Effect of different variants of filler metal S Ni 6625 on properties and microstructure by additive layer manufactured using CMT process

The influence of arc energy and different filler metal composition on the mechanical properties and macro- and microstructure of additively welded thin-walled structures of Ni-based alloy were investigated using four different variants commercially available solid wire electrodes of type S Ni 6625. As the welding process, the Cold Metal Transfer (CMT) process was used. The heat input and cooling rate were varied by adjusting wire feed and travel speed. The results show that an increase in arc energy leads to longer t10/6 cooling times. This leads to an increase in the dendrite arm spacing and thus to a reduction in the strength values and hardness of the thin-walled structures. The higher Fe-containing variant of S Ni 6625 produces the highest strength and hardness values, while the W-alloyed solid wire electrode produces the lowest values. The porosity in the walled structures was very low, and unacceptable weld defects, hot cracks and lack of fusion did not occur. Segregations occur in all weld metal specimens. While niobium, molybdenum and titanium are the preferred segregations in the Nb-alloyed Ni 6625 type weld metal, only Mo is present in the W-alloyed Ni 6660 type weld metal.


Introduction
Alloy 625 (NiCr22Mo9Nb, material no. 2.4856) is a nickelchromium-molybdenum-niobium alloy, which has excellent corrosion resistance to a wide range of corrosive media. As the alloy was already developed and patented at the end of the 50s [1], a great deal of experience is available regarding the weldability and welding possibilities of this alloy. The alloy is used for both joint welding and cladding of carbon steels in a wide range of industrial sectors, such as aeronautical, aerospace, chemical, petrochemical and marine industries [2,3]. The semi-finished products of Alloy 625 are manufactured in two grades of different heat-treated conditions. Grade 1 (C ≤ 0.03 wt% and annealed at 950-1050°C) is normally applied for wet corrosion applications and service temperatures up to 600°C. In contrast, grade 2 (C ≤ 0.10 wt% and solution annealed at 1080-1160°C) is employed for high-temperature applications and at service temperatures above 600°C [4]. The similar solid wire electrode S Ni 6625 with a C content of max. 0.10 wt% and max. 5.0 wt% Fe is available for both variants (see Table 1).
In the past, however, the Fe content of the filler metal has been steadily reduced to below 1.0 wt%, as it is mainly used for cladding [7], although customer specifications often only require Fe limits of 5 wt%.
Since this material is used in a wide range of industrial applications, it is also of great interest for additive manufacturing. As is well known, additive manufacturing with wirebased arc processes offers the possibility of producing small and large-volume components of low and medium complexity at high assembly rates. A disadvantage is the poorer surface quality and accuracy and thus the need for mechanical finishing of functional surfaces [8,9]. In a survey conducted by various German companies, the most important requirement for additive welding was the guarantee of the property profile of the manufactured components according to the operating stresses, followed by process time, component volume, dimensional accuracy and rework. This property profile depends strongly on the material and welding regime [10].
Direct energy deposition processes with arc (DED-arc) for additive layer manufacturing (ALM) with Ni-based solid wires is typically performed by plasma arc welding (PAW), tungsten arc welding (GTAW) and gas metal arc welding (GMAW) processes. The cold metal transfer (CMT) process is a variant of GMAW, which are widely used industrially for cladding with S Ni 6625 [2,[11][12][13]. This is due to the very low dilution with substrate, high deposition rate, very low heat input, less spatter and low susceptibility to hot cracking [14]. Factors are also advantageous for the ALM.
The focus of investigations on Alloy 625 during the manufacture of different structures (thin wall square, round, konus and compact block) in as-deposited and heat-treated conditions is the influence of the process technology mentioned and the associated heat input on macro-and microstructure, formation of intermetallic phases (e.g., Laves phase) and seam irregularities (e.g., hot cracks and pores) and mechanical properties (tensile test by room temperature, hardness) in travel or build direction [15][16][17][18][19][20][21][22]. Current studies are concerned also with the influence of the additive generated microstructure on corrosion resistance [23,24]. It was also shown that the presence of Laves and other intermetallic phases in the Inconel 625 deposit accelerated the localised corrosion rate and pitting corrosion under high-temperature and highpressure (HTHP) H 2 S/CO 2 conditions [23]. Table 2 summarises the results with respect to the mechanical properties of the ALM structures at room temperature in the as-deposited state of alloy 625. Similar to cladding with Alloy 625, strong accumulations of the elements Nb and Mo in the interdendritic regions of the weld metal are reported, which promotes the formation of Laves phase and mixed carbides. The morphology and the content of Laves phase depend on the temperature gradient and the cooling rate during solidification [25].
The paper informs about the effects of different energy input on cooling times, seam irregularities, chemical composition, mechanical properties and microstructure CMT welded thin-walled wall structures of wire electrodes of the type S Ni 6625 and S Ni 6660. In addition to the standard variant of this filler metal, the influence of two further variants of S Ni 6625, which have been specially developed for additive manufacturing, is discussed. While one variant has an increased Fe content of approx. 4 wt%, the other variant is said to have a higher degree of purity. In chemical analysis, the welding filler S Ni 6660 is basically similar to the welding filler S Ni 6625. However, here, the element niobium is substituted by tungsten (Table 1).
2 Experimental procedure

Methods for characterisation of the wire electrodes
To determine the exact chemical composition, the wire electrodes were melted into buttons with the Arc Melter MAM-1 (Edmund Bühler GmbH) in pure argon atmosphere (99.996 %) using a TIG arc. The methodology is described in [26]. After mechanical grinding, optical emission spectrometry (OES) on SPECTROLAB (SPECTRO Analytical Instruments GmbH) was performed on the buttons. In addition, the contents for oxygen, nitrogen, hydrogen, carbon and sulphur were measured by means of carrier gas melt extraction (CGME) on the G8 GALILEO ONH and on the G4 ICARUS Series 2 (Bruker) directly on the sample material of the wire electrodes in the delivery condition. Afterwards, measurements of the wire diameter, the surface roughness (axial) with the tactile cut method [27], and tensile tests were carried out.

Methods for assessment of welding process behaviour and cooling time
CMT welding was carried out on two different welding stands using the Fronius CMT 4000 Advanced and Fronius TPS 2700 CMT welding power sources with the respective RCU 5000 control unit. Accompanying the welds, the electrical welding parameters, the shielding gas flow and the wire feed speed were recorded. While the sampling rate in the welding power source is fixed at 1 kH, the external measuring system WeldAnalyst-S2 (HKS Prozesstechnik GmbH) was used to measure of electrical welding parameters at a sampling rate of max. 25.6 kHz. Alloy 625 with dimensions of 250 mm × 150 mm × 5 or 10 mm (length × width × thickness) was used as a substrate sheet. The production of the wall structures was done in a 1-welding bead/layer-technique. The welding direction was changed after each layer (Fig. 1). A mixed gas consisting of 30 % He, 2 % H 2 , 0.05 % CO 2 , and rest Ar was used as shielding gas. There was no brushing between the layers. The contact tip was changed after each bar. To vary the deposition rate and heat input, the wire feed and welding speeds were varied as a function of the wire diameter (see Table 3). The wire feed rate was varied between 6.0, 7.5 and 9.0 m/min for 1.2 mm wire diameter and between 9.0 and 11.0 mm for 1.0 mm wire diameter. For each wire feed speed, the welding speed was used between 10, 13 and 17 mm/s (for Ø 1.2 mm) and 7, 10 and 13 mm/s (for Ø 1.0 mm). The CMT welds were performed in synergic mode with different welding programmes to ensure high arc stability. Both codes ensure this but result in small differences in the arithmetic mean values of current and voltage and consequently of heat input. During the welding process, non-contact temperature measurements were carried out on selected welds using infrared pyrometers of two different types: the 1-channel IR pyrometer from Micro Epsilon CTLM-2HCF4-C3 (385-1600°C) and the 2-channel IR pyrometer Metis M311/M322 (350-1300°C ) from Sensotherm. For the 1-channel pyrometer, it was necessary to determine the emissivity for the basic conditions during welding. This was done by comparative measurements of the pyrometer with a type K thermocouple on a previously manufactured bar of each filler metal. The welded bar was heated with a gas flame and then cooled down. The emissivity was then adjusted until the T-t curves of both measuring devices were almost congruent (see Fig. 2). When using the S Ni 6625 AM2, an emissivity of 0.75 was determined, whereas the emissivity of S Ni 6660 was 0.85.

Methods for non-destructive and destructive testing
The finished wall structures have been subjected to a visual and dye penetration test. Subsequently, the samples were taken for further tests (see Fig. 3). First of all, a radiographic inspection was realised with the Eresco MF3 (GE S&IT) Xray system of the General Electric Company. For this purpose, the central wall structure area has been mechanically processed, since the surface waviness of the wall structures makes it difficult to evaluate the X-ray images. This procedure achieves an image quality indicator of 16 acc. to [28].
OES was performed in the upper part of the bar on the surface of the milled bar. Then took place the removal of the two tensile samples in the welding direction, one cross (Y-Z plane) and one plane (Y-X plane) section each for macro-and microstructure investigations and samples for carrier gas melt extraction (CGME). The thickness of the flat tensile specimens and the initial gauge length for the elongation at break varied as a function of the wall structure width. The tensile specimens were tested at a test speed of 10 mm/min on the Z250 testing machine (Zwick). On the Y-X plane sections, investigations were carried out on the primary dendrite arm spacing (PDAS) with 5 measurements each and on the segregation behaviour. The cross-sections were divided for preparation reasons. They were used to determine the bar dimensions and final contour proximity, the macro hardness, as well as the microstructure.
The macro-hardness was measured as HV 10 (1 kg load for a dwell time of 15 s). The measurements were carried out from bottom to top (along straight line) either manually with the manual hardness tester DIA Testor 2 Rc (Otto-Wolpert Werke GmbH) or automatically (one hardness impression per layer) with the fully automatic hardness tester Q60 A/A+ (Qness GmbH). The preparation of the metallographic samples was carried out with grinding using silicon paper with several granulometries, followed by mechanical polishing using diamond paste with 3 μm and end polishing with O.P.S (SiO 2 ) with 0.5 μm. To reveal the macro-and microstructure of the walls, colour etching acc. Beraha III and electrolytic etching

Characterisation of the wire electrodes
The chemical composition of the wire electrodes (see Table 4) is within the normative specifications (see Table 1) and show no divergences. The AM1 variant of S Ni 6625 has an Fe content of 4.81 wt%, while the standard and AM2 variants only contain 0.23, respectively, 0.20 wt% Fe. Furthermore, S Ni 6625 AM2 has slightly lower contents of Nb and Si and a smaller C/Nb ratio than comparable wire electrodes. From a material point of view, both the C/Nb ratio and the Si content influence which secondary phases are formed during solidification [29]. While a high C/Nb ratio favours the formation of NbC carbides, low values lead to the exclusive formation of Laves phase. For average values, both phases can occur side by side. High Si contents favour the formation of the Laves phase. In the literature, the exclusive formation of a Laves phase is reported at values of C/Nb = 0.003 and Si contents of at least 0.36 wt% [30]. Both Laves phase and MC carbide are observed at C/Nb = 0.01 and Si contents of 0.46 wt% [31]. At lower values of Si content and higher C/Nb  [32][33][34].
The welding filler S Ni 6660 has no niobium, the lowest C content and the highest S and N contents. The calculation of the pitting resistance equivalent (PREN) on the basis of the given chemical composition shows that S Ni 6600 achieves the highest value due to the W-content. The differences in the Nb-containing variants of S Ni 6625 are only slight.
One of the basic requirements of a trouble-free gas-metal arc welding process is a permanently uniform feed of the wire electrode, even with hose packages of different lengths. The main factors influencing this are the surface condition of the wire electrode (roughness, roundness and foreign matter deposits), mechanical properties (tensile strength and buckling stiffness) and also technological characteristics (cross-sectional tolerances and pre-bending). For application reasons, the wire electrode for gas-metal arc welding should have a high tensile strength with sufficient elongation at break to ensure high buckling stiffness even in long hose packages [35,36]. This is also given for all wire electrodes. Nevertheless, the standard variant has the highest tensile strength and lowest elongation at break, while the AM2 variant has the lowest strength and highest elongation at break (see Table 5). For the sliding behaviour in long hose assemblies, the basic rule is that with lower average roughness and greater pre-bending, the sliding ability of wire electrodes in the hose assembly increases [37]. S Ni 6625 AM2 and S Ni 6660 have the lowest average roughness values, which also correlate with the appearance of the wire electrode surfaces (matt/bright). Despite the different properties and characteristics, no significant   Table 3 shows the mean values of the arithmetic averages of the individual weld layers of each bar. In function of wire feed and welding speed, the values for the heat input varied between 0.10 and 0.46 kJ/mm. The standard deviations for welding current and voltage have been calculated for the arithmetic mean values of the bars, which were calculated from the individual arithmetic mean values of each welding position of a bar (Fig. 4). Higher values in the standard deviations generally mean a slightly more unsteady process behaviour. Nevertheless, the droplet separation of the tough Ni melt can be controlled very well by the CMT process principle, and a sufficiently stable, low-spatter welding process can be achieved overall. It should also be noted that there were sometimes deviations of up to 28 % between the set and measured wire feed speed (Fig. 5). This is due to the fact that the used characteristic curves are created for defined boundary conditions (contact tip to work distance, material, shielding gas and welding position). Due to the deviating boundary conditions of the additive wall structure welds, there is, amongst other things, an internal control of the frequency of the wire backward movement and thus the wire feed speed.

Welding process behaviour and cooling time
IR pyrometers were used to measure the temperatures directly on the seam surface for every second layer at the wall structures of two wire electrodes during welding as a function of time. Since there is no specific temperature interval for the cooling time for Ni-based materials, this was calculated for cooling from 1000°C to 600°C. In this temperature range, the precipitation of secondary phases takes place in many Nibased alloys. Figure 6 shows the determined cooling times as a function of welding position and heat input. Due to the faster heat conduction in the first layers, shorter cooling times occur here.
From about the 10th layer, the 3D heat dissipation changes to a 2D heat dissipation, which is why the cooling time remains almost constant. The fluctuations can result from slight differences in the interlayer temperature, which also influences the cooling time. Figure 7 gives the arithmetic mean values of the t 10/6 cooling times from the 10 th position. As expected, the cooling times increase with increasing heat input. With the S Ni 6660, they reach a value of approx. 21 s at the highest heat input of 0.46 kJ/mm.

Non-destructive testing
The penetration test on the manufactured wall structures resulted in some indications independent of wire feed and welding speed (see Fig. 8). The appearance of the indications suggested surface pores. On the basis of the cross-sections, however, the indicators were classified as micro blowholes that can reach the surface. These micro blowholes, which are understood to be a spongelike or microporous structure, are preferably visible in the last welded layer (Fig. 9). Initially, it is assumed that the cause is a slight geometry-related lateral run-off of the melt. During solidification, the shrinkage of the Ni melt cannot be compensated and micro-pits are formed. In principle, this also occurs in the lower layers, but here, the micro blowholes are melted again by welding the next layer.
The radiographic examination revealed only a few small pores and no binding defects. The porosity, calculated according to equation 2, was below 0.001 % for all wall structures and filler metals.
3.4 Macrostructure of the welded walls

Macro hardness of the wall structures
Macro hardness was measured from sample deposited at deposited to top along vertical section. Figure 12, top left shows the average values calculated from 10 individual values depending on the filler metal used, independent of the setting values. The wall structures of the higher Fe alloyed wire electrode S Ni 6625 AM1 achieve the highest hardness. The hardness of the wall structures of the alloy-similar weld filler metals S 6625 and 6625 AM2 is lower and at a similar level. The weld metal of S Ni 6660 is the softest. No significant influence of the bare height on the hardness can be seen. The measurements were carried out exemplary for the wall structures with the highest heat input with one hardness impression per layer. In contrast, however, a slight increase in the average hardness of all wire electrodes was observed with increasing heat input (Fig. 12, bottom left). In comparison to the soft-annealed base material 244±6 HV10, all weld metals are slightly softer. Table 6 and Fig. 13 compare the determined mechanical properties of the different wall structures. These are average values from two tensile samples each. As expected, the wall structures of the higher Fe-containing weld filler metal S Ni 6625 AM1 achieve on average the highest tensile strength and yield tensile strength (R p0,2 ) as well as the lowest elongation at break. The lowest strengths are shown by the wall structures of the W-containing S Ni 6660. The chemically comparable S Ni 6625 AM1 has significantly lower tensile strength values and a comparable yield tensile strength (R p0,2 ) compared to a soft-annealed 5 mm thick sheet of Ni 6625.

Mechanical properties
In Ref. [17], wall structures manufactured for GTAWs with the same build-up strategy from S Ni 6625 with average tensile strengths of 722±17 MPa and 42.3±2.4 % for elongation at break are given (see Table 1). As the values for welding voltage or welding speed are not given, the heat input cannot be calculated. A direct comparison is therefore not possible.
In addition, it was observed in our own investigations that the strength values of all wire electrodes decrease slightly with increasing heat input (Fig. 14). A slight increase in elongation at break can be seen in the Ni 6625 weld metal type. This is attributed to the increase in the primary dendrite arm spacing (see Fig. 17 under point 3.8.). For example, in laser cladding samples made of S Ni 7718, it was found that a larger PDAS increases the proportion of segregation-induced brittle phases, which leads to lower strength values [38].

Chemical analysis
Since a schielding gas with low active and reducing gas components (0.05 % CO 2 and 2 % H 2 ) was used and no brushing between the individual layers took place, the chemical composition of the wall structures was determined by spectral analysis and melt extraction. Table 7 shows the results as a function of the wire electrodes used as an example of the lowest and highest heat input For the highest heat input, the most intensive metallurgical reactions can be expected in the droplet stage. However, the results do not show any burn-off or burn-up reactions of alloying elements, even though no brushing took place between the individual layers. The small scattering results from measurement inaccuracies of the analysis methods. Likewise, the PREN calculated with equation (1) differs only very slightly. The C/Nb ratio also calculated is lowest for the S Ni 6625 AM1 and highest for the S Ni 6625 AM2.  A significant influence of the heat input on the contents of C, N and H cannot be proven. Only in the case of oxygen, there is a greater scattering and a slight increase in values can be observed (Fig. 15). However, depending on the parameters, slightly increased contents of oxygen and nitrogen can be observed in the weld metal compared to the respective wire electrodes.

Microstructure
The typical microstructure of the cross-sections (x-z-plane) is shown in the middle of Fig. 16. As the heat flow direction of the solidifying weld pool is almost perpendicular to the surface of the previously welded layer or substrate, this leads to an epitaxial growth of the columnar dendrites almost parallel to the build-up direction, as described in [17]. The seam profile shows a finger-shaped penetration in the middle of the wall structure in each welded layer. In this zone, the PDAS for the selected example is approx. 9 μm (Fig. 16, right), while in the weld metal area above it, it is approx. 20 μm (Fig. 16,  left). This grain refinement is attributed to a higher local cooling gradient.
The distances of the mostly equiaxial primary dendrite arms (PDAS) were measured in the middle of the wall structure on the plane sections (X-Y plane), which were taken at the height of the upper tensile sample. Figure 17 shows an increase in the distances for all welded wall structures with increasing heat input. As already documented in many publications [2,19,12,25,39], the weld metal of the niobium-and molybdenum-containing Nibased alloy S Ni 6625 has a strong tendency to segregation. For this reason, EDS analyses of segregation behaviour were carried out on the wall structure welds, which were each produced with the highest heat input. Table 8 gives an overview of the different chemical concentrations in the dendrite core (C s ) and the global chemical compositions (C 0 ) depending on the filler metal used.
For the quantitative measurements in the dendrite core and in the interdendritic areas, spot analyses were carried out at 5 points in each region. The global composition was determined with an area analysis (A = 0.11 mm 2 ). From the different compositions, the distribution coeffizient (k), which is derived from the Scheil equation, can be calculated for each element according to equation 3.
This procedure is described and justified in [12]. The calculated distribution coeffizient (k) of Al, Cr, Fe and Ni are slightly higher than 1 and therefore indicate a slight segregation into the core. Mo, Nb and Ti show a distribution coeffizient (k) less than 1, indicating a tendency to segregate into the liquid metal during solidification and to accumulate in the interdendritic regions at the end of solidification. Niobium has the lowest k-values independent of the welding filler metal, which indicates a more intensive segregation into the liquid metal than is the case with Mo. According to [12], this strong segregation of Nb is regarded as the cause for the formation of secondary phases in the microstructure of weld metal made of the alloy Ni 6625. In the weld metal of the walled structures of S Ni 6660, we have not found strong segregations.
The microstructural investigations carried out so far on the SEM indicated the presence of two main types of secondary phases in the weld metal of type S Ni 6625 (regardless of whether standard or AM variant). SEM images at 2500× magnification give an overview of the microstructure of cross (Y-Z plane) sections (Fig. 18). One type of the interdendritic secondary phase has an elongated or rod-shaped form, which, according to the literature [15,19,39,40], indicates Laves phase (see Fig.  19). The other cubic particles are TiN/NbC or NbC. In the weld metal of S Ni 6660, which contains 606 ppm nitrogen and only 30 ppm carbon, preferably cubic particles are visible. They are provisionally classified as nitrides according to colour and shape.
In the case of cubic TiN/NbC particles, a point inside is very often observed. This indicates the presence of Mg and also Ca or Al (see Figs. 19 and 20). Ca, Mg, CaSi and MgSi are added to high-purity steels and Ni alloys during smelting metallurgical production for complete deoxidation and desulfurization.
Despite the precipitation of the described secondary phases, unacceptable hot cracks, lack of fusions, or porosity did not occur in any of the fabricated webs of the various wire electrodes, indicating good suitability of alloy 625 for additive CMT welding.

Further studies
Further investigations are planned into the influence of the filler metal on pitting corrosion resistance and hightemperature strength, as both are important for the practical use of additively welded structures made of S Ni 6625. Furthermore, the influence of additional shielding gases and modified component geometries (block instead of web) as well as the application of cooling measures during welding on the properties and microstructure will be investigated

Conclusions
The influence of heat input and filler metal composition on the technological aspects, mechanical properties and macro-and microstructure of additively welded thin-walled Ni-based structures was investigated. The heat input was varied between 0.10-0.46 kJ/mm using the CMT process with shielding    Three different filler metals of Nb-alloyed S Ni 6625 (one standard version and two variants specially developed for additive welding) and the chemically similar, Nb-free, but Walloyed filler metal S Ni 6660 were used in the investigations. The following conclusions can be drawn: (1) The four wire electrodes have differences in the appearance of the wire surface, roughness and strength values. Nevertheless, no influence on the process stability of the CMT process could be detected. The standard deviation of the electrical parameters can be used to assess the process stability. The higher the standard deviation, the more unstable the process behaviour is       (2) Due to the low arc power and the integrated wire movement in the melting process, the CMT process is very suitable for the production of additively welded thinwalled structures from Ni-based welding filler despite the high viscosity of the Ni melt. Please note the possible deviations between the set and real wire feed (3) Variable width and height of the wall structures can be adjusted via the wire feed and welding speed. The build-up rates are between 320 and 650 cm 3 /h depending on the parameters. 80 % of the wall structures achieved the required final contour proximity of at least 75% (4) Because of the interpass temperatures and the slow heat conduction due to the geometry, the pure welding time is about 3-7 % of the total production time of a wall structure. For this reason, the development of suitable cooling strategies is absolutely necessary (5) t 10/6 cooling times increase significantly with increasing number of layers and heat input. From the 10 th layer at the latest, the 3D heat conduction changes into a 2D heat conduction and the cooling times stabilise. The average t 10/6 cooling then amount to about 6-21 s from the 10th layer onwards, depending on the heat input (6) The wall structures produced have a very low porosity, no hot cracks and no binding defects. Only in the area of the last layer are micro-pits visible, which can reach the surface. Initially, it is assumed that the cause is a slight geometry-related lateral run-off of the melt. During solidification, this shrinkage of the Ni melt cannot be compensated and micro-pits are formed. If this area is further mechanically processed, no influence on the corrosion resistance can be assumed (7) The mechanical properties of the wall structures depend on the filler metal used and the heat input. Basically, the strength is slightly reduced with increasing heat input, irrespective of the filler metal. The S Ni 6625 AM1 (high Fe content), which is similar to the base material, achieves the highest yield tensile strength (R p0,2 ). This is at base material level. However, the elongation at break is lower than that of the base material. The lowest yield tensile strength (R p0,2 ) is found in the welded wall structures of the W-containing filler metal S Ni 6660 (8) No burn-off or additional burn-up of alloying elements in the weld metal occurred despite the slightly active shielding gas. However, there is sometimes an increase in oxygen and nitrogen compared to the wire electrodes (9) The primary dendrite arm spacing, whose values are between 13 and 27 μm, increases with increasing heat input for all filler metals. This is also the reason for the slightly decreasing strength values in the weld metal (10) In all S Ni 6625 type weld metal, the elements Nb, Mo and Ti tend to be segregated. This results in the formation of secondary phases (Laves phase and carbide/ nitride (NbC or NbC/TiN)). This is often reported in the literature. The C/Nb ratio is highest in the welded wall structures of S Ni 6625 AM1 and lowest in those of S Ni 6625 AM2. The proportions of secondary phases in the weld metal of the Fe containing wire electrode S Ni 6625 AM1 are subjectively also slightly higher.