Skip to main content
Log in

Properties evaluation of double silane system compound gel as a protective coating on concrete

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Inhibiting moisture transfer at the surface of concrete plays a vital role on the durability of concrete, and permeable protective coating can effectively resist the intrusion of external moisture into concrete. A double silane system compound gel was prepared through sol–gel synthesis method by using isobutyl triethoxy silane and tetraethyl orthosilicate, solving the problems of volatility and poor adhesion of traditional silane-based penetrating protective materials. The performance of the compound gel was verified through static contact angle, capillary water absorption of concrete with cracks, electrochemical accelerated ion penetration, and rapid carbonation tests. The test results showed that the capillary water absorption coefficient for concrete with cracks up to 0.5 mm and coating compound gel was reduced by more than 70% compared to blank; the corrosion time of inserted reinforcement in concrete treated with the compound gel was extended by more than two times compared to blank. The research of compound gel can expand the application market of silane-based protective materials, especially for some longitudinal concrete structural parts that need higher durability requirements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Wang, H, Zhang, A, Zhang, L, et al. “Study on the Influence of Compound Rust Inhibitor on Corrosion of Steel Bars in Chloride Concrete by Electrical Parameters.” Constr. Build. Mater., 262 120763 (2020)

    Article  CAS  Google Scholar 

  2. Liu, D, Yong Ming, T, Gabrie, IS, et al. “Freeze-Thaw Damage Evaluation and Model Creation for Concrete Exposed to Freeze-Thaw Cycles at Early-Age.” Constr. Build. Mater., 312 125352 (2021)

    Article  Google Scholar 

  3. Xiao, Q, Cao, Z, Guan, X, et al. “Damage to Recycled Concrete with Different Aggregate Substitution Rates from the Coupled Action of Freeze-Thaw Cycles and Sulfate Attack.” Constr. Build. Mater., 221 74–83 (2019)

    Article  CAS  Google Scholar 

  4. Baloch, WL, Siad, H, Lachemi, M, et al. “A Review on the Durability of Concrete-to-Concrete Bond in Recent Rehabilitated Structures.” J. Build. Eng., 44 103315 (2021)

    Article  Google Scholar 

  5. Wang, R, Zhiyao, H, Li, Y, et al. “Review on the Deterioration and Approaches to Enhance the Durability of Concrete in the Freeze–Thaw Environment.” Constr. Build. Mater., 321 126371 (2022)

    Article  CAS  Google Scholar 

  6. Muhammad, NZ, Keyvanfar, A, Abd, MZ, et al. “Waterproof Performance of Concrete: A Critical Review on Implemented Approaches.” Constr. Build. Mater., 101 80–90 (2015)

    Article  Google Scholar 

  7. Creasey, R, Andrews, JP, Ekolu, SO, Kruger, D, “Long-term 20-year Performance of Surface Coating Repairs Applied to Façades of Reinforced Concrete Buildings.” Case Stud. Constr. Mater., 7 348–360 (2017)

    Google Scholar 

  8. Zhang, M, Hongyan, X, Zeze, ALP, et al. Cem. Concr. Compos., 129 104495 (2022)

    Article  CAS  Google Scholar 

  9. Sarde, B, Patil, YD, “Recent Research Status on Polymer Composite Used in Concrete-An Overview.” Mater. Today Proc., 18 3780–3790. https://doi.org/10.1016/j.matpr.2019.07.316 (2019)

    Article  CAS  Google Scholar 

  10. Moodi, F, Kashi, A, Ramezanianpour, AA, et al. “Investigation on Mechanical and Durability Properties of Polymer and Latex-Modified Concretes.” Constr. Build. Mater., 191 145–154. https://doi.org/10.1016/j.conbuildmat.2018.09.198 (2018)

    Article  CAS  Google Scholar 

  11. Zhang, C, Zhang, S, Jianwei, Y, et al. “Water Absorption Behavior of Hydrophobized Concrete Using Silane Emulsion as Admixture.” Cem. Concr. Res., 154 106738 (2022)

    Article  CAS  Google Scholar 

  12. Gao, J, Geng, Y, Li, S, et al. “Effect of Silane Emulsion on Waterproofing and Anti-icing Performance of Foamed Concrete.” Constr. Build. Mater., 301 124082 (2021)

    Article  CAS  Google Scholar 

  13. Karthick, S, Park, D-J, Lee, YS, et al. “Development of Water-Repellent Cement Mortar Using Silane Enriched with Nanomaterials.” Prog. Org. Coat., 125 48–60. https://doi.org/10.1016/j.porgcoat.2018.08.021 (2018)

    Article  CAS  Google Scholar 

  14. Shen, L, Jiang, H, Wang, T, et al. “Performance of Silane-Based Surface Treatments for Protecting Degraded Historic Concrete.” Prog. Org. Coat., 129 209–216 (2019)

    Article  CAS  Google Scholar 

  15. Sakr, MR, Bassuoni, MT, “Silane and Methyl-methacrylate Based Nanocomposites as Coatings for Concrete Exposed to Salt Solutions and Cyclic Environments.” Cem. Concr. Compos., 115 103841 (2021)

    Article  CAS  Google Scholar 

  16. Zhang, P, Wittmann, FH, Zhao, T, et al. “Neutron Imaging of Water Penetration into Cracked Steel Reinforced Concrete.” Phys. B Condens. Matter., 405 1866–1871 (2010)

    Article  CAS  Google Scholar 

  17. Pan, X, Shi, C, Zhang, J, et al. “Effect of Inorganic Surface Treatment on Surface Hardness and Carbonation of Cement-based Materials.” Cem. Concr. Compos., 90 218–224 (2018)

    Article  CAS  Google Scholar 

  18. Gong, C, Jianzhong, L, Cuicui, C, Changfeng, L, Liang, S, “Study on Silane Impregnation for Protection of High Performance Concrete.” Procedia Eng., 27 301–307 (2012)

    Article  Google Scholar 

  19. Safiuddin, M, Soudki, KA, “Water Vapor Transmission and Waterproofing Performance of Concrete Sealer and Coating Systems.” J. Civ. Eng. Manage., 7 837–844 (2015)

    Article  Google Scholar 

  20. Soudki, KA, Safiuddin, M, Jeffs, P, et al. “Chloride Penetration Resistance of Concrete Sealer and Coating Systems.” J. Civ. Eng. Manage., 4 492–502 (2015)

    Article  Google Scholar 

  21. Peng, C, Li, L, You, Z, et al. “Influence of Silane-Hydrolysate Coupling Agents on Bitumen–Aggregate Interfacial Adhesion: An Exploration from Molecular Dynamics Simulation.” Int. J. Adhes. Adhes., 112 102993 (2022)

    Article  CAS  Google Scholar 

  22. Hon, AK, Matinlinna, JP, Shibata, Y, et al. “Evaluation of Five Silane Coupling Agents on Resin-Titanium Adhesion.” Int. J. Adhes. Adhes., 90 132–137. https://doi.org/10.1016/j.ijadhadh.2019.02.007 (2019)

    Article  CAS  Google Scholar 

  23. Kong, X-M, Liu, H, Lu, Z-B, et al. “The Influence of Silanes on Hydration and Strength Development of Cementitious Systems.” Cem. Concr. Res., 67 168–178 (2015)

    Article  CAS  Google Scholar 

  24. Cai, Y, Hou, P, Duan, C, et al. “The Use of Tetraethyl Orthosilicate Silane (TEOS) for Surface-Treatment of Hardened Cement-based Materials: A Comparison Study with Normal Treatment Agents.” Constr. Build. Mater., 117 144–151 (2016)

    Article  CAS  Google Scholar 

  25. Barberena-Fernández, AM, Blanco-Varela, MT, Carmona-Quiroga, PM, “Use of Nanosilica- or Nanolime-Additioned TEOS to Consolidate Cementitious Materials in Heritage Structures: Physical and Mechanical Properties of Mortars.” Cem. Concr. Compos., 95 271–276 (2019)

    Article  Google Scholar 

  26. GB/T 50082, Standard for Test Methods of Long-term Performance and Durability of Ordinary Concrete. China Building Industry Press, Beijing, China (2009)

    Google Scholar 

  27. Chen, X, Zhang, Y, Li, S, et al. “Influence of a New Type of Graphene Oxide/Silane Composite Emulsion on the Permeability Resistance of Damaged Concrete.” Coatings, 11 208 (2021)

    Article  CAS  Google Scholar 

  28. Zhang, XY, Li, SC, Zhao, TJ, “Effect of Octyl-Triethoxysilane Emulsion on Protection of Concrete.” Key Eng. Mater., 629 504–509 (2014)

    Article  Google Scholar 

  29. Li, G, Yue, J, Guo, Cenhao, et al. “Influences of Modified Nanoparticles on Hydrophobicity of Concrete with Organic Film Coating.” Constr. Build. Mater., 169 1–7 (2018)

    Article  CAS  Google Scholar 

  30. Chen, Y, Liu, P, Yu, Z, “Study on Degradation of Macro Performances and Micro Structure of Concrete Attacked by Sulfate Under Artificial Simulated Environment.” Constr. Build. Mater., 260 119951 (2020)

    Article  CAS  Google Scholar 

  31. Li, F, Yang, Y, Tao, M, Li, X, “A Cement Paste–Tail Sealant Interface Modified with a Silane Coupling Agent for Enhancing Waterproofing Performance in a Concrete Lining System.” RSC Adv., 9 (13) 7165–7175 (2019)

    Article  CAS  Google Scholar 

  32. Xue, X, Liu, Y-L, Dai, J-G, Poon, C-S, Zhang, W-D, Zhang, P, “Inhibiting Efflorescence Formation on Fly Ash–based Geopolymer via Silane Surface Modification.” Cem. Concr. Compos., 94 43–52 (2018)

    Article  CAS  Google Scholar 

  33. Sahoo, G, Balasubramaniam, R, “On the Corrosion Behaviour of Phosphoric Irons in Simulated Concrete Pore Solution.” Corros. Sci., 50 131–143 (2008)

    Article  CAS  Google Scholar 

  34. Geng, Y, Zhou, P, Li, S, et al. “Superior Corrosion Resistance of Mild Steel Coated with Graphene Oxide Modified Silane Coating in Chlorinated Simulated Concrete Solution.” Prog. Org. Coat., 164 106716 (2022)

    Article  CAS  Google Scholar 

  35. Zhou, Z, Li, S, Cao, J, et al. “The Waterproofing Effect and Mechanism of Graphene Oxide/Silane Composite Emulsion on Cement-Based Materials Under Compressive Stress.” Constr. Build. Mater., 308 124945 (2021)

    Article  CAS  Google Scholar 

  36. Courard, L, Zhao, Z, Michel, F, “Influence of Hydrophobic Product Nature and Concentration on Carbonation Resistance of Cultural Heritage Concrete Buildings.” Cem. Concr. Compos., 115 103860 (2021)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Financial support from the National Natural Science Foundation of China (Grant No. 51978355, No. 52078260), Cooperative Innovation Center of Engineering Construction and Safety in Shandong Blue Economic Zone, and Shandong Province Marine Environment Concrete Material Corrosion Control and Monitoring Research Innovation Team.

Author information

Authors and Affiliations

Authors

Contributions

XC was involved in writing—original draft, writing—review & editing, methodology, investigation, visualization. SL helped in conceptualization, writing—review & editing. SS contributed to conceptualization, writing—review & editing. YG was involved in resources. MH helped in review & editing. YZ contributed to validation, formal analysis. YG contributed to visualization, data curation. GL helped in data curation, formal analysis.

Corresponding authors

Correspondence to Shaochun Li or Shiyu Sui.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, X., Gao, Y., Zhang, Y. et al. Properties evaluation of double silane system compound gel as a protective coating on concrete. J Coat Technol Res 21, 329–340 (2024). https://doi.org/10.1007/s11998-023-00824-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-023-00824-0

Keywords

Navigation