Abstract
As a kind of essential hydrated salt phase change energy storage materials, mirabilite with high energy storage density and mild phase-transition temperature has excellent application potential in the problems of solar time and space mismatch. However, there are some disadvantages such as supercooling, substantial phase stratification and leakage problem, limiting its further applications. In this work, for the preparation of shaped mirabilite phase change materials (MPCMs), graphene (GO), sodium carboxymethyl cellulose (CMC), and carbon nanofibers (CNFs) were used as starting materials to prepare lightweight CMC/rGO/CNFs carbon aerogel (CGCA) as support with stable shape, high specific surface area, and well-arranged hierarchically porous structure. The results show that CGCA has regular layered plentiful pores and stable foam structure, and the pore and sheet interspersed structure in CGCA stabilizes PCMs via capillary force and surface tension. The hydrophilic aerogels supported MPCMs decrease mirabilite leaking and reduce supercooling to around 0.7–1 °C. The latent heats of melting and crystallization of CGCA-supported mirabilite phase change materials (CGCA-PCMs) are 157.1 and 114.8 J·g−1, respectively. Furthermore, after 1500 solid—liquid cycles, there is no leakage, and the retention rate of crystallization latent heat is 45.32%, exhibiting remarkable thermal cycling stability.
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References
Anam M Z, Bari A B M M, Paul S K, et al. Modelling the drivers of solar energy development in an emerging economy: implications for sustainable development goals. Resources, Conservation & Recycling Advances, 2022, 13(2): 200068
Jacobson M Z, von Krauland A K, Coughlin S J, et al. Zero air pollution and zero carbon from all energy at low cost and without blackouts in variable weather throughout the U. S. with 100% wind—water—solar and storage. Renewable Energy, 2022, 184(12): 430–442
Sodano D, Decarolis J F, Rodrigo de Queiroz A, et al. The symbiotic relationship of solar power and energy storage in providing capacity value. Renewable Energy, 2021, 177(6): 823–832
Mohammad A N, Malekib A, Mamdouh E H A, et al. A review of nanomaterial incorporated phase change materials for solar thermal energy storage. Solar Energy, 2021, 228(11): 725–743
Chen Y, Jiang Q, Xin J, et al. Research status and application of phase change materials. Journal of Materials Engineering, 2019, 47(7): 1–10
Qiu X, Lu L, Tang G, et al. Preparation and thermal properties of microencapsulated paraffin with polyurea/acrylic resin hybrid shells as phase change energy storage materials. Journal of Thermal Analysis and Calorimetry, 2020, 143(5): 3023–3032
Wang J, Li Y, Zheng D, et al. Preparation and thermophysical property analysis of nanocomposite phase change materials for energy storage. Renewable & Sustainable Energy Reviews, 2021, 151(11): 111541
Aslfattahi N, Saidur R, Arifutzzaman A, et al. Experimental investigation of energy storage properties and thermal conductivity of a novel organic phase change material/mxene as a new class of nanocomposites. Journal of Energy Storage, 2020, 27(2): 101115
Li Y Z, Kumar N, Hirschey J, et al. Stable salt hydrate-based thermal energy storage materials. Composites Part B: Engineering, 2022, 233(3): 109621
Díez N, Fuertes A B, Sevilla M. Molten salt strategies towards carbon materials for energy storage and conversion. Energy Storage Materials, 2021, 38(6): 50–69
Saito A, Okawa S, Shintani T, et al. On the heat removal characteristics and the analytical model of a thermal energy storage capsule using gelled Glauber’s salt as the PCM. International Journal of Heat and Mass Transfer, 2001, 44(24): 4693–4701
Khaleghi Dehghan A, Manteghian M, Sadrameli S M. A turbidity titration procedure for the nucleation mechanism determination of sodium sulfate decahydrate (Glauber salt) in unseeded aqueous solution. Journal of Materials Research and Technology, 2021, 11(3): 285–300
Li M, Wang W, Zhang Z, et al. Monodisperse Na2SO4·10H2O@SiO2 microparticles against supercooling and phase separation during phase change for efficient energy storage. Industrial & Engineering Chemistry Research, 2017, 56(12): 3297–3308
García-Romero A, Diarce G, Ibarretxe J, et al. Influence of the experimental conditions on the subcooling of Glauber’s salt when used as PCM. Solar Energy Materials and Solar Cells, 2012, 102(7): 189–195
García-Romero A, Delgado A, Urresti A, et al. Corrosion behaviour of several aluminium alloys in contact with a thermal storage phase change material based on Glauber’s salt. Corrosion Science, 2009, 51(6): 1263–1272
Liu X, Tie J, Tie S N. Corrosion on metal packaging materials by sodium sulfate decahydrate composite phase change material. Journal of Synthetic Crystals, 2016, 4(54): 986–994
Tie S N, Liu X. Research progress on corrosion of phase change energy storage materials and encapsulation materials. Materials Guide, 2015, 29(6): 138–142
Liu X, Tie J, Wang Z, et al. Improved thermal conductivity and stability of Na2SO4·10H2O PCMs system by incorporation of Al/C hybrid nanoparticles. Journal of Materials Research and Technology, 2021, 12(6): 982–988
Qian Y, Han N, Zhang Z, et al. Enhanced thermal-to-flexible phase change materials based on cellulose/modified graphene composites for thermal management of solar energy. ACS Applied Materials & Interfaces, 2019, 11(49): 45832–45843
Xin G, Sun H, Scott S M, et al. Advanced phase change composite by thermally annealed defect-free graphene for thermal energy storage. ACS Applied Materials & Interfaces, 2014, 6(17): 15262–15271
Liu X, Tie J, Tie S N. Energy storage properties of mans nitro phase transition materials of multiwalled carbon nano tubes of greenhouse. Transactions of the Chinese Society of Agricultural Engineering, 2016, 32(6): 226–231
Jiang Z P, Tie S N. Study on the thermal conductivity of 2-D graphene enhance Glauber’s salt-based composites PCMs. Journal of Synthetic Crystals, 2016, 45(7): 1820–1825
Ding C, Liu L, Ma F, et al. Enhancing the heat storage performance of a Na2HPO4·12H2O system via introducing multiwalled carbon nanotubes. ACS Omega, 2021, 6(43): 29091–29099
Zhou Y, Sun W, Ling Z, et al. Hydrophilic modification of expanded graphite to prepare a high-performance composite phase change block containing a hydrate salt. Industrial & Engineering Chemistry Research, 2017, 56(50): 14799–14806
Oh K, Kwon S, Xu W, et al. Effect of micro- and nanofibrillated cellulose on the phase stability of sodium sulfate decahydrate based phase change material. Cellulose, 2020, 27(9): 5003–5016
Huang K, Li J, Luan X, et al. Effect of graphene oxide on phase change materials based on disodium hydrogen phosphate dodecahydrate for thermal storage. ACS Omega, 2020, 5(25): 15210–15217
Tran N, Zhao W, Carlson F, et al. Metal nanoparticle—carbon matrix composites with tunable melting temperature as phase-change materials for thermal energy storage. ACS Applied Nano Materials, 2018, 1(4): 1894–1903
Ahmet A A, Gizem T. Synthesis and characterization of new organic phase change materials (PCMs): diesters of suberic acid. Solar Energy Materials and Solar Cells, 2021, 220(1): 110822
Zhang Z, Lian Y, Xu X, et al. Synthesis and characterization of microencapsulated sodium sulfate decahydrate as phase change energy storage materials. Applied Energy, 2019, 255(12): 113830
Xi S, Wang L, Xie H, et al. Superhydrophilic modified elastomeric RGO aerogel based hydrated salt phase change materials for effective solar thermal conversion and storage. ACS Nano, 2022, 16(3): 3843–3851
An J, Liang W, Mu P, et al. Novel sugar alcohol/carbonized kapok fiber composites as form-stable phase-change materials with exceptionally high latent heat for thermal energy storage. ACS Omega, 2019, 4(3): 4848–4855
Cheng Z, Li J, Wang B, et al. Scalable and robust bacterial cellulose carbon aerogels as reusable absorbents for high-efficiency oil/water separation. ACS Applied Bio Materials, 2020, 3(11): 7483–7491
Du X, Qiu J, Deng S, et al. Alkylated nanofibrillated cellulose/carbon nanotubes aerogels supported form-stable phase change composites with improved n-alkanes loading capacity and thermal conductivity. ACS Applied Materials & Interfaces, 2020, 12(5): 5695–5703
Li A, Dong C, Dong W, et al. Hierarchical 3D reduced graphene porous-carbon-based PCMs for superior thermal energy storage performance. ACS Applied Materials & Interfaces, 2018, 10(38): 32093–32101
Ren Y, Xu Q, Zhang J, et al. Functionalization of biomass carbonaceous aerogels: selective preparation of MnO2@CA composites for supercapacitors. ACS Applied Materials & Interfaces, 2014, 6(12): 9689–9697
Song M, Jiang J, Qin H, et al. Flexible and super thermal insulating cellulose nanofibril/emulsion composite aerogel with quasi-closed pores. ACS Applied Materials & Interfaces, 2020, 12(40): 45363–45372
Wang B, Li G, Xu L, et al. Nanoporous boron nitride aerogel film and its smart composite with phase change materials. ACS Nano, 2020, 14(12): 16590–16599
Yang L, Yang J, Tang L S, et al. Hierarchically porous PVA aerogel for leakage-proof phase change materials with superior energy storage capacity. Energy & Fuels, 2020, 34(2): 2471–2479
Zhao J, Luo W, Kim J K, et al. Graphene oxide aerogel beads filled with phase change material for latent heat storage and release. ACS Applied Energy Materials, 2019, 2(5): 3657–3664
Xie L Y, Gan B C. Application and study situation of sodium carboxymethyl cellulose in food industry. Academic Periodical of Farm Products Processing, 2007(1): 51–54
Li W, Zhao X H, Ji Y H, et al. Progresses in preparation and production technology for carboxymethycellulose. Petrochemical Technology, 2013, 42(6): 693–700
Huang T, Shao Y W, Zhang Q, et al. Chitosan-cross-linked graphene oxide/carboxymethyl cellulose aerogel globules with high structure stability in liquid and extremely high adsorption ability. ACS Sustainable Chemistry & Engineering, 2019, 7(9): 8775–8788
Xu W L, Chen S, Zhang J H, et al. Preparation and adsorption of carboxymethyl cellulose graphene composite aerogels. Journal of Materials Engineering, 2020, 9(48): 77–85
Jiang W, Yao C, Chen W, et al. A super-resilient and highly sensitive graphene oxide/cellulose-derived carbon aerogel. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2020, 8(35): 18376
Chen Q, Chu Y H. Graphene oxide prepared by Hummers method. Sichuan Chemistry Industry, 2016, 19(2): 14–16 (in Chinese)
Wu G, Bing N, Li Y, et al. Three-dimensional directional cellulose-based carbon aerogels composite phase change materials with enhanced broadband absorption for light-thermal-electric conversion. Energy Conversion and Management, 2022, 256(2): 115361
Wang J, Wang P J, Gao P, et al. Distinguishing channel-type crystal structure from dispersed structure in β-cyclodextrin based polyrotaxanes via FTIR spectroscopy. Frontiers of Materials Science, 2011, 5(3): 329–334
Wu J, Shi C, Zhang Y, et al. Photocatalytic mechanism of high-activity anatase TiO2 with exposed (0 0 1) facets from molecular-atomic scale: HRTEM and Raman studies. Frontiers of Materials Science, 2017, 11(4): 358–365
Qian M, Li Z, Fan L, et al. Ultra-light graphene tile-based phase-change material for efficient thermal and solar energy harvest. ACS Applied Energy Materials, 2020, 3(6): 5517–5522
Zhang R Y, et al. Phase Change Materials and Phase Change Energy Storage Materials. Beijing, China: Science Press, 2008 (in Chinese)
Man Y H, Wu W J. Calculation of Na2SO4·10H2O phase transition process and latent heat of phase change. Journal of National University of Defense Technology, 2009, 31(2): 41–43
Acknowledgements
The authors would like to thank the financial supports from the Natural Science Foundation of Qinghai Province (Grant Nos. 2020-ZJ-909 and 2021-ZJ-906), the Qinghai Thousand Talents Program (Grant No. 724112), and the Opening Project of State Key Laboratory of the New Technologies for Material Composites, Wuhan University of Technology (Grant No. 2020-KF-1).
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Chen, F., Liu, X., Wang, Z. et al. Hierarchically porous CMC/rGO/CNFs aerogels for leakage-proof mirabilite phase change materials with superior energy thermal storage. Front. Mater. Sci. 16, 220619 (2022). https://doi.org/10.1007/s11706-022-0619-3
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DOI: https://doi.org/10.1007/s11706-022-0619-3