Abstract
The divinyl silane modified self-crosslinking polyacrylate latex was successfully prepared by semicontinuous seeded emulsion polymerization. Methyl methacrylate (MMA) and butyl acrylate (BA) were used as main monomers and the reaction was initiated by potassium persulfate (KPS). The modified monomer 1, 3-divinyltetramethyldisiloxane (DVMS) and crosslinked monomer hydroxyethyl acrylate (HEA) were introduced into the basic dispersion. Sodium dodecyl sulfonate (SDS) anionic surfactant and alkyl polyglycoside (APG) nonionic emulsifier were utilized as composite emulsifiers. The structure of latex film was characterized by Fourier transform infrared spectroscopy (FTIR). The latex films were tested by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and contact angle (CA) and apparent crosslinking percentage. The particle size of the emulsion was measured by Zetatrac dynamic light scattering instrument. The optimum conditions are as follows: the amount of composite emulsifier is 5.0%, the mass ratio of SDS to APG is 1:1, the amount of initiator is 0.5%, the amount of DVMS is 5.0%, and the amount of HEA is 1.0%. The emulsion has good mechanical stability and chemical stability, and the storage stability is ideal. The dispersion is blue and translucent, with a small particle size. The apparent crosslinking percentage of the latex film is above 89%, and the highest contact angle was more than 98°. The polyacrylate colloidal film prepared in this paper has outstanding thermal stability and hydrophobicity.
Similar content being viewed by others
References
Machotová, J, Černošková, E, Honzíček, J, Šňupárek, J, “Water Sensitivity of Fluorine-Containing Polyacrylate Latex Coatings: Effects of Crosslinking and Ambient Drying Conditions.” Progress in Organic Coatings, 120 266–273. https://doi.org/10.1016/j.porgcoat.2018.03.016 (2018)
Jiang, XB, Zou, D, Kong, XZ, Zhu, XL, Zhang, ZG, “Styrene-Butyl Acrylate Copolymers Latexes Prepared with Different Functional Monomers and Their Application as Anti-icing Coatings.” Journal of Polymer Research, 21 (6) 1–7. https://doi.org/10.1007/s10965-014-0473-9 (2014)
Xu, W, An, QF, Hao, LF, Zhang, D, Zhang, M, “Synthesis of Self-crosslinking Fluorinated Polyacrylate Soap-Free Latex and Its Waterproofing Application on Cotton Fabrics.” Fibers and Polymers, 15 (3) 457–464. https://doi.org/10.1007/s12221-014-0457-8 (2014)
Lin, J, Zheng, C, Zhu, MN, Chen, YZ, Lu, PP, Liu, Q, Cai, XF, Zhuang, JW, Cai, XM, Liao, LP, Yuan, GY, Xu, CL, “Comparison of Copolymer Emulsions of Fluorine and Siloxane-Containing Acrylates with Core-Shell Structure for Water-Repellent Cotton Fabrics Coatings.” Polymers for Advanced Technologies, 26 (1) 68–76. https://doi.org/10.1002/pat.3420 (2015)
Fang, C, Zhu, K, Zhu, XB, Lin, ZX, “Preparation and Characterization of Self-crosslinking Fluorinated Polyacrylate Latexes and Their Pressure Sensitive Adhesive Applications.” International Journal of Adhesion and Adhesives. https://doi.org/10.1016/j.ijadhadh.2019.102417 (2019)
Fang, C, Yan, QM, Liu, ZZ, Lu, YF, Lin, ZX, “The Influence of Monobutyl Itaconate and β-Carboxyethyl Acrylate on Acrylic Latex Pressure Sensitive Adhesives.” International Journal of Adhesion and Adhesives, 84 387–393. https://doi.org/10.1016/j.ijadhadh.2018.05.007 (2018)
Cui, MY, Liu, C, Xu, Q, Li, RH, “Effect of Hybrid Emulsifier (Reactive Coupling with Anionic) on the Properties of Acrylic Emulsion.” Journal of Adhesion Science and Technology, 29 (16) 1758–1769. https://doi.org/10.1080/01694243.2015.1046730 (2015)
Wang, XM, Xu, TT, Zhang, CF, Chen, LJ, “Synthesis and Surface Properties of a Novel Fluorine Modified Acrylate Colloid.” Advances in Polymer Technology, 37 (6) 2152–2157. https://doi.org/10.1002/adv.21874 (2018)
Machotova, J, Podzimek, S, Kvasnicka, P, Zgoni, H, Snuparek, J, Cerny, M, “Effect of Molar Mass on Film-Forming Properties of Self-crosslinking Latexes Based on Structured Acrylic Microgels.” Progress in Organic Coatings, 92 23–28. https://doi.org/10.1016/j.porgcoat.2015.12.003 (2016)
Zhang, CF, Xu, TT, Bao, ZB, Chen, LJ, “Synthesis and Characterization of Fluorinated Polyacrylate Latex Emulsified with Novel Surfactants.” Designed Monomers and Polymers, 20 (1) 118–124. https://doi.org/10.1080/15685551.2016.1231040 (2017)
Chen, LJ, Shao, TT, Gong, YL, Wang, XM, “Preparation and Characterization of Novel VAc/VeoVa10/DBM/VTES Quadripolymer Latex Emulsified with Green Surfactants.” Progress in Rubber, Plastics and Recycling Technology, 35 (4) 188–197. https://doi.org/10.1177/1477760619861980 (2019)
Parvate, S, Mahanwar, P, “Advances in Self-crosslinking of Acrylic Emulsion: What We Know and What We Would Like to Know.” Journal of Dispersion Science and Technology, 40 (4) 519–536. https://doi.org/10.1080/01932691.2018.1472012 (2019)
Tillet, G, Boutevin, B, Ameduri, B, “Chemical Reactions of Polymer Crosslinking and Post-crosslinking at Room and Medium Temperature.” Progress in Polymer Science, 36 (2) 191–217. https://doi.org/10.1016/j.progpolymsci.2010.08.003 (2011)
Fourdrin, S, Rochery, M, Lewandowski, M, Ferreira, M, Bourbigot, S, “Rheological and Thermogravimetric Studies of the Crosslinking Process of Functionalized Acrylic Latexes.” Journal of Applied Polymer Science, 99 (3) 1117–1123. https://doi.org/10.1002/app.22281 (2006)
Zhou, JH, Chen, X, Duan, H, Ma, JZ, “Synthesis and Properties of Fluorine-Silicon Modified Polyacrylate Hybrid Latex Particles with Core-Shell Structure Obtained via Emulsifier-Free Emulsion Polymerization.” Polymer International, 64 (10) 1373–1380. https://doi.org/10.1002/pi.4926 (2015)
Gong, YL, Shao, TT, Chen, XL, Cao, SS, Chen, LJ, “Silicone Acrylate Dispersion Based on Semi-continuous Seed Emulsion Polymerization Using Polymerizable Emulsifiers.” Chemical Papers, 74 (9) 2875–2882. https://doi.org/10.1007/s11696-020-01127-z (2020)
Chen, LJ, Zhang, X, Wang, XM, Dai, OY, “Synthesis and Characterization of Fluoro-Silicone Polyacrylate Latex Emulsified with Novel Green Surfactants.” Progress in Rubber, Plastics and Recycling Technology, 35 (2) 102–114. https://doi.org/10.1177/1477760618798428 (2019)
Zhao, HC, Gao, LL, Li, QF, Guo, JL, “Synthesis and Characterization of Poly(Styrene/n-Butyl Acrylate/Vinyltrimethoxysilane) by Emulsifier-Free Emulsion Polymerization.” Advanced Materials Research, 150–151 1551–1554 (2011)
Jiang, Y, Sun, X, Li, B, Ren, XJ, Zhang, HW, Zhang, R, “Synthesis and Characterization of Monodisperse Emulsion Copolymer.” Chemical Research in Chinese Universities, 32 (1) 134–139. https://doi.org/10.1007/s40242-016-5291-7 (2016)
Jiao, CY, Shao, Q, Wu, MY, Zheng, B, Guo, Z, Yi, JM, Zhang, JX, Lin, J, Wu, SD, Dong, MY, Guo, ZH, “2-(3,4-Epoxy) Ethyltriethoxysilane-Modified Waterborne Acrylic Resin: Preparation and Property Analysis.” Polymer. https://doi.org/10.1016/j.polymer.2020.122196 (2020)
Naghash, HJ, Mallakpour, S, Kayhan, N, “Synthesis and Characterization of Silicone Modified Acrylic Resin and Its Uses in the Emulsion Paints.” Iranian Polymer Journal, 14 (3) 211–222 (2005)
Park, H-S, Kim, S-R, Park, H-J, Kwak, Y-C, Hahm, H-S, Kim, S-K, “Preparation and Characterization of Weather Resistant Silicone/Acrylic Resin Coatings.” Journal of Coatings Technology, 75 (1) 55–64. https://doi.org/10.1007/bf02697923 (2003)
Zhang, JD, Yang, MJ, Zhu, YR, Yang, H, “Synthesis and Characterization of Crosslinkable Latex with Interpenetrating Network Structure Based on Polystyrene Andpolyacrylate.” Polymer International, 55 (8) 951–960. https://doi.org/10.1002/pi.2056 (2006)
Shao, TT, Gong, YL, Chen, XL, Chen, LJ, “Preparation and Characterization of Modified Self-crosslinking Fluorocarbon Acrylate Latex.” Chemical Papers, 75 (3) 853–862. https://doi.org/10.1007/s11696-020-01350-8 (2021)
Keshavarz, MH, Esmaeilpour, K, Taghizadeh, H, “A New Approach for Assessment of Glass Transition Temperature of Acrylic and Methacrylic Polymers from Structure of Their Monomers Without Using Any Computer Codes.” Journal of Thermal Analysis and Calorimetry, 126 (3) 1787–1796. https://doi.org/10.1007/s10973-016-5701-6 (2016)
Chen, LJ, Wu, FQ, “Preparation and Characterization of Novel Self Cross-Linking Fluorinated Acrylic Latex.” Journal of Applied Polymer Science, 123 (4) 1997–2002. https://doi.org/10.1002/app.34685 (2011)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Chen, X., Cao, S., Zhao, W. et al. Preparation and characterization of self-crosslinking acrylate emulsion modified by divinyl silane. J Coat Technol Res 19, 887–895 (2022). https://doi.org/10.1007/s11998-021-00566-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-021-00566-x