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Structural, physico-chemical properties of a hybrid material based on Anderson-type polyoxomolybdates

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Abstract

A new organic–inorganic hybrid compound based on a rare β-isomer of Anderson polyoxomolybdates cluster with mixed cations, ammonium and hexamethylenetetramine has been synthesized by the slow-evaporation method. The hybrid material was characterized by single crystal X-ray diffraction, infrared spectroscopy, UV-Visible spectroscopy and thermogravimetric analysis. Hirshfeld surface analysis helps to investigate all the intermolecular interactions within the structure. (C6H14N4)2(NH4)2[β-HSbMo6O24]·8H2O crystallizes in an orthorhombic system and Pnma space group, with a = 23.6649(6) Å, b = 19.5394(5) Å, c = 8.6683(2) Å, α = β = γ = 90 (°) and Z = 4. The structure is deposited in the Cambridge Crystallographic Data Center (CCDC) (deposition number CCDC 2184536). The new hybrid organic–inorganic polyoxometalates based material three-dimensional structure is shaped by the connection of the structure components with N–H···N, N–H···O, N–H···Ow, Ow–H···O hydrogen bonds types and their interactions. The infrared spectrum fully confirms the X-ray crystal structure. The UV-Vis spectrum shows two absorption bands with an optical energy gap of 4 eV, consequently the hybrid material is classified as an insulator. Thermogravimetric and differential thermal analysis was used to study thermal stability of the hybrid organic–inorganic compounds. Hirshfeld surface fingerprint graphics showed several types of intermolecular interactions, where hydrogen bonds are the majority.

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Data availability

The datasets generated during the current study are available in the Cambridge Crystallographic Data Center. CCDC No. 2184536 contains the supplementary crystallographic data for this structure. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by e-mailing data_request@ccdc.cam.ac.uk. or by contacting the Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK. Fax: C44 122333603.

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Funding

The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

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Authors and Affiliations

  1. Laboratory of Physico-chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir, Street Ibn Al Jazzar, 5000, Monastir, Tunisia

    Thamer Bouallegui & Brahim Ayed

  2. Department of Physics, Faculty of Arts and sciences, Ondokuz Mayıs University, 55139, Samsun, Turkey

    Necmi Dege

Authors
  1. Thamer Bouallegui
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by TB, ND and BA. The first draft of the manuscript was written by [full name] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.”

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Correspondence to Thamer Bouallegui.

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Bouallegui, T., Dege, N. & Ayed, B. Structural, physico-chemical properties of a hybrid material based on Anderson-type polyoxomolybdates. J IRAN CHEM SOC 20, 2373–2382 (2023). https://doi.org/10.1007/s13738-023-02845-3

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  • DOI: https://doi.org/10.1007/s13738-023-02845-3

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