Abstract
The dissolved oxygen concentration must be well controlled in liquid Pb for use as a primary coolant of fast spectrum nuclear reactors. We have measured fundamental data of oxygen in liquid Pb. The Sieverts constant and solubility of oxygen were measured by coulometric titration. Thermal cycling of liquid Pb allowed a quantification of the excess oxygen above solubility required to initiate solid PbO nucleation, which is the metastable limit in liquid Pb. The data obtained in this study are as follows:
-
Sieverts constant (k): \({\text{log }}k \left( {{\text{bar}}^{0.5} \,{\text{wt}}.{\text{\% }}^{ - 1} } \right) = 2.43 - \frac{6700}{T}\quad \left( {{623}\,{\text{K}} < T < {823}\,{\text{K}}} \right)\)
-
Solubility (Co,s): \(\log C_{{{\text{o}},{\text{s}}}} { }\left( {{\text{wt}}.{\text{\% }}} \right) = 2.90 - \frac{4863}{T}\quad \left( {{623}\,{\text{K}} < T < {823}\,{\text{K}}} \right)\)
-
Metastable limit for PbO nucleation (Co,m): \(\log C_{{{\text{o}},{\text{m}}}} { }\left( {{\text{wt}}.{\text{\% }}} \right) = 2.67 - \frac{4631}{T}\quad \left( {{663}\,{\text{K}} < T < { 790}\,{\text{K}}} \right).\)
Similar content being viewed by others
References
A. Alemberti, V. Smirnov, C.F. Smith, and M. Takahashi, Prog. Nucl. Energy 77, 300. (2014).
N. Li, J. Nucl. Mater. 300, 73. (2002).
L. Brissonneau, F. Beauchamp, O. Morier, C. Schroer, J. Konys, A. Kobzova, F. Di Gabriele, and J.-L. Courouau, J. Nucl. Mater. 415, 348. (2011).
J. Zhang, J. Appl. Electrochem. 43, 755. (2013).
C.B. Alcock, and T.N. Belford, Trans. Faraday Soc. 60, 822. (1964).
R. Ganesan, T. Gnanasekaran, and R.S. Srinivasa, J. Nucl. Mater. 349, 133. (2006).
J. Lim, M. Gabriele, A. Marino, K. Gladinez, and A. Aerts, J. Electrochem. Soc. 164, H743. (2017).
K. Gladinez, K. Rosseel, J. Lim, A. Marino, G. Heynderickx, and A. Aerts, Phys. Chem. Chem. Phys. 19, 27593. (2017).
J. Lehmann, P. Rocabois, and H. Gaye, J. Non-Cryst. Solids 282, 61. (2001).
R. Becker, and W. Döring, Ann. Phys. 416, 719. (1935).
J. Lim, G. Manfredi, A. Mariën, and J. Van den Bosch, Sens. Actuators B Chem. 188, 1048. (2013).
G. Manfredi, J. Lim, K. Rosseel, J. Van den Bosch, T. Doneux, C. Buess-Herman, and A. Aerts, Sens. Actuators B Chem. 214, 20. (2015).
J. Lim, D. Parkison, G. Manfredi, and A. Aerts, J. Electrochem. Soc. 166, E542. (2019).
Handbook on lead-bismuth eutectic alloy and lead properties, material compatibility, thermal-hydraulics and technologies, OECD-NEA, 2015
E.N. Rodigina, K.Z. Gomel’skii, and V.F. Luginina, Zhur. Fiz. Khim. 35, 1799. (1961).
B.F. Gromov, V.I. Orlov, P.N. Martynov, V.A. Goulevsky, The problems of technology of the heavy liquid metal coolant. Paper presented at the conference on heavy liquid metal coolant in nuclear technology, 5–9 October 1998
Acknowledgements
This work is supported by the Belgian government through the MYRRHA project. The technical assistance of Stefan Huysmans (SCK CEN) is greatly appreciated.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
On behalf of all authors, the corresponding author states that there are no conflicts of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Lim, J., Gladinez, K., Marino, A. et al. Solubility of Oxygen and Metastable Limit for PbO Nucleation in Liquid Pb. JOM 73, 4023–4029 (2021). https://doi.org/10.1007/s11837-021-04909-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11837-021-04909-2