Abstract
Unmanned, autonomous air-to-sea vehicles, fully capable of transitioning between the two mediums, have only recently become technologically possible and have attracted great interest due to their numerous applications. However, current vehicles are unable to withstand the environmental conditions of the deep sea, especially with regards to their electronics. Previous methods for protecting electronics in the deep sea are not optimized for transitions to air. Here, a novel, lightweight, thermally-conductive, easily processed, mechanically robust, epoxy-based nanocomposite coating is presented. This material was developed with the intention of bringing the multi-domain air-water drone, known as the Naviator, to the deep ocean. In this work, the coating is thoroughly characterized and demonstrated to protect electronics submerged in water at high-pressure benchtop conditions as well as in an actual deep sea mission. The coating is also contrasted against unmodified epoxy, as well as commercial syntactic foam, and deemed superior for this application.
Graphical Abstract
Similar content being viewed by others
References
Thiede, C, Buscher, M, Luck, M, Lehr, H, Korner, G, Martin, J, Schlichting, M, Krueger, S and Huth, H, "An Overall Pressure Tolerant Underwater Vehicle: DNS Pegel." OCEANS 2009-EUROPE, pp. 1-6. IEEE, (2009)
Craven, R, Graham, D, Dalzel-Job, J, “Conceptual Design of a Composite Pressure Hull.” Ocean Eng., 128 153–162 (2016)
Imran, M, Shi, D, Tong, L, Waqas, HM, “Design Optimization of Composite Submerged Cylindrical Pressure Hull Using Genetic Algorithm and Finite Element Analysis.” Ocean Eng., 190 106443 (2019)
Liang, C-C, Chen, H-W, Jen, C-Y, “Optimum Design of Filament-Wound Multilayer-Sandwich Submersible Pressure Hulls.” Ocean Eng., 30 (15) 1941–1967 (2003)
Maia, MM, Soni, P and Diez, FJ, "Demonstration of an Aerial and Submersible Vehicle Capable of Flight and Underwater Navigation with Seamless Air-Water Transition." https://arxiv.org/abs/1507.01932, (2015)
Edwards, D, Arnold, NS, Heinzen, S, Strem, C and Young, T, "Flying Emplacement of an Underwater Glider." pp. 1-6. IEEE, OCEANS 2017 - Anchorage (2017)
Lu, D, Xiong, C, Zhou, H, Lyu, C, Hu, R, Yu, C, Zeng, Z, Lian, L, “Design Fabrication and Characterization of a Multimodal Hybrid Aerial Underwater Vehicle.” Ocean Eng., 219 108324 (2020)
Alzu’bi, H, Mansour, I, Rawashdeh, O, “Loon Copter: Implementation of a Hybrid Unmanned Aquatic-Aerial Quadcopter with Active Buoyancy Control.” J. Field Robot., 35 (5) 764–778 (2018)
Weisler, W, Stewart, W, Anderson, MB, Peters, KJ, Gopalarathnam, A, Bryant, M, “Testing and Characterization of a Fixed Wing Cross-Domain Unmanned Vehicle Operating in Aerial and Underwater Environments.” IEEE J. Ocean. Eng., 43 (4) 969–982 (2018)
Barnes, HE and Gennari, JJ, "A Review of Pressure-Tolerant Electronics (PTE)." Naval Research Lab Washington, DC (1976)
Verma, S, Mohanty, S, Nayak, SK, “A Review on Protective Polymeric Coatings for Marine Applications.” J. Coat. Technol. Res., 16 (2) 307–338 (2019)
Kampmann, P, Lemburg, J, Hanff, H and Kirchner, F, "Hybrid Pressure-Tolerant Electronics." pp. 1–5. IEEE, 2012 Oceans (2012)
Willcox, JS, Streitlien, K, "Pressure-Tolerant Batteries for Autonomous Undersea Applications." In: Bluefin Robotics Corp Cambridge, MA (ed.) (2002)
Narkis, M, Gerchcovich, M, Puterman, M, Kenig, S, “Syntactic Foams III. Three-Phase Materials Produced from Resin Coated Microballoons.” J Cell. Plast., 18 (4) 230–232 (1982)
Gupta, N, Zeltmann, SE, Shunmugasamy, VC, Pinisetty, D, “Applications of Polymer Matrix Syntactic Foams.” JOM, 66 (2) 245–254 (2014)
Kallas, DH and Chatten, CK, "Buoyancy Materials for Deep Submergence." Ocean Eng., (1968)
Porfiri, M, Nguyen, NQ, Gupta, N, “Thermal Conductivity of Multiphase Particulate Composite Materials.” J. Mater. Sci., 44 (6) 1540–1550 (2009)
Shabde, VS, Hoo, KA, Gladysz, GM, “Experimental Determination of the Thermal Conductivity of Three-Phase Syntactic Foams.” J. Mater. Sci., 41 (13) 4061–4073 (2006)
Grosjean, F, Bouchonneau, N, Choqueuse, D, Sauvant-Moynot, V, “Comprehensive Analyses of Syntactic Foam Behaviour in Deepwater Environment.” J. Mater. Sci., 44 (6) 1462–1468 (2009)
Fu, YX, He, ZX, Mo, D-C, Lu, S-S, “Thermal Conductivity Enhancement with Different Fillers for Epoxy Resin Adhesives.” Appl. Therm. Eng., 66 (1–2) 493–498 (2014)
Noh, YJ, Kim, HS, Ku, BC, Khil, MS, Kim, SY, “Thermal Conductivity of Polymer Composites With Geometric Characteristics of Carbon Allotropes.” Adv. Eng. Mater., 18 (7) 1127–1132 (2016)
Himes, GR, “Block Copolymeric Rubber Compositions for Soles.” US Patent No. 4,904,725. 27 Feb. 1990
Hasan, M, Patel, Y, Gamboa, AR, Grzenda, M, Saro-Cortes, V, Mhatre, V and Singer, J, "Shear-Induced Microporous Nanocomposite Epoxy Thermosets (MiNET)." Under Review, (2020)
Pickering, SU, “CXCVI.—Emulsions.” J. Chem. Soc. Trans., 91 2001–2021 (1907)
Chandrasekaran, S, Seidel, C, Schulte, K, “Preparation and Characterization of Graphite Nano-Platelet (GNP)/Epoxy Nano-Composite: Mechanical, Electrical and Thermal Properties.” Eur. Polym. J., 49 (12) 3878–3888 (2013)
Raza, MA, Westwood, AVK, Stirling, C, “Effect of Processing Technique on the Transport and Mechanical Properties of Graphite Nanoplatelet/Rubbery Epoxy Composites for Thermal Interface Applications.” Mater. Chem. Phys., 132 (1) 63–73 (2012)
Tang, L-C, Wan, Y-J, Yan, D, Pei, Y-B, Zhao, L, Li, Y-B, Wu, L-B, Jiang, J-X, Lai, G-Q, “The Effect of Graphene Dispersion on the Mechanical Properties of Graphene/Epoxy Composites.” Carbon (New York), 60 16–27 (2013)
Kargar, F, Barani, Z, Salgado, R, Debnath, B, Lewis, JS, Aytan, E, Lake, RK, Balandin, AA, “Thermal Percolation Threshold and Thermal Properties of Composites with High Loading of Graphene and Boron Nitride Fillers.” ACS Appl. Mater. Interfaces, 10 (43) 37555–37565 (2018)
Aboul-Enein, S, Olofa, SA, “Thermophysical Properties of Heat-of-Fusion Storage Materials for Cooling Applications.” Renew. Energy, 1 (5) 791–797 (1991)
Funding
This work has been financially supported by the Office of Naval Research through award N0001418C2063.
Author information
Authors and Affiliations
Contributions
MG contributed to methodology, validation, investigation, writing—original draft, writing—review and editing, visualization. MM contributed to conceptualization, methodology, software, validation, resources, writing—review and editing, project administration, funding acquisition. AC contributed to methodology, validation, investigation, resources. PF contributed to validation, investigation, resources. FJD contributed to conceptualization, methodology, writing—review and editing, supervision, project administration, funding acquisition. JPS contributed to conceptualization, methodology, writing—review and editing, supervision, project administration, funding acquisition.
Corresponding author
Ethics declarations
Conflict of interest
Authors Francisco Javier Diez and Marco Maia are both partial owners of SubUAS LLC.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Grzenda, M.J., Maia, M.M., Costeas, A. et al. Optimization and application of a low-density epoxy composite coating for autonomous air-to-deep sea vehicles. J Coat Technol Res 19, 1523–1534 (2022). https://doi.org/10.1007/s11998-022-00627-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-022-00627-9