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Waterborne hybrid (alkyd/styrene acrylic) emulsion polymers and exterior paint applications

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Abstract

Since alkyd resins include hazardous solvents, converting alkyds into waterborne hybrid polymers is an essential research topic. Here, alkyd/styrene acrylic waterborne hybrid polymers were synthesized in the presence of monomers, water, emulsifiers, and an initiator by using synthesized alkyd resins at 0%, 5%, 10%, and 15% ratios based on the total monomer ratio. A mini-emulsion technique and a semi-batch polymerization method were used to synthesize the latexes. Two different biosources, tall oil fatty acids (TOFA) and hemp seed oils (HSO), were used to synthesize the alkyd resins. Synthesized waterborne hybrid latexes and their films were analyzed by using FTIR, NMR, particle size, MFFT, TGA, DSC, CA, AFM, and mechanical tests. It was determined that the type and concentration of the alkyds affected the viscosity, particle size, Tg and MFFT values, and appearance. It was also identified that alkyd incorporation took place with grafting and that the alkyd concentration was particularly effective in increasing the particle size. In addition, experiments were carried out on waterborne paint systems for exterior paint by using synthesized hybrid polymer emulsions. It was observed that the alkyd content was not effective in changing the paint color in hybrid latexes. As a result, it is suggested that hybrid waterborne latexes could be used for exterior paints.

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References

  1. Deyab, MA, “Anticorrosion Properties of Nanocomposites Coatings: A Critical Review.” J. Mol. Liq., 313 113533 (2020)

    Article  CAS  Google Scholar 

  2. Kausar, A, “Polymer Coating Technology for High Performance Applications: Fundamentals and Advances.” J. Macromol. Sci. Part A, 55 (5) 440–448 (2018)

    Article  CAS  Google Scholar 

  3. Chardon, F, Denis, M, Negrell, C, Caillol, S, “Hybrid Alkyds, The Glowing Route to Reach Cutting-Edge Properties?” Prog. Org. Coat., 151 106025 (2021)

    Article  CAS  Google Scholar 

  4. Jiao, C, Sun, L, Shao, Q, Song, J, Hu, Q, Naik, N, Guo, Z, “Advances in Waterborne Acrylic Resins: Synthesis Principle, Modification Strategies, and Their Applications.” ACS Omega, 6 (4) 2443–2449 (2021)

    Article  CAS  Google Scholar 

  5. Mukhtar, A, Ullah, H, Mukhtar, H, “Fatty Acid Composition of Tobacco Seed Oil and Synthesis of Alkyd Resin.” Chin. J. Chem., 25 (5) 705–708 (2007)

    Article  CAS  Google Scholar 

  6. Ifijen, IH, Odi, HD, Maliki, M, Omorogbe, SO, Aigbodion, AI, Ikhuoria, EU, “Correlative Studies on the Properties of Rubber Seed and Soybean Oil-Based Alkyd Resins and Their Blends.” J. Coat. Technol. Res., 18 (2) 459–467 (2021)

    Article  CAS  Google Scholar 

  7. Büyükyonga, ÖN, Akgün, N, Acar, I, Güçlü, G, “Synthesis of Four-Component Acrylic-Modified Water-Reducible Alkyd Resin: Investigation of Dilution Ratio Effect on Film Properties and Thermal Behaviors.” J. Coat. Technol. Res., 14 (1) 117–128 (2017)

    Article  Google Scholar 

  8. Wang, H, Li, Y, Fei, G, Sun, L, Wang, Y, Liu, X, Wang, M, Rang, N, “Comparison Study on Chelated and Non-chelated Titanate Functionalized Graphene Nanosheets for Enhancement of Waterborne Alkyd Anticorrosion Coating.” Prog. Org. Coat., 150 105961 (2021)

    Article  CAS  Google Scholar 

  9. Pathan, S, Ahmad, S, “Green and Sustainable Anticorrosive Coating Derived from Waterborne Linseed Alkyd Using Organic–Inorganic Hybrid Cross Linker.” Prog. Org. Coat., 122 189–198 (2018)

    Article  CAS  Google Scholar 

  10. Hadzich, A, Gross, GA, Leimbach, M, Ispas, A, Bund, A, Flores, S, “Effect of Polyalcohols on the Anticorrosive Behaviour of Alkyd Coatings Prepared with Drying Oils.” Prog. Org. Coat., 145 105671 (2020)

    Article  CAS  Google Scholar 

  11. Wang, H, Hu, G, Liu, X, Guo, L, Li, X, Guo, R, Li, Y, “Concurrent Alkylation and Crosslinking of Polyaniline for Enhanced Anticorrosive Performance of Waterborne Alkyd Coating.” Prog. Org. Coat., 168 106865 (2022)

    Article  CAS  Google Scholar 

  12. Chukwuebuka, AS, Samuel, EO, Asadu, CO, Onoghwarite, OE, Celestine, O, Ezema, CA, “Optimal Analysis of the Effects of Process Conditions on the Yield of Alkyd Resins from Castor and Soybean Seed Oils Using Response Surface Methodology.” Chem. Eng. J. Adv., 9 100217 (2022)

    Article  CAS  Google Scholar 

  13. Das, P, Sharma, N, Puzari, A, Kakati, DK, Devi, N, “Synthesis and Characterization of Neem (Azadirachta indica) Seed Oil-Based Alkyd Resins for Efficient Anticorrosive Coating Application.” Polym. Bull., 78 (1) 457–479 (2021)

    Article  CAS  Google Scholar 

  14. Obregón, D, Toledo, C, Hadzich, A, Flores, S, “Low Viscosity Alkyd Resins Based on Trimethylolpropane and Peruvian Oil.” J. Polym. Res., 28 (6) 203 (2021)

    Article  Google Scholar 

  15. Saravari, O, Phapant, P, Pimpan, V, “Synthesis of Water-Reducible Acrylic–Alkyd Resins Based on Modified Palm Oil.” J. Appl. Polym. Sci., 96 (4) 1170–1175 (2005)

    Article  CAS  Google Scholar 

  16. Ogunniyi, DS, Odetoye, TE, “Preparation and Evaluation of Tobacco Seed Oil-Modified Alkyd Resins.” Bioresour. Technol., 99 (5) 1300–1304 (2008)

    Article  CAS  Google Scholar 

  17. Odetoye, TE, Ogunniyi, DS, Olatunji, GA, “Preparation and Evaluation of Jatropha curcas Linneaus Seed Oil Alkyd Resins.” Ind. Crops Prod., 32 (3) 225–230 (2010)

    Article  CAS  Google Scholar 

  18. Eren, M, Akbulut, G, Senler, S, Kayaoğlu, BK, “Synthesis of Core–Shell-Type Styrene Acrylic Latexes with Low NMA Content and Their Application in Pigment Printing Pastes.” J. Coat. Technol. Res., 15 (1) 121–129 (2018)

    Article  CAS  Google Scholar 

  19. Delibaş, A, Yıldız, U, Tauer, K, “Composite Latex Production with High Solid Content.” J. Appl. Polym. Sci., 136 (18) 47423 (2019)

    Article  Google Scholar 

  20. Delibaş, A, “Synthesis of (Sty-co-BA-AA) Latexes Including ZnO and TiO2 Nanoparticle by Miniemulsion Polymerization.” J. Coat. Technol. Res., 18 (3) 717–727 (2021)

    Article  Google Scholar 

  21. Eren, M, Can, HK, “Preparation of Zinc Methacrylate-Methylmethacrylate-Butyl Acrylate Emulsions and Their Application in Exterior Paints.” Prog. Org. Coat., 135 424–437 (2019)

    Article  CAS  Google Scholar 

  22. Lovell, PA, Schork, FJ, “Fundamentals of Emulsion Polymerization.” Biomacromolecules, 21 (11) 4396–4441 (2020)

    Article  CAS  Google Scholar 

  23. Akgün, N, Büyükyonga, ÖN, Acar, I, Güçlü, G, “Synthesis of Novel Acrylic Modified Water Reducible Alkyd Resin: Investigation of Acrylic Copolymer Ratio Effect on Film Properties and Thermal Behaviors.” Polym. Eng. Sci., 56 (8) 947–954 (2016)

    Article  Google Scholar 

  24. Elrebii, M, Ben Mabrouk, A, Boufi, S, “Synthesis and Properties of Hybrid Alkyd–Acrylic Dispersions and Their Use in VOC-Free Waterborne Coatings.” Prog. Org. Coat., 77 (4) 757–764 (2014)

    Article  CAS  Google Scholar 

  25. Nabuurs, T, Baijards, RA, German, AL, “Alkyd-Acrylic Hybrid Systems for Use as Binders in Waterborne Paints.” Prog. Org. Coat., 27 (1) 163–172 (1996)

    Article  CAS  Google Scholar 

  26. Ma, Y, Lei, R, Yang, X, Yang, F, “Eco-friendly Waterborne Alkyd Resin from Polyethylene Terephthalate Waste.” J. Polym. Environ., 28 (3) 1083–1094 (2020)

    Article  CAS  Google Scholar 

  27. Assanvo, EF, Baruah, SD, “Synthesis and Properties of Ricinodendron heudelotii Oil Based Hybrid Alkyd–Acrylate Latexes via Miniemulsion Polymerization.” Prog. Org. Coat., 86 25–32 (2015)

    Article  CAS  Google Scholar 

  28. Guyot, A, Landfester, K, Joseph Schork, F, Wang, C, “Hybrid Polymer Latexes.” Prog. Polym. Sci., 32 (12) 1439–1461 (2007)

    Article  CAS  Google Scholar 

  29. Landfester, K, Schork, FJ, Kusuma, VA, “Particle Size Distribution in Mini-Emulsion Polymerization.” Comptes Rendus Chimie, 6 (11) 1337–1342 (2003)

    Article  CAS  Google Scholar 

  30. Vale, HM, McKenna, TF, “Modeling Particle Size Distribution in Emulsion Polymerization Reactors.” Prog. Polym. Sci., 30 (10) 1019–1048 (2005)

    Article  CAS  Google Scholar 

  31. Wang, T, de las Heras Alarcón, C, Goikoetxea, M, Beristain, I, Paulis, M, Barandiaran, MJ, Asua, JM, Keddie, JL, “Cross-linked Network Development in Compatibilized Alkyd/Acrylic Hybrid Latex Films for the Creation of Hard Coatings.” Langmuir, 26 (17) 14323–14333 (2010)

    Article  CAS  Google Scholar 

  32. Uschanov, P, Heiskanen, N, Mononen, P, Maunu, SL, Koskimies, S, “Synthesis and Characterization of Tall Oil Fatty Acids-based Alkyd Resins and Alkyd–acrylate Copolymers.” Prog. Org. Coat., 63 (1) 92–99 (2008)

    Article  CAS  Google Scholar 

  33. Goikoetxea, M, Reyes, Y, de las Heras Alarcón, CM, Minari, RJ, Beristain, I, Paulis, M, Barandiaran, MJ, Keddie, JL, Asua, JM, “Transformation of Waterborne Hybrid Polymer Particles into Films: Morphology Development and Modeling.” Polymer, 53 (5) 1098–1108 (2012)

    Article  CAS  Google Scholar 

  34. Limousin, E, González, E, Martínez-Tong, DE, Ballard, N, Asua, JM, “Modelling the Dynamic Development of the Curing Process and Film Morphology of Films Cast from Waterborne Acrylic-Alkyd Hybrids.” Chem. Eng. J., 400 125891 (2020)

    Article  CAS  Google Scholar 

  35. Limousin, E, Martinez-Tong, DE, Ballard, N, Asua, JM, “Cure-Dependent Morphology of Acrylic/Alkyd Hybrid Latex Films via Nanomechanical Mapping.” ACS Appl. Polym. Mater., 1 (8) 2213–2223 (2019)

    Article  CAS  Google Scholar 

  36. Liz Manning, DOM, Hamacek, K, Opportunities for the Alkyd Resin Market to Create a Sustainable Future for the European Coatings Industry. Paint Coatings Industry (2019)

    Google Scholar 

  37. Elrebii, M, Kamoun, A, Boufi, S, “Waterborne Hybrid Alkyd–Acrylic Dispersion: Optimization of the Composition Using Mixture Experimental Designs.” Prog. Org. Coat., 87 222–231 (2015)

    Article  CAS  Google Scholar 

  38. Athawale, VD, Nimbalkar, RV, “Waterborne Coatings Based on Renewable Oil Resources: An Overview.” J. Am. Oil Chem. Soc., 88 (2) 159–185 (2011)

    Article  CAS  Google Scholar 

  39. Fei, G, Sun, L, Wang, H, Gohar, F, Ma, Y, Kang, Y-M, “Rational Design of Phosphorylated Poly(vinyl alcohol) Grafted Polyaniline for Waterborne Bio-based Alkyd Nanocomposites with High Performance.” Prog. Org. Coat., 140 105484 (2020)

    Article  CAS  Google Scholar 

  40. Hofland, A, “Alkyd Resins: From Down and Out to Alive and Kicking.” Prog. Org. Coat., 73 (4) 274–282 (2012)

    Article  CAS  Google Scholar 

  41. Somtürk, SM, Emek, İY, Senler, S, Eren, M, Kurt, SZ, Orbay, M, “Effect of Wollastonite Extender on the Properties of Exterior Acrylic Paints.” Prog. Org. Coat., 93 34–40 (2016)

    Article  Google Scholar 

  42. Lewarchik, R, Basics of Alkyd Resin Technology. Prospector Knowledge Center (2016)

    Google Scholar 

  43. Siano, F, Moccia, S, Picariello, G, Russo, GL, Sorrentino, G, Di Stasio, M, La Cara, F, Volpe, MG, “Comparative Study of Chemical, Biochemical Characteristic and ATR-FTIR Analysis of Seeds, Oil and Flour of the Edible Fedora Cultivar Hemp (Cannabis sativa L.).” Molecules, 24 (1) 83 (2019)

    Article  Google Scholar 

  44. Abd El-Wahab, H, Abd El-Hai, F, Abd El-Fattah, M, Lin, L, “Effect of Short Oil-Length Alkyd Additive on the Properties of Coal Tar Binder.” Pigment Resin Technol., 40 (5) 305–310 (2011)

    Article  CAS  Google Scholar 

  45. Muhammad, A, Abbas, S, Shafeeq, A, Al-Turaif, HA, Taimoor, AA, Ali, AM, Deshannavar, UB, “Synthesis and Characterization of Pentaerythritol Phthalic Anhydride Resin from Soybean Oil.” Asian J. Chem., 30 572–574 (2018)

    Article  CAS  Google Scholar 

  46. Hadzich, A, Gross, GA, Leimbach, M, Ispas, A, Bund, A, Flores, S, “Characterization of Plukenetia volubilis L. Fatty Acid-Based Alkyd Resins.” Polym. Test., 82 106296 (2020)

    Article  CAS  Google Scholar 

  47. Assanvo, EF, Gogoi, P, Dolui, SK, Baruah, SD, “Synthesis, Characterization, and Performance Characteristics of Alkyd Resins Based on Ricinodendron heudelotii Oil and Their Blending with Epoxy Resins.” Ind. Crops Prod., 65 293–302 (2015)

    Article  CAS  Google Scholar 

  48. Tiwari, S, Saxena, M, Tiwari, S, “Preparation and Characterization of Penta Alkyds Based on Mahua Oil.” J. Sci. Ind. Res., 61 110–116 (2002)

    CAS  Google Scholar 

  49. Neelambaram, P, Shankar, A, Sykam, K, Kumar, DBR, Chakrabarty, A, Narayan, R, “Siloxane-Based High Solid Acrylic Latex by Mini-Emulsion Polymerization for Coatings with Improved Water Resistance.” Prog. Org. Coat., 171 107011 (2022)

    Article  CAS  Google Scholar 

  50. Iizuka, Y, Yamamoto, Y, Kawahara, S, “Latex-State 13C-NMR Spectroscopy for Poly(butyl acrylate).” Colloid Polym. Sci., 297 (1) 133–139 (2019)

    Article  CAS  Google Scholar 

  51. Zhu, X, Jiang, X, Zhang, Z, Kong, XZ, “Influence of Ingredients in Water-Based Polyurethane–Acrylic Hybrid Latexes on Latex Properties.” Prog. Org. Coat., 62 (3) 251–257 (2008)

    Article  CAS  Google Scholar 

  52. Wu, L, You, B, Li, D, “Synthesis and Characterization of Urethane/Acrylate Composite Latex.” J. Appl. Polym. Sci., 84 (8) 1620–1628 (2002)

    Article  CAS  Google Scholar 

  53. Do Amaral, M, Van Es, S, Asua, JM, “Effect of the Particle Size Distribution on the Low Shear Viscosity of High-Solid-Content Latexes.” J. Polym. Sci. Part A Polym. Chem., 42 (16) 3936–3946 (2004)

    Article  CAS  Google Scholar 

  54. Wu, XQ, Schork, FJ, Gooch, JW, “Hybrid Miniemulsion Polymerization of Acrylic/Alkyd Systems and Characterization of the Resulting Polymers.” J. Polym. Sci. Part A Polym. Chem., 37 (22) 4159–4168 (1999)

    Article  CAS  Google Scholar 

  55. Yousefi, AA, Pishvaei, M, Yousefi, A, “Preparation of Water-Based Alkyd/Acrylic Hybrid Resins.” Prog. Color Colorants Coat., 4 (1) 15–25 (2011)

    Google Scholar 

  56. Li, H, Yuan, J, Qian, H, Wu, L, “Synthesis and Properties of SiO2/P(MMA-BA) Core–Shell Structural Latex with Siloxanes.” Prog. Org. Coat., 97 65–73 (2016)

    Article  CAS  Google Scholar 

  57. Wei, Z, Ling, H, Junyan, L, Gang, C, Na, W, “Preparation and Properties of Core–Shell Nanosilica/Poly(methyl methacrylate–butyl acrylate–2,2,2-trifluoroethyl methacrylate) Latex.” J. Appl. Polym. Sci., 120 (2) 1152–1161 (2011)

    Article  Google Scholar 

  58. Ifijen, IH, Ikhuoria, EU, Omorogbe, SO, Aigbodion, AI, “Ordered Colloidal Crystals Fabrication and Studies on the Properties of Poly (Styrene–Butyl Acrylate–Acrylic Acid) and Polystyrene Latexes.” Proc. Nanocomposites VI: Nanoscience and Nanotechnology in Advanced Composites, Cham, 2019

  59. Zhenqian, Z, Bo, X, Pei, W, Ninyyi, Y, “Hybrid Latex Particles Preparation with Seeded Semibatch Emulsion Polymerization.” Colloids Surf. A Physicochem. Eng. Asp., 482 422–430 (2015)

    Article  Google Scholar 

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Acknowledgments

This study was supported by Yozgat Bozok University Scientific Research Projects Unit with code 6602c-FEN/21-459. We also thank Betek Boya ve Kimya San. A.Ş. for their support of the analyses and studies.

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Authors and Affiliations

  1. Department of Chemistry, Graduate Education Institute, Yozgat Bozok University, 66900, Yozgat, Turkey

    Nurullah Kartaloğlu

  2. Science and Technology Application and Research Center, Yozgat Bozok University, 66900, Yozgat, Turkey

    Nurullah Kartaloğlu

  3. Betek Boya ve Kimya San. A.Ş., 34852, Istanbul, Turkey

    Suna Elif Akçin & Mesut Eren

  4. Department of Chemistry, Faculty of Arts and Sciences, Yozgat Bozok University, 66900, Yozgat, Turkey

    Ali Delibaş

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  1. Nurullah Kartaloğlu
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Contributions

NK: Investigation, Visualization, Methodology, Formal analysis, Validation, Writing. SEA: Investigation, Formal Analysis, Validation. ME: Resources, Methodology, Writing, Review and Editing. AD: Project administration, Writing—review and editing, Funding acquisition, Supervision.

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Correspondence to Ali Delibaş.

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Kartaloğlu, N., Akçin, S.E., Eren, M. et al. Waterborne hybrid (alkyd/styrene acrylic) emulsion polymers and exterior paint applications. J Coat Technol Res 20, 1621–1637 (2023). https://doi.org/10.1007/s11998-023-00767-6

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