Abstract
High-performance flexible electronic textiles exhibit considerable potential for use as wearable energy storage and sensor fields. In this paper, we fabricated multifunctional PANI/PLA composite electronic fabrics by a simple in-situ polymerization reaction. The fabrics have an areal specific capacitance of 1171.4 mF/cm2 when used as an electrode, and the capacitance retention of 93.02% after 2000 charge/discharge cycles. The symmetric all-solid-state supercapacitors assembled based on PANI/PLA fabrics demonstrated an attractive capacitive performance with a high energy density of 30.27 μWh/cm2 at a power density of 0.217 mW/cm2. Meanwhile, the PANI/PLA electronic fabrics can also be used as flexible sensors to monitor the movement of the human body in real time. More importantly, the PANI/PLA functional fabrics also possess good flame retardant performance, antibacterial and electromagnetic shielding properties. These results indicate that the prepared PANI-coated PLA fabrics have broad application potential in wearable electronic textiles.
Similar content being viewed by others
References
X. Chu, G. Chen, X. Xiao, Z. Wang, T. Yang, Z. Xu, H. Huang, Y. Wang, C. Yan, N. Chen, H. Zhang, W. Yang, J. Chen, Small 17, 2100956 (2021)
M.R. Islam, S. Afroj, C. Beach, M.H. Islam, C. Parraman, A. Abdelkader, A.J. Casson, K.S. Novoselov, N. Karim, iScience 25, 103945 (2022)
Y. Yang, Q. Huang, L. Niu, D. Wang, C. Yan, Y. She, Z. Zheng, Adv. Mater. 29, 1606679 (2017)
J. Lv, P. Zhou, L. Zhang, Y. Zhong, X. Sui, B. Wang, Z. Chen, H. Xu, Z. Mao, Chem. Eng. J. 361, 897–907 (2019)
X. Yin, H. Li, Y. Fu, R. Yuan, J. Lu, Chem. Eng. J. 392, 124820 (2020)
Q. Cheng, C. Meng, Y. Qian, J. He, X. Dong, Prog. Org. Coat. 138, 105439 (2020)
J. Yan, S. Li, B. Lan, Y. Wu, P.S. Lee, Adv. Funct. Mater. 30, 1902564 (2019)
Z. Li, K. Xu, Y. Pan, Nanotechnol. Rev. 8, 35–49 (2019)
S.A. Delbari, L.S. Ghadimi, R. Hadi, S. Farhoudian, M. Nedaei, A. Babapoor, A. Sabahi Namini, Q.V. Le, M. Shokouhimehr, M. Shahedi Asl, M. Mohammadi, J. Alloy Compd. 857, 158281 (2021)
Y. Wang, Y. Ding, X. Guo, G. Yu, Nano Res. 12, 1978–1987 (2019)
Y. Shen, Z. Qin, S. Hu, L. Yang, X. Xu, L. Ding, Y. Zhang, Carbon 158, 711–718 (2020)
J. Orangi, F. Hamade, V.A. Davis, M. Beidaghi, ACS Nano 14, 640–650 (2020)
T. Wang, Y. Zhang, Q. Liu, W. Cheng, X. Wang, L. Pan, B. Xu, H. Xu, Adv. Funct. Mater. 28, 1705551 (2018)
Z. Wu, K. He, Y. Wu, J. Mao, Z. Yang, Y. Xu, C. Yuan, B. Zeng, L. Dai, J. Power Sources 442, 227215 (2019)
Z. Liu, J. Chen, Y. Zhan, B. Liu, C. Xiong, Q. Yang, G. Hu, ACS Sustain. Chem. Eng. 7, 17653–17660 (2019)
J. Cao, C. Wang, Org. Electron. 55, 26–34 (2018)
Z. Kucekova, P. Humpolicek, V. Kasparkova, T. Perecko, M. Lehocky, I. Hauerlandova, P. Saha, J. Stejskal, Colloid Surf. B 116, 411–417 (2014)
E.N. Zare, P. Makvandi, B. Ashtari, F. Rossi, A. Motahari, G. Perale, J. Med. Chem. 63, 1–22 (2020)
G. Wang, L. Zhang, J. Zhang, Chem. Soc. Rev. 41, 797–828 (2012)
J. Fang, C. Zhao, C. Meng, G. Zhang, Mater. Today Commun. 30, 103031 (2022)
Q. Wang, P. Du, J. Liu, D. Liu, J. Niu, P. Liu, Appl. Surf. Sci. 487, 295–303 (2019)
G. Kister, G. Cassanas, M. Vert, Polymer 39, 267–273 (1998)
H. Ma, Y. Li, S. Yang, F. Cao, J. Gong, Y. Deng, J. Phys. Chem. C 114, 9264–9269 (2010)
M. Li, X. Huang, C. Wu, H. Xu, P. Jiang, T. Tanaka, J. Mater. Chem. 22, 23477–23484 (2012)
H. Cai, Z. Liu, M. Xu, L. Chen, X. Chen, L. Cheng, Z. Li, F. Dai, Electrochim Acta 390, 138895 (2021)
X. Liu, N. Wen, X. Wang, Y. Zheng, ACS Sustain. Chem. Eng. 3, 475–482 (2015)
H. Wang, Q. Hao, X. Yang, L. Lu, X. Wang, Nanoscale 2, 2164–2170 (2010)
X. Zheng, Y. Wang, W. Nie, Z. Wang, Q. Hu, C. Li, P. Wang, W. Wang, Compos. Part A—Appl. S 158, 106985 (2022)
S. Dhibar, P. Bhattacharya, G. Hatui, S. Sahoo, C.K. Das, ACS Sustain. Chem. Eng. 2, 1114–1127 (2014)
X. Wang, Z. Li, J. Zhao, T. Xiao, X. Wang, J. Alloy Compd. 781, 101–110 (2019)
G. Yang, T. Takei, S. Yanagida, N. Kumada, Appl. Surf. Sci. 498, 143872 (2019)
H. Zhou, L. Hou, W. Zhang, H. Zhai, Mater. Chem. Phys. 240, 122259 (2020)
J. Upadhyay, T.M. Das, R. Borah, Int. J. Polym. Anal. Ch. 26, 354–363 (2021)
L. Liu, H. Zhao, Y. Wang, Y. Fang, J. Xie, Y. Lei, Adv. Funct. Mater. 28, 1705107 (2017)
M.M. Mezgebe, K. Xu, G. Wei, S. Guang, H. Xu, J. Alloy. Compd. 794, 634–644 (2019)
C. Liu, Z. Yu, D. Neff, A. Zhamu, B.Z. Jang, Nano Lett. 10, 4863–4868 (2010)
S.R. Sivakkumar, W.J. Kim, J.A. Choi, D.R. MacFarlane, M. Forsyth, D.W. Kim, J. Power Sources 171, 1062–1068 (2007)
M. Lee, W.G. Hong, H.Y. Jeong, S.K. Balasingam, Z. Lee, S.J. Chang, B.H. Kim, Y. Jun, Nanoscale 6, 11066–11071 (2014)
X. Liu, J. Wang, G. Yang, ACS Appl. Mater. Inter. 10, 20688–20695 (2018)
P. Song, X. He, J. Tao, X. Shen, Z. Yan, Z. Ji, A. Yuan, G. Zhu, L. Kong, Appl. Surf. Sci. 535, 147755 (2021)
C. Jin, H. Wang, Y. Liu, X. Kang, P. Liu, J. Zhang, L. Jin, S. Bian, Q. Zhu, Electrochim Acta 270, 205–214 (2018)
T. Das, B. Verma, J. Energy Storage 26, 100975 (2019)
N. Mao, W. Chen, J. Meng, Y. Li, K. Zhang, X. Qin, H. Zhang, C. Zhang, Y. Qiu, S. Wang, J. Power Sources 399, 406–413 (2018)
Q. Wang, Y. Wu, T. Li, D. Zhang, M. Miao, A. Zhang, J. Mater. Chem. A 4, 3828–3834 (2016)
X. Zang, X. Li, M. Zhu, X. Li, Z. Zhen, Y. He, K. Wang, J. Wei, F. Kang, H. Zhu, Nanoscale 7, 7318–7322 (2015)
J. Fang, C. Meng, G. Zhang, Ind. Crop. Prod. 177, 114440 (2022)
M.R. Gizdavic-Nikolaidis, J.R. Bennett, S. Swift, A.J. Easteal, M. Ambrose, Acta Biomater 7, 4204–4209 (2011)
A.R. Ramos, A.K.G. Tapia, C.M.N. Piñol, N.B. Lantican, M.L.F. del Mundo, R.D. Manalo, M.U. Herrera, Mater. Chem. Phys. 238, 121972 (2019)
Y. Sun, S. Luo, H. Sun, W. Zeng, C. Ling, D. Chen, V. Chan, K. Liao, Carbon 136, 299–308 (2018)
K. Rohith Vinod, P. Saravanan, T.R. Suresh Kumar, R. Radha, M. Balasubramaniam, S. Balakumar, Nanoscale 10, 12018–12034 (2018)
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of Interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Fang, J., Meng, C., Zhang, G. et al. High-Performance Flexible PANI/PLA Textiles with Antibacterial, Flame Retardant and Electromagnetic Shielding for All-Solid-State Supercapacitors and Sensors. Fibers Polym 24, 1015–1028 (2023). https://doi.org/10.1007/s12221-023-00107-w
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-023-00107-w