMD at the coal mine site. Thus, AMD from coal and mine OB are highly acidic at the coalfield site during the rainy season. The gradual increase in pH values of leachates at 45°C from 1 to 5 h indicates the low acidity of leachates with rise in leaching temperature. A high pH value of leachates may be attributed to the formation of Ca(OH) 2 from CaCO 3 present in overburden due to long time leaching (up to 8 h), since the pH of a solution is an important determinant for counting aquatic toxicity. The amount of toxicity tends to be higher at low pH or high pH situations than at an approximately neutral pH (near pH 7), since the dissolution of many metals can be considered as amphoteric, with a high tendency to dissolve and can form cations at low pH or anions at high pH values (Langmuir 1997 (Nordstrom and Ball 1986;Bigham and Nordstrom 2000) and even relatively low concentrations of dissolved Al can exert toxic effect to fish and other aquatic organisms (Baker and Schofield 1982;Elder 1998). The Environmental Protection Agency (EPA 2000(EPA , 2002a recommends a pH 6.5-9.0 for protection of freshwater aquatic life and pH 6.5-8.5 for public drinking purposes. In the present study the maximum pH values for leachates of overburdens were found to have a pH 9.4. This indicates a lower contamination of water resources from overburden than for coal. It should however be noted that pH is not the only determining factor of metals dissolution. Comparing the physical parameters of aqueous leachates of coal and overburden with the mine waste water it was found that the  Table 1, it was revealed that at room temperature the value of EC and TDS of leachates increase with leaching time. The high value of EC and TDS at a temperature higher than room temperature indicates the high mobility of ions present in the samples which were leached out of the sample as a result of leaching.

Elemental characteristics of aqueous leachates
4.2.1 Ions present in the aqueous leachates of coals and overburdens Figures 9 and 10 show that the leaching of Ca 2? ion from Ledo coal is maximum at high temperature 65°C which is an indication of maximum leaching of Ca 2? ion in monsoon season. The low concentration of Na ? , Mg 2? , NH 4 ?
and Li ? ions in the leachates of coal and overburden at high temperature indicates minimum leaching of these ions in monsoon season. Table S5 shows the decrease in leaching of Li ? ion with leaching duration. Since lithium is generally associated in coal and overburden as lithium silicate and the decrease in concentration of Li ? ion in leachates with leaching time is attributed to the production of orthosilicic acid ( an important factor which determine the amount of elements leached from the raw coal (Moyo et al. 2011). The leaching of SO 4 2ion from coal and overburden was increased with leaching temperature from 25 to 65°C and time (in Figs. 15,16,17,18,19,20,21,22) (Fig. 25). This implies the mining temperature (ranges from 25 to 55°C) is favorable for release of Pb from coal as well as from overburden. The release of Cu, Co and Zn from the coal and overburden is temperature as well as the leaching time dependent (Figs. 25,26,27,28) which can be interpreted from the ICP-OES results of the mine water collected in different season and the leachates of coal and overburden at different temperatures. From the Figs. 29 and 30 it can be concluded that at high temperature most of elements are leached from coal even at a short leaching time. Since the concentration of Fe is more in aqueous leachates than in raw samples. This indicates that the maximum amount of Fe associated in coal can be leached with rain water due to continuous raining. In the present work the leaching experiment has been carried out to compare the leaching type of different elements with the natural processes like weathering. The process was associated with continuous stirring of the water mixture of the samples for increasing time interval (1, 3, 5 and 8 h) at temperatures 25, 45, 65 and 90°C.

Field-emission-scanning-electron microscopic (FE-SEM) analysis
Although association of barite and galena with pyrite was revealed by FE-SEM analysis (Fig. 35), but the EDS analysis of the leached coal sample (Fig. 36) has not shown any indication of the presence of both Pb and Ba. The association of these sulfur minerals is responsible for highly acidic leachates due to weathering under natural condition. Ba and Pb present in coal can easily be released from coal at a lower pH (Giere and Stille 2004). Under the natural weathering condition, the coal associated with Pb and Ba undergoes leaching to release them and dissolve in AMD water, which was also confirmed by ICP-OES analysis of aqueous leachates of the Ledo coal at various time intervals. From the FE-SEM/EDS analysis of raw and leached samples (LC-20A, LOB-15A), it was found that the atomic percentage of Fe is different in both samples (raw and leached). It is happened because during the leaching process, the coal samples lost their structural behavior due to increased porosity owing to release of inorganic minerals from their surface (Manoj et al. 2009 It is to be noted that the intensity of the peaks found in the EDS graph of a sample cannot give a quantitative measure of elemental concentration; however, the EDS analysis could be used for qualitative identification of elements in the respective sample (Kutchko and Kim 2006). The composition of the elements is expressed in atomic and weight percentage (wt%) and the detection limit of EDS is about 0.1 wt% (Kursula 2000).

Mineralogy and functional groups in leached coals
From the XRD analyses, it is reported that the minerals leached from coal and overburden (Fig. 33) are absent after leaching. In raw samples of coal (Fig. 34)  The absence of these minerals in the leached samples of coal and overburden indicates the easy leaching with rain water to form acid mine drainage (AMD). FTIR analysis of raw and leached coal and overburden of Ledo colliery (see Figs. 31,32) revealed the absence of some of the leached components from the samples of coal and overburden. The absorption bands for CH, CH 2 , CH 3 (al) are absent in the leached OB and the bands for both -OH ar , -OH al are absent in both coal and OB. Although the absorption bands for C al -O-C al , SO 4 2etc. are present in both raw and leached samples of coal and OB but the intensity of these peaks in the FTIR spectra of the leached samples are weak. This is due to the leaching of these samples which causes a low carbon and sulfur contents in the leached samples.
The major minerals present in coal are quartz, kaolinite, illite, calcite, carbonate, dolomite and sulfide mineral like pyrite (Ward 2002). From the XRD and FTIR analyses it was revealed that quartz, kaolinite and pyrite are the major minerals in the Ledo coal. Other Indian coals like Bokaro coal samples contain mostly kaolinite and quartz, but other minerals such as siderite and analcine are found as intermediate phases. In Neyeveli coal, dolomite and kaolinite are the major constituents with trace amounts of hematite and bassanite (Equeenuddin 2015). From analytical data it was found that the aqueous leachates of the Ledo coal are highly acidic (pH range 1.99-3.09). But the leachates of other Indian coals have the normal pH range (6.8-7.4) (Equeenuddin 2015). The strong acidic nature of the leachates of Ledo coal is due to the leaching of pyrite which is present in high amounts in the Ledo coal. The high concentration of iron (1670 ppm) in the leachates is attributed to maximum leaching of pyrite. Low pH of aqueous leachates of Ledo coal leads to leach out most of the heavy metal from the coal.

Comparison of aqueous leachates with coal mine water characteristic
The aqueous leachates generated from coal and OB are compared with the AMD water collected from the coal mine. The parameters (pH, EC, TDS) are found to be similar as given in the Tables 1 and 2 respectively. The increase of pH values in mine water samples in comparison with aqueous leachates may be due to dilution during raining as well as ground water contamination. The comparable data reveals the simulation experiment of AMD on a large scale.
Physico-chemical and elemental investigation of aqueous leaching of high sulfur coal… 279

Conclusions
Leaching is found to be one of the primary pathways for trace elements entering into the ecosystem. Dumping of coal and overburden causes large environmental degradation due to direct release of potentially hazardous elements through leaching and oxidation of pyrite minerals. The leaching property of different elements has been found to be dependent to several factors like specific element solubility and availability or release potential. Also the other factors that enhance the metal leaching include swiftly weathering metal containing minerals and the mine drainage conditions that can increase the solubility and flow rates through the contaminated mineral. The potential to produce acidity of drainage from mine water and mine wastes can be predicted by both geochemical methods static and kinetic leaching processes. The leachates generated from overburden dump are found to be rich in heavy metals specially Fe, Cu, Mn and Ni. The concentration of some of these elements increases with increase in leaching time and temperature. High concentration of elements in AMD water and other mine affected water resources is attributed to the continuous raining. Thus Ledo coal mine can cause more threat to the quality of water resources, ground as well as the surface water. Some measures can be taken to minimize the natural leaching including re-mining, reclamation, and vegetation. These steps can reduce acid loads by covering acid producing materials, decreasing infiltration rates, removing the residual coal which at large area is the source of most of the pyrite. Vegetation can alter the soil cover systems by way of holes through roots and can uptake and transport contaminants present below the soil cover. Also, vegetation growth may increase the organic matter of the soil cover, and the decay of the plants consumes oxygen thereby decreasing the oxygen availability.