Abstract
Solar thermal desalination (STD) is a promising and sustainable technology for extracting clean water resources. Whereas recent studies to improve STD performance primarily focus on interfacial solar evaporation, a non-traditional bottom heating method was designed in this study. Herein, we prepared the polyvinyl alcohol/graphene oxide (PVA-GO) composite membrane and adhered to the bottom of a beaker using crystallized PVA. The GO was loaded on a non-woven fabric and different concentrations of PVA were compared for their effect on the evaporation efficiency. The results showed that the addition of PVA increased the evaporation rate. The surface characteristic of GO membrane without PVA was a fibrous filamentous structure as observed by SEM, whereby the fibers were clearly visible. When the PVA concentration reached 6%, the non-woven fiber was completely wrapped by PVA. Under the action of a fixed light intensity, the photothermal conversion rates of GO, 2% PVA-GO, 4% PVA-GO and 6% PVA-GO membrane device could reach 39.93%, 42.61%, 45.10% and 47.00%, respectively, and the evaporation rates were 0.83, 0.88, 0.94 and 0.98 kg·m−2h−1, respectively. In addition, the PVA-GO composite membrane showed an excellent stability, which has significance for industrial application.
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References
Yu S, Zhang Y, Duan H, et al. The impact of surface chemistry on the performance of localized solar-driven evaporation system. Scientific Reports, 2015, 5(1): 13600
Alcamo J, Flörke M, Märker M. Future long-term changes in global water resources driven by socio-economic and climatic changes. Hydrological Sciences Journal, 2007, 52(2): 247–275
Li C, Jiang D, Huo B, et al. Scalable and robust bilayer polymer foams for highly efficient and stable solar desalination. Nano Energy, 2019, 60: 841–849
Yanovsky M J, Mora-Garcia S. The sun doesn’t shine equally on everyone. New Phytologist, 2016, 211(2): 377–378
Elimelech M, Phillip W A. The future of seawater desalination: Energy, technology, and the environment. Science, 2011, 333 (6043): 712–717
Shannon M A, Bohn P W, Elimelech M, et al. Science and technology for water purification in the coming decades. Nature, 2008, 452(7185): 301–310
Kummu M, Guillaume J H, de Moel H, et al. The world’s road to water scarcity: Shortage and stress in the 20th century and pathways towards sustainability. Scientific Reports, 2016, 6(1): 38495
Stankovich S, Dikin D A, Dommett G H, et al. Graphene-based composite materials. Nature, 2006, 442(7100): 282–286
Han D, He W F, Yue C, et al. Study on desalination of zero-emission system based on mechanical vapor compression. Applied Energy, 2017, 185: 1490–1496
Balandin A A, Ghosh S, Bao W, et al. Superior thermal conductivity of single-layer graphene. Nano Letters, 2008, 8(3): 902–907
Qi J, Zhang W, Cao R. Solar-to-hydrogen energy conversion based on water splitting. Advanced Energy Materials, 2018, 8(5): 1701620
Ma C, Yan J, Huang Y, et al. The optical duality of tellurium nanoparticles for broadband solar energy harvesting and efficient photothermal conversion. Science Advances, 2018, 4(8): eaas9894
Guo A, Ming X, Fu Y, et al. Fiber-based, double-sided, reduced graphene oxide films for efficient solar vapor generation. ACS Applied Materials & Interfaces, 2017, 9(35): 29958–29964
Mu P, Bai W, Zhang Z, et al. Robust aerogels based on conjugated microporous polymer nanotubes with exceptional mechanical strength for efficient solar steam generation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6 (37): 18183–18190
Zhang Z, Mu P, He J, et al. Facile and scalable fabrication of surface-modified sponge for efficient solar steam generation. ChemSusChem, 2019, 12(2): 426–433
Bae K, Kang G, Cho S K, et al. Flexible thin-film black gold membranes with ultrabroadband plasmonic nanofocusing for efficient solar vapour generation. Nature Communications, 2015, 6(1): 10103
Zhu M, Li Y, Chen F, et al. Plasmonic wood for high-efficiency solar steam generation. Advanced Energy Materials, 2018, 8(4): 1701028
He S, Zhang F, Cheng S, et al. Synthesis of sodium acrylate and acrylamide copolymer/GO hydrogels and their effective adsorption for Pb2+ and Cd2+. ACS Sustainable Chemistry & Engineering, 2016, 4(7): 3948–3959
Mu P, Zhang Z, Bai W, et al. Superwetting monolithic hollow-carbon-nanotubes aerogels with hierarchically nanoporous structure for efficient solar steam generation. Advanced Energy Materials, 2019, 9(1): 1802158
Yang Y, Zhao R, Zhang T, et al. Graphene-based standalone solar energy converter for water desalination and purification. ACS Nano, 2018, 12(1): 829–835
Inose T, Oikawa T, Shibuya K, et al. Fabrication of silica-coated gold nanorods and investigation of their property of photothermal conversion. Biochemical and Biophysical Research Communications, 2017, 484(2): 318–322
Liu X, Hou B, Wang G, et al. Black titania/graphene oxide nanocomposite films with excellent photothermal property for solar steam generation. Journal of Materials Research, 2018, 33 (6): 674–684
Battista L, Mecozzi L, Coppola S, et al. Graphene and carbon black nano-composite polymer absorbers for a pyro-electric solar energy harvesting device based on LiNbO3 crystals. Applied Energy, 2014, 136: 357–362
Reina A, Jia X, Ho J, et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Letters, 2009, 9(1): 30–35
Hu X, Xu W, Zhou L, et al. Tailoring graphene oxide-based aerogels for efficient solar steam generation under one sun. Advanced Materials, 2017, 29(5): 1604031
Yang J, Pang Y, Huang W, et al. Functionalized graphene enables highly efficient solar thermal steam generation. ACS Nano, 2017, 11(6): 5510–5518
Wang Y, Wang C, Song X, et al. A facile nanocomposite strategy to fabricate a rGO-MWCNT photothermal layer for efficient water evaporation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(3): 963–971
Ito Y, Tanabe Y, Han J, et al. Multifunctional porous graphene for high-efficiency steam generation by heat localization. Advanced Materials, 2015, 27(29): 4302–4307
Jia J, Liang W, Sun H, et al. Fabrication of bilayered attapulgite for solar steam generation with high conversion efficiency. Chemical Engineering Journal, 2019, 361: 999–1006
Li X, Xu W, Tang M, et al. Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path. Proceedings of the National Academy of Sciences of the United States of America, 2016, 113(49): 13953–13958
Peresin M S, Habibi Y, Zoppe J O, et al. Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: Manufacture and characterization. Biomacromolecules, 2010, 11(3): 674–681
Truong Y B, Choi J, Mardel J, et al. Functional cross-linked electrospun polyvinyl alcohol membranes and their potential applications. Macromolecular Materials and Engineering, 2017, 302(8): 1700024
Choi Y H, Lee S S, Lee D M, et al. Composite microgels created by complexation between polyvinyl alcohol and graphene oxide in compressed double-emulsion drops. Small, 2020, 16(9): 1903812
Jin Y, Chang J, Shi Y, et al. A highly flexible and washable nonwoven photothermal cloth for efficient and practical solar steam generation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(17): 7942–7949
Chang C, Tao P, Fu B, et al. Three-dimensional porous solar-driven interfacial evaporator for high-efficiency steam generation under low solar flux. ACS Omega, 2019, 4(2): 3546–3555
Liu Y, Chen J, Guo D, et al. Floatable, self-cleaning, and carbon-black-based superhydrophobic gauze for the solar evaporation enhancement at the air-water interface. ACS Applied Materials & Interfaces, 2015, 7(24): 13645–13652
Chen Q, Pei Z, Xu Y, et al. A durable monolithic polymer foam for efficient solar steam generation. Chemical Science, 2018, 9(3): 623–628
Ghasemi H, Ni G, Marconnet A M, et al. Solar steam generation by heat localization. Nature Communications, 2014, 5(1): 4449
Deng Z, Liu P F, Zhou J, et al. A novel ink-stained paper for solar heavy metal treatment and desalination. Solar RRL, 2018, 2(10): 1800073
Liu P F, Miao L, Deng Z, et al. A mimetic transpiration system for record high conversion efficiency in solar steam generator under one-sun. Materials Today Energy, 2018, 8: 166–173
Zhou J, Gu Y, Deng Z, et al. The dispersion of Au nanorods decorated on graphene oxide nanosheets for solar steam generation. Sustainable Materials and Technologies, 2019, 19: e00090
Li H, Ding X, Han B H. Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability. Chemistry, 2016, 22(33): 11863–11868
Acknowledgements
The authors gratefully acknowledge the support from the Scientific Research Staring Foundation of Hainan University (No. KYQD(ZR)20042), the Young Talents’ Science and Technology Innovation Project of Hainan Association for Science and Technology (No. QCXM202027), and the Hainan Provincial Natural Science Foundation of China (No. 520QN228).
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Li, C., Gao, Z. & Liu, Z. Preparation and properties of substrate PVA-GO composite membrane for solar photothermal conversion. Front. Mater. Sci. 15, 632–642 (2021). https://doi.org/10.1007/s11706-021-0578-0
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DOI: https://doi.org/10.1007/s11706-021-0578-0