Abstract
Diamond-like carbon (DLC) films with various nitrogen content were deposited on TC4 titanium (Ti) alloys using a plasma-enhanced chemical vapor deposition (PECVD) technology. The microstructure and mechanical properties of undoped DLC and nitrogen-doped DLC (DLC-N) film were investigated systematically. In addition, the effects of the doped content of nitrogen on the electrochemical behavior and tribocorrosion properties of the DLC-N film in Hanks’ solution were evaluated in detail. The results showed that the doped nitrogen into the carbon network induced the formation of new sp2 sites, which was conducive to the graphitization in the doped DLC film. The doped content of nitrogen greatly affected the mechanical properties of the DLC-N film. The adhesion strength between the DLC-N film and Ti alloy substrate increased with the increase of the doped nitrogen in the film. Unexpectedly, the electrochemical properties of the DLC film became worse as the nitrogen was doped into the film, because of graphitization improving the electron migration speed in the DLC-N film. Interestingly, the tribocorrosion resistance of the doped DLC film was greatly improved as compared to the undoped DLC film. The higher adhesion strength of the DLC-N film resulted in fewer microcracks produced on the film during the tribocorrosion process in Hanks’ solution, which prevented the ionic solution from penetrating through the film and effectively protected the substrate.
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Z. Zhao, G. Wang, H. Hou, B. Han, Y. Zhang, and N. Zhang, Influence of High-Energy Pulse Current on the Mechanical Properties and Microstructures of Ti-6Al-4V Alloy, J. Mater. Eng. Perform., 2017, 26(10), p 5146–5153.
G. Li, S.G. Qu, Y.X. Pan, X.Q. Li, and F.J. Sun, Influence of Oxidation Temperature and Exposure Time on Surface and Tribological Properties of Ti-6Al-4V Alloy After Surface Rolling, J. Mater. Eng. Perform., 2017, 26(7), p 3489–3499.
Y. Zhao, S.M. Wong, H.M. Wong, S. Wu, T. Hu, K.W.K. Yeung, and P.K. Chu, Effects of Carbon and Nitrogen Plasma Immersion Ion Implantation on in vitro and in vivo Biocompatibility of Titanium Alloy, ACS Appl. Mater. Interfaces., 2013, 5(4), p 1510–1516.
S. Tamilselvi, V. Raman, and N. Rajendran, Evaluation of Corrosion Behavior Of Surface Modified Ti–6Al–4V ELI Alloy in Hanks Solution, J. Appl. Electrochem., 2009, 40(2), p 285–293.
Z.-Y. Zhou, X.-B. Liu, S.-G. Zhuang, X.-H. Yang, M. Wang, and C.-F. Sun, Preparation and High Temperature Tribological Properties of Laser in-situ Synthesized Self-Lubricating Composite Coatings Containing Metal Sulfides on Ti6Al4V Alloy, Appl. Surf. Sci., 2019, 481, p 209–218.
G.D. Revankar, R. Shetty, S.S. Rao, and V.N. Gaitonde, Wear Resistance Enhancement of Titanium Alloy (Ti-6A1-4V) by Ball Burnishing Process, J. Mater. Res. Technol., 2017, 6(1), p 13–32.
J. Komotori, N. Hisamori, and Y. Ohmori, The Corrosion/Wear Mechanisms of Ti-6Al-4V Alloy for Different Scratching Rates, Wear, 2007, 263, p 412–418.
S. Saleem, R. Ahmad, R. Ayub, U. Ikhlaq, W. Jin, and P.K. Chu, Investigation of Nano-Structured Zirconium Oxide Film on Ti6Al4V Substrate to Improve Tribological Properties Prepared by PIII&D, Appl. Surf. Sci., 2017, 394, p 586–597.
L. Cao, Y. Wan, S. Yang, and J. Pu, The Tribocorrosion and Corrosion Properties of Thermally Oxidized Ti6Al4V Alloy in 0.9 wt.% NaCl Physiological Saline, Coatings, 2018, 8(8), p 285.
G. Zhou, H. Ding, Y. Zhang, A. Liu, Y. Lin, and Y. Zhu, Fretting Wear Study on Micro-Arc Oxidation TiO2 Coating on TC4 Titanium Alloys in Simulated Body Fluid, Tribol. Lett., 2010, 40(3), p 319–326.
T.M. Manhabosco, S.M. Tamborim, C.B. dos Santos, and I.L. Mueller, Tribological, Electrochemical and Tribo-Electrochemical Characterization of Bare and Nitrided Ti6Al4V in Simulated Body Fluid Solution, Corros. Sci., 2011, 53(5), p 1786–1793.
I.M. Pohrelyuk, V.M. Fedirko, O.V. Tkachuk, and R.V. Proskurnyak, Corrosion Resistance of Ti-6Al-4V Alloy with Nitride Coatings in Ringer’s Solution, Corros. Sci., 2013, 66, p 392–398.
I. Caron, R. Gras, T. Ganne, and J.M. De Monicault, Coatings on Ti6Al4V as Palliatives for Fretting Fatigue in Cryogenic Environment, Tribol. Int., 2006, 39(10), p 1045–1051.
F. Ma, J. Li, Z. Zeng, and Y. Gao, Structural, Mechanical and Tribocorrosion Behaviour in Artificial Seawater of CrN/AlN nano-Multilayer Coatings on F690 Steel Substrates, Appl. Surf. Sci., 2018, 428, p 404–414.
D. Li, S. Guruvenket, and J.E. Klemberg-Sapieha, Corrosion and Tribo-Corrosion Enhancement of SS301 and Ti-6Al-4V Substrates by Amorphous Hydrogenated SiN/SiC/a-C Multilayer Coating Architecture, Surf. Coat. Technol., 2011, 206(7), p 1893–1898.
L. Shan, Y. Wang, Y. Zhang, Q. Zhang, and Q. Xue, Tribocorrosion Behaviors of PVD CrN Coated Stainless Steel in Seawater, Wear, 2016, 362, p 97–104.
J. Liu, X. Wang, B.J. Wu, T.F. Zhang, Y.X. Leng, and N. Huang, Tribocorrosion Behavior of DLC-Coated CoCrMo Alloy in Simulated Biological Environment, Vacuum, 2013, 92, p 39–43.
T.F. Zhang, Q.Y. Deng, B. Liu, B.J. Wu, F.J. Jing, Y.X. Leng, and N. Huang, Wear and Corrosion Properties of Diamond-Like Carbon (DLC) Coating on Stainless Steel, CoCrMo and Ti6Al4V Substrates, Surf. Coat. Technol., 2015, 273, p 12–19.
L. Fengji, Z. Sam, K. Junhua, Z. Yujuan, and Z. Wali, Multilayer DLC Coatings via Alternating Bias during Magnetron Sputteringo, Thin Solid Films, 2011, 519(15), p 4910–4916.
A. Escudeiro, N.M. Figueiredo, T. Polcar, and A. Cavaleiro, Structural and Mechanical Properties of Nanocrystalline Zr co-Sputtered a-C(:H) Amorphous Films, Appl. Surf. Sci., 2015, 325, p 64–72.
K.A.M. Aboua, N. Umehara, H. Kousaka, X. Deng, H.A. Tasdemir, Y. Mabuchi, T. Higuchi, and M. Kawaguchi, Effect of Carbon Diffusion on Friction and WEAR properties of Diamond-Like Carbon in Boundary Base Oil Lubrication, Tribol. Int., 2017, 113, p 389–398.
W. Yang, Y. Gao, P. Guo, D. Xu, L. Hu, and A. Wang, Adhesion, Biological Corrosion Resistance and Biotribological Properties of Carbon Films Deposited on MAO Coated Ti Substrates, J. Mech. Behav. Biomed., 2020, 101, 103448.
W.Q. Bai, L.L. Li, Y.J. Xie, D.G. Liu, X.L. Wang, G. Jin, and J.P. Tu, Corrosion and Tribocorrosion Performance of M (M Ta, Ti) Doped Amorphous Carbon Multilayers in Hank’s Solution, Surf. Coat. Technol., 2016, 305, p 11–22.
A.Y. Wang, H.S. Ahn, K.R. Lee, and J.P. Ahn, Unusual stRess Behavior in W-Incorporated Hydrogenated Amorphous Carbon Films, Appl. Phys. Lett., 2005, 86(11), p 111902.
M. Azzi, M. Paquette, J.A. Szpunar, J.E. Klemberg-Sapieha, and L. Martinu, Tribocorrosion Behaviour of DLC-coated 316L Stainless Steel, Wear, 2009, 267(5–8), p 860–866.
F. Su, G. Chen, and J. Sun, Synthesis of Hydrogenated DLC Film by PECVD and its Tribocorrosion Behaviors under the Lubricating Condition of Graphene Oxide Dispersed in Water, Tribol. Int., 2019, 130, p 1–8.
M. Cui, J. Pu, J. Liang, L. Wang, G. Zhang, and Q. Xue, Corrosion and Tribocorrosion Performance of Multilayer Diamond-Like Carbon Film in NaCl Solution, RSC Adv., 2015, 5(127), p 104829–104840.
R. Bayon, A. Igartua, J.J. Gonzalez, and U. Ruiz de Gopegui, Influence of the Carbon Content on the Corrosion and Tribocorrosion Performance of Ti-DLC Coatings for Biomedical Alloys, Tribol. Int., 2015, 88, p 115–125.
S.C. Ray, W.F. Pong, and P. Papakonstantinou, Iron, Nitrogen and Silicon Doped Diamond like Carbon (DLC) Thin Films: A Comparative study, Thin Solid Films, 2016, 610, p 42–47.
L. Cao, J. Liu, Y. Wan, and J. Pu, Corrosion and Tribocorrosion Behavior of W Doped DLC Coating in Artificial Seawater, Diam. Relat. Mater., 2020, 109, 108019.
S. Gayathri, N. Kumar, R. Krishnan, T.R. Ravindran, S. Dash, A.K. Tyagi, and M. Sridharan, Influence of Cr Content on the Micro-Structural and Tribological Properties of PLD Grown Nanocomposite DLC-Cr Thin Films, Mater. Chem. Phys., 2015, 167, p 194–200.
H.G. Kim, S.H. Ahn, J.G. Kim, S.J. Park, and K.R. Lee, Corrosion Performance of Diamond-Like Carbon (DLC)-Coated Ti Alloy in the Simulated Body Fluid Environment, Diam. Relat. Mater., 2005, 14(1), p 35–41.
T. Imai, T. Harigai, T. Tanimoto, R. Isono, Y. Iijima, Y. Suda, H. Takikawa, M. Kamiya, M. Taki, Y. Hasegawa, S. Kaneko, S. Kunitsugu, and M. Ito, Hydrogen-Free Fluorinated DLC Films with High Hardness Prepared by using T-Shape Filtered Arc Deposition System, Vacuum, 2019, 167, p 536–541.
Y.-J. Jang, Y.-J. Kang, K. Kitazume, N. Umehara, and J. Kim, Mechanical and Electrical Properties of Micron-Thick Nitrogen-Doped Tetrahedral Amorphous Carbon Coatings, Diam. Relat. Mater., 2016, 69, p 121–126.
S. Bhattacherjee, H. Niakan, Q. Yang, Y. Hu, and J. Dynes, Enhancement of Adhesion and Corrosion Resistance of Diamond-Like Carbon Thin Films on Ti-6Al-4V Alloy by Nitrogen Doping and Incorporation of Nanodiamond Particles, Surf. Coat. Technol., 2015, 284, p 153–158.
C. Zeng, Q. Chen, M. Xu, S. Deng, Y. Luo, and T. Wu, Enhancement of Mechanical, Tribological and Morphological Properties of Nitrogenated Diamond-Like Carbon Films by Gradient Nitrogen Doping, Diam. Relat. Mater., 2017, 76, p 132–140.
N.W. Khun, E. Liu, and X.T. Zeng, Corrosion Behavior of Nitrogen Doped Diamond-Like Carbon Thin Films in NaCl Solutions, Corros. Sci., 2009, 51(9), p 2158–2164.
O. Sharifahmadian, F. Mahboubi, and S. Yazdani, Comparison Between Corrosion Behaviour of DLC and N-DLC Coatings Deposited by DC-Pulsed PACVD Technique, Diam. Relat. Mater., 2019, 95, p 60–70.
S. Meskinis, A. Ciegis, A. Vasiliauskas, K. Slapikas, R. Gudaitis, I. Yaremchuk, V. Fitio, Y. Bobitski, and S. Tamulevicius, Annealing Effects on Structure and Optical Properties of Diamond-Like Carbon Films Containing Silver, Nanoscale Res. Lett., 2016, 11, p 146.
S.E. Rodil, and S. Muhl, Bonding in Amorphous Carbon Nitride, Diam. Relat. Mater., 2004, 13(4–8), p 1521–1531.
E. Liu, X. Shi, H.S. Tan, L.K. Cheah, Z. Sun, B.K. Tay, and J.R. Shi, The effect of Nitrogen on the Mechanical Properties of Tetrahedral Amorphous Carbon Films Deposited with a Filtered Cathodic Vacuum Arc, Surf. Coat. Technol., 1999, 120, p 601–606.
M. Marton, D. Kovalcik, M. Vojs, E. Zdravecka, M. Varga, L. Michalikova, M. Vesely, R. Redhammer, and P. Pisecny, Electrochemical Corrosion Behavior of Amorphous Carbon Nitride Thin Films, Vacuum, 2012, 86(6), p 696–698.
S. Mahieu, P. Ghekiere, D. Depla, and R. De Gryse, Biaxial Alignment in Sputter Deposited Thin Films, Thin Solid Films, 2006, 515(4), p 1229–1249.
A. Leyland and A. Matthews, On the Significance of the H/E Ratio in Wear Control: A Nanocomposite Coating Approach to Optimised Tribological Behaviour, Wear, 2000, 246(1–2), p 1–11.
J.P. Sullivan, T.A. Friedmann, and A.G. Baca, Stress Relaxation and Thermal Evolution of Film Properties in Amorphous Carbon, J. Electron. Mater., 1997, 26(9), p 1021–1029.
G. Leal, M.A. Fraga, L.A. Rasia, and M. Massi, Impact of High N-2 Flow Ratio on the Chemical and Morphological Characteristics of Sputtered N-DLC Films, Surf. Interface Anal., 2017, 49(2), p 99–106.
C.L. Liu, D.P. Hu, J. Xu, D.Z. Yang, and M. Qi, In vitro Electrochemical Corrosion Behavior of Functionally Graded Diamond-Like Carbon Coatings on Biomedical Nitinol Alloy, Thin Solid Films, 2006, 496(2), p 457–462.
L.X. Liu and E. Liu, Nitrogenated Diamond-Like Carbon Films for Metal Tracing, Surf. Coat. Technol., 2005, 198(1–3), p 189–193.
N.W. Khun and E. Liu, Linear Sweep Anodic Stripping Voltammetry of Heavy Metals from Nitrogen Doped Tetrahedral Amorphous Carbon Thin Films, Electrochim. Acta, 2009, 54(10), p 2890–2898.
Y. Fu, F. Zhou, Q. Wang, M. Zhang, and Z. Zhou, Electrochemical and tribocorrosion Performances of CrMoSiCN Coating on Ti-6Al-4V Titanium Alloy in Artificial Seawater, Corros. Sci., 2020, 165, 108385.
Acknowledgments
The authors are grateful for the financial support from the National Natural Science Foundation of China (52175168) and 173 project (2021-JJ-0175), Guangzhou Basic and Applied Basic Research Foundation (202102080422), and the University Scientific Research Platform Project of Guangdong Province (2020KCXTD043).
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Sun, J., Tang, Y., Xu, X. et al. Synthesis of Nitrogen-Doped Diamond-Like Carbon Films Produced by Plasma-Enhanced Chemical Vapor Deposition and their Tribocorrosion Behavior in Hanks’ Solution. J. of Materi Eng and Perform 31, 8334–8345 (2022). https://doi.org/10.1007/s11665-022-06984-1
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DOI: https://doi.org/10.1007/s11665-022-06984-1