Effect of process parameters and heat treatments on delta-phase precipitation in directed energy deposited alloy 718

This article outlines a detailed study of solution treatments and delta precipitation treatments carried out on laser-directed energy deposited (DED) alloy 718 specimens. Two different sets of DED process parameters were used in high and low energy conditions that yield different microstructural features to study the effect of process parameters on delta precipitation. These two conditions were subjected to solution treatment at 1010 °C and 1050 °C each for 1 h, which improved homogeneity and altered grain texture with introduction of annealing twins. The as-built and solution-treated specimens served as the initial reference condition for subsequent delta processing treatments (DPT) performed at three temperatures of 850 °C, 900 °C, and 950 °C to study the effect of short- and long-term exposures ranging from 1 to 48 h. When as-built specimens were subjected to DPT, interdendritic delta precipitates were observed at Nb-rich regions. In contrast, solution-treated specimens under short-term exposure to DPT resulted in intergranular delta phase precipitates whereas under long-term exposures to DPT yielded predominantly intragranular delta precipitates, which grew denser and longer with increased time of treatment. For longer exposure times of 24 and 48 h, a continuous film of intergranular delta phase was noticed. The morphology, location, and volume fraction of delta phase precipitates studied in this research are imperative for designing the performance of alloy 718 built by DED process.


Introduction
Alloy 718 is a nickel, iron-based superalloy which is primarily used in aerospace, space, petrochemical, and oil and gas industries due to its superior high-temperature properties and corrosion resistance, with service temperatures varying between − 200 and 650 °C. The alloy mainly derives its strength from precipitation of primarily coherent gamma double prime (γʺ-Ni 3 Nb body-centred tetragonal) and gamma prime (γʹ-Ni 3 Al,Ti face-centred cubic) phases, whereas controlled precipitation of delta phase (δ-Ni 3 Nb orthorhombic) is known to induce grain stability in wrought form of alloy 718 [1]. The metastable γʺ-phase transforms into a more stable δ-phase at temperatures exceeding 750 °C [2]. δ-precipitation occurs in alloy 718 between the temperature range of 800 and 1000 °C, and the corresponding thermal treatment designed to achieve δ-phase saturation in the alloy is sometimes called delta processing treatment (DPT) [3]. Based on the location of precipitation, δ-phase can be distinguished as intergranular-or intragranular-δ. Morphologically, intergranular-δ appears as discrete globular or blocky particles, whereas the intragranular-δ appears as acicular precipitates [4]. During long-term precipitation treatment, a continuous long-striped intergranular δ-phase film forms at the grain boundaries (GBs) [5]. Many material properties of importance in aerospace applications, such as tensile strength, creep resistance, fatigue strength, and ductility, depend on precipitation strengthening and grain stability, which in turn is affected by morphology, distribution, and volume fraction (V f ) of δ-phase in alloy 718. Alloy 718 components often undergo repetitive repair and refurbishing activities during their lifetime, which exposes the material to DPT temperatures for longer times than actual heat treatments [6,7]. Therefore, in order to simulate these effects, long-term exposure of material subjected to DPT protocols (up to 48 h) is studied in the present work.
The evolution study of δ-phase by Anderson et al. [8] revealed that the interplay between the amount of inter-and intragranular precipitation of δ-phase can affect formability of alloy 718. Uniaxial tensile testing showed increase in both yield and tensile strength for wrought specimens subjected to solution treatment at 1100 °C/water quenched (WQ), and DPT performed at 900 °C/8 h/WQ as the mode of δ-precipitation was predominantly intergranular [4]. Furthermore, increasing DPT time resulted in loss of strength and ductility, which was attributed to the precipitation of intragranular acicular δ-plates. A research by Kuo et al. [9] claimed that the morphology, amount, and orientation of δ-phase determined the creep and stress-rupture properties of alloy 718.  [10] showed that a minimum of 0.6%wt. δ-phase is needed for alloy 718 to resist notch rupture, when notches are present as features added as a part of basic design or occur during service of components. However, the tensile strength and ductility were not affected when δ-phase is present in low amount (V f = 0.6-1.3%) [11]. The creep life and resistance to crack propagation behavior were both affected by the presence of δ-phase precipitates as per the work performed by Li et al. [12]. The authors argued that intergranular crack propagation is hindered by the presence of globular delta precipitates which form a γʺ/γʹ denuded zone resulting in regions having more plasticity. Low-cycle fatigue properties showed no direct correlation with the amount of δ-phase V f in wrought alloys [13], although the bimodal distribution of grains that resulted due to uneven δ-precipitation decreased the fatigue life. The presence of higher amount of δ-phase resulted in a microstructure of non-recrystallized grains having large V f of δ-phase that decreases the loadbearing capability. In summary, short intergranular δ-phase precipitates have been reported to be beneficial in enhancing the tensile strength, ductility, creep life, stress-rupture, and notch-rupture properties of alloy 718. On the other hand, the intragranular δ-phase enhances the tensile strength but depletes the ductility of alloy 718 and is of no consequence in affecting the fatigue and creep resistance.
The literature reviewed above shows the importance of δ-phase precipitation in alloy 718. However, these studies pertain to alloy 718 manufactured by conventional wrought or forged routes, which is essentially different from additive manufacturing [14,15]. In the present work, laser-directed energy deposited (DED) specimens produced by varying process parameters are subjected to various heat treatment protocols to study their effect on δ-precipitation. Due to the differences in solidification modes of wrought alloys and DED builds, a variation is expected in δ-precipitation in DED builds. The DED builds are shown to have strengths comparable with that of the wrought counterparts but have lower ductility properties [16][17][18]. These studies evaluate standard heat treatment procedures recommended for wrought and forged materials which may not be ideal for DED builds. Therefore, the DPT within the temperature range of 850 and 950 °C for short-and long-term exposures of up to 48 h is considered in this work. The study reveals the differences in precipitation patterns of δ-phase based on DED processing conditions and prior solution treatments through comprehensive microstructural analysis.

Equipment and material
The DED equipment consisted of the deposition head affixed to an ISEL M40 gantry system with a coaxial nozzle (COAX50, Fraunhofer, Germany) arrangement for laser and powder delivery. Diode lasers coupled with ytterbium-doped fiber laser (IPG Photonics, Germany) were used to produce a coherent beam which was collimated and focused (focal lengths of 160 and 200 mm, respectively) onto the substrate. A screw-type dual powder feeder arrangement (Uniquecoat Technologies, USA) was used to feed a plasma atomized alloy 718 powder with an average particle size (D50) of 79 µm and chemical composition as shown in Table 1. Argon served as both carrier gas (5 l/min) and shielding gas (12 l/min) throughout the building process. Duplex steel was used as a substrate, and the dilution region at the bottom (approx. 2 mm) was discarded from analysis due to the

Process parameters
Two different process parameter sets, one with a high heat input and high specific energy and another with low heat input and low specific energy, were utilized in building specimens with an intent to obtain varied microstructures. The basic process parameters along with the energy conditions and capture efficiencies are as shown in Table 2. The laser power (P) was kept constant, whereas the change in speed (v) and feed rates (m) essentially resulted in varied energy conditions. The extent of overlap, which is the percentage of track width enveloped by consecutive tracks as defined by Oliari et al. [19], was varied between the two conditions. As the speed doubled from condition A (A) to condition B (B), the resultant theoretical heat input (P/v) halved from 96 J/ mm in A to 48 J/mm in B. Furthermore, the feed rate in B was higher, and, hence, the specific energy (P/m) in B was lower compared to A. These two conditions were chosen from an array of other parameters used for preliminary evaluation as they showed an aspect ratio (ratio of bead width to bead height) of 2-2.5 and capture efficiencies (> 65%). DED builds measuring 15 × 20 × 700 mm 3 were built which were, in turn, used to extract specimens measuring 15 × 20 × 5 mm 3 for studying effects of various heat treatment protocols. The dwell time between each pass was maintained at 5 s to keep the inter-pass temperature below 100 °C, which did not exceed even for the topmost layer. The substrates were allowed to cooldown to room temperature between successive layers. The specimens from various sections of the build were analyzed using optical microscope and scanning electron microscopes to check for microstructural differences. The results showed no major changes in terms of grain size and V f of Nb-rich phases (Laves + carbides).

Heat treatment
The as-built specimens (AB) from DED process in A and B were subjected to heat treatments in a box-type furnace which was calibrated for various temperatures and times used in the protocols. Two different solutionizing treatments of 1010 °C (ST1010) and 1050 °C (ST1050) for 1 h followed by air cooling were performed. Furthermore, the AB, ST1010, and ST1050 specimens were subjected to DPT at three different temperatures: 850 °C, 900 °C, and 950 °C for varied dwell times of 1 h, 8 h, 24 h, and 48 h followed by air cooling. Each of the 6 starting conditions was subjected to 12 different DPT protocols which resulted in 72 different conditions.

Metallography and image analysis
The AB-and heat-treated specimens were mounted using a Bakelite compound, ground and polished with successive steps of finer grit papers and suspensions. The specimens were etched electrolytically using a 10% oxalic acid solution at 2 V, 2 A/cm 2 for 15-18 s. Furthermore, the specimens were characterized using a light optical microscope (LOM) and a scanning electron microscope (SEM). The SEM images were characterized at a working distance (WD) of 7.5-8 mm with an accelerating voltage of 5-10 kV. Electron backscatter diffraction (EBSD) analysis was performed at a higher voltage of 20 kV at a WD of 12-14.5 mm on specimens that were mechanically polished using a vibratory polisher. AZtecCrystal 2.0 was used for processing EBSD data and to analyze grain data. The grain sizes are expressed in terms of ASTM grain number (G) in accordance with ASTM E112 standard [20]. The LOM and SEM images were analyzed using ImageJ software V1.53c. A minimum of 50 dendrite colonies were analyzed to measure the arm spacing. For analyses of V f of Nb-rich and δ-phases, a minimum of 8 fields under 2 different magnifications (3000 × and 5000 ×) were considered. The average δ-precipitate length was taken from measuring at least 50 δ-plates from 6 different fields so that the variation is accurately depicted.

As-built microstructure
The microstructure of AB deposits at high and low energy conditions (see Table 2) is as shown in Fig. 1a and b. The specimens in AB condition predominantly show columnar-dendritic microstructure, typical of DED builds. The different processing conditions result in varied microstructural features such as secondary dendritic arm spacing (λ 2 ) and grain size. The measured values of λ 2 in AB-A and AB-B specimens are 2.55 ± 0.35 and 1.82 ± 0.08 µm, respectively. The cooling rate (T) is related to secondary dendritic arm spacing through a relationship, λ 2 = aṪ− n , where a and n are material-specific constants [21,22]. Based on the works of Patel et al. [23] and Nie et al. [24], the values of a and n for alloy 718 are 32 and 0.31, respectively. Cooling rates of 3500 °C/s and to 10,500 °C/s are obtained for AB-A and AB-B, which shows that high-energy input results in relatively low cooling rate. Consequently, AB-A specimens had relatively larger grain size corresponding to ASTM G4.7 compared to ASTM G6 in case of AB-B, as evident from EBSD analysis further elaborated in Sect. 3.3.
The SEM analysis of AB-A and AB-B specimens as seen in Fig. 1c and d shows the presence of Nb-rich phases (bright particles -Laves and NbC) in the interdendritic region and MC type carbides (dark particles -TiC/TiN) in dendrites and dendritic cores regions, as confirmed by earlier research of DED built specimens [25,26]. The amount of Nb-rich phases is of primary importance as this can affect the precipitation of γʺ and δ phases upon aging treatments [27]. The V f of Nb-rich phases in AB-A is 2.87% compared to 1.9% in AB-B, indicating the influence of cooling rates on segregation behavior of L-DED processed alloy 718. A similar conclusion on increase in Laves phase with increase in processing energy conditions was reached by other researchers [28,29]. The cooling rate also influences the average size of Nb-rich precipitates in AB-A and AB-B which are 0.38 µm 2 and 0.18 µm 2 , respectively. A SEM micrograph with 5000 × magnification consisted of 54 and 79 particles in AB-A and AB-B with an average length between nearestneighbor particles measuring 7.2 µm and 4.5 µm, respectively, which is a further confirmation of varied distribution of precipitates as a consequence of processing conditions. In a research performed by Chen et al. [30], laser beam having varied energy distribution was used to produce DED specimens with higher V f of long-striped, fine Nb-rich precipitates and lower V f of discrete, coarse Nb-rich precipitates. The specimen with discrete, coarse precipitates showed higher tensile strength compared to the one with fine particles, although both specimens showed similar ductility. Chen et al. attributed the higher V f of long-striped, fine precipitation of Laves phase as the reason for loss of strength in the material. The study also shows the importance of morphology, distribution, and amount of precipitation on properties of alloy 718.

Effect of solution treatment
Specimens from AB condition were subjected to solution heat treatments in order to minimize inhomogeneities caused by the segregation of Nb-rich phases. A total of 1010 °C and 1050 °C are chosen as solutionizing temperatures as they correspond to delta solvus and stress-relieving temperatures for alloy 718 [31]. A better homogenization is achieved in ST1050 condition compared to ST1010 as the mobility of Nb atoms increases with temperature, accompanied by GB migration which results in increased grain size.
As seen in Fig. 2a and b, the solidification substructures such as dendrites are legible in specimens that undergo ST1010, whereas specimens that undergo ST1050 show annealing twins indicative of recrystallization. The grain sizes in AB-A and AB-B are ASTM 4.7 and 6, respectively. In AB-A, there is no indication of grain growth when subjected to ST1010, whereas considerable grain growth is noticed when subjected to ST1050. A relatively fine-grained AB-B shows grain growth under both ST1010 and ST1050 conditions. The larger grains grow at the expense of smaller grains during grain growth due to GB diffusion [32]. Therefore, the fine-grained AB-B specimens show higher amount of grain growth compared to AB-A condition.

EBSD analysis
The EBSD analysis that shows variations in grain morphology and texture, depending on the DED process and solution treatment conditions, is tabulated in Table 3. The AB specimens show a steady increase in grain size when subjected to ST1010 and ST1050 treatments except for AB-A specimen subjected to ST1010 as seen in the IPF textural maps in Fig. 3. The small-angle grain boundaries (SAGBs) made of dislocations networks get annihilated upon heat treatment, and, therefore, the %SAGBs gradually reduce from about  39% in AB-A condition to 20% and 2% when subjected to ST1010 and ST1050 treatments, respectively. A similar trend is found in AB-B in which the initial %SAGB of 29% is reduced to 17% and 14% upon ST1010 and ST1050 treatments. The strain in the specimens due to processing condition, especially the energy input and extent of overlap, plays an important role in governing the initial amount of SAGBs in the DED builds and, in turn, the formation of annealing twins upon heat treatments as indicated by Cao et al. [33]. ST1050 treatment generally used for stress relieving shows a higher rate of recrystallization indicated by percentage of grains twinned, which is 68% in case of AB-A compared to 39% in AB-B. As AB-A displays higher degree of recrystallization, more SAGBs participate in the formation of twin boundaries compared to AB-B specimens which have a 14% SAGBs at the termination of ST1050 treatment. A study performed by Li et al. [34] showed that increase in deformation from 30 to 70% resulted in increased twin boundaries in alloy 718, indicating the effect of strain on recrystallization. Also, the fraction recrystallization increased from 24 to 50% on increasing the solution treatment temperature from 1000 to 1040 °C, with greater extent of twinning noted at higher temperature corroborating results observed in this research. The (001) pole figures for specimens in AB condition show a strong textural orientation in < 101 > direction. Specimens subjected to ST1010 condition show a relatively weaker texture compared to AB conditions, having a preferred orientation of < 001 > along the build axis.
A random orientation is found in specimens subjected to ST1050 with (100) pole figure indicating a very weak texture in < 111 > and < 101 > directions. Twinning is found to introduce a more random texture with less elongated grains in the specimens indicated by the average aspect ratio changes from 2.7 to 1.9 in case A and from 3.2 to 2.7 in case B when subjected to ST1050. A study by Smith et al. [35] showed the microstructure of as-produced direct metal laser sintered (DMLS) specimen showed a strong texture in < 100 > direction built horizontally, vertically, and diagonally to the built plate. However, upon post-processing through hot isostatic pressing treatment, all the specimens showed random texture with recrystallized microstructure. Formation of annealing twins is noted in specimens subjected to solution treatment, and prior reports have shown these to be beneficial in enhancing material properties both in terms of strength and ductility of material [36].

Effect of delta processing treatments on as-built specimens
AB specimens subjected to direct DPT show precipitation of intragranular δ-phase predominantly in interdendritic region accompanied by fair amounts of Laves phase as shown in Fig. 4a-d. In DED builds, Nb preferably partitions into interdendritic region during solidification leading to Nb-rich segregates, which is a preferable site for δ-precipitation [26,37]. Interfacial strain energy due to lattice misfit between matrix and an incoherent phase (either Laves or δ-phase) leads to increase in dislocation density as mentioned by Mahadevan et al. [2] in their research, which results in precipitation of δ-phase in interdendritic regions. The material in AB condition showed variations in grain size, segregation, and Nb-rich phase distribution due to different processing conditions as discussed in Sect. 3.1. Post DPT, the specimens in A and B conditions show minor differences in %V f and average length of δ-precipitates as shown in Fig. 5. Upon DPT, the Laves phase tend to solutionize as the temperatures are high enough for diffusion of Nb. Longer exposure times lead to better dissolution of Nb-rich phases, irrespective of AB specimen condition which effects similar precipitation morphology and phase fraction upon DPT protocols. Although the Laves phase were excluded during ImageJ analysis based on the appearance, thickness, and sphericity factors, an error of ± 0.6% is expected in estimating V f of δ-phase for AB conditions based on the metallographic preparations and filters applied when performing image analysis.
For AB specimens subjected to shorter time DPT of 1 h (Fig. 4a), the V f (0.5-3%) and the average length of δ-precipitates are quite small (0.5-1.5 µm) as seen in Fig. 5a-d (indicated by circle motifs) compared to solutiontreated conditions. When the time of treatment increases from 1 to 8 h, intergranular δ-precipitates are formed at the GBs (indicated by red arrows in Fig. 4b). This might be the result of dissolution of Nb-rich phase such as Laves (marked by yellow arrows in Fig. 4a, b, and d) during longtime exposures. Similar results of Laves dissolution have been reported for laser-DED [26] and laser welding [38] processes. Morphologically, the intergranular δ-phase appears as thicker and shorter globular, blocky, or plate-like precipitates (indicated by red arrows in Fig. 4b) compared to acicular intragranular δ-phase [2]. A grouping of data points is observed in 950 °C DPT for V f of around 4%, which shows saturation of δ-phase precipitation, thereby rendering longtime treatments ineffective. However, subtle changes in morphology are noticed. A similar observation of grouping can be made for 900 °C DPT for longer exposure times of 8, 24, and 48 h for a V f of about 10%, which is indicative of an equilibrium volume fraction of δ-phase being reached under these DPT conditions. The study of δ-phase precipitation in different forms of forged alloys Azadian et al. [39] showed similar treatment times (long-term exposure) to reach equilibrium phase fraction. The average length of the δ-precipitates (2.5-3.5 µm) in AB + DPT condition does not vary much for treatment times of 8, 24, and 48 h, although an increase in V f of δ-phase indicates an increase in density of precipitates and appearance of plate-like intragranular-δ at higher temperatures and treatment times. The scatter in data for length of δ-precipitates vs. DPT for long exposure times as shown in Fig. 5c and d is due to the nucleation and growth of δ-precipitates at different junctures of time during treatment. This observation is similar to delta precipitation sequence in wrought materials as reported by Azadian et al. [39] and Anderson et al. [8]. Moreover, only subtle changes exist in V f of δ-precipitates in AB-A and AB-B specimens subjected to DPT, and the length scales almost appear the same for both conditions. Kuo et al. [40] showed that the tensile strength and ductility properties of DMLS alloy 718 specimens were a function of build direction when subjected to delta precipitation treatment and aging (DPT + A) as well as direct aging (DA) conditions. The horizontally built DT + A specimens showed least ductility as the δ-phase precipitates had a preferred orientation perpendicular to the loading direction. The loss of ductility can be attributed to the presence of Laves phase along with δ-precipitates as discussed by [41]. The Laves phase precipitates lead to the formation of micro-voids under loading, and the Nb-denuded zones in the vicinity of δ-phase can lead to debonding resulting in the loss of ductility. The effect of varied volume fraction of interdendritic δ-precipitates on mechanical properties of alloy 718 needs further investigation, although higher amounts of δ-precipitation are found to have negative effects on ductility properties [13].

Effect of DPT on as-built specimens subjected to solution treatment at 1010 °C/1 h
When the AB specimens are subjected to an intermediate solution treatment before DPT, noticeable change occurs in the precipitation pattern as shown for AB-A specimens in Fig. 6a-d. The precipitation changes from predominantly interdendritic-δ in AB + DPT to intergranular δ-phase (Fig. 6a) for short-term aging of 1 h in AB + ST1010 + DPT treatment. As the dendritic boundaries are solutionized, a Nb-saturated gamma matrix is formed. This results in longer δ-precipitates compared to AB + DPT for exposure times of 8 h and more as seen in Fig. 7a-d. However, for longer times of exposure, intragranular δ-precipitates outnumber the amount of intergranular δ-phase, similar to the research findings of Anderson et al. [8]. Noticeably, the length of the δ-precipitates increases with time between 1 and 24 h, and no appreciable changes can be seen between 24 and 48 h for both A and B specimens. Similar to AB + DPT, for The tensile strength and ductility properties of specimens subjected to DPT protocols between the temperature range of 875 and 975 °C showed no correlation with the V f of δ-precipitation [8], although the temperature of treatment dictated the strength and ductility property of alloy 718, where the higher temperature of treatment corresponded with better ductility but reduced tensile and yield strengths. The specimens subjected to DPT at 875 °C/0.5 h having about 1% V f of δ-phase showed better strength compared to specimens that are subjected to DPT at 900 °C/24 h (16% V f of δ-phase), attributable to the presence of γʺ-precipitates at 875 °C.

Effect of DPT on as-built specimens subjected to solution treatment at 1050 °C/1 h
Upon subjecting AB specimens to ST1050 and DPT protocols, intergranular δ-phase is precipitated at the GBs for short-term exposure (1 h) as seen in Fig. 8a, which is similar to AB + ST1010 + DPT protocol discussed in Sect. 3.4.2 Fig. 7 Analysis of δ-phase volume fraction in specimen a A, b B; and δ-precipitate length in specimen c A, d B; subjected to ST1010 and DPT protocols (Fig. 6a). For long-term exposures (8-48 h), predominantly intragranular δ-phase precipitates are noticeable ( Fig. 8b-d) along with long-striped intergranular-δ. The δ-phase precipitates have the highest average length in AB + ST1050 + DPT condition ( Fig. 9c and d) compared to AB + DPT and AB + ST1010 + DPT protocols. ST1050 offers better homogenization compared to ST1010 condition, as reflected in the lower number of Nb-rich precipitates which act as sites for δ-phase precipitation. This minimizes the density of intragranular δ-phase precipitates in ST1050 condition subjected to DPT protocols. The δ-phase precipitates, although fewer, tend to grow longer which influences the total V f of δ-phase in AB + ST1050 + DPT condition ( Fig. 9a and b). Upon solution treatment, the specimens undergo changes in terms of crystallography and microstructure. The elimination of dendritic substructures on solution treatment of AB specimen changes the interdendritic precipitation morphology of δ-phase upon DPT. The saturation of Nb on solution treatment [26] promotes formation of intergranular δ-phase at the GBs which are defects and offers nucleation sites for δ-precipitation [2]. The shearing of δ-precipitates as described by Mahadevan et al. [2] was noticed in solutiontreated specimens undergoing DPT treatments as seen in Fig. 6 and Fig. 8. The precipitation pattern upon solution treatment and DPT of DED specimens resembles that of wrought alloys [8,39]. The number of precipitates per unit area in specimens undergoing ST1050 treatment appears to be lower compared to ST1010 specimens upon DPT. The number of nucleation sites, directly related to the number of defects and Nb-rich precipitates, is lower in case of ST1050 condition compared to ST1010 condition, thereby minimizing the number of intragranular δ-precipitates.

Influence of δ-phase morphology
The performance of alloy 718 depends on the variation in morphology of δ-phase under different treatment conditions. The intergranular δ-precipitation noticed on short-term DPT of solution-treated specimens is known to have beneficial effects on tensile strength, ductility, and stressrupture properties [13,42]. Fatigue strength and resistance to creep are shown to be unaffected by intragranular δ-precipitation obtained by long-term exposure (8-48 h) under DPT conditions [13]; however, the material ductility is affected adversely. Due to a poor misfit between the matrix and δ-precipitates, the intragranular delta provides sites for void nucleation and crack propagation. Also, the fragmentation and coalescence of micro-voids are shown to affect the material ductility upon subjecting material to DPT [41]. Contrarily, a weldability analysis performed through thermomechanical simulation shows that grain size is the main cause of decrease in ductility in alloy 718 specimens having varied amount of δ-phase precipitates upon subjecting the material to high temperatures. The researchers subjected wrought form of alloy 718 to varied solution treatment and DPT protocols with heating-cooling rates of 111 °C/s and 50 °C/s, respectively. The specimen subjected to 954 °C/15 h treatment which had the highest amount of δ-phase showed better ductility compared to other counterparts as per the study of Andersson et al. [43]. However, Fig. 9 Analysis of δ-phase volume fraction in specimen a A, b B; and δ-precipitate length in specimen c A, d B; subjected to ST1050 and DPT protocols specimen subjected to 1050 °C/3 h + 954 °C/1 h treatment which evidently showed no δ-precipitation which leads to grain growth and thereby proved to be least ductile material. Therefore, long-term exposure of alloy 718 to DPT temperatures during repair activities might call for reconditioning of the material to eliminate the excess amounts of intragranular δ-phase.

Conclusions
The effect of heat treatments on δ-precipitation characteristics for DED specimens is studied in this article. The conditions for varied δ-morphologies are revealed, and an effort is made to correlate the properties that can be expected in different scenarios of δ-precipitation. A few salient features of this study are as follows: 1. The initial as-built condition had varied microstructural features due to the processing conditions, including differences in grain size and segregation behavior. However, these variations had little effect on precipitation of δ-phase as both specimens with different DED conditions showed similar volume fractions and lengths of interdendritic δ-phase precipitation when subjected to direct delta processing treatment.

An intermediate solution treatment performed either at
1010 °C or at 1050 °C resulted in dissolution of most of the Nb-rich precipitates and induced grain growth in the material. Furthermore, the grains recrystallized more notably at the higher solution treatment temperature of 1050 °C. 3. Specimens subjected to solution treatment and delta processing treatment for short-term exposures showed low volume fractions of intergranular δ-phase precipitates. For long-term exposures, intragranular δ-precipitates were predominantly seen for specimens solution treated at 1010 °C, and both inter-and intragranular δ-precipitates were formed for specimens solution treated at 1050 °C. 4. The length scale of δ-precipitates was highest in case of specimens solution treated at 1050 °C followed by 1010 °C solution treatment, while as-built condition showed the shortest δ-precipitates. Intergranular precipitation of long-striped δ-plates was noted on long-term exposure of delta processed specimens solution treated at 1050 °C