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Effect of Calcium on the Rate of Grain Boundary Migration in Pure Magnesium During Annealing

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Abstract

This study investigates the influence of calcium (Ca) on grain boundary migration in pure magnesium (Mg) during annealing. Pure Mg and Mg-0.5Ca alloy samples undergo compression and subsequent annealing at various temperatures to reveal that the presence of Ca impedes grain growth through solute drag effects and Zenner pinning induced by Mg2Ca particles. The segregation of Ca solute atoms at grain boundaries imposes solute drag, reducing boundary mobility, while Mg2Ca intermetallic particles also act as barrier to grain boundary migration. The research demonstrates weakened basal texture and smaller grain size in Mg-0.5Ca, attributed to particle-stimulated nucleation (PSN). Twin boundaries (TBs) also influence grain growth kinetics, with dislocation effects limiting grain coarsening at lower annealing temperatures. As annealing temperature increases, dislocation annihilation occurs, enabling freer grain boundary migration. Vickers hardness test was employed which revealed increased hardness in Mg-0.5Ca alloy because of stress accumulations arising from obstacles hindering the movement of dislocations, which are generated by solute elements and second-phase particles. Conversely, the reduction in hardness values as annealing temperature rises in both materials indicates a heightened dislocation annihilation process due to static recovery occurring at elevated temperatures.

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Acknowledgements

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2020R1C1C1004434) and the Commercialization Promotion Agency for R&D Outcomes (COMPA) funded by the Ministry of Science and ICT (MSIT) (1711198546, Development of Core Technologies in Photon/Charged-particle Triple Beam for 3D Microstructure Fabrication and Characterization).

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Authors and Affiliations

  1. Department of Mechanical Engineering, Incheon National University, Incheon, 22012, Republic of Korea

    Hafiz Muhammad Rehan Tariq, Umer Masood Chaudry & Tea-Sung Jun

  2. Research Institute for Engineering and Technology, Incheon National University, Incheon, 22012, Republic of Korea

    Umer Masood Chaudry & Tea-Sung Jun

  3. Advanced Forming Process R&D Group and 3D Printing Manufacturing Process Centre, Korea Institute of Industrial Technology, Ulsan, 44776, Republic of Korea

    Chung-Soo Kim

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  1. Hafiz Muhammad Rehan Tariq
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  2. Umer Masood Chaudry
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  4. Tea-Sung Jun
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Correspondence to Tea-Sung Jun.

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Tariq, H.M.R., Chaudry, U.M., Kim, CS. et al. Effect of Calcium on the Rate of Grain Boundary Migration in Pure Magnesium During Annealing. Met. Mater. Int. (2024). https://doi.org/10.1007/s12540-023-01612-6

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