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Antistatic and antibacterial two-component waterborne polyurethane coating

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Abstract

Hydroxyl acrylate emulsion was prepared firstly by the semicontinuous seeded emulsion polymerization, and then adding polyaniline (PANI)/Cu/ZrO2 ternary nanocomposites, two-component waterborne polyurethane (2 K WPU) composite coatings with antistatic and antibacterial properties were obtained by mixing the emulsion with hydrophilic modified polyisocyanate. The structure and morphology of the PANI/Cu/ZrO2 were observed by Fourier transform infrared spectroscopy, scanning electron microscopy, and X-ray diffractometer. The thermal, antistatic, antibacterial, anticorrosion, and mechanical properties of the 2 K WPU composite coatings were determined. The results showed that the addition of the ternary nanocomposites increased the antistatic, antibacterial, anticorrosion, and mechanical properties of the 2 K WPU coating. The initial decomposition temperature increased from 200 to 225°C, and the tensile strength increased by 44.4%. The coatings still maintained good impact strength of 50/50 kg cm, adhesion of grade 2, flexibility of 1 mm, pendulum hardness of 293 s, and the gloss (60°) of 119.4.

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References

  1. Akbarian, M, Olya, ME, Ataeefard, M, Mahdavian, M, “The Influence of Nanosilver on Thermal and Antibacterial Properties of a 2 K Waterborne Polyurethane Coating.” Prog. Org. Coat, 75 (4) 344–348 (2012)

    Article  CAS  Google Scholar 

  2. Ansari, MO, Mohammad, F, “Thermal Stability, Electrical Conductivity and Ammonia Sensing Studies on p-Toluenesulfonic Acid Doped Polyaniline: Titanium Dioxide (pTSA/Pani:TiO2) Nanocomposites.” Sensors Actuators B: Chem., 157 (1) 122–129 (2011)

    Article  CAS  Google Scholar 

  3. Anju, C, Palatty, S, “Ternary Doped Polyaniline-metal Nanocomposite as High Performance Supercapacitive Material.” Electrochim. Acta, 299 626–635 (2019)

    Article  CAS  Google Scholar 

  4. Chatterjee, AK, Chakraborty, R, Basu, T, “Mechanism of Antibacterial Activity of Copper Nanoparticles.” Nanotechnology, 25 (13) 135101 (2014)

    Article  Google Scholar 

  5. Cloutier, M, Mantovani, D, Rosei, F, “Antibacterial Coatings: Challenges, Perspectives, and Opportunities.” Trends Biotechnol., 33 (11) 637–652 (2015)

    Article  CAS  Google Scholar 

  6. Cheng, X, Kumar, V, Yokozeki, T, Goto, T, Takahashi, T, Koyanagi, J, Wu, L, Wang, R, “Highly Conductive Graphene Oxide/Polyaniline Hybrid Polymer Nanocomposites with Simultaneously Improved Mechanical Properties.” Comp. Part A, 82 100–107 (2016)

    Article  CAS  Google Scholar 

  7. Dhonde, M, Sahu, K, Murty, VVS, Nemala, SS, Bhargava, P, “Surface Plasmon Resonance Effect of Cu Nanoparticles in a Dye Sensitized Solar Cell.” Electrochim. Acta, 249 89–95 (2017)

    Article  CAS  Google Scholar 

  8. Fayemi, OE, Adekunle, AS, Swamy, BEK, Ebenso, EE, “Electrochemical Sensor for the Detection of Dopamine in Real Samples Using Polyaniline/NiO, ZnO, and Fe3O4 Nanocomposites on Glassy Carbon Electrode.” J. Electroanal. Chem., 818 236–249 (2018)

    Article  CAS  Google Scholar 

  9. Bogdanović, U, Vodnik, V, Mitrić, M, Dimitrijević, S, Škapin, SD, Žunič, V, Budimir, M, Stoiljković, M, “Nanomaterial with High Antimicrobial Efficacy-Copper/Polyaniline Nanocomposite.” ACS Appl. Mater. Interfaces, 7 (3) 1955–1966 (2015)

    Article  Google Scholar 

  10. Spanhel, L, “Colloidal ZnO Nanostructures and Functional Coatings: A Survey.” J. Sol-Gel Sci. Technol., 39 (1) 7–24 (2006)

    Article  CAS  Google Scholar 

  11. Al-Shabander, BM, Kareem, AA, “The Effect of Zirconium Dioxide on Dielectric Properties and Thermal Conductivity of Polymers.” Int. J. Res. Mech. Mater. Eng., 1 (1) 15–18 (2015)

    Google Scholar 

  12. Yousefi E, Dolati A, Najafkhani H, "Preparation of Robust Antistatic Waterborne Polyurethane Coating." Prog. Org. Coat, 139 (2020)

  13. Gizdavic-Nikolaidis, MR, Pagnon, JC, Ali, N, Sum, R, Davies, N, Roddam, LF, Ambrose, M, “Functionalized Polyanilines Disrupt Pseudomonas aeruginosa and Staphylococcus aureus Biofilms.” Colloids Surf. B-Biointerf., 136 666–673 (2015)

    Article  CAS  Google Scholar 

  14. Geilich, BM, van de Ven, AL, Singleton, GL, Sepúlveda, LJ, Sridhar, S, Webster, TJ, “Silver Nanoparticle-embedded Polymersome Nanocarriers for the Treatment of Antibiotic-Resistant Infections.” Nanoscale, 7 (8) 3511–3519 (2015)

    Article  CAS  Google Scholar 

  15. Armelin, E, Aleman, C, Iribarren, JI, “Anticorrosion Performances of Epoxy Coatings Modified with Polyaniline: A Comparison Between the Emeraldine Base and Salt Forms.” Prog. Org. Coat, 65 (1) 88–93 (2009)

    Article  CAS  Google Scholar 

  16. Chen, Y, Wang, XH, Li, J, Lu, JL, Wang, FS, “Long-term Anticorrosion Behaviour of Polyaniline on Mild Steel.” Corrosion Sci., 49 (7) 3052–3063 (2007)

    Article  CAS  Google Scholar 

  17. Chu, D, Wang, J, Han, Y, Ma, Q, Wang, Z, “High Performance Epoxy Protective Coatings Incorporated with Polyaniline Nanowires Using Cardanol-Based Phenalkamine as the Curing Agent.” RSC Adv., 5 (15) 11378–11384 (2015)

    Article  CAS  Google Scholar 

  18. Akbarinezhad, E, Ebrahimi, M, Faridi, HR, “Corrosion Inhibition of Steel in Sodium Chloride Solution by Undoped Polyaniline Epoxy Blend Coating.” Prog. Org. Coat, 64 (4) 361–364 (2009)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Materials Science and Engineering, Guilin University of Technology, No. 12, Jiangan Road, Guilin, 541004, People’s Republic of China

    Xianwen Li, Xinmeng Xu & Faai Zhang

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  1. Xianwen Li
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  2. Xinmeng Xu
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Correspondence to Faai Zhang.

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Li, X., Xu, X. & Zhang, F. Antistatic and antibacterial two-component waterborne polyurethane coating. J Coat Technol Res 20, 869–881 (2023). https://doi.org/10.1007/s11998-022-00708-9

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  • DOI: https://doi.org/10.1007/s11998-022-00708-9

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