Groundwater quality assessment using water quality index (WQI) under GIS framework

Groundwater is an important source for drinking water supply in hard rock terrain of Bundelkhand massif particularly in District Mahoba, Uttar Pradesh, India. An attempt has been made in this work to understand the suitability of groundwater for human consumption. The parameters like pH, electrical conductivity, total dissolved solids, alkalinity, total hardness, calcium, magnesium, sodium, potassium, bicarbonate, sulfate, chloride, fluoride, nitrate, copper, manganese, silver, zinc, iron and nickel were analysed to estimate the groundwater quality. The water quality index (WQI) has been applied to categorize the water quality viz: excellent, good, poor, etc. which is quite useful to infer the quality of water to the people and policy makers in the concerned area. The WQI in the study area ranges from 4.75 to 115.93. The overall WQI in the study area indicates that the groundwater is safe and potable except few localized pockets in Charkhari and Jaitpur Blocks. The Hill-Piper Trilinear diagram reveals that the groundwater of the study area falls under Na+-Cl−, mixed Ca2+-Mg2+-Cl− and Ca2+-HCO3-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${\text{HCO}}_{3}^{ - }$$\end{document} types. The granite-gneiss contains orthoclase feldspar and biotite minerals which after weathering yields bicarbonate and chloride rich groundwater. The correlation matrix has been created and analysed to observe their significant impetus on the assessment of groundwater quality. The current study suggests that the groundwater of the area under deteriorated water quality needs treatment before consumption and also to be protected from the perils of geogenic/anthropogenic contamination.


Introduction
In India, there has been a tremendous increase in the demand for groundwater due to rapid growth of population, accelerated pace of industrialization and urbanization (Yisa and Jimoh 2010). The availability and quality of groundwater are badly affected at an alarming rate due to anthropogenic activities viz. overexploitation and improper waste disposal (industrial, domestic and agricultural) to groundwater reservoirs (Panda and Sinha 1991;Kavitha et al. 2019aKavitha et al. , 2019b. Consequently, human health is seriously threatened by the prevailing agricultural practices particularly in relation to excessive application of fertilizers; unsanitary conditions and disposal of sewage into groundwater (Panigrahi et al. 2012). The groundwater quality also varies with depth of water, seasonal changes, leached dissolved salts and subsurface environment (Gebrehiwot et al. 2011). According to the World Health Organization (WHO 2017), about 80% of all the diseases in human beings are water-borne. Once the groundwater is contaminated, it is difficult to ensure its restoration and proper quality by preventing the pollutants from the source. It, therefore, becomes imperative to monitor the quality of groundwater regularly, and to device ways and means to protect it from contamination. The quality of groundwater is deciphered using various physical, chemical and biological characteristics of water (Diersing and Nancy 2009;Panneerselvam et al. 2020a). It is a measure of health and hygiene of groundwater concerning the need and purpose of human consumption (Johnson et al. 1997;Panneerselvam et al. 2020b).
In recent years, the assessment and monitoring of groundwater quality on a regular basis is being carried out using Geographic Information System (GIS) technique added with the IDW interpolation method and has proved itself as a powerful tool for evaluating and analysing spatial information of water resources Shankar et al. 2010Shankar et al. , 2011aVenkateswaran et al. 2012;Selvam et al. 2013b;Magesh and Elango 2019;Balamurugan et al. 2020b;Soujanya Kamble et al. 2020). It is an economically feasible and time-efficient technique for transforming huge data sets to generate various spatial distribution maps and projections revealing trends, associations and sources of contaminants/pollutants. In this work, GIS technique has been used for spatial evaluation of various groundwater quality parameters.
In this study, the physicochemical properties of fortythree groundwater samples collected from wells and hand pumps were determined and compared with international standards of WHO for drinking and domestic uses based on Water Quality Index (WQI). The WQI was first developed by Horton (1965) based on weighted arithmetical calculation. A number of researchers (Brown et al. 1972;GEMS UNEP 2007;Kavitha and Elangovan 2010;Alobaidy et al. 2010; Shankar and Kawo 2019; Bawoke and Anteneh 2020 developed various WQI models based on weighing and rating of different water quality parameters which is derived by the weighted arithmetic method. The WQI is a dimensionless number with values ranking between 0 and 100. The WQI is a unique digital rating expression that expresses overall water quality status viz. excellent, good, poor, etc. at a certain space and time based on various water quality parameters. Thus, the WQI is being used as an important tool to compare the quality of groundwater and their management (Jagadeeswari and Ramesh 2012) in a particular region; and is helpful for selecting appropriate economically feasible treatment process to cope up with the concerned quality issues. It depicts the composite impact of different water quality parameters and communicates water quality information to the public and legislative policy-makers to shape strong policy and implement the water quality programs (Kalavathy et al. 2011) by the government.
Mineral intractions strongly influence groundwater hydrochemistry in aquifers and disintegration of minerals from various source rocks (Cerar and Urbanc 2013;Modibo Sidibé et al. 2019). Hydrochemistry of the analysed samples indicates that the mean abundance of major cations is present in order of Na ++ > Ca 2+ > Mg 2+ > K + while major anions in order of HCO − 3 > NO − 3 > Cl − > SO 2− 4 > F − . The study shows that the sodium is dominant alkali while calcium and magnesium are the dominant alkaline earth metal leached in the aquafer due to rock water interaction affecting the quality of groundwater. Sodium in aquafer is derived from the weathering of halite and silicate minerals such as feldspar (Khan et al. 2014;Mostafa et al. 2017). The critical evaluation of Hill-Piper Trilinear diagram reflects Na + -Cl − , mixed Ca 2+ -Mg 2+ -Cl − , Ca 2+ -HCO − 3 , mixed Ca 2+ -Na + -HCO − 3 , Na + -HCO − 3 and Ca 2+ -Cl − type hydro-chemical facies in decreasing order of dominance. The Hydro-chemical characterization of groundwater reveals that the nature of aquifer is controlled by type of water, source and level of contamination (Aghazadeh et al. 2017;Brhane 2018). Hence, in order to keep the health of any aquaculture system, particularly an aquifer system at an optimal level, certain water quality indicators or parameters must be regularly monitored and controlled. Therefore, the objective of the study is to calculate the WQI of groundwater in order to assess its suitability for human consumption using the GIS interpolation technique and statistical approach in the study area.

Study area
Mahoba district is the south-western district of Uttar Pradesh which is adjacent to the state of Madhya Pradesh in south and Hamirpur (UP) in the north. The study area falls under the survey of India (SOI) toposheets no. 54O and 63C lies between latitude N25°01′30″ to N25°39′40″ and longitude E79°15′00″ to E80°10′30″ and covers an area of approximately 2933.59 km 2 . River Dhasan separates the district Mahoba from Jhansi in the west. A certainpart of Jhansi and Banda district has been merged in newly constructed Mahoba district in 1995 (bifurcated from Hamirpur). Mahoba district consists of three tehsils Kulpahar, Charkhari, Mahoba and four blocks Panwari, Jaitpur, Charkhari, Kabrai (Fig. 1a). Kabrai is the biggest block fromaerial coverage as well as population point of view. Jaitpur is the smallest block from aerial coverage and Charkhari from population point of view. The study area experiences a typical subtropical climate punctuated by long and intense summer, with distinct seasons. The area receives an average annual precipitation of 864 mm mainly from the south-west monsoon. The temperature of the coldest month (January) is 8.3°C while the temperature of the hottest month (May) shoots upto 47.5°C. The entire area under investigation is characterised by highly jointed/fractured Bundelkhand granite (Archean age) with thin soil cover. Physiographically, the area is characterised by Bundelkhand massif terrain and is marked by the occurrence of solitary or clustered hillocks and intervening low relief with undulating plains. Two major physiographic units are: (1) Southern part having high relief with hillocks-This is south of 20°25′ N latitude & maximum altitude is 340 mamsl, reserved forest. Granitoids and intervening pegmatitic veins and numbers of quartz veins a Study Area Map depecting the sampling sites (2) Northern part relatively low relief with lower hillocks-In between 25°25′N and 25°39′N latitude and maximum altitude is 310 mamsl. The area in and around Panwari is mainly covered with thick alluvium, and hard rock is encountered only below 35 mbgl, coverage with seasonal forest. Pedi plain, pediment inselberg and buried pediplains are present.

Geological and hydrogeological set-up
The granite, particularly leucogranite, older and younger alluvium consisting of clay, silt, sand and gravel mainly comprises the study area. The geological set-up of the study area indicates that the most dominant lithology is leucogranite covering mainly central and eastern part while recent alluvium covers the northern part ( Fig. 1b). At places, few patches of pink granite have also been recorded which appears enclosed in leucogranite or adjacent to its outcrop. The occurrence of groundwater is highly uncertain and unpredictable in this hilly and rugged terrain as it does not allow percolation and storages underground. The presence of porosity depends on the intensity of weathering and rock fracture which is responsible for groundwater occurrence, its quantity and flow mostly in permeable zones of weathered rock formations and under secondary porosity in the deep fractured zone. Groundwater recharge in the study area is triggered by the depth of overburden 7 m (Jaitpur-Kulpahar area) to 35 m (parts of Mahoba Tahsil and Charkhari block) as well as the intensity of weathering.

Materials and methods
The groundwater samples were collected during pre-monsoon (June 2016) period from the study area according to standard procedures of the American Public Health Association (APHA, 2017). The sampling locations were marked with the help of global positioning system (GPS) as shown in the Fig. 1a. Samples were collected from the location through hand pump (depth: approx. 40 m) and dug wells (depth: 8-30 m) as shown in Fig. 2a-t. The collecting bottles (High-Density Polythene, HDPE) of one-litre capacity each were sterilized under the aseptic condition to avoid  The samples were stored in a chemical laboratory at temperature 4-5 °C. The samples for metallic parameters were added 2 ml elemental grade nitric acid to obtain the pH 2-3 after acidification. The samples were pre-filtered in the laboratory to carry out the analysis. In the present study, a total of 20 groundwater quality parameters of forty-three samples were analysed as per test standard methods (APHA 2017) in the laboratory except for unstable parameters viz. hydrogen ion concentration (pH), electrical conductivity (EC) and total dissolved solids (TDS) which are determined by portable device (pH-meter, EC-meter and TDS-meter) in situ. Alkalinity (AK), Total hardness (TH), calcium (Ca 2+ ), magnesium (Mg 2+ ), bicarbonate ( HCO − 3 ) and chloride (Cl − ) were analysed using volumetric titrations; sodium (Na + ) and potassium (K + ) were analysed using systronics flame photometer model 129; nitrate ( NO − 3 ), fluoride (F − ), sulfate ( SO 2− 4 ), were analysed using shimadzu 1800 spectrophotometer. Prior to analysis of the heavy metals viz. copper (Cu), manganese (Mn), silver (Ag), zinc (Zn), iron (Fe) and nickel (Ni); the groundwater samples were acidified with 1:1 nitric acid and concentrated ten times. The samples were subjected to analysis using Shimadzu 6701 Atomic Absorption Spectrophotometer (AAS) on flame mode with hollow cathode lamps of metal under analysis. The concentration of metal is displayed on the monitor. The standards of the metallic parameters were prepared from National Institute of Standards and Technology (NIST) certified (Certified Reference Materials) CRM as per NABL guidelines of 17,025:2017.
The quality assurance and quality control (QA/QC) procedure of the data has been considered during the study. Approximately half of the volume (500 ml) of samples were specially separated and checked in the laboratory to ensure QA/QC mechanisms. The accuracy of the chemical analysis has been validated by charge balance errors and samples < 5% error were considered.
The inverse distance weighted (IDW) interpolation technique used in this study is now-adays an effective tool for spatial interpolation of groundwater quality parameters leading to the generation of spatial distribution maps (Magesh et al. 2013;Kawo and Shankar 2018;Balamurugan et al. 2020b;Sarfo and Shankar 2020). The weights were assigned to various parameters at each location based on distance and were calculated, taking into consideration the closest specified locations. The distribution of each groundwater quality parameter has been demarcated in different zones on spatial distribution map viz. acceptable/desirable and permissible limits according to BIS (2012BIS ( , 2015 and WHO (2017) for drinking purpose. The statistical analysis and correlation matrix of the analysed groundwater quality parameters have been laid down as shown in Tables 1 and 2, respectively.

The water quality index (WQI)
The WQI has been determined using the drinking water quality standard recommended by the World Health Organization (WHO 2017). The Water Quality Index has been calculated using the weighted arithmetic method, which was originally proposed by Horton (1965) and developed by Brown et al. (1972). The weighted arithmetic water quality index (WQI) is represented in the following way: where n = number of variables or parameters, W i = unit weight for the ith parameter, Q i = quality rating (sub-index) of the ith water quality parameter.
The unit weight (W i ) of the various water quality parameters are inversely proportional to the recommended standards for the corresponding parameters.
where, W i = unit weight for the ith parameter, S n = standard value for ith parameters, K = proportional constant, The value of K has been considered '1′ here and is calculated using the mentioned equation below: According to Brown et al. (1972), the value of quality rating or sub-index (Q i ) is calculated using the equation as given below: where V o = observed value of ith parameter at a given sampling site, V i = ideal value of ith parameter in pure water, S n = standard permissible value of ith parameter. All the ideal values (V i ) are taken as zero for drinking water except pH and dissolved oxygen (Tripathy and Sahu 2005). In case of pH, the ideal value is 7.0 (for natural/ pure water) while the permissible value is 8.5 (for polluted water). Similarly, for dissolved oxygen, the ideal value is 14.6 mg/L while the standard permissible value for drinking water is 5 mg/L. Therefore, the quality rating for pH and Dissolved Oxygen are calculated from the equations respectively as shown below: where, V pH = observed value of pH, V do = observed value of dissolved oxygen.
If, Q i = 0 implies complete absence of contaminants while 0 < Q i < 100 implies that, the contaminants are within the prescribed standard. When Q i > 100 implies that, the contaminants are above the standards.  The classification of water quality, based on its water quality index (WQI) after Brown et al. (1972); Chatterjee and Raziuddin (2002) and Shankar and Kawo (2019) have been considered here in this study for further reference which is mentioned in Table 3.

Groundwater quality parameters
In this study based on the selected parameters as discussed above the groundwater quality maps have been prepared with the help of ArcGIS software 10.1 as shown in Fig. 2a-t. In the following lines, the various parameters considered in the study are being discussed: The Bureau of Indian Standard (BIS 2012(BIS , 2015 and World Health Organization (WHO 2017) of drinking water standards have been considered as a reference in this study.

Hydrogen ion concentration (pH)
It is an important indicator for assessing the quality and pollution of any aquifer system as it is closely related to other chemical constituents of water. The presence of hydrogen ion concentration is measured in terms of pH range. Water, in its pure form shows a neutral pH which indicates hydrogen ion concentration. In the present study, the range of pH varies between 6.81 (minimum) to 8.32 (maximum) which is within the acceptable limit (6.5-8.5, avg: 7.81) indicating the alkaline nature of groundwater (ideal range of pH for human consumption: 6.5-8.5).

Electrical conductivity (EC)
In fact, it is a measure of the ability of any substance or solution to conduct electrical current through the water. EC is directly proportional to the dissolved material in a water sample. The desirable limit of EC for drinking purpose is 750 µS/cm. In this study, the electrical conductivity varies between 286 and 1162 µS/cm. High EC at some sites suggests the mixing of sewage in groundwater as these sites are near dense urbanization.

Total dissolved solids (TDS)
The weight of residue expresses it after a water sample is evaporated to dry state. It includes calcium, magnesium, sodium, potassium, carbonate, bicarbonate, chloride and sulfate. In the present study, it ranges between 280 to 879 mg/l (< 500 mg/l TDS for potable water as per BIS.). The agricultural practices, residential runoff, leaching of soil causing contamination and point source water pollution discharge from industrial or sewage treatment plants are the primary sources for TDS (Boyd 2000).

Alkalinity (AK)
It is a measure of the carbonate, bicarbonate and hydroxide ions present in water. The desirable limit of alkalinity in potable water is 200 mg/l, above which the taste of water becomes unpleasant. In the study area, the alkalinity ranges between 50 to 452 mg/l, which is within the permissible limit (600 mg/l).

Total hardness (TH)
It is the amount of dissolved calcium and magnesium in the water. Water moving through soil and rock dissolves naturally occurring minerals and carries them into the groundwater as it is a great solvent for calcium and magnesium. In this study, hardness ranges between 70 to 592 mg/l, which is within the permissible limits (600 mg/l). The high concentration of TH in groundwater may cause heart disease and kidney stone in human beings.

Calcium (Ca 2+ )
It enters into the aquifer system from the leaching of calcium bearing minerals. In the study area, the calcium concentration ranges from 12 to 112 mg/l and is within the permissible limit (200 mg/l). The lesser concentration of Ca 2+ in the groundwater satisfies the chemical weathering and dissolution of fluorite, consequently resulting in an increase of fluoride concentration.

Magnesium (Mg 2+ )
It is an important parameter responsible for the hardness of the water. In the study area, the concentration ranges between 2.4 to 120 mg/l and is present in little excess of the permissible limit (100 mg/l).

Sodium (Na + )
It is a highly reactive alkali metal. It is present in most of the groundwater. Many rocks and soils contain sodium compounds, which easily dissolves to liberate sodium in groundwater. In the study area, it ranges from 48.71 to 244.4 mg/l. The high concentration of Na + indicates weathering of rockforming minerals i.e., silicate minerals (alkali feldspars) and/ or dissolution of soil salts present therein due to evaporation (Stallard and Edmond 1983). In the aquifers, the high Na + concentration in groundwater may be related to the mechanism of cation exchange (Kangjoo Kim and Seong-Taekyun 2005).

Potassium (K + )
It is present in many minerals and most of the rocks. Many of these rocks are relatively soluble and releases potassium, the concentration of which increases with time in groundwater. In this study, it varies between 0.87 to 2.7 mg/l.

Bicarbonate ( HCO −
3 ) It is produced by the reaction of carbon dioxide with water on carbonate rocks viz. limestone and dolomite. The carbon-dioxide present in the soil reacts with the rock-forming minerals is responsible for the presence of bicarbonate, producing an alkaline environment in the groundwater. In the study area it varies between 36.61 to 536.95 mg/l and is within the permissible limit of 600 mg/l.

Sulfate ( SO 2−
4 ) It is dissolved and leached from rocks containing gypsum, iron sulfides, and other sulfur bearing compounds. In the present study, it ranges between the 2.23 to 75.17 mg/l, which is well within the acceptable limit of 200 mg/l.

Chloride (Cl − )
In the present study the Cl − ranges between 70.92 to 276.59 mg/l which exceed the permissible limit (250 mg/l). The higher value of chlorine in groundwater makes it hazardous to human health (Pius et al. 2012;Sadat-Noori et al. 2014).

Fluoride (F − )
In groundwater fluoride is geogenic in nature. It is the lightest halogen, and one of the most reactive elements (Kaminsky et al. 1990). It usually occurs either in trace amounts or as a major ion with high concentration (Gaciri and Davies 1993;Apambire et al. 1997;Fantong et al. 2010). The groundwater contains fluorides released from various fluoride-bearing minerals mainly as a result of groundwater-host rock interaction. The study area comprising granite, granitic gneiss etc. is commonly found to contain fluorite (CaF 2 ) as an accessory mineral (Ozsvath 2006;Saxena and Ahmed 2003) which plays a significant role in controlling the geochemistry of fluo-ride (Deshmukh et al. 1995). In addition to fluorite it is also abundant in other rock-forming minerals like apatite, micas, amphiboles, and clay minerals (Karro and Uppin 2013;Narsimha and Sudarshan 2013;Naseem et al. 2010;Jha et al. 2010;Rafique et al. 2009;Carrillo-Rivera et al. 2002). In the present study, the fluoride concentration ranges from 0.11 to 3.91 mg/l. The concentration of fluoride exceeds the permissible limit (1.5 mg/l) in about 25% of the groundwater samples.

Nitrate ( NO −
3 ) Nitrate is naturally occurring ions and is a significant component in the nitrogen cycle. However, nitrate ion in groundwater is undesirable as it causes Methaemoglobinaemia in infants less than 6 months of age (Egereonu and Nwachukwu 2005). In general, its higher concentration causes health hazards if present beyond the permissible limit, 45 mg/l (Kumar et al. 2012(Kumar et al. , 2014. In the study area, its concentration ranges from 86.95 to 210.4 mg/l. It is in excess of the permissible limits throughout the study area. The higher values of nitrate in potable water increases the chances of gastric ulcer/cancer, and other health hazards to infants and pregnant women (Rao 2006) also birth malformations and hypertension (Majumdar and Gupta 2000). The area under study is granite-gneiss terrain where the atmospheric nitrogen is fixed and added to the soil as ammonia through lightning storms, bacteria present in soil and root of plants. Further, animal wastes, plants and animals remain also undergo ammonification in the soil producing ammonia which undergoes nitrification/ammonia oxidation by Nitrosomonas and Nitrobacter bacteria to form nitrate (Rivett et al. 2008;Galloway et al. 2004). Granitic rocks contain nitrogen concentrations up to 250 mg Nkg −1 with ammonium partitioned into the orthoclase feldspar to a greater extent than muscovite or biotite (Boyd et al. 1993). Geologic nitrogen (nitrogen contained in bedrock) contribute to the ecosystem with nitrogen saturation (more nitrogen available than required by biota) leading to leaching of nitrogen and consequently elevating nitrate concentrations in groundwater (Dahlgren 1994;Holloway et al. 1998). Nitrogen released through weathering has a greater impact on soil and water quality. Also, denitrification is significant in modifying the level to which nitrogen released through weathering of bedrock influencing the supply of nitrate in groundwater (McCray et al. 2005).

Copper (Cu)
It is a naturally occurring metal in rock, soil, plants, animals, and groundwater in very less concentration. The concentration of Cu may get enriched into the groundwater through quarrying and mining activities, farming practices, manufacturing operations and municipal or industrial waste released. Cu gets into drinking water either by contaminating of well water or corrosion of copper pipes in case of water is acidic. In this study, it ranges between 0 and 0.0078 mg/l, which is within the permissible limit (0.05 mg/l).

Manganese (Mn)
It occurs naturally in groundwater, especially in an anaerobic environment. The concentrations of Mn in groundwater is dependent upon rainfall chemistry, aquifer lithology, geochemical environment, groundwater flow paths and residence time, etc. which may vary significantly in space and time. It may be released by the leaching of the overlying soils and minerals in underlying rocks as well as from the minerals of the aquifer itself in groundwater. In the present study, manganese ranges between 0.005 and 0.221 mg/l, which is within the permissible limit (0.3 mg/l).
Silver It naturally occurs usually in the form of insoluble and immobile oxides, sulfides and some salts. It is rarely present in groundwater, surface water and drinking water at concentrations above 5 µg/litre (WHO 2017). In the present study, the silver ranges between 0.000 and 0.021 mg/l, which is within the permissible limit (0.1 mg/l).
Zinc Though it occurs in significant quantities in rocks, groundwater seldom contains zinc above 0.1 mg/l. In the present study, the groundwater shows the negligible concentration of Zn (0.0136 mg/l) which is well within the acceptable limit (5 mg/l).

Iron (Fe)
The most common sources of iron in groundwater is weathering of iron-bearing minerals and rocks. The iron occurs naturally in the reduced Fe 2+ state in the aquifer, but its dissolution increases its concentration in groundwater. Iron in this state is soluble and generally does not create any health hazard. If Fe 2+ state is oxidised to Fe 3+ state in contact with atmospheric oxygen or by the action of iron-related bacteria which forms insoluble hydroxides in groundwater. So, the concentration of iron in groundwater is often higher than those measured in surface water. In the present study, the iron ranges between 0.0994 and 0.4018 mg/l, which is within of the permissible limit 1.0 mg/l (BIS 2015).

Nickel (Ni)
The primary source of nickel in groundwater is from the dissolution of nickel ore bearing rocks. The source of nickel in drinking water is leaching from metals in contact such as water supply pipes and fittings. Ni usually occurs in the divalent state, but oxidation states of + 1, + 3, or + 4 may also exist in nature. In the study area, it ranges between 0 and 0.0408 mg/l, and it crosses the permissible limit (0.02 mg/l).

Statistical analysis, correlation matrix and relative weightage
The relative weightage, general statistical analysis and correlation matrix of groundwater quality parameters are tabulated in Tables 4, 1 and 2, respectively. The correlation matrix of various 20 groundwater quality parameters, including 6 heavy metals was created and has been analysed using MS Excel 2016 Table 2. Out of these, eight parameters viz. TDS, EC, Na + , Alkalinity, TH, Ca 2+ , Mg 2+ , HCO − 3 are significantly correlated, reflecting more than 0.50 correlation value. Further, TDS vs EC, Na + vs Alkalinity, TH as CaCO 3 − vs Ca 2+ and Mg 2+ , HCO − 3 vs Alkalinity and Na + indicates most relevant correlation having a significant impetus on the overall assessment of the quality of groundwater than any other major radicals and physical parameters. However, the majority of quality parameters are positively correlated with each other. A critical analysis of the correlation matrix for the heavy metals indicates that Cu is positively correlated with EC, TDS, Na + , K + , Cl − and NO − 3 . Similarly, Mn is positively correlated with pH, EC, TDS and Cu. While, Ag is positively correlated with pH, Ca 2+ , Mg 2+ , K + , TH, Cl − , NO − 3 and Mn. Further, Fe is positively correlated with TDS, Mg 2+ , Na + , TH, HCO − 3 , SO 2− 4 , NO − 3 , Cu and Ag. Similarly, Ni is positively correlated with pH, EC, TDS, Ca 2+ , K + , NO − 3 and Mn.  The higher concentration of Ni, Fe and Mn may trigger the presence of other heavy metals viz. Pb, Cd and Cr which are very sensitive and significant heavy metal and needs to be observed carefully in future for groundwater quality in the study area. The presence of Fe, SO 2− 4 and NO − 3 may trigger the presence of Cd (Chaurasia et al. 2018).

Spatial distribution pattern
The spatial distribution pattern of the contour maps of the groundwater quality parameters have been generated as represented in Fig. 2a-t. The spatial distribution pattern of the pH indicates that the central part along NW-SE across the district with some scattered small patches throughout indicating the presence of alkaline groundwater (Fig. 2a). In acidic water, fluoride is adsorbed on a clay surface, while in alkaline water, fluoride is desorbed from solid phases; therefore, alkaline pH is more favourable for fluoride dissolution, (Keshavarzi et al. 2010;Rafique et al. 2009;Saxena and Ahmed 2003;Rao 2009;Ravindra and Garg 2007;Vikas et al. 2009). The southern portion of the district in Kabrai Block is having high TDS (> 750 mg/l) in groundwater (Fig. 2c) due to poor fluxing and highly weathered rock formations. Similarly, EC is mainly highest (> 900 mg/l) in the southern part with small scattered patches in central and NE part of the district (Fig. 2b). This is in consonance with the higher TDS (significant positive correlation with EC) as evidenced by the correlation matrix of the quality parameters ( Table 2). The alkalinity map clearly and significantly indicates that it is highest in the central part surrounded by gradually decreasing alkalinity outwards (Fig. 2d). The bicarbonates trigger the alkalinity in groundwater (Adams et al. 2001). The quality of groundwater in a major portion of the study area is alkaline in nature, indicating that the dissolved carbonates are predominantly in the form of bicarbonates. A positive correlation is observed between the alkalinity of groundwater and fluoride (Table 2), consequently releasing fluoride in the groundwater. The spatial distribution map of Ca 2+ suggests varying concentration within permissible limit throughout the study area (Fig. 2f) due to the presence of alkali feldspar in granite. Similarly, Mg 2+ is also distributed unevenly but falls within permissible limit with an exception in NE part of the district (Fig. 2g). The spatial distribution pattern of TH reflects that the study area is characterized by moderately hard groundwater. Figure 2e The Ca 2+ and Mg 2+ ions present in the groundwater are possibly derived from leaching of calcium and magnesium bearing rock-formations in the study area. The fluoride in groundwater shows a negative correlation with Ca 2+ , indicating the high value of fluoride in groundwater in association with low Ca 2+ content. The correlation matrix clearly marks a significant positive correlation among Na + , alkalinity and TDS, which is being reflected from their respective spatial distribution maps (Fig. 2c, d and h). Na + is highest in the central part (with small patches in the eastern part and insignificantly in the western part) which is in conformity with the alkalinity and TDS spatial distribution patterns. Although, the presence of K + is insignificant and its lower concentration within the permissible limit is covering a major portion of the district due to poor weathering of orthoclase. Its distribution pattern indicates conformity more or less with the TDS and Na + (Fig. 2c, h, and i). HCO − 3 is an important quality parameter showing significant positive correlation (> 0.50) with alkalinity and Na + (Table 2) which is also reflected in the spatial distribution pattern of these parameters (Fig. 2d, h, j). Although sulphate ( SO 2− 4 ) is an important quality parameter. It is present within the permissible limit in the study. area (Fig. 2k). Chloride is slightly in excess in a larger patch, particularly in SE-part of the study area which may cause a health hazard. It is revealed from the spatial distribution map of chloride (Fig. 2l). This is due to poor fluxing and presence of halite mineral. Fluoride (F − ) is an important quality parameter, especially with respect to the study area where it is present noticeably in scattered patches throughout the district. It is observed that mainly in NE part, the central part and SE part of the district the concentration of fluoride is in excess (2.82 mg/l to 3.91 mg/l) of permissible limit 1.5 mg/l (Fig. 2m). The higher concentration (> 3.0 mg/l) of fluoride may lead to skeletal fluorosis (Raju et al 2009). Several factors viz. temperature, pH, presence or absence of complexing or precipitating ions and colloids, the solubility of fluorine bearing minerals (biotite and apatite), anion exchange capacity of the aquifer (OH − with F − ), size and type of geological formations traversed by groundwater and the contact time during which water remains in contact with the formation are responsible for fluoride concentration in groundwater (Apambire et al. 1997). The lithology of fractured rock reveals that it contains more fluoride bearing minerals than massive rocks (Pandey et al. 2016). Nitrate (NO 3 − ) in groundwater is mainly anthropogenic in nature which could be due to leaching from waste disposal, sanitary landfills, over-application of inorganic nitrate fertilizer or improper manure management practice (Chapman 1996). In this study, it is observed that nitrate is in excess of the permissible limits with varying degree of concentration throughout the district, causing health hazard (Fig. 2n). The area under study is granite-gneiss terrain where the atmospheric nitrogen is fixed and added to the soil as ammonia through lightning storms, bacteria present in soil and plants roots. Further, animal wastes, plants and animals remain also undergo ammonification in the soil producing ammonia which undergoes nitrification. The high values of nitrate in groundwater samples in the area may be due to unlined septic tanks and unplanned sewerage system that contaminates to the phreatic aquifer (Hei et al. 2020). Proper monitoring and concerned regulated effort are consistently required to get the assessment of nitrate impact on human health.
As far as heavy metals concentration in groundwater is concerned, Cu does not mark its noticeable presence (Fig. 2o). Another, naturally occurring quality parameter is Mn which shows its presence within the permissible limit (Fig. 2p). Silver and Zinc do not show any remarkable presence in the study area ( Fig. 2q and r). The study reveals a higher concentration of iron in groundwater in the Eastern part of the district due to secondary porosity and where ferrous (Fe 2+ ) ion usually occurs below the water table. The Fe 2+ after converting into Ferric (Fe 3+ ) state, becomes harmful and precipitated. This condition can be avoided naturally by raising the water table through groundwater recharging the affected area (Fig. 2s). Nickel shows its remarkable presence in smaller patches in different areas (Fig. 2t) due to the presence of heavy minerals like rutile and apatite.

Water quality index
The water quality index (WQI) map has been prepared using ArcGIS 10.1 on the basis of the selectively chosen quality parameters to decipher the various quality classes viz. excellent, good, poor, very poor and unsuitable at each hydrostation for drinking purpose (Tables 3 and 5; Fig. 3). The WQI Map of the study area indicates that major portion is having excellent (0-25) quality of groundwater while very poor (75-100) to unsuitable (> 100) quality is prevailing in small pockets in SW part (Fig. 3). The map clearly indicates that the quality of groundwater in Panwari Block belongs to excellent to good categories as for as potability for human consumption is concerned.
There is gradual variation in groundwater quality from very poor to excellent at the central part and outwards in the Charkhari Block. There is no noticeable change in the quality of groundwater except in the SW part of the Kabari Block. In the Jaitpur block, there is a significant.
variation in the quality class and the SW part (Nanwara, Ajnar and Khama) is characterized by poor, very poor and unsuitable categories (Fig. 3). Remaining part of the block falls under good to excellent groundwater quality. Overall, the quality of groundwater belongs to the excellent category in a major portion of the study area and is suitable for drinking as well as domestic uses.

Hydro-chemical facies
The major ions analysed are unevenly distributed and have been plotted on a Hill-Piper Trilinear diagram (Fig. 4). This diagram is comprised of two triangles at the base and one diamond shape at the top to represent the major significant cations and anions responsible for the nature of groundwater (Balamurugan et al. 2020a (Table 1). This reveals that sodium, chloride and bicarbonate dominate the ionic concentration in the groundwater due to action of weathering of minerals like halite and dolomite as well as ion exchange process.

Conclusion
• The outcome of the present research in the hard rock area of the Bundelkhand region of India reveals that the groundwater has been deteriorated due to both geogenic and anthropogenic activities. • The study area is comprised mainly of granite and alkali granite, specifically in extreme southern which is responsible for leaching of fluoride in groundwater. • The thickness of overburden (loose soil and weathered rock) in the northern part of the study area is negligible. Therefore, there is a poor fluxing of groundwater which in turn triggers the concentration of TDS, fluoride and bicarbonate in groundwater. • Anthropogenic activities like unlined septic tanks and unplanned sewerage system have triggered the nitrate concentration in groundwater, particularly in the central and northern part of the study area. The rest of the area is safe and has potable groundwater. In addition, the area under study is granite-gneiss terrain where the atmospheric nitrogen is fixed and added to the soil as ammonia through natural lightning, bacteria present in soil and plants roots. Further, ammonification of animal wastes, plants and animal remains produces ammonia which undergoes nitrification. • Hydro-chemical facies reveal that the nature of groundwater is Na + -Cl − , mixed Ca 2+ -Mg 2+ -Cl − and Ca 2+ -HCO − • The high value of WQI has been found, which is due to the higher values of chloride, fluoride, nitrate, manganese, iron, and nickel in the groundwater, which warrants immediate attention.
• On the basis of WOI, it is concluded that the groundwater is safe and potable in the study area except for localized pockets in Jaitpur and Charkhari Blocks.