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Characteristics of urushi film prepared through thermal polymerization

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Abstract

Urushi (oriental lacquer) is a natural material that forms thin films with excellent durability and water resistance. There are two methods for curing urushi: oxidative and thermal polymerizations. Urushi is mainly applied to wood; therefore, the oxidative polymerization method has mainly been used to cure it. Oxidative polymerization requires temperature and humidity control and takes a long time to fully cure urushi. Urushi mixed with pigments has poor coloration. In contrast, the use of a thermal polymerization reaction can achieve curing in a short time. In this study, we focused on the thermal curing reaction of urushi, formed 13 different colored urushi coating films, and investigated their properties and coloration. We observed that urushi coatings produced through thermal polymerization took less time to cure than those produced through oxidative polymerization, and that urushi coatings with better coloration and high water repellency were obtained.

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References

  1. Ma, X, Shi, Y, Khanjian, H, Schilling, M, Li, M, Fang, H, Cui, D, Kakoulli, I, “Characterization of Early Imperial Lacquerware from the Luozhuang Han Tomb, China.” Archaeometry, 59 (1) 121–132 (2017)

    Article  CAS  Google Scholar 

  2. Sakaguchi, T, “Mortuary Variability and Status Differentiation in the Late Jomon of Hokkaido Based on the Analysis of Shuteibo (Communal Cemeteries).” J. World Prehistory, 24 (4) 275–308 (2011)

    Article  Google Scholar 

  3. Kumanotani, J, “Urushi (Oriental Lacquer)—A Natural Aesthetic Durable and Future-promising Coating.” Prog. Org. Coat., 26 (2) 163–195 (1995)

    Article  CAS  Google Scholar 

  4. Snyder, DM, “An Overview of Oriental Lacquer: Art and Chemistry of the Original High-Tech Coating.” J. Chem. Educ., 66 (12) 977 (1989)

    Article  CAS  Google Scholar 

  5. Yoshida, H, “LXIII.—Chemistry of Lacquer (Urushi). Part I. Communication from the Chemical Society of Tokio.” J. Chem. Soc. Trans., 43 472–486 (1883)

    Article  CAS  Google Scholar 

  6. Vogl, O, “Oriental Lacquer, Poison Ivy, and Drying Oils.” J. Polym. Sci. Part A Polym. Chem., 38 (24) 4327–4335 (2000)

    Article  CAS  Google Scholar 

  7. Hüttermann, A, Mai, C, Kharazipour, A, “Modification of Lignin for the Production of New Compounded Materials.” Appl. Microbiol. Biotechnol., 55 (4) 387–394 (2001)

    Article  Google Scholar 

  8. Lu, R, Honda, T, Kamiya, Y, Yoshida, K, Miyakoshi, T, “Analysis of Japanese Jōmon Lacquer-Ware by Pyrolysis-Gas Chromatography/Mass Spectrometry.” J. Anal. Appl. Pyrolysis, 103 68–72 (2013)

    Article  CAS  Google Scholar 

  9. Oyabu, H, Asami, T, “Effects of Curing Condition on Transparency of Urushi Films.” J. Jpn Soc. Colour Mater., 60 (2) 94–99 (1987)

    Article  CAS  Google Scholar 

  10. Asami, T, Oyabu, H, Yamauchi, A, “Spreading the Gamut of Color of Urushi Enamel Films.” J. Jpn Soc. Colour Mater., 58 (3) 129–134 (1985)

    Article  Google Scholar 

  11. Watanabe, H, Fujimoto, A, Takahara, A, “Characterization of Catechol-Containing Natural Thermosetting Polymer ‘Urushiol’ Thin Film.” J. Polym. Sci. Part A Polym. Chem., 51 (17) 3688–3692 (2013)

    Article  CAS  Google Scholar 

  12. McGuire, RG, “Reporting of Objective Color Measurements.” HortScience, 27 (12) 1254–1255 (1992)

    Article  Google Scholar 

  13. "CIE 15:2004 Colorimetry, 3rd Edition."

  14. Xia, J, Lin, J, Xu, Y, Chen, Q, “On the UV-Induced Polymeric Behavior of Chinese Lacquer.” ACS Appl. Mater. Interfaces, 3 (2) 482–489 (2011)

    Article  CAS  Google Scholar 

  15. Narita, C, Yamada, K, Tsujii, T, “Solvent Influence on Crosslinking and Surface Characteristics of Urushi Films.” Mater. Chem. Phys., 199 387–392 (2017)

    Article  CAS  Google Scholar 

  16. Maguregui, M, Morillas, H, Marcaida, I, García-Florentino, C, de Errazti, IO, Aransay, C, Madariaga, JM, “A Non-invasive In Situ Methodology to Characterise the Lacquers and Metals from the Edo Period Japanese Armour.” Microchem. J., 137 160–167 (2018)

    Article  CAS  Google Scholar 

  17. Jung, J, Cho, HJ, Kim, D, Hwang, SS, Won, J, “Degradable Natural Lacquer (Urushi) Adhesives Using a Reversible Polymer Based on Hemiaminal Dynamic Covalent Networks.” ChemistrySelect, 3 (23) 6665–6670 (2018)

    Article  CAS  Google Scholar 

  18. Kumanotani, J, “Enzyme Catalyzed Durable and Authentic Oriental Lacquer: A Natural Microgel-Printable Coating by Polysaccharide–Glycoprotein–Phenolic Lipid Complexes.” Prog. Org. Coat., 34 (1) 135–146 (1998)

    Article  CAS  Google Scholar 

  19. Narita, C, Okahisa, Y, Yamada, K, “Plasticizing Effect of Lignin on Urushi in Bio-composite Films.” Polymer, 161 49–54 (2019)

    Article  CAS  Google Scholar 

  20. Yagihashi, S, “The Preservation and Handing Down of Traditional Urushi Art Techniques in Japan.” Proc. Urushi. Proceedings of the Urushi Study Group. June 10–27, 1985 Tokyo, 1988

  21. Lee, Y-K, Kim, H-J, Rafailovich, M, Sokolov, J, “Curing Monitoring of Phenolic Resol Resins via Atomic Force Microscope and Contact Angle.” Int. J. Adhes. Adhes., 22 (5) 375–384 (2002)

    Article  CAS  Google Scholar 

  22. Okahisa, Y, Narita, C, Yoshimura, T, “Resistance of Wood Coated with Oriental Lacquer (Urushi) Against Damage Caused by Subterranean Termite.” J. Wood Sci., 65(1) (2019)

  23. Normand, AC, Charrier, AM, Arnould, O, Lereu, AL, “Influence of Force Volume Indentation Parameters and Processing Method in Wood Cell Walls Nanomechanical Studies.” Sci. Rep., 11 (1) 5739 (2021)

    Article  CAS  Google Scholar 

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Acknowledgments

This study was supported by grants from the Harmonic Ito Foundation.

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Correspondence to Chieko Narita.

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Narita, C., Okahisa, Y., Kitaguchi, S. et al. Characteristics of urushi film prepared through thermal polymerization. J Coat Technol Res 20, 1299–1310 (2023). https://doi.org/10.1007/s11998-022-00745-4

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  • DOI: https://doi.org/10.1007/s11998-022-00745-4

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