Effect of operating parameters on coal gasification

Coal combustion and gasification are the processes to utilize coal for production of electricity and many other applications. Global energy demand is increasing day by day. Coal is an abundant source of energy but not a reliable source as it results into high CO2 emissions. Energy industries are expected to decrease the CO2 emission to prevent global warming. Coal gasification is a process that reduces the CO2 emission and emerges as a clean coal technology. Coal gasification process is regulated by several operating parameters. A Number of investigations have been carried out in this direction. A critical review of the work done by several researchers in the field of coal gasification has been compiled in this paper. The effect of several operating parameters such as coal rank, temperature, pressure, porosity, reaction time and catalyst on gasification has been presented here.


Introduction
The drastic rise in the world population and continuous increasing energy demand due to improvement in living standards has led to a rise in demand of energy worldwide. Among the various energy resources in the world, coal is the most abundant and cheapest but its use results into high carbon dioxide emission. Awareness of public towards increasing environmental pollution and impact of CO 2 and other gas emissions on climate change has led to the utilization of clean coal technology. Clean coal technology along with carbon capture and sequestration is competent to emerge as zero emission technology. Carbon capture and storage (CCS) has been identifies as a key technology for moderate global climate change (Rubin et al. 2015). The comparatively high cost of the current CCS system is major hurdle in its extensive development at power plants and other industrial services (IPCC 2014). In order to develop better lower cost technologies, worldwide efforts are in progress (NCC 2015). Now a day's coal gasification has emerged as a clean and effective way to convert solid coal to gaseous fuels which in turn are used to produce power or heat.
Coal gasification is defined as a reaction of solid coal with limited amount of oxygen, air, steam, carbon dioxide or the mixture of these gases at or above 700°C, which yields gaseous products used as source of energy. The gasification of coal consists of two consecutive steps: pyrolysis of coal and gasification of char obtained from coal pyrolysis. There are several types of coal gasifiers such as moving bed, fluidized bed and entrained flow gasifiers where complete gasification reactions take place. Among the two steps of coal gasification the rate of second step i.e., gasification of char is much slower than that of the first, so the construction and design of coal gasifier is dependent on the gasification of char. Pyrolysis of coal in gasification process is mainly dependent on the organic properties of the coal and it is important because it has influence on the subsequent conversion process. Gasification offers several advantages over conventional combustion such as reduction of carbon dioxide in the environment and for a given amount of fuel; the volume of the gas obtained from gasification is less compared to that obtained from the combustion. The lesser gas volume needs smaller equipment which in turn lowers overall cost (Basu 2006). The drawback of the gasification is that carbon conversion efficiency is not 100%, useful part of the fuel remains as char in the gasifier (Basu 2006). Gasification characteristics of coal are significantly dependent on the type of coal and operating conditions. Integrated gasification combined cycle (IGCC) has been developed to be an eco friendly power generation system via coal. IGCC is highly efficient in reducing CO 2 emissions. In many counties such as USA coal gasification power plants are used commercially and experts are predicting that coal gasification will be the best for power generation sector in future. IGCC plants produce syngas (mainly hydrogen and carbon monoxide) which is cleaned from H 2 , NH 3 and Particulate Matter. Clean syngas is burnt in a combustion turbine as a fuel. Electrical generator is driven by a combustion turbine (CT). Exhaust heat coming out from CT is recovered and used to boil water which creates steam for a steam turbine generator. IGCC is termed as combine cycle because of the use of two turbines simultaneously i.e., combination of combustion turbine and steam turbine. Combination of two turbines is one of the reason by which IGCC based power generation becomes efficient. Higher power generation efficiency means less amount of fuel is used to generate the rated power which will result in better economics and reduced formation of green house gases (Kristiansen 1996). Big companies, such as Siemens, Shell, and ConocoPhillips have put up IGCC facilities around the world (Hoffmann and Szklo 2011). Mahinpey and Gomez (2016) reported that the IGCC plants are designed with CO 2 and sulfur capture in order to take away the majority of such harmful constituents from the product gas. Mahinpey and Gomez (2016) explained one of the possible gasification routes of power generation from different feedstock. They reported chemical synthesis is also possible with syngas by using of the Fischer-Tropsch (FT) (Fig. 1).
The objective of this paper is to provide an overview of gasification process and to review the findings of several researchers in this area, so that comprehensive information on coal gasification will be available for new researchers and energy sector people. The observations reported by different authors in terms of different variable parameters like catalytic load, porosity, volatile matter, reaction time and effect of pressure on yield products have been reviewed critically under the following headings.

Coal quality
Coalification is a transformation of vegetable matter to form peat, lignite, Semi bituminous, bituminous, semi-anthracite and anthracite. The degree of coalification is termed as rank of coal. Reactivity of the coal is related to its rank. Rank of the coal is a most important variable in the nature of the coals. It is determined by carbon content of the coal, volatile matter and calorific value. Coal is composed of hydroaromatic and aromatic building blocks. The building blocks are connected to each other via variable cross-links. The level of porosity in the coals has been decided by the extent of cross-links between the building blocks. There are three types of structures present in the wide range of coal which is suggested by Hirsch (1954): (1) Open structure: This type of structure is found in low rank coal (carbon content is up to about 85%). These types of coals are generally highly porous because lamellae are connected by significant number of cross links and these cross-links are randomly oriented.
(2) Liquid structure: This type of structure is found in bituminous coal (carbon content is from about 85%-91%). These types of coals are less porous because with increase in coal rank cross-links start to disappear and lamellae show some specific orientation.
(3) Anthracite structure: This type of structure is typically found in high rank coal (carbon content is above 91%). As the rank of the coal increases, the cross links disappear completely and the degree of orientation of lamellae increases greatly with respect to each other.
Pore structure of the coal has significant role in coal combustion and gasification. International Union of Pure & Applied Chemistry classified the pores into three categories: Microporse (diameter \ 2 nm), Mesopores (diameter 2-50 nm) and Macropores (diameter [ 50 nm) (Saha 2013). Several models have been proposed in order to explain the gas-solid reaction on porous char during combustion and gasification, like: random pore model, isolated pore model, lattice model and pore tree model. Several researches such as Simons (1983) and Bhatia and Gupta (1994) studied several models in detail. Porosity of the coal is usually calculated from the particle density (D p ) and true (H t ) density:

Coal gasification
Coal gasification is carried out in limited amount of oxygen i.e., one-fifth to one-third of the theoretically oxygen required for complete combustion. Hydrogen and carbon monoxide are the main products of gasification, only a fraction of carbon is combusted for generation of heat. In gasifiers the following two physicochemical processes take place (Basu 2006): (1) Pyrolysis or devolatilization As coal enters into a gasifier, it is first dried by the hot gases present in the gasifier. A series of complex physical and chemical process start slowly at temperature \ 350°C and accelerate as temperature exceeds 700°C. The composition of the release products of pyrolysis is depending upon the temperature, pressure and gas composition during pyrolysis. The pyrolysis process can be represented by the following reaction: Coal ! Heat ! Char ! Gases ! Vapors or liquid ð1Þ Following three products are produced by pyrolysis: (1) Light gases like: CO, CO 2 , H 2 , H 2 O, CH 4 .
(2) Tar which is a corrosive and viscous liquid composed of heavy inorganic and organic molecules. (3) Char which is a solid residue mainly contains carbon.
Gasification Gasification process involves a series of endothermic reactions which are supported by the heat produced from the following combustion reactions occurred inside a gasifier: The major gasification reactions are (Rodrigues-Reinoso 1991; Saha 2013): (2) Water gas shift reaction The partial oxidation of carbon by steam occurred in this reaction.
(3) Boudouard reaction The char present in the gasifier reacts with the carbon dioxide and produces CO: (4) Shift conversion This endothermic reaction is known as water-gas shift reaction which results in increasing ratio of hydrogen to carbon monoxide in the gas. This reaction is employed in production of synthesis gas.
CO þ H 2 O $ CO 2 þ H 2 DH ¼ À 42:3 kJ/mol ð6Þ (5) Methanation Nickel based catalysts at 1100°C and 6-8 bar pressure accelerate this reaction. Formation of methane is preferred in IGCC applications because of its high heating value. Figure 2 represents above mentioned exothermic and endothermic reactions in updraft gasifier. It is difficult to predict the exact composition of the gases obtained from gasifier because it depends upon number of parameters such as: temperature, operating pressure, gasifying medium, fuel composition, moisture content etc.

Types of gasifiers
The complete gasification reactions carried out in the gasifiers which need to be operate at certain temperature in  (2016) Effect of operating parameters on coal gasification 115 order to drive certain endothermic carbon-steam and carbon-carbon dioxide reactions, the required temperature is maintained by heat evolved from exothermic reaction between oxygen and fuel. Depending upon the medium of gasification, gasifiers can be classified into two categories (Basu 2006): (1) Air Blown: Air is used as a gasification medium in this type of gasifiers.
(2) Oxygen-Blown: Pure oxygen is used as a gasification medium.
When air is used as gasification medium, the N 2 is simultaneously brought into the process which results in the product gas dilution. As a result product gas will have a lower calorific value i.e., 3-6 MJ/m 3 compared to that of oxygen blown (10-12 MJ/m 3 ) which is free from diluents like N 2 .
Depending upon the contact between gas and fuel, gasifiers can be further divided into following three types: (1) Moving or Fixed Bed Gasifier.
(1) Moving bed gasifier: Moving Bed Gasification is an oldest technology which is extensively used in commercial practices. Moving bed gasifier is also known as fixed bed gasifier. Gasification medium is slowly flow through a fixed bed of solid particles. Up-draft and down draft are the two possible configurations of this type of gasifiers, depending upon the direction of flow of gasification medium. The up-draft configuration is more commonly used because there is low tar content. The preferred feed coal size is 5-80 mm. The combustion zone attains a maximum temperatures of the order of 1500-1800 and 1300°C for the slagging and dry ash gasification, respectively. Temperature profile is formed over the bed, so that the feed coal is successively preheated, dried, pyrolyzed, gasified and combusted. Lurgi gasifier is the oldest moving bed gasifier technology which is commercially proven. The major disadvantage offered by moving bed gasifier is processing of highly caking coal without pre-treatment (Saha 2013). (2) Fluidized bed gasifier: In fluidized bed gasifiers the bed of solid particles behaves as a fluid. In this type of gasifier feedstock of particle size less than 5 mm is suspended in the oxygen rich gas. The rising gas reacts with the feedstock and maintained the fluidized state of the coal particles. A uniform temperature distribution is obtained in this type of gasifiers. Fluidized bed gasifiers avoid clinker formation and defluidization of the bed because they are operated in the temperature range of 800-1050°C which is well below the ash fusion temperature. Ash discharge conditions may differ in fluidized bed gasifiers, either dry or agglomerated ash. Dry ash fluidized bed gasifier has traditionally operated on low rank of coal; whereas agglomerated ash fluidized bed gasifiers are suitable for any rank of coal.
(3) Entrained flow gasifier: Pulverized coal particles of size less than 0.1 mm are suspended in a stream of steam and oxygen at high speed. Depending upon the method of coal feeding, dry (Nitrogen as a transport gas used) or wet (carried in water slurry), gasifiers are accepting almost any type of coal. Entrained flow gasifiers ensures high carbon conversion because they operate at a high temperature of 1400-1600°C (well above the ash slagging temperature). Entrained flow gasifiers are high capacity gasifiers because the gas residence time is measured in seconds. Commercial entrained bed gasifiers for a large scale of applications are Texo, Koppers-Totzek and Shell. Entrained bed gasifiers are available for the much larger capacities such as greater than 100 MWe than other two types of gasifiers.
The thermal efficiency and output of the gasification process are greatly subjective to the magnitude and location of heat transfer in the gasifiers. A proper understanding of the heat transfer mechanism in a gas solid interface inside a gasifier is critical. So the modes of heat transfer in the gasifiers are the important aspect of the study. The modes of heat transfer may be considered as: heat transfer between the gas and particles, between the bed and walls of bed furnace, from the bed to immersed tube surfaces, to the tubes of boiler immersed in the heat exchanger and to the wall of cyclone.

Gas cleaning
The product of gasification contains desirable components like CO, H 2 , CH 4 and undesirable components like ash, entrained soot, tar, certain amount of H 2 S and traces of NH 3 , COS, HCl and HCN (Basu 2006). The undesirable components need to be removed from product gas. There are number of techniques used to remove undesirable compounds, some of which are discussed here: Limestone can be fed into the fluidized bed gasifiers along with coal to capture most of the H 2 S. An external desulfurization system is used to remove any residual H 2 S. Chemical and physical methods are used to remove the tar from the product gas. Tar is destroyed and converted into smaller molecules in chemical method and tar yielding is removed by physical method. Cyclones are used to remove particulate matter. In order to remove particulate matter at high temperature, number of technique are developed which includes granular bed filters, ceramic barrier filter, high temperature fabric filters etc.
2 Effect of operating parameters 2.1 Effect of catalytic activity on coal gasification Catalytic gasification of coal is extensively studied for the development of efficient and economic gasification processes. Several researchers (Agarwal and Sears 1980;Radovic et al. 1983;Takarada et al. 1986;Miura et al. 1989;Ochoa et al. 2001;Song and Kim 1993;Li 2007;Hattingh et al. 2011) investigated the effect of catalyst on reactivity of char obtained from coals ranging peat to anthracite during gasification in the presence of varying gasifying mediums. Presence of catalyst in char can be inherent or may be impregnated. From the investigation of several researchers (Agarwal and Sears 1980;Radovic et al. 1983;Takarada et al. 1986;Miura et al. 1989;Song and Kim 1993;Ochoa et al. 2001;Li 2007;Hattingh et al. 2011), it can be said that the reactivity of char having inherent or impregnated catalyst is dependent upon a number of factors such as weight and type of catalyst. Song and Kim (1993) investigated the effect of presence of catalyst by weight percentage on char reactivity. They reported that under the 3% catalyst addition with same operating conditions, pure salt catalytic activity is in the order of K 2 CO 3 [ Na 2 CO 3 [ FeSO 4 [ K 2 SO 4 [ -Fe(NO 3 ) 3 during steam gasification of bituminous coal char. They have also reported that the reactivity increases with the addition of catalyst up to 6 wt%. Hattingh et al. (2011) reported that increased amount of CaO and MgO content enhances catalytic effect of coal which in turn enhances reactivity of coal. Schobert (1992) reported that the presence of Na 2 O and K 2 O also increases the reactivity but their effect is not considered due to negligible amount of such species in ash.
Hence, it may be concluded that all the catalyst either present or added to coal, affects the gasification behavior of coal by changing the reactivity of coal.

Effect of porosity of char on coal gasification
Pyrolysis results in removal of volatile matters and yields a solid residue called char (Kiihl et al. 1992). It is important to study the internal structure of solid residue after heat Effect of operating parameters on coal gasification 117 treatment because it affects the char reactivity. There are number of randomly oriented and different shapes pores with radii ranging from one length of nanometers to tens of nanometer (Liu et al. 2000). To explain the formation of pores during gasification, there are three mechanisms (Rodrigues-Reinoso 1991): (1) the width of existing pores, (2) the formation of new pores by selective gasification of certain structural components and (3) the opening of formerly unreachable pores. The total pore volume measured is further divided into two groups i.e., micropore region and the combined mesopore and macropore region (Siauw et al. 1984 andRodrigues-Reinoso 1991). The micropores play important role in the reactivity of char particles because micro-pores take up approximately 95% of total surface area, while the meso-pores and macro-pores provide the passage to reactant gases to reach the active carbon sites in the micro-pores where actual gasification reaction take place (Siauw et al. 1984;Liu et al. 2000). At low carbon conversion, pore swelling is dominant which result in an increased surface area, as reaction proceeds pores starts collapsing which leads to decrease in surface (Liu et al. 2000). Kiihl et al. (1992) reported that steam gasification produces a less microporous structure than CO 2 gasification. Feng and Bhatia (2003) reported that in air gasification pore structure development is different from CO 2 gasification. During CO 2 gasification, volume and surface area of small micropores increases very dramatically as gasification reaction progresses whereas in air gasification volume and surface area of small micropores does not change appreciably with carbon conversion after a particular extent of carbon conversion (Feng and Bhatia 2003). So the gasifying agents also play an important role in finding effect of porosity on coal reactivity. Siauw et al. (1984) have reported that the total pore volume and micropore volume decreases with increase in carbon content or rank of coal because the lower rank coal are much more porous than higher rank coal. The microporous volume of sample coal decreases linearly with increase in the coal rank (Siauw et al. 1984). Most of the pores of lignite lie in the range of micro and meso-pores (Siauw et al. 1984). The reactivity of coal with change in rank can be justified by the explanation of (Jenkins et al. 1973) i.e., higher rank coal has less feeder pores and lower reactive sites on the surface compared to lignite, which reduces the reactivity of higher rank coal. Siauw et al. (1984) have also investigated that the coal reactivity is almost constant up to certain total pore volume and then sudden rise in reactivity observed with increase in total pore volume. This sudden rise in reactivity can be understood by opening of unreachable pores and formation of new pores as reaction proceeds. Jenkins et al. (1973) reported that the reactivity of char having large proportion of feeder pores is high, because the reactivity of reactant gas to diffuse into the internal surface of micropores is enhanced.
Effect of temperature on pores formation has also been investigated by Jenkins et al. (1973). They explained that as the temperature increases up to a certain level (i.e., 600°C) porosity increases and concentration of feeder coal decreases but results in lower reactivity, with further increase in temperature. The reactivity of coal after certain temperature can be decreased because of heat treatment which promotes closing of pores. Closing of pores caused due to presence of large molecules, compressing disorganized carbon, cross linking and collapsing of pores at higher temperature due to plasticity of char (Feng and Bhatia 2003). But in contrast to above discussion, Feng and Bhatia (2003) also reported that with the increase in heat treatment time and temperature, volume of closed pores increases and there is no change in size of various pores with carbon conversion because shrinkage occurs maintaining the same distance between crystalline structures. In contrast to above results, Miura et al. (1989) and Hurt et al. (1991) have reported that the pore structure is not a factor which controls the gasification reaction rate of highly reactive char. Jenkins et al. (1973), Beamish et al. (1998), Messenbock et al. (2000, Zhang et al. (2006) and Kim et al. (2011) have reported that the reactivity of coal char during gasification is dependent on volatile matter content in coal and rank of coal. Reactivity of char is directly proportional to the volatile content of coal, i.e., reactivity of char increases with increase in volatile matter content (Beamish et al. 1998;Zhang et al. 2006;Kim et al. 2011). Messenbock et al. (2000 reported the variation of volatile content of coal with respect to change in pressure. Tread of Messenbock et al. (2000) showed that there is a decrease in total volatile content with increasing pressure during pyrolysis, this trend is observed because of deposition of secondary char on the particles and suppression of volatile yield at higher temperature.

Effect of reaction time/residence time on coal gasification
Shufen and Ruizheng (1994), Ye et al. (1998), Harris et al. (2006) and Wu et al. (2009) have investigated the effect of reaction time on carbon conversion during gasification. Ye et al. (1998) investigated that fixed carbon conversion during CO 2 and H 2 O gasification is a function of reaction time and gasification temperature (Fig. 3). Ye et al. (1998) reported that the rate of fixed carbon conversion increases with increasing gasification temperature at a particular reaction time for both CO 2 and steam gasification. Ye et al. (1998) also mentioned that the fixed carbon conversion increases with increasing reaction time at a particular gasification temperature. Results of Ye et al. (1998) are in good agreement with other researchers (Shufen and Ruizheng 1994;Harris et al. 2006;Wu et al. 2009).
So from the above discussed results, it may be concluded that for the same reaction time with increase in temperature carbon conversion increases and also with the increase in reaction time carbon conversion increases irrespective of different pyrolysis and gasification atmosphere.

Effect of temperature on coal gasification
Temperature plays an important role in gasification of coal. Higher gasification temperature increases the carbon conversion which improves gasification rate. Kim et al. (2011) have reported the effect of temperature ranging from 1050 to 1350°C on carbon conversion during gasification. They found that as the gasification temperature increases gasification time required for carbon conversion decreases. According to them nearly half gasification time is required for complete carbon conversion at 1350°C than that of 1050°C (Fig. 4). Liu et al. (2008) have studied the effect of temperature on gasification rate of char namely SC, RC and RDC prepared from Chines Binxian coal. The gasification rate of SC char decreased with increase in carbon conversion during gasification reaction and gasification rate increased with increase in temperature. The gasification rate of char SC and RC was similar (Fig. 5a, b). At 1300°C the profile of RC showed highest gasification rate at 27% carbon conversion. Similarly for RDC coal char gasification rate showed parabolic profile at 1150, 1200 and 1300°C for the carbon conversion 24%, 31%, 32% respectively (Fig. 5c).
According to them the variation in gasification rate was due to structural variation of char which was due to difference in material concentration and char preparation method.
According to Xiao et al. (2006) the gasification temperature plays an important role in char gasification. As the bed temperature increases, the carbon conversion during gasification reaction increases by oxidation, Boudouard and water gas shift reaction which shows almost linear relationship. Results of Xiao et al. (2006) are in good agreement with the other authors (Liu et al. 2008;Kim et al. 2011). Corella et al. (2006) have reported that gasification temperature has both the positive effect as well as negative effect on coal gasification reaction. For the high carbon conversion, enhanced gasification rate, high throughput and low tar content in product gases, high gasification temperature (850-900°C) is required. But apart from this while operating gasifier at atmospheric pressure it is taken into consideration that above 750°C product gases always contain less than 20% by volume CO 2 , therefore there is no CO 2 capture. To capture CO 2 with CaO at atmospheric pressure it is required to operate gasifier at below 750°C which in turn exceeds the tar content in product gases beyond a limit. Such gasification is called dirty gas and it has no further use in any field. Hence they concluded that there is a confliction for the optimum gasification temperature.
Several researchers (Alvarez et al. 1994;Ahn et al. 2001;Zhang et al. 2006;Cakal et al. 2007;Liu et al. 2008;Everson et al. 2008;Fouga et al. 2011;Tanner and Bhattacharya 2016;Wang et al. 2015) have studied kinetic behavior of coal gasification using different kinetic models. They have used different raw materials and various operating conditions. They have reported the values of activation energy which has been compiled in Table 1. In this table the material used by various researchers, gasification medium, kinetic model and the values of activation energy has been compiled.
2.6 Effect of pressure on yield products during coal gasification Sha et al. (1990), Roberts et al. (2003), Canel et al. (2005) and Yu et al. (2007) have investigated the effect of pressure on yield products during pyrolysis and gasification. Sha et al. (1990) and Roberts et al. (2003) have reported that the pyrolysis pressure of coal affects the morphology of the produced char. It is also reported that with the increase in pyrolysis pressure tendency of char to become sponge is increased due to opening of large void areas and accessible porosity (Roberts et al. 2003). Sha et al. (1990) reported that the char reactivity is decreased when it is produced by high pressure pyrolysis. Sha et al. (1990) investigated the effect of operating pressure on coal gasification. They have reported that there is increase in yield of CH 4 and C 2 H 6 irrespective of pyrolysis medium (H 2 or N 2 ) with increase in operating pressure but as compared to N 2 pyrolysis   Effect of operating parameters on coal gasification 121 medium percentage of yield products is higher in H 2 atmosphere. From the Fig. 6a, b it can be seen that there is slight increase in yield of CH 4 and C 2 H 6 with increase in pressure during N 2 pyrolysis atmosphere which could be because of secondary cracking of tar where as there is higher increase in yield of CH 4 and C 2 H 6 with increase in pressure during H 2 pyrolysis atmosphere which is due to rapid hydro-gasification of coal char and hydrogenation of gaseous hydrocarbons. They also reported that irrespective of pyrolysis atmosphere there is decrease in yield of C 2 H 2 with increase in pressure where as the decrease in yield of C 2 H 2 during N 2 atmosphere is less as compared to H 2 atmosphere because of hydro generation of unsaturated hydrocarbons.
Results of Sha et al. (1990) are in good agreement with the results of Canel et al. (2005) and Yu et al. (2007) with respect to increase in yield of CH 4 as pressure increases but Canel et al. (2005) have reported that there is a decreases in methane yield between 5 and 10 MPa. Results of Sha et al. (1990) for the increase in yield in C 2 H 6 with pressure are similar with Canel et al. (2005). Messenbock et al. (2000) reported the effect of pressure (1-30 bar) on total volatile yield during pyrolysis in the atmosphere. Figure 7 represented that there is a decrease in total volatile yield as pyrolysis pressure increases which is because of deposition of secondary char over particles and volatile release inhibition at higher pressure, this fall in total volatile yield is also been measured by other researcher (Yu et al. 2007). Yu et al. (2007) have reported the decrease in tar yield and increased gas generation. The results of Yu et al. (2007) are contradicted by the results of Canel et al. (2005). Canel et al. (2005) reported that with increase in pressure tar yield increases (Fig. 8) and char yields decreases. They also reported that yield of gases increases with pressure and then started decreasing (Fig. 8).
Thus, it may be concluded that the effect of pyrolysis pressure on the gasification reactivity of char is not systematically proven.

Conclusion
This review has provided an overview of coal-char-gasification process. Coal gasification emerges to be an excellent green technology which along with securing energy demands will keep global warming in check. The coalchar-gasification process is affected by number of parameters. From the above study following conclusions are drawn in order to identify the effect of different operating parameters on coal gasification: (1) Carbon conversion is a function of reaction time and it increases with increase in reaction time irrespective of different operating atmosphere.
(2) Carbon conversion and gasification rate increases with increase in gasification temperature. (3) Pressure during pyrolysis affects the gasification reactivity of char but still no general trend has been found which establishes a relation between pyrolysis pressure and gasification reactivity. (4) Lower rank coals are highly reactive than higher rank coals due to high concentration of active sites in a coal matrix of lower rank coal. (5) Pore structure of char is a factor which controls the gasification reaction rate although it is not a controlling factor for highly reactive chars. (6) Reactivity of char is a function of catalyst percentage i.e., reactivity increases with increasing catalyst percentage up to a certain limit beyond that it not considerable. Rank of coal also considerably affects the catalytic reactivity.
Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://crea tivecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.