Abstract
Reducing the amount of industrial crop waste and converting it into high value-added products in a sustainable manner will not only promote the use of biological resources but will also help in reducing the environmental impact. Bast fibers of Kozo (Broussonetia kazinoki) are a raw material of traditional Japanese paper, known as “Washi.” However, the wood part of this plant is not used for Washi and is discarded. The aim of this study was to find a new future use for the wood parts of the plant. The first step was to confirm whether the wooden part of Kozo could be converted into cellulose nanofibers (CNFs). CNFs made from bast fiber alone and from bast fiber that included the outer bark were prepared as samples for comparison. Subsequently, the morphological and chemical structures of the raw materials, wood powder, pulp, and CNFs from each sample were analyzed. Consequently, we found that CNFs made from wooden parts have a chemical structure similar to that of the bast fiber, which is the raw material of Washi; however, it is the thinnest CNF of all those investigated. In addition, the CNF solution prepared from wooden parts adjusted to a 0.5-wt% concentration showed the highest viscosity characteristics and also the highest adhesive strength when applied to Japanese paper. These results indicate that waste wood parts have potential applications as chemical-free thickeners, adhesives, and restorative materials.
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References
Arrieta MP, Fortunati E, Dominici F, Lopez J, Kenny JM (2015) Bionanocomposite films based on plasticized PLA-PHB/cellulose nanocrystal blends. Carbohydr Polym 121:265–275
Battistel D, Padovani I, Dallo F, Barbante C, Zendri E, Balliana E (2018) Evaluation of the volatile organic compound emissions in modern and naturally aged Japanese paper. J Cult Herit 33:18–29
Boufi S, González I, Delgado-Aguilar M, Tarrès Q, Pèlach MÀ, Mutjé P (2016) Nanofibrillated cellulose as an additive in papermaking process: a review. Carbohyd Polym 154:151–166
Carrillo F, Colom X, Suñol JJ, Saurina J (2004) Structural FTIR analysis and thermal characterisation of lyocell and viscose-type fibres. Eur Polymer J 40(9):2229–2234
Chang S, Condon B, Edwards JV (2010) Preparation and characterization of aminobenzyl cellulose by two step synthesis from native cellulose. Fibers Polym 11(8):1101–1105
Figen AK, Terzi E, Yilgör N, Kartal SN, Pişkin S (2013) Thermal degradation characteristic of Tetra Pak panel boards under inert atmosphere. Korean J Chem Eng 30(4):878–890
Garg UK, Kaur M, Garg V, Sud D (2007) Removal of hexavalent chromium from aqueous solution by agricultural waste biomass. J Hazard Mater 140(1–2):60–68
Han Y-H, Enomae T, Isogai A, Yamamoto H, Hasegawa S, Song J-J, Jang S-W (2006) Traditional papermaking techniques revealed by fibre orientation in historical papers. Stud Conserv 51(4):267–276
Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3(1):71–85
Iwamoto S, Abe K, Yano H (2008) The effect of hemicelluloses on wood pulp nanofibrillation and nanofiber network characteristics. Biomacromol 9(3):1022–1026
Iwamoto S, Lee S-H, Endo T (2013) Relationship between aspect ratio and suspension viscosity of wood cellulose nanofibers. Polym J 46(1):73–76
Kataoka Y, Kondo T (1998) FT-IR microscopic analysis of changing cellulose crystalline structure during wood cell wall formation. Macromolecules 31(3):760–764
Kyutoku H, Maeda N, Sakamoto H, Nishimura H, Yamada K (2019) Effect of surface treatment of cellulose fiber (CF) on durability of PLA/CF bio-composites. Carbohyd Polym 203:95–102
Malucelli LC, Matos M, Jordão C, Lomonaco D, Lacerda LG, Carvalho Filho MAS, Magalhães WLE (2018) Influence of cellulose chemical pretreatment on energy consumption and viscosity of produced cellulose nanofibers (CNF) and mechanical properties of nanopaper. Cellulose 26(3):1667–1681
Muhamad II, Salehudin MH, Salleh E (2015) Cellulose nanofiber for eco-friendly polymer nanocomposites. Eco-friendly polymer nanocomposites. Springer, Berlin, pp 323–365
Narita C, Okahisa Y, Yamada K (2019) A novel technique in the preparation of environmentally friendly cellulose nanofiber/silk fibroin fiber composite films with improved thermal and mechanical properties. J Clean Prod 234:200–207
Narita C, Okahisa Y, Wataoka I, Yamada K (2020) Characterization of ground silk fibroin through comparison of nanofibroin and higher order structures. ACS Omega 5:22786
Nishitsuji S, Shinozaki C, Miyata K, Yamada S, Yoshida J (2021) Study of the interfacial adhesive strength of a heat-shrinkable multilayer film. Polym Eng Sci 61(3):836–842
Nogi M, Iwamoto S, Nakagaito AN, Yano H (2009) Optically transparent nanofiber paper. Adv Mater 21(16):1595–1598
Nuruddin M, Hosur M, Uddin MJ, Baah D, Jeelani S (2016) A novel approach for extracting cellulose nanofibers from lignocellulosic biomass by ball milling combined with chemical treatment. J Appl Polym Sci. https://doi.org/10.1002/app.42990
Okahisa Y, Yoshida A, Miyaguchi S, Yano H (2009) Optically transparent wood–cellulose nanocomposite as a base substrate for flexible organic light-emitting diode displays. Compos Sci Technol 69(11–12):1958–1961
Okahisa Y, Abe K, Nogi M, Nakagaito AN, Nakatani T, Yano H (2011) Effects of delignification in the production of plant-based cellulose nanofibers for optically transparent nanocomposites. Compos Sci Technol 71(10):1342–1347
Okahisa Y, Furukawa Y, Ishimoto K, Narita C, Intharapichai K, Ohara H (2018) Comparison of cellulose nanofiber properties produced from different parts of the oil palm tree. Carbohyd Polym 198:313–319
Okahisa Y, Matsuoka K, Yamada K, Wataoka I (2020) Comparison of polyvinyl alcohol films reinforced with cellulose nanofibers derived from oil palm by impregnating and casting methods. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2020.116907
Olsson A-M, Salmén L (2004) The association of water to cellulose and hemicellulose in paper examined by FTIR spectroscopy. Carbohyd Res 339(4):813–818
Popescu C-M, Popescu M-C, Vasile C (2011) Structural analysis of photodegraded lime wood by means of FT-IR and 2D IR correlation spectroscopy. Int J Biol Macromol 48(4):667–675
Santos SM, Carbajo JM, Gómez N, Quintana E, Ladero M, Sánchez A, Villar JC (2016) Use of bacterial cellulose in degraded paper restoration. Part II: application on real samples. J Mater Sci 51(3):1553–1561
Sato A, Yoshimura T, Kabusaki D, Okumura H, Homma Y, Sano H, Yano H (2021) Influences of dispersion media for chemically modified cellulose nanofibers on rheological and mechanical properties of cellulose nanofiber reinforced high-density polyethylene. Cellulose 28(8):4719–4728
Shimizu M, Saito T, Isogai A (2016) Water-resistant and high oxygen-barrier nanocellulose films with interfibrillar cross-linkages formed through multivalent metal ions. J Membr Sci 500:1–7
Soni B, el Hassan B, Mahmoud B (2015) Chemical isolation and characterization of different cellulose nanofibers from cotton stalks. Carbohydr Polym 134:581–589
Stephens CH, Whitmore PM (2013) Comparison of the degradation behavior of cotton, linen, and kozo papers. Cellulose 20(3):1099–1108
Wang T, Drzal LT (2012) Cellulose-nanofiber-reinforced poly(lactic acid) composites prepared by a water-based approach. ACS Appl Mater Interfaces 4(10):5079–5085
Wang L-F, Shankar S, Rhim J-W (2017) Properties of alginate-based films reinforced with cellulose fibers and cellulose nanowhiskers isolated from mulberry pulp. Food Hydrocoll 63:201–208
Yamada K, Miyata K, Konishi R, Okada K, Tsujii T (2015) Molecular orientation effect of heat-sealed pp film on peel strength and structure. Adv Mater Phys Chem 05(11):439–446
Yamada K, Miyata K, Kumaresan R (2017) A novel methodology for peel strength enhancement of heat-sealed oriented polypropylene/cast polypropylene film by tensile cyclic loading. Mater Chem Phys 187:112–118
Yonenobu H, Tsuchikawa S, Sato K (2009) Near-infrared spectroscopic analysis of aging degradation in antique washi paper using a deuterium exchange method. Vib Spectrosc 51(1):100–104
Acknowledgements
The authors would like to acknowledge Mr. Shinji Hayashi at the Kurotani Washi Cooperative Association, Japan, which supplied the valuable raw material used in this study.
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Narita, C., Okahisa, Y. & Yamada, K. A novel approach of adhesive property of cellulose nanofibers obtained from the discarded wooden part of Kozo plant. Appl Nanosci 11, 2717–2726 (2021). https://doi.org/10.1007/s13204-021-02151-5
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DOI: https://doi.org/10.1007/s13204-021-02151-5