Skip to main content
Log in

Clogging behavior of submerged entry nozzles for Ti-bearing IF steel

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

The nozzle clogging behavior of Ti-bearing IF steel was studied by metallographic analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). According to the experimental results, nozzle clogging primarily appears three layers. There are a lot of large-sized iron particles in the inner layer and mainly slag phase in the middle and outer layers. The principal clog constituents of the inner layer are loose alumina cluster inclusions and granular shaped alumina inclusions, containing iron particles. The clog constituents of the middle layer are mainly dendrite alumina inclusions. The primary phases existing in nozzle clogging are FeO·TiO2 and FeO·Al2O3 besides α-Al2O3 and α-Fe. The FeO·TiO2 phases among the deposits adhere the deposits together firmly enough to lead to the inferior castability of Ti-bearing ultra low carbon steel compared with that of Ti-free low carbon Al-killed steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L.A. Frank, Castability—from alumina to spinels, Iron Steelmaker, 26(1999), No.4, p.33.

    CAS  Google Scholar 

  2. S.K. Choudhary and A.J. Khan, Nozzle clogging during continuous slab casting at Tata Steel, Steel Times Int., 24(2000), No.5, p.21.

    Google Scholar 

  3. F. Fuhr, G. Cicutti, G. Walter, et al., Relationship between nozzle deposits and inclusion composition in the continuous casting of steels, Iron Steelmaker, 30(2003), No.12, p.53.

    Google Scholar 

  4. F.M. Yuan, X.H. Wang, J.M. Zhang, et al., Online forecasting model of tundish nozzle clogging, J. Univ. Sci. Technol. Beijing, 13(2006), No.1, p.21.

    Google Scholar 

  5. G.C. Duderstadt, R.K. Iyengar, and J.M. Matesa, Tundish nozzle blockage in continuous casting, J. Met., 20(1968), No.4, p.89.

    Google Scholar 

  6. J.W. Farrell and D.C. Hilty, Steel flow through nozzles: Influence of deoxidizers, Electr. Furnace Conf. Proc., 29(1971), p.31.

    CAS  Google Scholar 

  7. P.M. Benson, Q.K. Robinson, and C. Dumazeau, New technique for prevention of alumina build-up in submerged entry nozzles for continuous casting, [in] United International Technical Conference on Refractories 1993, San Paulo, Brazil, 1993, p.1087.

  8. Y. Hiraga, Y. Yashima, and K. Fujii, Behavior of alumina-deposition on tundish nozzles in continuous casting of Ti-added Al killed steel, Taikabutsu Overseas, 15(1995), No.1, p.22.

    Google Scholar 

  9. J. Poirier, B. Thillou, and M.A. Guiban, Mechanisms and countermeasures of alumina clogging in submerged nozzles, [in] 78th Steelmaking Conference Proceedings, Nashville, 1995, p.451.

  10. S. Basu, S.K. Choudhary, and N.U. Girase, Nozzle clogging behaviour of Ti-bearing Al-killed ultra low carbon steel, ISIJ Int. 44(2004), No.10, p.1653.

    Article  CAS  Google Scholar 

  11. M.K. Sun, I.H. Jung, and H.G. Lee, Morphology and chemistry of oxide inclusions after Al and Ti complex deoxidation, Met. Mater. Int., 14(2008), No.6, p.791.

    Article  CAS  Google Scholar 

  12. K. Sasai and Y. Mizukami, Mechanism of alumina adhesion to continuous caster nozzle with reoxidation of molten steel, ISIJ Int., 41(2001), No.11, p.1331.

    Article  CAS  Google Scholar 

  13. Y. Fukuda, Y. Ueshima, and S. Mizoguchi, Mechanism of alumina deposition on alumina graphite immersion nozzle in continuous caster, ISIJ Int., 32(1992), No.1, p.164.

    Article  CAS  Google Scholar 

  14. K. Sasai and Y. Mizukami, Reaction mechanism between alumina graphite immersion nozzle and low carbon steel, ISIJ Int., 34(1994), No.10, p.802.

    Article  CAS  Google Scholar 

  15. R. Tsujino, A. Tanaka, A. Imamura, et al., Mechanism of deposition of inclusion and metal in ZrO2-CaO-C immersion nozzle of continuous casting, ISIJ Int., 34(1994), No.11, p.853.

    Article  CAS  Google Scholar 

  16. Y. Vermeulen, B. Coletti, B. Blanpain, et al., Material evaluation to prevent nozzle clogging during continuous casting of Al killed steels, ISIJ Int., 42(2002), No.11, p.1234.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yan-ping Bao.

Additional information

This work was financially supported by the National Key Technologies R&D Program of China (No.2006BAE03A06).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cui, H., Bao, Yp., Wang, M. et al. Clogging behavior of submerged entry nozzles for Ti-bearing IF steel. Int J Miner Metall Mater 17, 154–158 (2010). https://doi.org/10.1007/s12613-010-0206-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-010-0206-y

Keywords

Navigation