Skip to main content
Log in

Effect of Carbon Nanotubes on Porosity and Mechanical Properties of Slag-Based Geopolymer

  • Research Article-Civil Engineering
  • Published:
Arabian Journal for Science and Engineering Aims and scope Submit manuscript

Abstract

In this study, the mechanical behavior and porosity of slag-based geopolymer composites containing multiwalled carbon nanotubes (MWCNTs) were investigated. Three parameters (water–binder ratio, carbon nanotube-to-dispersant ratio (CNT/dispersant ratio), and MWCNT content) were varied, and the compressive strength, flexural strength, and porosity of the composite matrix were determined. The results indicated that in comparison with the reference sample, the compressive and flexural strengths of the composites increased with the addition of 0.045wt% MWCNTs, owing to matrix porosity refinement. The mechanical properties of the composites reached their maximum values when the water–binder ratio was 0.4. Moreover, the dispersant influenced the mechanical properties of the composites. The optimal CNT–dispersant ratio was found to be 2.5:1, and the compressive and flexural strengths of the samples with this ratio increased by 48% and 55%, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Hardjito, D.; Rangan B.V.: Development and properties of low-calcium fly ashbased geopolymer concrete, Research Report GC1 Curtin University of Technology Perth, Australia (2005)

  2. Kong, D.L.Y.; Sanjayan, J.G.: Damage behaviour of geopolymer composites exposed to elevated temperatures. Cem. Concr. Compos. 30(10), 986–991 (2005)

    Article  Google Scholar 

  3. Hardjito, D.; Rangan B.V.: Development and properties of low-calcium fly ashbased geopolymer concrete, Research Report GC, Curtin University of Technology Perth, Australia (2005)

  4. Pan, Z.; Sanjayan, J.G.; Rangan, V.: Fracture properties of geopolymer paste andconcrete. Mag. Concr. Res. 63(10), 763–771 (2011)

    Article  Google Scholar 

  5. Rashad, A.M.: Alkali-activated metakaolin: a short guide for civil engineer—an overview. Constr. Build. Mater. 41, 751–765 (2013)

    Article  Google Scholar 

  6. Iijima, S.: Helical microtubules of graphitic carbon. Nature 354(6348), 56–58 (1991)

    Article  Google Scholar 

  7. Wong, W.E.; Sheehan, P.E.; Lieber, C.M.: Nanobeam mechanics: elasticity, strength, and toughness of nanorods and nanotubes. Science 277(5334), 1971–1975 (1997)

    Article  Google Scholar 

  8. Yu, M.F.; Kowalewski, T.; Ruoff, R.S.: Investigation of the radial deformability of individual carbon nanotubes under controlled indentation force. Phys. Rev. Lett. 85(7), 1456 (2000)

    Article  Google Scholar 

  9. Yu, Y.: Effects and Mechanism Analysis of PVA Fibers and Carbon Nanotubes on Geopolymer, Academic Dissertation, Zhejiang University, China (2018)

  10. Ruoff, R.S.; Lorents, D.C.: Mechanical and thermal properties of carbon nanotubes. Carbon 33(7), 925–930 (1995)

    Article  Google Scholar 

  11. Da Luz, G.; Gleize, P.J.P.; Batiston, E.R.; Pelisser, F.: Effect of pristine and functionalized carbon nanotubes on microstructural, rheological, and mechanical behaviors of metakaolin-based geopolymer. Cem. Concr. Compos. 104, 103332 (2019)

    Article  Google Scholar 

  12. Abu Al-Rub, R.K.; Tyson, B.M.; Yazdanbakhsh, A; Grasley, Z.: Mechanical properties of nanocomposite cement incorporating surface-treated and untreated carbon nanotubes and carbon nanofibers. Nanomech. Micromech. 2, 1–6 (2012)

    Article  Google Scholar 

  13. Abbasi, S.M.; Ahmadi, H.; Khalaj, G.; Ghasemi, B.: Microstructure and mechanical properties of a metakaolinite-based geopolymer nanocomposite reinforced with carbon nanotubes. Ceram. Int. 42(14), 15171–15176 (2016)

    Article  Google Scholar 

  14. Parveen, S.; Raba, S.; Fangueiro, R.: A review on nanomaterial dispersion, microstructure and mechanical properties of carbon nanotube and nanofiber reinforced cementitious composites. J. Nanomater. 2013 (2013)

  15. Gong, X.; Liu, J.; Baskaran, S.: Surfactant-assisted processing of carbon nanotube/polymer composites. Chem. Mater. 12(4), 1049–1052 (2016)

    Article  Google Scholar 

  16. Heister, E.; Lamprecht, C.; Neves, V.; Tîlmaciu, C.; Datas, L.; Emmanuel Flahaut, E., et al.: Higher dispersion efficacy of functionalized carbon nanotubes in chemical and biological environments. ACS Nano 4(5), 2615–2626 (2010)

    Article  Google Scholar 

  17. Saafi, M.; Andrew, K.; Tang, P.L.; McGhon, D.; Taylor, S.; Rahman, M.; Yang, S.; Zhou, X.: Multifunctional properties of carbon nanotube/fly ash geopolymeric nanocomposites. Constr. Build. Mater. 49, 46–55 (2013)

    Article  Google Scholar 

  18. Ye, M.X., Hooton, R.D.: Study on determination method of cement porosity. Hydro-Sci. 1, 63–73 (1991)

    Google Scholar 

  19. Cao, X.Y.; Yang, J.S.: Overview of Cementing Properties of Geopolymer and Geopolymer Concrete. Bulletin Of The Chinese Ceramic Society. 38(7), 2095–2103 (2019)

    Google Scholar 

  20. Zhou, M.L.: Research and Application on New Type of Forming Agent. Hunan University, Changsha (2010)

    Google Scholar 

  21. Shi, H.S.; Xia, M.; Guo, X.L.: Research development on mechanism of fly ash-based geopolymer and effect of each component. J. Chin. Ceram. Soc. 41(7), 972–980 (2013)

    Google Scholar 

  22. Xu, P.: Study on Surface Treatment and Dispersion of Carbon Nanotube. South China University of Technology, Guangzhou (2018)

    Google Scholar 

  23. Haghighi, S.; Ansari, R.; Ajori, S.: Interfacial properties of 3D metallic carbon nanostructures(T6 and T14)-reinforced polymer nanocomposites: a molecular dynamics study. J. Mol. Graph. Model. 92, 341–356 (2019)

    Article  Google Scholar 

  24. Haghighi, S.; Ansari, R.; Ajori, S.: Influence of polyethylene cross-linked functionalization on the interfacial properties of carbon nanotube-reinforced polymer nanocomposites: a molecular dymamics study. J. Mol. Graph. Model. 25(4), 1–13 (2019)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shan Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, Z., Li, F., Li, W. et al. Effect of Carbon Nanotubes on Porosity and Mechanical Properties of Slag-Based Geopolymer. Arab J Sci Eng 46, 10731–10738 (2021). https://doi.org/10.1007/s13369-021-05555-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13369-021-05555-1

Keywords

Navigation