Enrichment of carbon recovery of high ash coal fines using air fluidized vibratory deck separator

Coal is primarily beneficiated by wet gravity methods. The wet processing of coal is an efficient practice. However, it introduces the moisture in the range of 6%–15%, depending upon the size of coal which is as detrimental as ash content to the heating value of coal. Dry beneficiation of coal fines was carried out using an air fluidized vibrating table in which the coal particles get separated from the heavier mineral particles as a result of horizontal and vertical stratification. Two level factorial design matrix was used to optimize and assess the interactive effects of the operational parameters of a pneumatic table viz. deck eccentric, side tilt and air flow rate on the clean coal yield and its ash content. Double stage processing was found to be more effective for reducing the ash content of the clean coal. Initial stage of processing at a higher ash level generates a reject of high ash with low combustibles. Cleaning of the rougher concentrate at 34%–35% ash level shows significant improvement in the organic efficiency (88.6%) and useful heat value of clean coal (15690 kJ/kg). The performance of air fluidized vibrating deck was measured by Ep value which is 0.18.


Introduction
The resources of coal in India are about 301.56 billion tonnes which are much higher compared to oil and gas (Geological survey of India (GSI) 2014). Out of total reserve, 266.00 billion tones are the proven reserve of noncoking coal. This indicates that about 88% is the noncoking coal. The coal contributes to about 55% of the commercial energy consumption as compared to 27% world average and more than 65% of electricity generation capacities are coal based. India is the third largest coal producing country after China and USA. The quality of the Indian coal is inferior because of drift origin and causes dissemination of the mineral matter.
An Indian power plant of high-ash coals is energy intensive, causing shortages of rail cars and trucks. The existing boilers are designed for treating the coal having ash of 25%-35%. The beneficiated thermal coal fines can increase the thermal efficiencies of the boilers. Coal is currently beneficiated by wet method through gravity and flotation techniques. Moisture retained in the washed products is about 6%-15%, depending upon the feed size. Removal of moisture requires significant amount of energy and subsequently increases the operating cost. Dry processing can be used in the area of arid region. It is more economic than wet cleaning as dewatering systems are not involved. The cost of cleaning fine coal by wet method is estimated at three to six times the cost of cleaning coarser coal, the range being dependent on particle size. So it can be eliminated by dry cleaning of coal. It is also examined that product of dry cleaning has higher thermal efficiency than that of wet cleaning. Indian Government has made a rule that coal transported from a distance of 1000 km or more for the thermal power plant or burnt in a sensitive area must be beneficiated to reduce the ash level to 34% (Ministry of Environment and Forest 1998).
Dry cleaning of coal has attracted the attention of the researchers worldwide because of the obvious economic advantages it offers. Studies have been carried out in most of the major coal producing countries to evaluate the performance of the dry coal cleaning units. Some researchers have worked on air dense-medium fluidised bed for large sized coal where fine magnetite powder is used. Test work has been carried out at different size spectra of coal.
Air tables are found to be more useable than any other dry gravity concentrator particularly in the food industry as they are originally developed for seed separation (Burt 1984). In early 1916, dry beneficiation of coal fines was introduced in United States (Lockhart 1984). The pneumatic density separators were widely practiced between 1930 and 1960. Several researchers found that dry beneficiation of coarse coals are found to be effective in reducing the ash in clean coal by different techniques (Li et al. 2011;Yang et al. 2013). In air fluidization technique, autogeneous medium is produced by mixture of air and fine coal power which behaves as a separating density. The dry processing of coal fines was carried out by Patil and Parekh (2011) and Shobhana et al. (2015) for reducing the ash content in the clean coal by air fluidization technique. Air tables are also being used for the dry beneficiation of beach sand for separation of heavy minerals (Gupta et al. 2012), enrichment of tungsten values (Honaker et al. 2008). The pneumatic table was also used for dry separation of mixture of plastics (Dodbiba et al. 2005). Zhao et al. studied on degree of segregation of fine lignite in a vibrated gas-fluidized bed (Zhao et al. 2015). Theoretical considerations show that effective separation in a table can be achieved when the time of free fall could be minimized (Osborne 1988;Haider and Levenspiel 1989;Zhao et al. 2002). The separation of fine particles in air is difficult due to low differences in settling velocity. However, the modern techniques assist to increase the efficiency of separation by introducing other parameters, like transverse oscillation, slanting the deck in longitudinal and transverse direction which increases the flow of the particles according to the desired grade.
In India the environmental regulations make it imperative for the thermal power plants to charge the coal having 34% ash in the boilers. Therefore, efforts have been made to produce a product that satisfies the ash requirement. In the present investigation, dry beneficiation of high ash coal fines has been studied for reduction of ash in clean coal, enrichment of carbon values and also for understanding the separation behavior. Interactive effects of process variables of an air fluidized vibratory table on the responses have been highlighted.

Material and method 2.1 Material
Thermal coal of G-grade collected from Talcher coal fieldwas used for the study. Characterization of the coal sample was carried out at -1 mm. Coal petrography was done through Advanced Polarising Microscope (Leica DM 4500, Germany) following BIS procedure (IS 9127-5) on polished mounts. It appears un-banded durainous in nature. Mineral matters are present in association with different maceral groups (Fig. 1a, b). On visual basis, mineral matters constituted 60.8%. Mineral matter occurs in dark colour either as cavity filling or in disseminated form. This component is rich in clay minerals, silica (quartz) and carbonates (siderite). Among the macerals, vitrinite group of macerals are dominating followed by the inertinite and liptinite macerals. Figure 1 also shows that presence of clear bands of mineral matter, vitrinite and inertinite assist in recovering of clean coal. However, there is also fine dissemination of mineral matter with the macerals which indicates the inter locking of coaly matters. The distribution of petrographic constituents is shown in Table 1. The proximate analysis (Table 2) of coal sample was carried out as per the IS standard (IS 1350-1) using Coal analyzer. The heat value of the coal sample is quite low as 4979 kJ/kg because of high ash content of 54.5% and this corroborate the petrographic analysis of the mineral matter in the coal sample.
From the characterization study of the coal sample, it was found that beneficiation would be effective at finer size as the coal sample is adequately liberated. The sample was stage crushed to 1 mm and -150 lm fraction was discarded. The -1 ? 0.15 mm fraction was treated in a pneumatic table. Characterization of the feed material was carried out in terms of size distribution, ash and heat values of each fraction (Fig. 2). The high ash in the fractions reflects that recovery of clean coal at low specific gravity is difficult to achieve. It also signifies to extend the washability study of the sample up to high density of the medium, varying from 1.4 to 2.2. The useful heat value in Fig. 2 indicates that the fractions -500 ? 300 and -300 ? 150 lm possess higher value compared to other fractions.

Methods
The coal sample (-1 ? 0.15 mm) was subjected to dry beneficiation using a vibratory-pneumatic deck. The separator consists of rectangular porous deck below which an air chamber. The deck is connected to an eccentric mechanism comprising of variable speed drive which triggers the required oscillation in the deck that imparts vibratory motion to the particles. As a result segregation of the particles takes place based on their densities. The deck can be slanted transversely and longitudinally. There are five process parameters, namely feed rate, deck eccentric, transverse angle, longitudinal angle and air flow rate. In present study, three variables, viz, deck eccentric, air flow rate and transverse angle were selected as operational parameters and the feed rate (90 kg/h) and longitudinal angle (78 mm) were kept constant throughout the experiments. The factorial design of experiments was followed to conduct the tests for establishing the relationship between the process parameters and the response functions of recovery of combustibles and ash of clean coal. The sample was fed across the width of the deck approximately at the centre point (Fig. 3). Longitudinal angle of the deck is related to the residence time and provides the time for the

Wt%
Ash % Heat value Fig. 2 Characterization of feed sample in terms of particle size distribution and heat value feed to expose for separation on the deck. The upward flow of air causes stratification of the bed. The heavier particles gravitate through the bed, come in contact with the deck and are moved up the deck surface due to the eccentric reciprocating motion. The lighter coal particles tend to float and move to the top of the bed and pushed down the deck by new feed material and resultant gravitational force. The deck eccentric pushes the heavier particles sideways towards the higher end of the deck. The side tilt governs the quality of separation. The dry beneficiation was also carried out in two stages. The first stage was targeted to generate a tailing with high ash content (about 80%). The middling and light streams of the first stage were combined together for the second stage processing under different conditions for producing a clean coal at 34%-36% ash level.

Process variables of vibratory table
In this investigation, three operational variables including deck eccentric (DE), air flow rate (AFR) and transverse angle (SA) are taken into consideration. Three variables at two level factorial design of experiments were followed.
There is an upper and lower limit of the range with a base level (average value of upper and lower values) for each process variable. The levels of different process variables are given in Table 3.

Results and discussion
Washability study of the coal sample and dry beneficiation carried out using an air fluidized vibratory deck are described below.

Washing amenability of coal sample
The washability study of coal sample conducted by using medium of varied specific gravities shows that at a specific gravity of 2.0, yield of clean coal is 40.4% at 24.3% ash level with recovery of combustibles 67.7% (Fig. 4). The amount of reject (sink) produced at this separation density is 59.6% with combustibles of 32.3% and 75.7% ash. Increasing the separating density to 2.1, yield of clean coal becomes 53.2% with 77.7% combustibles and 34% ash.  Enrichment of carbon recovery of high ash coal fines using air fluidized vibratory deck… 265

Light
The combustible matter in reject stream reduces to 22.3% with 78.5% ash. Further increase of the specific gravity to 2.15, combustible matter in the concentrate could be significantly improved to 82.6% at 38% ash level and the same in the reject drastically reduces to 17.4% (Table 4). The coal desired for thermal power plant should be in the range of 34%-36% ash which was the objective to achieve from this study. The washability study also shows that Near Gravity Material (NGM) varies from 19.8% to 24.7%. At higher separating density, NGM reduces which reveals that misplacement of the carbon values is less.

Dry beneficiation
Dry separation of high ash fine coal using an air fluidized vibratory separator under different conditions was carried out. The results are shown in Fig. 5. It shows that separation characteristics are dependent on the process parameters. Analyzing the experimental data of Air

Physics behind segregation of particles on deck
When the air current is blown through packed bed of solid materials it dilates the bed and produces a pressure drop due to drag force. When this drag force is equal to bed weight, particles behave like a fluid. The phenomenon is called fluidization. The manner of fluidisation depends upon airflow rate and proportion of fines present in feed. The fluid acts as pseudo-pneumatic fluid which segregate particles based on their densities. Particles having lower density report to the upper layer and particles with higher density move to the bottom of the bed. The heavier particles come in contact with the deck surface and acted upon by frictional force and vibrational force provided to the deck of table.
The lighter particles at the upper layer are not affected by these two forces. Under combined effect of fluidisation, net gravitational force due to longitudinal angle of deck and vibrational force, particles move along the deck surface from the feed end towards the discharge end following the different trajectories and also by the resultant force arising out of all the forces acting on the particles. These are the frictional and vibrational forces due to the deck movement, drag force due to upward air flow and gravitational force for the heavier particle, while there is only effective gravitational force for the lighter particle. All these forces are associated with the particle movement. By the action of air flow, heavier particles fall onto the deck surface and come in contact with deck surface whereas lighter particles migrate to the upper layer. This phenomenon is called vertical segregation of particle (Fig. 6a). As heavier particle (Fig. 6b) comes in contact with surface, it is acted upon by vibrational force and moves towards upslope. Lighter particles move down slope along the shorter route by net gravitational force mainly as a result of side tilt and displacement caused by new feed entering the table. This separation of heavier and lighter particles is called horizontal segregation (Fig. 6b). Both horizontal and vertical segregation is presented pictorially in Fig. 6.

Forces acting on the particles on deck
Referring to the Fig. 3, when the transverse and longitudinal angles of the separating deck are in a position of b and c respectively, particles move with the resultant angle (h) of b and c. Forces acting on both heavier and lighter particles have been shown in Fig. 7 Let, m = mass of the particle, mg = gravitational force due to mass of the particle, F N = normal force due to weight of the particle Gravitational force (mg) is resolved into two vectors, F air = drag force due to air blown through porous bed F vib = vibrational force due to deck eccentric F fric = frictional force in the direction of opposite to the motion = lF N = lmgcos h a = angle between vibrational force and frictional force Now, net force acting on lighter particle F net = F accln = mgsin h ? force due to new particle entering Net force acting on heavier particle F net = F net = mgsin h -F fric -F vib ? F air

Effect of variables on response
The effect of single process variable in isolation cannot be studied as the process variables are inter-dependent. The combined effects are causing the effective separation. The contribution of individual and combined effect listed from the model is shown in Table 5. It seems that the contribution of the deck eccentric on yield is more than 56% Deck eccentric Deck eccentric   followed by air flow rate and transverse angle. Similarly for the ash of the clean coal, within the design domain, effect due to deck eccentric is 62.7%. The influences of the variables are discussed in the subsequent section.

Interactive effect of deck eccentric and airflow
The vibratory motion of the deck spreads the bed of particles on the deck. As the deck eccentric increases it allows the heavy particles to move towards the up slope of deck. The effect of deck eccentric was found to be dominant. This reflects that slight changes in deck vibration cause significant effect on the yield and also on the ash (Fig. 8a,  b). The vibrating force acting on the particles has major contribution in the separation process. Combined effect of deck eccentric and airflow rate confers the separation of the heavier particles from coal sample. When there is only drag force of airflow, finer particles are blown into the upper layer (Fig. 6). In that case, feed material fails to undergo stratification according to the density difference. The contour Fig. 8 obtained from ANOVA indicates that the Fig. 9 Interaction effect of Transverse angle and Airflow rate on ash of clean coal at 21 Hz lower deck eccentric with higher airflow rate does not give effective separation, resulting high yield with high ash of about 51%. At deck eccentric of 20 Hz and high air flow rate of 47 rpm, yield recovered is 68% with 45% ash. Figure 8 shows that clean coal below 37% ash level is difficult to achieve in a single stage operation.

Effect of airflow rate and transverse angle
The increase in transverse angle and air flow rate of the deck decides the yield and grade of the clean coal ( Fig. 9a, b). The increased transverse angle results in dominant gravitational force on particle. So flow of the material towards the lower side of the deck increases the ash of lighter fraction (clean coal). The heavier particles possessing high ash bearing minerals also have a tendency to report towards the lower end of the deck. Hence the effective reduction of ash does not occur. When the side tilt is decreased, more material moves towards the higher end of the deck. At air flow rate of 32 rpm and transverse angle of 45 mm, recovered yield is only 2.7% with 25.7% ash. However, with increase of air flow rate to 50 rpm and transverse angle at 60 mm, yield increases to 43.5% with 38.4% ash (condition 2 in Fig. 5). Due to the increase of air flow rate, drag force on the particle increases. According to the second law of thermodynamics, any system will show a tendency to achieve minimum i.e. reduction in free energy. The potential energy of the bed decreases when the bed is dilated. The stratification is a free energy reduction process completed through the redistribution and rearrangement of the particles.

Optimization of operating conditions
The optimization of the process parameters was carried out at different conditions with the help of a model formed by design expert software. From surface plot (Fig. 10) it is found that no significant clean coal could be obtained at 35% ash level. However, when the deck eccentric was reduced from 19.5 to 18.3 Hz and the air flow rate increased to 44 rpm, yield of clean coal increases from 30% to 50% with the increase of ash in clean coal. About 20% yield could be obtained at 35% ash. The organic efficiency is only 35. Figure 10 shows also that at 21 Hz deck eccentric, 50 rpm air flow rate and 60 mm transverse angle, concentrate of 42% with 37.6% ash could be recovered. The yields of clean coal at 35% and 37% ash level obtained from washability study and Air table are compared in Table 6.

Multi stage processing
From Figs. 8 and 9, it was found that clean coal with significant yield at 34%-35% ash level could not be achieved in single stage operation. Therefore, there is a need for two stages cleaning, where all the possible mineral matter associated with coal sample could be rejected in the first stage and the rougher concentrate would be reprocessed in the second stage for recovering the final concentrate. From the experimental values (Fig. 5), it was found that condition 19.5 Hz, 50 mm, 50 rpm for DE-SA-AFR respectively was selected for first stage separation and produces 84.4% yield with 45.6% ash content. The combustible in the reject stream is only 3.7%. The concentrate of first stage was fed to the vibratory deck for second stage cleaning at 20-40-50 (DE-SA-AFR) condition. The overall yield of 48.6% could be achieved with ash of 35.4%. Separation efficiency and organic efficiency are shown in Table 7 and higher separation efficiency was found in second stage. The partition coefficient represents the weight fraction of coal particle report to the reject stream. The value of probable error E could be calculated as (q75 -q25)/2. The coal particles with densities of q25, q50 and q75 have the mass fractions of 25, 50 and 75%, respectively. The q50 represents the deshaling density in the experiment. The E p of the separation process is 0.18 (Fig. 11).

Conclusions
(1) The coal fines having high ash could be processed effectively by air fluidization technique and the combustible matters could be enriched significantly.
(2) Drag force due to air velocity and vibratory motion of the deck eccentric play significant role in segregation and stratification of the particles. Increased air velocity (32-50 rpm) plays important role in reducing the ash in clean coal. (3) Increased deck eccentric had negative effect on the recovery of clean coal yield comparing with other variable parameters. (4) In a single stage processing, ash level could be reduced to 37% with a yield of 42%. However, there is a loss of combustibles in reject stream and organic efficiency of separation is 71.7%. (5) Multistage processing brought a significant improvement in separation. It improves the clean coal yield to 48.6% with 70.8% combustibles and ash content could be reduced from 54.5% to 35%. The organic efficiency increases from 71.7% to 88.6%. The value ParƟiƟon co-efficient (%) Specific gravity Fig. 11 Partition curve of the separation efficiency of probable error of 0.317 is an indicative of a favourable separation performance in a vibratory deck separator. (6) Heat value of clean coal could be increased by three fold (15,690 kJ/kg) of the feed sample. The processed coal sample would be useful for the boiler of thermal power plant and would increase the efficiency.