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A Two-dimensional Covalent Organic Framework for Iodine Adsorption

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Chemical Research in Chinese Universities Aims and scope

Abstract

Radioactive iodine is a notorious pollutant in gas radioactive nuclear waste due to its radiation hazard, volatility, chemical toxicity, and high mobility. Therefore, developing a material with high efficiency-specific iodine capture is significant. Covalent organic framework(COF) has attracted significant attention as a new crystalline porous organic material. Due to its large specific surface and high chemical stability, it is an excellent alternative to adsorbents. Herein, we report a chemically stable two-dimensional COF(termed JUC-609) with specific adsorption of iodine. Adsorption experiments show that JUC-609 has an excellent iodine adsorption capacity as high as 5.9 g/g under 353 K and normal pressure condition, and iodine adsorption after multiple cycles is still maintained. Our study thus promotes the potential application of COFs in the field of environment-related applications.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos.22025504, 21621001, 21390394), the “111” Project of China(Nos. BP0719036, B17020), the China Postdoctoral Science Foundation(Nos. 2020TQ0118, 2020M681034), and the Program for JLU Science and Technology Innovative Research Team.

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Authors and Affiliations

  1. School of Information Engineering, Zhongshan Polytechnic, Zhongshan, 528404, P. R. China

    Jianhui Zhang

  2. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, 130012, P. R. China

    Jianchuan Liu, Yaozu Liu, Yujie Wang, Qianrong Fang & Shilun Qiu

Authors
  1. Jianhui Zhang
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  2. Jianchuan Liu
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  3. Yaozu Liu
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  4. Yujie Wang
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  5. Qianrong Fang
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  6. Shilun Qiu
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Correspondence to Jianhui Zhang or Yujie Wang.

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Cite this article

Zhang, J., Liu, J., Liu, Y. et al. A Two-dimensional Covalent Organic Framework for Iodine Adsorption. Chem. Res. Chin. Univ. 38, 456–460 (2022). https://doi.org/10.1007/s40242-022-1513-3

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  • DOI: https://doi.org/10.1007/s40242-022-1513-3

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