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Preparation of PEO/polymer coatings on aluminum alloy with antifouling properties

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Abstract

A study on the development of an effective composition of polymeric antifouling coating based on acrylic copolymer with microencapsulated extract of natural origin and superdispersed polytetrafluoroethylene was carried out. A Raman spectroscopy study of the bacterial extract composition showed that the main component was a polyene pigment with 5 conjugated bonds. Encapsulation of ethyl acetate extract of Pseudoalteromonas piscicida 2202 was carried out, two types of microcapsules containing the microbial extract were obtained, and their morphology and efficiency of antifouling action in the coating were studied. Comprehensive studies of antifouling, anticorrosion, and mechanical properties of the coatings allowed identification of the most effective composition providing long-term protection in combination with satisfactory mechanical properties. It is shown that the use of silica nanocapsules with microbial extract in the coating is more effective for enhanced antifouling and mechanical performance.

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Acknowledgments

The authors wish to thank colleagues from the Joint Vietnam-Russia Tropical Science and Technology Research Center in Nha Trang (Vietnam) for invaluable assistance during field experiments.

Funding

The work was financially supported by the RFBR, project number 19–29–13020. The work was also performed as part of the research project Ecolan T-1.2, task 1 on “Full-scale tests of modern structural materials, steels, welded joints and protective equipment for resistance to marine corrosion and fouling” and Ecolan T-1.4 “Development of physico-chemical approaches to the formation of effective coatings with antifouling properties based on biologically active metabolites of marine microorganisms.”

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, pr. 100-letiya Vladivostoka, 159, Vladivostok, Russia, 690022

    U. Kharchenko, V. Egorkin, I. Vyalyi, N. Izotov & A. Tsvetnikov

  2. A.V. Zhirmunsky National Scientific Center of Marine Biology, Far Eastern Branch, Russian Academy of Sciences, Palchevskogo str. 17, Vladivostok, Russia, 690041

    I. Beleneva & A. Karpenko

  3. Joint Vietnam - Russia Tropical Science and Technology Research Center, 30 Nguyen Thien Thuat, Nha Trang, Vietnam

    Chi V. Nguyen

Authors
  1. U. Kharchenko
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  2. I. Beleneva
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  3. V. Egorkin
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  4. I. Vyalyi
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  5. N. Izotov
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  6. A. Tsvetnikov
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  7. A. Karpenko
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  8. Chi V. Nguyen
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Uliana Kharchenko, Irina Beleneva, Nikolay Izotov, Igor Vyaliy, and Alexander Karpenko. Funding acquisition was performed by Nguen Van Chi. Alexander Tsvetnikov provided materials for the study and Vladimir Egorkin supervised the overall investigation. The first draft of the manuscript was written by Uliana Kharchenko and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to U. Kharchenko.

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Kharchenko, U., Beleneva, I., Egorkin, V. et al. Preparation of PEO/polymer coatings on aluminum alloy with antifouling properties. J Coat Technol Res 20, 763–779 (2023). https://doi.org/10.1007/s11998-022-00706-x

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  • DOI: https://doi.org/10.1007/s11998-022-00706-x

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