Prospect evaluation based on integrated petroleum system analysis: Block E case study, south-eastern edge of Precaspian Basin (Kazakhstan)

Generative potential and thermal maturity for Upper Palaeozoic source rocks from the south-eastern edge of Precaspian Basin were determined using Rock–Eval. A high hydrocarbon source rock generative potential and high degree of thermal maturity for the Lower Permian, Mid-Carboniferous strata have been revealed based on 39 rock samples. TOC values of 0.4–5.5% have been obtained for mature source rocks. Integrated geochemical analysis determined from Rock–Eval studies combined with 1D basin modelling was utilized in order to reconstruct thermal evolution for the Upper Palaeozoic source rocks. Calibrated 1D models for three wells had been constructed to understand petroleum system. For two deep exploration wells (Nur-1 and Tassym SE-1), which penetrated pre-salt strata at the depths of 5.7 and 7 km, respectively, the impact of salt diapirism on timing of maturation was modelled. Type II kerogen was used, which is based on previous palaeogeographic studies. The stratigraphic framework and major stages of geodynamic evolution were analysed. Salt-related structural traps in post-salt strata have been described based on 3D seismic data, and additional intra-salt sediment packages have been delineated. Discovered producing oil fields in the Upper Triassic and Jurassic–Cretaceous stratigraphic sections are mainly confined to the four-way dip structural closures above the steep flanks of salt structures. Based on burial and thermal modelling, the maturation and generation behaviour of kerogen Type II below salt-related minibasins and close to thick salt diapirs were inferred. For Lower Permian SR with type II kerogen, the generation peak (maturity over 50%) occurs in Middle to Late Jurassic. For predominantly carbonate and terrigenous-carbonate Mid-Carboniferous marine SR, generation peak occurs earlier below salt withdrawal minibasins. Implications for deeper hydrocarbon prospectivity were made for the study area, and methodology for evaluating hydrocarbon potential adopting 1D basin modelling technique and geochemical data is presented.


Introduction
The Precaspian Basin (PCB) is one of the world's largest hydrocarbon provinces; it is a deep (over 20 km) salt-dominated continental margin basin located mostly in Kazakhstan with the western and north-western edges extending to Russia (Fig. 1).
In PCB, there are several proven conventional plays: Jurassic and Cretaceous clastics, Permian-Triassic minibasins in salt-related structural traps, pre-salt Permian and Carboniferous isolated carbonate platform reefs and shoals. The evaporitic sequences and salt diapirism control the evolution of petroleum system and thermal regime of sedimentary basins Jackson 2007, Jackson andPeel et al. 2014;Cedeno et al. 2019). Salt acts as an effective seal for largest Precaspian pre-salt oilfields, and salt evacuation leads to minibasin welding, through which generated hydrocarbons can migrate vertically from pre-salt source rocks (Rowan et al. 2012).
Exploration in PCB started in the early part of the twentieth century; the majority of presently producing oil fields had been discovered within post-salt shallow Jurassic and Cretaceous clastic reservoirs by 1970. Further supergiant and giant pre-salt discoveries were made in the 1970s to early 1980 s and included Tengiz, Karachaganak, Zhanazhol.
Despite the long exploration and production history, the Precaspian petroleum system remains poorly understood; it is generally accepted that Upper Devonian to Lower Permian source rocks charge the pre-salt and post-salt reservoirs. Devonian source rocks are poorly known as only a few wells on the northern and eastern edges have penetrated these sediments (Pairazian 1999; Barde et al. 2002).
The discovery of super giant fields in the pre-salt complex of Precaspian Basin in the 1970s and policy reforms in the early 1990s led to a suspension in exploration activities for the post-salt complex and shifting the hydrocarbon exploration focus to the pre-salt Palaeozoic strata (Akhmetshina 1993;Volozh and Antipov 2003;Akhmetkalieva and Shestoperova 2011). Significant upside hydrocarbon potential is associated with the deep pre-salt Palaeozoic complex of the Precaspian Basin (Belopolsky and Talwani 2007;Abilkhasimov 2016;Zholtayev et al. 2018;Abishev and Kassenov 2016). Most recent exploration shifted back to post-salt Permian-Triassic and Jurassic-Cretaceous reservoirs (Okere and Toothill 2012).
3D seismic surveys acquired in Block E during 2007-2013 have resulted in numerous commercial oil discoveries within the shallow Upper Triassic and Jurassic-Cretaceous sandstones in the south-eastern edge of PCB indicating that the post-salt complexes have not been adequately studied and that new oil fields may be discovered.
This study aims to better understand generative potential and thermal evolution of Upper Palaeozoic source rocks, timing of hydrocarbon generation based on 1D basin modelling. Seismostratigraphic and geochemical analysis was carried out, and thermal maturity of potential source rocks had been described based on Rock-Eval pyrolysis.
Qualitative evaluation of hydrocarbon potential for the pre-salt, salt and post-salt complexes is of great theoretical and practical importance and is a challenging task at the same time. Sparse exploration data and results of 3D seismic interpretation at Block E were used in order to understand the Precaspian petroleum system and identify exploration opportunities.
The main stages of the geodynamic evolution of the study area were analysed based on the published literature (Zonenshein et al. 1990;Khain 2000;Brunet et al. 1999;Volozh et al. 2003;Shein et al. 2020), and thermal history was reconstructed. The results of thermal modelling confirm the possibility of vertical migration of hydrocarbons generated in pre-salt source rocks. A revision of the 3D seismic data interpretation has been carried out, and for the first time, intrasalt sedimentary packets of presumably Upper Permian age have been identified as independent objects, which can be potential hydrocarbon traps in the intra-salt play and that have been previously overlooked.
The Block E study area (9300 km 2 ) is tectonically located within the Guryevsky height of the south-eastern part of the Precaspian Basin (Western Kazakhstan). The area also features a complex history of geological development and salt tectonics (Fig. 1).
More than 30 small oilfields have been explored in the Mesozoic post-salt complex at Block E. Oil deposits are four-way dip structural closures, mainly confined to the crestal parts of the salt domes (Fig. 2). No hydrocarbon accumulations have been identified in the inter-dome depressions yet. Cretaceous, Jurassic and Upper Triassic strata have been penetrated, logged and cored by numerous dedicated exploration and production wells and carefully characterized (Dalyan et al. 1993;Kukhtinov and Crasquin-Soleau, 1999;Barde et al. 2002;Zholtayev et al. 2019;Akhmetzhanov et al. 2020).
Three deep exploration wells were drilled within and close to the boundaries of the study area of the Guryevsky height ( Fig. 1). Two of them, Akatkol P-3 (1990) and Tassym Southeast-1 (2010), yielded representative Upper Palaeozoic rock samples which were further analysed by Rock-Eval 6 in the present study (Table 2). All wells drilled in the studied area display similar lithostratigraphy (Fig. 3), most of the wells targeted the hydrocarbon production from the shallow Upper Triassic and Middle Jurassic reservoirs, and only 3 deep exploration wells drilled to the Upper Palaeozoic section (Fig. 1).
The Nur-1 deep exploration well (2011) at Block E was drilled in centre of partially welded minibasin (Figs. 2,4,5). The targeted Devonian reservoirs were not reached due to the multiple differential drill string struck, and the well was abandoned near the top of the Kungurian salt at a depth of 5721.5 m. Real-time mud gas monitoring detected hydrocarbons shows increasing with depth for Jurassic (at 1300-1520 MD) and Permian-Triassic strata (at 3650, 4200, 4500, 4900 MD).
According to the logging interpretation results of Tassym Southeast-1 drilled in a neighbouring area (Fig. 2), the well penetrated hydrocarbon-bearing Lower Permian and Carboniferous carbonate-terrigenous reservoirs.
In this study, the authors conducted an integrated evaluation of the generative potential of the Upper Palaeozoic source rocks within Block E, constructed 1D basin models using available pyrolysis data and reconstructed the burial and thermal histories based on the major geodynamic stages   Barde et al. 2002). Tectonic history is based on palaeogeographic reconstructions (Volozh et al. 2003;Shein et al. 2020) of the PCB evolution (Shein et al. 2020). Palaeoezoic source rocks had been evaluated, and implications for improving hydrocarbon prospectivity for intrasalt and pre-salt complexes were provided based on petroleum system elements and processes (Hood et al. 2002;Dembicki 2017).
Taking into account difficult drilling conditions in salt and pre-salt stratigraphic intervals and deep levels (more than 5-6 km) of possible hydrocarbon plays, comprehensive analysis of petroleum system elements with basin modelling techniques will enable reducing exploration risks. Uninterpreted (a) and interpreted (b) South-North seismic cross-section illustrating salt diapirs with the associated thick interdome minibasins. Salt complex is severely deformed due to halokinesis, according to Fernandes и Duffy (2017) analogue intrasalt sediment packages can be defined. Low amplitude normal faults confined to the crests of salt domes and related to the later salt tectonics. The salt domes have steeply dipping flanks. Pre-salt complex is uncomfortably overlained by Permian-Triassic sequences. The major angular unconformity at the base Jurassic (seismic reflector V) can be observed, the basin-wide seismic horizon V is well traced across the study area. Asanketken oil field is structural trap in Jurassic section located above the steep slope of the salt Asanketken dome. The piercing salt dome has northwest strike (Fig. 2). The Nur-1 well has penetrated the bottom of Permian-Triassic strata, in the pre-salt complex at the level of seismic reflector P 2 d (the presumed top of the Lower-Middle Devonian) and P 2 1 (top of Upper Devonian) stratigraphic traps can be delineated

Tectonostratigraphic framework
Three main seismic reflectors have been identified in the Palaeozoic sedimentary succession based on regional geological and geophysical surveys of the PCB. The P 1 horizon corresponds to the bottom of Kungurian sediments, the P 2 horizon corresponds to the surface of the Middle Carboniferous unconformity, and the deepest P 3 horizon, which has been penetrated by several wells and is not precisely dated, could represent the Lower to Upper Devonian (Brunet et al. 1999;Volozh et al. 2003).
Acquisition of 3D seismic surveys (2007)(2008)(2009)(2010) at the study area provided new information on the deep structure up to 8 km depth (Fig. 2). In the Mesozoic stratigraphic interval, principal seismic reflector III (base of Cretaceous sediments), V (unconformity at the base Jurassic), VI (top of salt) were mapped ( Fig.4 through 7). Seismic reflector IV in the Jurassic section cannot be defined; internal unconformities within the Permian-Triassic sequences can be locally traced (Barde et al. 2002;Kukhtinov and Crasquin-Soleau 1999).
The thick Kungurian diapiric salt section contains internal anhydrites, shales, carbonates, initial thickness of salts estimated as 1000-2000 m within the study area (Akhmetzhanov et al. 2020). Salt tectonics has led to the The seismic reflector V (Fig. 2) shows that salt diapirs predominate in the north-eastern part of Block E, with the buried deep-seated salt domes predominating in the south. The extension of diapir belts is predominantly submeridional. The discovered shallow hydrocarbon accumulation in the Block E (Asanketken and Kyzylzhar-I East oil fields) is structural fault-bounded oil traps that overly the crest of the salt diapirs (Figs. 4,6).
In general, the salt interface dips gradually or through ledges towards their peripheral areas. In some cases, the steeply dipping flanks of the isolated salt domes or diapir belts have secondary minor salt swells, overlaid by  (Fig. 4). Thus, the halokinesis during the Permian-Triassic has led to the formation of inter-dome minibasins with different sedimentary fill and geometry.
Based on interpretation large 3D seismic data sets intrasalt bodies can be delineated, they are similar to «intrasalt sediment packages» and «encased minibasins» Jackson et al. 2020) in Zharkamys West 1 block (eastern edge of PCB). The mechanism of encasement of minibasins is considered to be density driven; most likely the encased minibasins formed above salt and later were encased .
Intrasalt sedimentary bodies are widespread in salt basins around the world and have different mechanisms of their formation. They can form both synsedimentary with salts and after salt deposition. Understanding the origin and evolution of intrasalt inclusions may indicate important stages In the pre-salt complex major reflective horizons can be interpreted: P 1 (bottom of the salt layer), P 2 C (top of Middle Carboniferous strata), reflectors P 2 1 (top of Upper Devonian) and P 2 d (presumably top of the Lower-Middle Devonian) 1 3 in the geodynamic evolution of a particular tectonic region. In addition, prediction the lithology and facies composition for these formations is necessary when planning exploration drilling.
The 3D seismic data interpretation results from Block E were reviewed, and intrasalt sedimentary packages were identified; they are of two major sets, encased minibasins and tabular packages of presumably Upper Permian age, which occur locally and do not have a wide area distribution (Figs. 4,5,6,7). These formations in Block E have not been penetrated by boreholes. The hydrocarbon prospectivity of these formations has been proved by exploration drilling in Zharkamys West-1 analogue area (Fernandes et al. 2017;Jackson 2020).
Discovered and proved Kyzylzhar I East (Fig. 6) oil field abutting the crestal part of the salt dome with encased minibasin may also indicate the high probability of vertical HC migration from the palaeoezoic source rocks and possible sedimentary minibasin trap filled with migrated hydrocarbons (Fig. 6).
In the Akatkol area, the quality of seismic data does not allow identifying the intrasalt inclusions; however, at the bottom of salt domes some turtle structures can be delineated interfacing with the P 1 seismic reflector (Fig. 7).

Source rock evaluation
The Late Devonian and Lower Carboniferous source rocks with Type II kerogen are considered major hydrocarbon kitchen for pre-salt reservoirs (Ulmishek 2001;Barde et al. 2002). Early Carboniferous organic deep water organic-rich shales interface with carbonates (Barde et al. 2002). Average TOC values 2-3.5% are documented for the sediments over Tengiz carbonate platform (Pairazian 1999). Lower Permian pre-salt sedimentary successions contain Type II organic matter with TOC up to 2.5% (Yensepbayev et al. 2009;Pairazian 1999). Most authors agree that post-salt reservoirs are charged by pre-salt Upper palaeozoic source rocks.
Recent biomarker studies and geochemical correlations between oils, reservoirs and source rocks in the eastern and southern edges of the PCB have linked Palaeozoic source rocks with the post-salt Precaspian petroleum system (Gurgey Warner et al. 2007;Yensepbayev et al. 2009Yensepbayev et al. , 2002Peters et al. 2005), indicating an important role for primary vertical migration from pre-salt to post-salt strata via welded regions. Despite the long-term study into the structure and formation of PCB salt structures, questions related to the mechanisms and pathways of hydrocarbon migration and accumulation in the post-salt complex remain debatable.
In Yensepbayev et al. (2009), earlier study based on Rock-Eval pyrolysis and molecular analysis of a large number of source rock samples from the Eastern Precaspian and Pre-Uralian Basins (Republic of Kazakhstan) determined the following, Early and Mid-Carboniferous source rocks are dominated by algal kerogen Type II, while the mixed kerogen Type II/III is established for predominantly marine siliciclastic Early Permian source rocks. The identified feature is presumably linked to the increasing of collisional processes during the Early Permian and contribution of terrestrial plants.
To evaluate the generative potential and degree of thermal of Upper Palaeozoic strata, Rock-Eval pyrolysis study for 39 rock samples from deep exploration wells of the Guryevsky height was analysed (Figs.1, 2, 3, Table 2). The rock samples from Tassym SE-1 were analysed using Rock-Eval 6 instrument in the Laboratory of Tomsk Polytechnic University (Tomsk, Russia). For other rock samples, the Rock-Eval results are borrowed from unpublished sources. Thermal maturity of the organic matter inferred from TOC, S2, HI, PI, Tmax values.

Model building
Petromod 2018 was used to reconstruct burial and thermal history of the study area; for the deep wells NUR-1 and Tassym South East-1 with TD in Upper Palaeozoic intervals, 1D models were implemented; for the shallow Asanketken-1 well with TD in Permian-Triassic 1D thermal modelling was done in order to estimate scenario for a possible Jurassic source rocks.
Basin modelling techniques integrate conceptual and a priori geological and geophysical information to numerically reproduce subsidence history and thermal evolution of sedimentary sequences. The stratigraphy and lithology model of the Nur-1 well is based on seismic, logging data and cuttings lithological description (Fig. 3, Table 1). Stratigraphic subdivision for modelled wells is based on detailed correlation with reference wells. The Palaeozoic section of the Nur-1 well is modelled by analogy with the penetrated Palaeozoic stratigraphic interval of the Akatkol P-3 and Tassym Southeast-1 wells (Fig. 4). The established thermal gradient in the Nur-1 well is 12 °C/km. The 100 °C isotherm is observed at a depth of 4 km in NUR-1 well and at a depth of 5 km in Tassym South-East-1 well (Fig. 8). That is associated with salt structures which control spatial thermal regime (Chekhonin et al. 2020).
The major stages of tectonic evolution used in basin modelling were updated following the latest regional palaeogeographic reconstructions of the East European palaeocontinent for a more reliable prediction of the kerogen thermal evolution (Volozh et al. 2003;Shein et al. 2020).
The sediment-water interface temperatures were automatically calculated from palaeo-water depths established by Brunet et al. 1999. The calibration of heat flow was done against the measured borehole temperatures by the RCI™ tool from Baker Hughes (Reservoir Characterization Instru-ment™). The good calibration was obtained by setting the heat flow to 50-55 mwatts/m 2 from Early Palaeozoic to Late Carboniferous; additionally salt tectonics and piercing Petromod functionality was adopted in order to simulate salt withdrawal as it severely effects spatial and temporal thermal regime (Fig. 9).
Vitrinite reflectance was simulated using Petromod kinetics (Sweeny and Burnham, 1990). The simulated EASY5Ro for the Upper Palaeozoic source rocks is correlated with the measured vitrinite reflectance values (Ro = 0.8-1.2%) at the  The detailed information on the stratigraphy, lithological composition and geochemical characteristics is given in Table 2. The lithostratigraphy is based on exploration drilling results and 3D seismostratigraphy of the study area (Figs. 3, 4, 5). Fig. 9 Diagram of burial and thermal history modelling for Nur-1, Tassym SE-1 and Asanketken-1 wells based on tectonic setting analysis. Major phases of tectonic evolution: 1-Progressive subsidence for Eastern European Craton (EEC), marine transgression; 2-Central Precaspian rift opening; 3-Uplifting following collision of EEC, Kazakhstan block and Turan microcontinent; 4-Closure of the Uralian Ocean, deposition of the pervasive thick salt layer, formation of Precaspian Basin orogenic belt; 5-Salt tectonics due to high sedimentation rates; 6-Regional isostatic equilibrium processes between tectonic elements, shallow marine depositional environment; 7-Extension of marine transgression due to collision processes in Caucasus, reactivating of salt tectonics

Burial history
Effective re-exploration of the petroleum province requires considering the processes of hydrocarbon generation, expulsion and migration within a sedimentary basin from the geodynamic evolution perspective.
Palaeotectonic reconstructions indicate that the PCB origin and evolution are related to the spreading between the East European and Kazakhstan tectonic plates followed by formation of the Atlantic-type continental margin Uralian palaeocean by the end of Ordovician (Zonenshain et al. 1990;Khain 2000).
The thick carbonate-terrigenous succession of passive continental margin of the Precambrian East European plate was deposited during Late Devonian-Carboniferous. The subsequent collision of the Eastern European and Kazakh continents in the Late Palaeozoic led to the formation of the Ural-Tien-Shan orogenic belt. Numerous concepts of geodynamic evolution were developed by various researchers worldwide during many years of study into the tectonic evolution of the East European craton (Zonenshain et al. 1990;Nikishin et al. 1996;Khain 2000;Brunet et al. 1999Brunet et al. , 2007Volozh et al. 2003;Zuza and Yin 2017;Shein et al. 2020).
The authors of this study adhere to the concept of East European continental margin revitalizing in Precaspian depression in the Middle Devonian (Fig. 9).
The tectonic evolution and depositional setting within Block E area were established based on the comparison with the regional palaeogeodynamic and palaeogeographic reconstructions of the East European Platform during the Riphean-Cenozoic period (Shein et al. 2020;Volozh et al. 2003;Brunet et al. 1999; Atlas of the Lithology-Palaeogeographical, Structural, Palinspastic and Geoenvironmental Maps of Central Eurasia 2002).
The Middle Devonian was marked by a major gradual transgression due to the subsidence of the East European continent, lasting until the end of the Tournaisian. The opening of the Central Precaspian rift in the Late Devonian-Early Carboniferous led to the formation of the Uralic palaeocean gulf, along the continental passive margin the sedimentation of thick carbonate-terrigenous successions occurred, favourable for petroleum generation and petroleum accumulation. Thus, potential source rocks of the Devonian-Lower Permian, partially penetrated by the wells at Block E, have a high generation potential.
The collision of Kazakh continent and the margin of the East European palaeocontinent progressed throughout the Visean age. The rising of the Ural Mountains served as a source of clastic sediments. The Early Permian collision of the East European plate with the Kazakh continent and TOC: total organic carbon (%). S1 peak: free hydrocarbons, at 300 °C (mg HC/g rock). S2 peak: heavy HC compounds, at 300-650 °C (mg HC/g rock). HI: hydrogen index, (100*S2)/TOC (mg HC/g TOC). OI: oxygen index, (100*S3)/TOC (mg HC/g TOC). S3: the amount of CO 2 (mg CO 2 /g rock). Tmax: temperature at which the maximum release of HC from cracking of kerogen occurs, top of S2 peak (°C.) PI: Production index, S1/ (S1 + S2), ROC, residual organic carbon content. Rock samples from Tassym SE-1 well were analysed using Rock-Eval 6 instrument the Turan microcontinent accelerated the uplift of the Precaspian depression and led to the beginning of strong salt accumulation compared to the northern regions of the East European palaeocontinent, where a shallow palaeobasin of increased salinity continued to exist and deposition of dolomite silt, gypsum and salt took place (Shein et al. 2020). By the beginning of the Kungurian age, the formation of the PCB margins with folded belts had been completed. By the end of the Kungurian age, the Uralic palaeoocean had completely closed, contributing to the formation of the regional salt sequence. There was a significant shift in sedimentation towards lagoon-continental conditions after a hiatus in sedimentation during the Late Permian age. In the Late Permian-Early Triassic period, the territory of the Precaspian depression was an area of erosion, periodically flooded by the sea. The Late Triassic to Cenozoic was dominated by isostasy and partitioning of previously formed structures into blocks with the formation of vertical faults that may have served as migration pathways for hydrocarbons from previously formed deposits in the Palaeozoic sediments (Zhenyun et al. 2015). During the Jurassic times, the Precaspian palaeobasin was dominated by a marine depositional environment (Atlas of the Lithology-Palaeogeographical, Structural, Palinspastic and Geoenvironmental Maps of Central Eurasia 2002); the expansion of marine transgression during the Late Cretaceous is related to plates collision in the Caucasus region (Shein et al. 2020). The described above geodynamic stages had been incorporated during burial and thermal modelling (Fig. 9).

Thermal maturity
Interpretation of pyrolysis studies of potential Middle Carboniferous-Lower Permian source rocks of Block E revealed the following geochemical characteristics (Fig. 10). The Rock-Eval Tmax values and corresponding sample depths, lithology and ROC parameters are listed in Table 2. As shown in Fig. 10, thermal maturity of Lower Permian and Mid-Carboniferous rock samples is varying from immature to overmature. The Lower Permian Asselian-Artinskian carbonate-terrigenous sediments have fair to good generative potential in terms of S1 + S2 ratios and TOC content (Fig. 10). Some source rock samples from Tassym SE-1 well can be interpreted to contain type II kerogen, high values of ROC/TOC ratio indicating that source rocks might have generated hydrocarbons.
The degree of maturation of Lower Permian source rock samples is represented by Tmax values ranging from 410 0 to 450 0 C, corresponding to the oil zone (Fig. 10, Table 2). For the Akatkol area, the Tmax values correspond to the onset of the oil window. The thermal evolution modelling results for the Block E wells complement the conclusions on kerogen maturity from pyrolysis study; there is a trend of gradual increasing of thermal maturity with depth (Fig. 12).
Thick intervals of Kungurian salt has significantly influenced the spatial thermal regime in the study area and lowered the oil window near salt structures. Maturity modelling results are shown in Figs. 11, 12.

Thermal modelling
The integrated geological, geophysical and geochemical data on Block E are used for constructing 1D basin models of thermal evolution for the wells that reached Jurassic and Upper Triassic productive horizons at Block E; 1D basin modelling of multiple scenarios confirmed that the possible Jurassic and Upper Triassic source rocks did not enter the oil window zone. According to borehole temperature data, the average isotherm at the level of the Jurassic and Upper Triassic oil reservoirs is 44-55 °C at Nur-1 well. The model is calibrated to borehole temperature data from Nur-1 well; the discrepancy is less than 5% (Fig. 8).
1D thermal history modelling and calculated vitrinite reflectance (EasyRo%) using Sweeney and Burnham (1990) algorithm for Nur-1 and Tassym SE-1 wells potential Upper Devonian, Mid-Carboniferous and Lower Permian Asselian-Artinskian source rocks indicate that the source rocks were entering the main oil zone (0.7-1%R o ) progressively from Triassic to Early Jurassic. Lower Permian SR are predominantly in the late oil generation zone (Fig. 11).
The Middle Carboniferous source rocks with predominant type II kerogen (Yensepbayev et al. 2009;Gurgey 2002;Ulmishek 2001) entered the main oil zone during the Late Triassic and Jurassic and may have been a source of HC for Mesozoic structural traps formed due to salt tectonics. The deepest Devonian source rocks are predominantly in the zone of wet gas generation (1.3-2%R o ).
Based on burial and thermal regime modelling, the maturation and generation behaviour of kerogen types II occurred differently below salt-related minibasins (Figs. 3, 11). For Lower Permian SR with type II kerogen, the generation peak (maturity over 50%) occurs in Middle to Late Jurassic. For predominantly carbonate and terrigenous-carbonate Mid-Carboniferous marine SR, generation peak occurs earlier below salt withdrawal minibasins (Fig. 12). Thus, Palaeozoic SR generated hydrocarbons progressively through time depending on salt-related thermal regime. The amount and type of expelled hydrocarbons will depend on the quality and areal extent of potential source rocks in the pre-salt hydrocarbon kitchen (Dembicki, 2017). Additionally, analysis of oil physical properties of oils at the discovered multilayer accumulations in the Upper Triassic and Jurassic-Cretaceous stratigraphic sections demonstrates a decrease in oil density from 45° to 33°API upwards through the section, which also indirectly confirms the hypothesis of vertical HC migration from the pre-salt complex.

Conclusions
• Geochemical analysis of potential Upper Palaeozoic source rocks within the study area was implemented.
The results demonstrate fair to good generative potential. The degree of thermal maturity ranges from immature to overmature. For mature and overmature Upper Permian and Mid-Carboniferous SR with Tmax between 430 and 480 0 C, there are high TOC values 0.4-5.5% and high ROC/TOC ratio, which indicated that source rocks had generated hydrocarbons. Kerogen Type II is predicted based on previous studies and regional palaeogeographic reconstructions. • Calibrated 1D models for 3 wells were constructed based on integrated geodynamic history analysis. The thermal regime is controlled by salt withdrawal and contributes to timing of maturation. • Revision of 3D seismic interpretation was done, and for the first time intrasalt sediment packages and encased minibasins of presumably Upper Permian age had been delineated as separate features, which may be potential HC traps near welded regions. Additionally, potential structural and stratigraphic traps in pre-salt strata can be delineated based on 3D seismic. • The integrated modelling results on southeastern Precaspian petroleum system suggest deeper hydrocarbon prospectivity of Guryevsky height within the study area. Similarly, to other salt-dominated sedimentary basins halokinesis in southeastern Precaspian basin controls thermal evolution, source rocks maturation and migration pathways. • The methodology described in the present paper was used for evaluation and justification of deeper hydrocarbon prospectivity at Block E; the method is based on tectonic evolution analysis, seismostratigraphy, geochemical analysis and thermal modelling. The integrated approach can be applied not only in other acreages in Precaspian Basin with the lack of exploration data but also in other salt-dominated basins to modify exploration strategies and models.