Investigation of using RFID for cure monitoring of glass fiber-reinforced plastics

Fiber composite components play an important role in the turnaround in energy policy as well as in stopping global warming. Therefore, it is essential to improve the manufacturing efficiency of these components. RFID technology is spreading to digitize and organize processes in production and logistics more efficiently. Since cure monitoring is a crucial factor in the manufacturing of composite components, the question arises whether the RFID technology is applicable for cure monitoring. This paper presents two methods of how an into glass fiber-reinforced plastics integrated RFID transponder could monitor the curing. Following the assumption that the change in permittivity of the glass fiber-reinforced plastic during curing influence the RFID signal, experiments in a measuring chamber (low-interference environment) were conducted. It was investigated whether the optimal response frequency of the integrated RFID transponder changes and whether the received signal strength indicator (RSSI) changes at a specific frequency during curing. As a reference method, the dielectric analysis as a well-known method for cure monitoring was used and compared with the RFID measurements. The results indicate that the optimal response frequency remains constant but the RSSI increases and possess a very high linear correlation with the measurement of the dielectric analysis in a low-interference environment. Consequently, the RFID technology is applicable to monitor the curing of glass fiber-reinforced plastics by measuring the RSSI in a low-interference environment.


Introduction
In the past years, a continuous increase of the production volume of fiber-reinforced plastics (FRP) can be observed [1]. Reasons for the increase are that these materials play a major role in the turnaround in energy policy, as they are an essential part of wind turbines, and in stopping global warming. The pressure to reduce CO 2 emissions is leading to increased efforts to make aircrafts, cars, trucks, and the like, more lightweight. FRP offer advantageous material properties for lightweight construction [1,2].
In order to achieve the advantageous material properties, it is essential to cure the components in a targeted manner. Cure monitoring can improve both the quality and efficiency of the curing process of FRP [3]. Thus, there are many current research activities to enhance the conventional cure monitoring methods, like the dielectric analysis [4], the differential scanning calorimetry [5], the dynamic mechanical analysis [6] and ultrasound monitoring [7,8]. However, these conventional methods are criticized because they require additional equipment, processes, and expertise generating additional costs without bringing any further benefit (beside the cure monitoring) in the product life cycle [9].
Konstantopoulos et al. observed a trend towards "sensing materials" [10], such as fiber Bragg sensors, which can be used both for cure monitoring [11] and for structure health monitoring [10]. However, these optical fibers are fragile and susceptible to mechanical stress [12]. Hence, there is a high risk of damaging the sensors, which leads to increased costs and inefficiency [10].
Consequently, besides the enhancement of conventional cure monitoring methods, new methods for cure monitoring are being pursued [13].
At the same time, a digitalization of the manufacturing process is demanded in order to reduce manufacturing costs of FRP [14]. In this context, radio frequency identification (RFID) technology comes into focus. Simulation studies indicate that the integration of RFID transponders into FRP components provides the basis for reducing throughput times, inventories, and rejects in FRP manufacturing as well as improving the due date adherence [15,16]. Moreover, RFID enables an autonomous production [17]. In addition, RFID offers the possibility to document the manufacturing and usage processes locally [15]. The resulting component history can be used for maintenance and component authentication [18].
This contribution examines the feasibility of using RFID for cure monitoring of FRP. Two measurement methods have been investigated in an experiment. The results have been compared to a reference method and discussed. The next section presents the state of the art and identifies the research gap. The third section introduces the measurement background and the fourth section describes the experimental design. It is followed by the results and a discussion in section five. In the sixth section, the contribution concludes with a summary and an outlook on further research.

Related work and research gap
Zettler et al. and Gray demonstrated RFID transponders integrated in FRP could still be read. Both authors investigated the effect of RFID integration on the final mechanical performance of the FRP [19,20]. Gray showed how to predict the influence of the RFID transponder on the mechanical properties by FEM simulations and, thus, how to determine a suitable transponder position [20].
Bernhard et al. conducted extensive tests to determine the influence of FRP on the reading range of RFID systems. Their results showed that carbon fiber-reinforced plastics strongly attenuate the RFID signal [21,22]. However, glass fiber-reinforced plastics (GFRP) barely influence the reading range of low frequency and high frequency systems. The reading range of ultra high frequency (UHF) systems decreases due to GFRP [21]. Furthermore, there was a shift in the best reading frequency. While the RFID transponders achieved the maximum reading range in free space at 868 MHz, the laminated transponders reached the maximum reading range at approx. 800 MHz. Considering 868 MHz the theoretical read range dropped from 8 to 5 m [21]. Hardi et al. used this effect to monitor the resin flow during a vacuum infusion of GFRP using an integrated UHF RFID transponder. In contrast to Bernhard et al., Hardi et al. measure the received signal strength indicator (RSSI). With experiments, they proved that this value drops significantly as soon as the resin flow reaches the integrated RFID transponder [23].
For the first time, Veigt et al. demonstrated experimentally that the received signal strength indication (RSSI) of an RFID transponder integrated into FRP increases synchronously with the curing process. This was proofed by comparing the RSSI measurements with a reference measurement of the dielectric analysis (DEA). In summary, the result shows that cure monitoring of GFRP and aramid FRP is possible by using UHF RFID transponder [24,25]. During curing, the dielectric properties of the GFRP change. This change affects the strength of the response signal of an integrated RFID transponder. However, reflections and other radio waves disturb the RSSI measurement. These interferences can be balanced by averaging the RSSI of several transponders [26], but there is still potential to enhance the measurement to make it more precise.
Groth et al. developed wireless and chipless sensors, which can be integrated into plastics and can be used at 25 GHz [13] or at 46 GHz [27]. These sensors shift their best response frequency during the curing process resulting from the dielectric permittivity change of the plastic. The shift of the best response frequency correlates with the curing process, which was proofed by comparing the shift with the measurement result of a differential scanning calorimetry.
Measuring the frequency shift has the advantage that signal reflections do not affect the measuring, unlike the RSSI. However, the use of UHF RFID transponders has the advantage that these standardized transponders are both inexpensive and offer further advantages in product life. For instance, they can be used in logistics and maintenance processes.
An open research gap is whether a frequency shift correlating with the curing process of GFRP occurs within the UHF range. This frequency shift could make the measuring of the cure monitoring less easily disturbed by interferences. Another open research gap is which impact the interference has on the RSSI measurement. This contribution examines these two gaps.

Radio frequency identification
An RFID system consists of a couple of components. The transponders are attached to objects to make them identifiable. An RFID reader (and writer) consists of a highfrequency module (transmitter and receiver), a control unit and one or more antennas. The RFID reader supplies the transponders with energy via air interface. A minimum field 1 3 strength E is required to activate the transponder and supply it with sufficient energy for data transmission. Equation (1) expresses the minimum field strength E min [28]: where µ is the magnetic permeability and the electric permittivity of the transmission medium, P e-min is the minimum required input power, is the wavelength, which depends on the frequency, and G is the transponder antenna gain. Further, the arriving field strength E depends on the transmission power of the reader P EIRP , the magnetic permeability µ and the electric permittivity of the transmission medium as well as the distance r between the reader antenna and the transponder antenna, see Eq. (2) [28]: The strength of a received signal, also called backscatter signal, can be measured utilizing the RSSI. It is only an indicator because interferences, such as other radio waves and reflections, affecting the measurement. RFID systems exist in many different variants. A significant distinguishing feature is the operating frequency. For low frequency systems, the used frequencies are between 30 and 300 kHz, for high frequency systems between 3 and 30 MHz, for ultra-high frequency (UHF) systems between 300 MHz and 3 GHz, and for microwave above 3 GHz. In case of application in production planning and control as well in logistics, the UHF is established. In Europe, the frequency range for UHF application is 865-868 MHz [28].

Dielectric analysis (DEA)
The DEA is a widely accepted method to characterize the polymeric resins during curing. Free ions and dipoles existing within it affect the dielectric behavior of the resin. In the uncured resin, the free ions can move and thus dominate the dielectric response. In the cured resin, ion migration reduces to nearly zero, and the alignment of the dipoles dominates the dielectric response, which is a frequency-dependent phenomenon [29]. Thus, the complex electrical impedance can be used to monitor the curing of thermoset resins or adhesives [30]. The frequency-independent resistivity or direct current resistivity (also called ion viscosity) correlates with the cure state throughout the curing process. Interdigitated electrodes on a substrate in contact with the material under test can be used as a sensor for studying the dielectric properties and for observation of cure state of the material under test. (1) The change in ion viscosity during the curing process is typically nonlinear, as shown in Fig. 1. Transition phases can be identified by measuring the ion viscosity and by defining 4 points [see CP (1) to CP(4) in Fig. 2

Bravais-Pearson correlation coefficient
In order to assess quantitatively the relationship between the RFID measurement and the DEA measurement we require an appropriate metric. Due to both methods measure the change of the dielectric material properties we expect a linear correlation between the measurement series. The Bravais-Pearson correlation coefficient is a suitable metric to measure the linear correlation of two measurement series [31]. It is calculated by: where x is one measurement series and y is the other. The value range of the correlation coefficient lies between 1 and − 1, where 1 is a linear correlation with the same direction and − 1 is a linear correlation with the opposite direction. For further interpretation of the correlation of measurement series, the following classification applies: 0.5 > |r| is considered as weak correlation, 0.8 > |r| ≥ 0.5 as mean correlation and |r| ≥ 0.8 as strong correlation [31].

Experimental setup
The experiment was conducted in a measuring chamber, see Fig. 2. The measuring chamber blocks radio waves from the environment, ensuring that the measurement is almost free of interferences. In addition, the measuring chamber absorbs the reflections of the RFID system. The used RFID system Cisc RFID Xplorer can perform a frequency between 800 MHz and 1000 MHz. It has two antennas. The first antenna transmits energy to the transponder. The second antenna receive the transponder signal. Consequently, the experimental setup was designed to be as interference-free and highly precise as possible.
For the experiment, an E-glass fabric with twill K2/2 and a weight of 390 g/m 2 , the EPIKOTE resin L20 and the curing agent H530 were used. The E-glass fabric was split into 16 layers of 160 × 160 mm each. These layers were laminated by hand. During this process, the RFID transponder Protag 3 mini (with an Impinj Monza R6 chip) was centrally integrated into the laminate (between layer 8 and 9); see Fig. 3. The Protag 3 mini is an UHF Gen 2-compliant transponders, which is designed for communications at 865-868 MHz. The laminate was cured at a constant room temperature of 23 °C inside the measuring chamber.
In intervals of 5 min, the frequency sweep from 800 to 1000 MHz was performed in 5 MHz steps and the RSSI of the RFID transponder was measured. Simultaneously, the DEA was conducted with a Netzsch Epsilon 230/10 to generate reference values for the cure monitoring. The DEA sensor was integrated at the side of the material under test between layers 8 and 9, see Fig. 3. Matlab 2019b was used to process the measured data.

Frequency variation
Since the transponder is designed for communication between 865 and 868 MHz, the highest signal strength of the transponder was expected at this frequency range when the composite is cured. Further, it was expected that the liquid resin would affect the transponder in such a way that the peak of the RSSI would shift as well as the RSSI would be increase during the curing process. This assumption is based on the physical relationships described in Eqs. 1 and 2. Accordingly, the usable energy by the transponder depends, among others, on the electric permittivity of the transmission medium and the wavelength. Due the changing electric permittivity of the resin, the peak of the RSSI should shift. Following Eq. 2, it was expected that the change of the electric permittivity of the resin would also affect the signal transmission and, thus, the RSSI would increase during the curing process. Figure 4 illustrates this expectation. The red arrow marks the expected shift and increase of the RSSI peak. So far, it can be concluded that no peak shift occurs with a Protag 3 mini between 800 and 1000 MHz. However, possibly this measurement method can work with another RFID transponder without the auto-tune function in this frequency range. Furthermore, a peak shift may also occur with the used transponder in the range below 800 MHz or above 1000 MHz.
The question remains where exactly the peak is below 800 MHz and whether this peak shifts. Due to technical restrictions, this question remains open.

RSSI measurement
Considering a specific frequency in Fig. 5, for instance 865 MHz, it can be determined that the RSSI increases over  As a result of the frequency sweeps (displayed every 120 min) during curing, the RSSI increases and the peak of the RSSI remains at the same frequency the curing time. Furthermore, the graph shows that this increase is over the first 240 min higher than during the time afterwards. Figure 6 illustrates the RSSI measurement at 865 MHz over the curing time (black asterisk) and compares this measurement with the ion viscosity measured by dielectric analysis at 1 Hz (red circle). Furthermore, the blue line displays the core temperature of the material under test. This measurement visualizes the self-heating of the laminate while the curing is starting. The RSSI and the ion viscosity measurements start with a significant slope, which decreases after approx. 300 min and finally levels out at an almost constant level. In this case, the slope of the ion viscosity is almost zero. However, by remembering the typical curve of ion viscosity illustrated in Fig. 1, it becomes clear that the ion viscosity can also level out with a low slope like the RFID measurement in this case. As the laminate heats up during curing and cools down accordingly at this late stage of curing, the slight increase of the RSSI may indicate that the RSSI measurement is influenced by temperature. As this is important for increasing the precision of the RSSI measurement (especially for curing in an oven or an autoclave), the degree to which the RSSI measurement is temperature depended should be investigated in further experiments.
In order to quantify the correlation between the measurement series of the RSSI and the ion viscosity, both measurement series was normalized to values between 0 and 1 and the correlation coefficient was calculated according to Eq. 3. The correlation coefficient of the two measurement series is 0.98. Consequently, the two measurement series possess a very high linear correlation. Hence, the correlation coefficient confirms the optical impression that there is a very high correlation between the two measurements.
A curve fitting was performed and the functions of the two measurement series were determined to examine them in detail. The curve fitting was executed with a Gauss function, a rational function, a polynomial function, and an exponential function. The Gauss function matches the measured values of both functions with the lowest sum of squared errors (SSE). Table 1 presents the general functions considered as well as the SSE and Table 2 details the functions with their variables. Figure 7 visualizes the measured values, the determined gauss functions, and their first derivation. Thus, Fig. 7 displays: • Both measurement series start after the viscosity minimum tCP(2) occurs. • Both measurement series initially increase. The slope of increase of the RFID signal is higher than the increase of the DEA measurement. • The RFID measurement series shows a turning point after approx. 50 min. The turning point of the DEA measurement series follows at approx. 110 min. The turning point indicates the inflection point tCP(3). • The RFID measurement series levels out after approx.
400 min, but still shows a slight slope afterward. The DEA measurement series levels out after approx. 550 min. Subsequently, the slope is almost zero. The levelling out of the slope indicates a cessation of the polymerisation reaction and, thus, the end of curing tCP(4). In both cases, the user can define a specific slope, which can be considered as the end of curing. 1.5008 0.0276 1.9913 6.0142 A detailed comparison of the two measurement series illustrates their similarity. Both measurement series follow the typical course of the DEA (displayed in Fig. 1). Nevertheless, there are differences in detail. The turning points tCP (3) are about 60 min apart. The decrease in slope and the associated end of curing tCP(4) can also be interpreted differently.
The differences may be due to the different positions of the sensors. Since the material under test was produced in a hand laminate process, the amount of resin remaining at the sensor positions may vary. In addition, self-heating of the resin during curing can cause the resin in the center of the laminate (position of the RFID transponder) to cure slightly faster than at the edges (position of the DEA sensor).
The result confirms the previous results of Veigt et al. [26] and demonstrates the feasibility of the UHF RFID technology for cure monitoring. The low-interference environment inside the measuring chamber leads to an almost ideal measurement curve. This result emphasizes the suitability of the UHF RFID transponder for cure monitoring. The difference of the RSSI measurement to the DEA measurement can be explained with the different position of the DEA sensor and the RFID transponder. Experiments with two DEA sensors prove that these measurement curves can also be shifted slightly to each other [26]. Questions which remain are: To which degree is the RSSI measurement temperature depended, to which degree does the DEA sensor cause interferences and how interferences can be filtered out. The filtering is essential to increase the precision and the reliable of the RSSI measurement in an environment with interference as it was the case in the preliminary work by Veigt et al.

Conclusion
This contribution introduces an experimental study investigating the possibility of using RFID for curing monitoring of GFRP. The contribution considers two methods. The frequency variation revealed that there was no shift of the high point of the response signal strength. Consequently, the optimum frequency remains the same during curing or the used transponder is not suitable for this measurement option.
At a fixed frequency, the RSSI increases over the curing time. During the experiment, all parameters was kept constant except the dielectric properties of the resin used in the GFRP. The permittivity of the transmission medium "GFRP laminate" changed over the curing time. This change influences the performance of the RFID system and leads to the increase of the RSSI. The curve of the RSSI measurement correlates very highly with the reference measurement of the DEA (correlation coefficient of 0.98). Consequently, the RSSI measurement is an indicator of the curing process of glass fiber reinforced plastics in a low-interference environment.
An advantage of using RFID is the wireless measurement. Hence, in the case of a vacuum infusion, there are no weak points in the vacuum structure due to cables. Furthermore, the transponders cost less than conventional sensors for cure monitoring, e.g. for the DEA. Compared to most conventional methods of cure monitoring, RFID has the advantage that transponders can be used in the further life of the product, e.g. for production planning and control, in logistics or maintenance. Due to these reasons, the use of RFID for cure monitoring in the manufacturing of composites can make the production more efficient. This efficiency is important in order to support the turnaround in energy policy as well as the stopping of global warming.
Further research is required to enhance the precision and reliability of the RSSI measurement in environments with interferences. For this purpose, approaches should be explored to filter out the interferences when measuring the RSSI. Besides, the suitability of the phase shift of the RFID signal should be investigated as an alternative or supplementary method and the temperature dependency of the RSSI measurement should be researched.
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