Abstract
Here, pulsed plasma nitriding of AISI-316L austenite stainless steel is conducted in a narrow range of temperature 510-550 °C and simultaneous combination of expanded austenite phase, and homogenous, dense chromium nitride phase is attained in a single processing unit, with relative low-cost equipment and single-step processing. The results show a noteworthy enhancement in nanohardness at 530 °C, whereas best wear resistance is achieved by processing at 550 °C. A dual-layer structure is obtained constituted of expanded austenite phase covered by quite homogenous chromium nitride phase, which is probably responsible for the dramatic surface improvement. The wear mechanism is changed after plasma processing (abrasive to adhesive wear), and the friction coefficient is reduced and smoother, particularly for the sample treated at 530 °C. Interestingly, the corrosion resistance is also found to be enhanced, even in the presence of chromium nitride (which usually deteriorate the corrosion resistance), which is probably credited to the formation of fine-grained and homogeneous CrN layer over the expanded austenite phase. This study suggests that the development of homogenous CrN layer over the expanded austenite structure is highly valuable for mechanical and tribological features, and it enhances the corrosion resistance.
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References
K. Bordjih, J.-Y. Jouzeau, D. Mainard, E. Payan, J.-P. Delagoutte, and P. Netter, Evaluation of the Effect of Three Surface Treatments on the Biocompatibility of 316L Stainless Steel Using Human Differentiated Cells, Biomaterials, 1996, 17(5), p 491–500
N. Mingolo, A.P. Tschiptschin, and C.E. Pinedo, On the Formation of Expanded Austenite during Plasma Nitriding of an AISI, 316L Austenitic Stainless Steel, Surf. Coat. Technol., 2006, 201(7), p 4215–4218
I. Braceras, I. Ibáñez, S. Dominguez-Meister, J.A. Sánchez-García, M. Brizuela, A. Larrañaga, and I. Garmendia, Plasma Nitriding of the Inner Surface of Stainless Steel Tubes, Surf. Coat. Technol., 2018, 355, p 116–122
J. Dobránszky and D. Kovács, Effects of Thermochemical Surface Treatments on the Industrially Important Properties of X2CrNiMo 17-12-2 Austenitic Stainless Steel, Period. Polytech. Mech. Eng., 2019, 63(3), p 214–219
D. Kovács, I. Quintana, and J. Dobránszky, Effects of Different Variants of Plasma Nitriding on the Properties of the Nitrided Layer, J. Mater. Eng. Perform., 2019, 28(9), p 5485–5493
Y. Teng, Y.-Y. Guo, M. Zhang, Y.-J. Yang, Z. Huang, Y.-W. Zhou, F.-Y. Wu, and Y.-S. Liang, Effect of Cr/CrNx Transition Layer on Mechanical Properties of CrN Coatings Deposited on Plasma Nitrided Austenitic Stainless Steel, Surf. Coat. Technol., 2019, 367, p 100–107
R. Jiang, G. Zou, W. Shi, Y. Liang, and S. Xiang, Corrosion Behavior of Plasma-Nitrided 904L Austenitic Stainless Steel in Hydrofluoric Acid, J. Mater. Eng. Perform., 2019, 28(3), p 1863–1872
G. Pintaude, A.C. Rovani, J.C.K. dasNeves, LE Lagoeiro, X. Li, and H.S. Dong, Wear and Corrosion Resistances of Active Screen Plasma-Nitrided Duplex Stainless Steels, J. Mater. Eng. Perform., 2019, 28(6), p 3673–3682
M.S. Libório, G.B. Praxedes, L.L.F. Lima, I.G. Nascimento, R.R.M. Sousa, M. Naeem, T.H. Costa, S.M. Alves, and J. Iqbal, Surface Modification of M2 Steel by Combination of Cathodic Cage Plasma Deposition and Magnetron Sputtered MoS2-TiN Multilayer Coatings, Surf. Coat. Technol., 2020, https://doi.org/10.1016/j.surfcoat.2018.03.024
A.B.V. Leitao, C.L. Lima, B.C. Viana, B. Neto, J.A.P. Costa, T.H.C. Costa, I.A. De Souza, M. Naeem, and R.R.M. Sousa, Novel Synthesis of Molybdenum Nitride/Oxide on AISI-316 Steel Assisted with Active Screen Plasma Treatment, Mater. Res. Express, 2019, 6(11), p 116501
M. Naeem, J. Iqbal, M. Zakaullah, M. Shafiq, Z.I. Mujahid, J.C. Díaz-Guillén, C.M. Lopez-Badillo, R.R.M. Sousa, and M.A. Khan, Enhanced Wear and Corrosion Resistance of AISI-304 Steel by Duplex Cathodic Cage Plasma Treatment, Surf. Coat. Technol., 2019, 375, p 34–45
F. Borgioli, A. Fossati, E. Galvanetto, and T. Bacci, Glow-Discharge Nitriding of AISI, 316L Austenitic Stainless Steel: Influence of Treatment Temperature, Surf. Coat. Technol., 2005, 200(7), p 2474–2480
W. Liang, Surface Modification of AISI, 304 Austenitic Stainless Steel by Plasma Nitriding, Appl. Surf. Sci., 2003, 211(1–4), p 308–314
J. Xu, H. Umehara, and I. Kojima, Effect of Deposition Parameters on Composition, Structures, Density and Topography of CrN Films Deposited by rf Magnetron Sputtering, Appl. Surf. Sci., 2002, 201(1–4), p 208–218
G. Bertrand, H. Mahdjoub, and C. Meunier, A Study of the Corrosion Behaviour and Protective Quality of Sputtered Chromium Nitride Coatings, Surf. Coat. Technol., 2000, 126(2–3), p 199–209
C. Lorenzo-Martin, O. Ajayi, A. Erdemir, G.R. Fenske, and R. Wei, Effect of Microstructure and Thickness on the Friction and Wear Behavior of CrN Coatings, Wear, 2013, 302(1–2), p 963–971
A.P. Ehiasarian, P.E. Hovsepian, L. Hultman, and U. Helmersson, Comparison of Microstructure and Mechanical Properties of Chromium Nitride-Based Coatings Deposited by High Power Impulse Magnetron Sputtering and by the Combined Steered Cathodic Arc/Unbalanced Magnetron Technique, Thin Solid Films, 2004, 457(2), p 270–277
J. Lin, J.J. Moore, W.D. Sproul, B. Mishra, Z. Wu, and J. Wang, The Structure and Properties of Chromium Nitride Coatings Deposited Using dc, Pulsed dc and Modulated Pulse Power Magnetron Sputtering, Surf. Coat. Technol., 2010, 204(14), p 2230–2239
M.R. Menezes, C. Godoy, V.T.L. Buono, M.M.M. Schvartzman, and J.C.A.-B. Wilson, Effect of Shot Peening and Treatment Temperature on Wear and Corrosion Resistance of Sequentially Plasma Treated AISI, 316L steel, Surf. Coat. Technol., 2017, 309, p 651–662
T. Wierzchoń, I. Ulbin-Pokorska, and K. Sikorski, Corrosion Resistance of Chromium Nitride and Oxynitride Layers Produced under Glow Discharge Conditions, Surf. Coat. Technol., 2000, 130(2–3), p 274–279
J. Díaz-Guillén, A. Campa-Castilla, S. Pérez-Aguilar, E. Granda-Gutiérrez, A. Garza-Gómez, J. Candelas-Ramírez, and R. Méndez-Méndez, Effect of Duty Cycle on Surface Properties of AISI, 4340 Using a Pulsed Plasma Nitriding Process, Superficies y vacío, 2009, 22(1), p 1–4
M. Naeem, M. Shafiq, M. Zaka-ul-Islam, M.I. Bashir, J.C. Díaz-Guillén, C.M. Lopez-Badillo, and M. Zakaullah, Novel Duplex Cathodic Cage Plasma Nitriding of Non-alloyed Steel Using Aluminum and Austenite Steel Cathodic Cages, J. Alloys Compd., 2017, 721, p 307–311
S. Adachi and N. Ueda, Wear and Corrosion Properties of Cold-Sprayed AISI, 316L Coatings Treated by Combined Plasma Carburizing and Nitriding at Low Temperature, Coatings, 2018, 8(12), p 456
F.A.P. Fernandes, S.C. Heck, R.G. Pereira, A. Lombardi-Neto, G.E. Totten, and L.C. Casteletti, Wear of Plasma Nitrided and Nitrocarburized AISI, 316L Austenitic Stainless Steel, J. Achiev. Mater. Manuf. Eng., 2010, 40(2), p 175–179
R.G. Kelly, J.R. Scully, D. Shoesmith, and R.G. Buchheit, Electrochemical Techniques in Corrosion Science and Engineering, CRC Press, Boca Raton, 2002
M. Naeem, H.A. Raza, M. Shafiq, M. Zaka-ul-Islam, J. Iqbal, J.C. Díaz-Guilléne, and M. Zakaullah, Effect of Pulsed Duty Cycle Control on Tribological and Corrosion Properties of AISI-316 in Cathodic Cage Plasma Nitriding, Mater. Res. Express, 2017, 4, p 116507
A. Fossati, F. Borgioli, E. Galvanetto, and T. Bacci, Glow-Discharge Nitriding of AISI, 316L Austenitic Stainless Steel: Influence of Treatment Time, Surf. Coat. Technol., 2006, 200(11), p 3511–3517
K. Marchev, C.V. Cooper, J.T. Blucher, and B.C. Giessen, Conditions for the Formation of a Martensitic Single-Phase Compound Layer in Ion-Nitrided 316L Austenitic Stainless Steel, Surf. Coat. Technol., 1998, 99(3), p 225–228
Y. Li, Z. Wang, and L. Wang, Surface Properties of Nitrided Layer on AISI, 316L Austenitic Stainless Steel Produced by High Temperature Plasma Nitriding in Short Time, Appl. Surf. Sci., 2014, 298, p 243–250
E. Menthe and K.T. Rie, Further Investigation of the Structure and Properties of Austenitic Stainless Steel After Plasma Nitriding, Surf. Coat. Technol., 1999, 116–119, p 199–204
J.C. Díaz-Guillén, M. Alvarez-Vera, J.A. Díaz-Guillén, J.L. Acevedo-Davila, M. Naeem, H.M. Hdz-García, E.E. Granda-Gutiérrez, and R. Muñoz-Arroyo, A Hybrid Plasma Treatment of H13 Tool Steel by Combining Plasma Nitriding and Post-Oxidation, J. Mater. Eng. Perform., 2018, 27, p 6118
Y. Li, H. Xu, F. Zhu, and L. Wang, Low Temperature Anodic Nitriding of AISI, 304 Austenitic Stainless Steel, Mater. Lett., 2014, 128, p 231–234
O. Öztürk, S. Okur, and J.P. Riviere, Structural and Magnetic Characterization of Plasma Ion Nitrided Layer on 316L Stainless Steel Alloy, Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. Atoms, 2009, 267(8–9), p 1540–1545
A. Turk and C. Bindal, Characterization of Plasma Nitrided X32CrMoV33 Die Steel, Mater. Manuf. Process., 2009, 24(7–8), p 898–902
M.H. Sohi, M. Ebrahimi, A.H. Raouf, and F. Mahboubi, Effect of Plasma Nitrocarburizing Temperature on the Wear Behavior of AISI, 4140 Steel, Surf. Coat. Technol., 2010, 205, p S84–S89
S. Ahangarani, F. Mahboubi, and A. Sabour, Effects of Various Nitriding Parameters on Active Screen Plasma Nitriding Behavior of a Low-Alloy Steel, Vacuum, 2006, 80(9), p 1032–1037
E. Zdravecká, J. Slota, P. Solfronk, and M. Kolnerová, Evaluation of the Effect of Different Plasma-Nitriding Parameters on the Properties of Low-Alloy Steel, J. Mater. Eng. Perform., 2017, 26(7), p 3588–3596
F. Borgioli, A. Fossati, E. Galvanetto, T. Bacci, and G. Pradelli, Glow Discharge Nitriding of AISI, 316L Austenitic Stainless Steel: Influence of Treatment Pressure, Surf. Coat. Technol., 2006, 200(18–19), p 5505–5513
M.A. Fontes, R.G. Pereira, F.A.P. Fernandes, L.C. Casteletti, and P.A. dePaulaNascente, Characterization of Plasma Nitrided Layers Produced on Sintered Iron, J. Mater. Res. Technol., 2014, 3(3), p 210–216
T. Suzuki and I. Mutoh, Effects of Nitrogen on Corrosion of Stainless Steels in a Liquid Sodium Environment, J. Nucl. Mater., 1990, 171(2–3), p 253–261
F. Haftlang, A. Habibolahzadeh, and M.H. Sohi, Duplex Treatment of AISI, 1045 Steel by Plasma Nitriding and Aluminizing, Vacuum, 2014, 107, p 155–158
V. Kvedaras and A. Ciuplys, Influence of Nitriding Temperature on Surface Structural Characteristics and Fatigue Strength of Steel, Mechanika, 2015, 21(5), p 372 ((in English))
A.P. Tschiptschin, A.S. Nishikawa, L.B. Varela, and C.E. Pinedo, Thermal Stability of Expanded Austenite Formed on a DC Plasma Nitrided 316L Austenitic Stainless Steel, Thin Solid Films, 2017, 644, p 156–165
X. Zhang, X.B. Tian, Z.W. Zhao, J.B. Gao, Y.W. Zhou, P. Gao, Y.Y. Guo, and Z. Lv, Evaluation of the Adhesion and Failure Mechanism of the Hard CrN Coatings on Different Substrates, Surf. Coat. Technol., 2019, 364, p 135–143
K.L. Dahm and P.A. Dearnley, On the Nature, Properties and Wear Response of s-Phase (Nitrogen-Alloyed Stainless Steel) Coatings on AISI, 316L, Proc. Inst. Mech. Eng. Part L J. Mater. Des. Appl., 2000, 214(4), p 181–198
Y.Q. Wu and M.F. Yan, Plasticity Characterization of the Modified Layer Produced by Plasma Nitrocarburizing of Nanocrystallized 18Ni Maraging Steel, Vacuum, 2011, 86(2), p 119–123
L.O.A. Affonso, Machinery Failure Analysis Handbook: Sustain Your Operations and Maximize Uptime, Elsevier, Amsterdam, 2013
D.L. Joslin and W.C. Oliver, A New Method for Analyzing Data from Continuous Depth-Sensing Microindentation Tests, J. Mater. Res., 1990, 5(1), p 123–126
T.Y. Tsui, G.M. Pharr, W.C. Oliver, C.S. Bhatia, R.L. White, S. Anders, A. Anders, and I.G. Brown, Nanoindentation and Nanoscratching of Hard Carbon Coatings for Magnetic Disks, MRS Online Proc. Libr. Arch., 1995, 383, p 447–452
B.D. Beake, G.A. Bell, S.R. Goodes, N.J. Pickford, and J.F. Smith, Improved Nanomechanical test Techniques for Surface Engineered Materials, Surf. Eng., 2010, 26(1–2), p 37–49
F.D.S. Severo, C.J. Scheuer, R.P. Cardoso, and S.F. Brunatto, Cavitation Erosion Resistance Enhancement of Martensitic Stainless Steel via Low-Temperature Plasma Carburizing, Wear, 2019, 428, p 162–166
M.L. Oyen and R.F. Cook, A Practical Guide for Analysis of Nanoindentation Data, J. Mech. Behav. Biomed. Mater., 2009, 2(4), p 396–407
S.Y. Sirin and E. Kaluc, Structural Surface Characterization of Ion Nitrided AISI, 4340 steel, Mater. Des., 2012, 1980–2015(36), p 741–747
Y. Li, Y. He, J. Xiu, W. Wang, Y. Zhu, and B. Hu, Wear and Corrosion Properties of AISI, 420 Martensitic Stainless Steel Treated by Active Screen Plasma Nitriding, Surf. Coat. Technol., 2017, 329, p 184–192
W.J. Yang, M. Zhang, Y.H. Zhao, M.L. Shen, H. Lei, L. Xu, J.Q. Xiao, J. Gong, B.H. Yu, and C. Sun, Enhancement of Mechanical Property and Corrosion Resistance of 316 L Stainless Steels by Low Temperature Arc Plasma Nitriding, Surf. Coat. Technol., 2016, 298, p 64–72
L.M. Ferreira, S.F. Brunatto, and R.P. Cardoso, Martensitic Stainless Steels Low-Temperature Nitriding: Dependence of Substrate Composition, Mater. Res., 2015, 18(3), p 622–627
M.D.C.R.L. Cesconetto, A.R. Franco, and E.A. Vieira, Improving the Abrasive Wear Resistance of a Microalloyed Steel by Plasma Nitriding, Mater. Res., 2015, 18(2), p 334–340
F. Zhang and M. Yan, Microstructure and Wear Resistance of In Situ Formed Duplex Coating Fabricated by Plasma Nitriding Ti Coated 2024 Al Alloy, J. Mater. Sci. Technol., 2014, 30(12), p 1278–1283
D. She, W. Yue, Z. Fu, C. Wang, X. Yang, and J. Liu, Effects of Nitriding Temperature on Microstructures and Vacuum Tribological Properties of Plasma-Nitrided Titanium, Surf. Coat. Technol., 2015, 264, p 32–40
H. Dogan, F. Findik, and A. Oztarhan, Comparative Study of Wear Mechanism of Surface Treated AISI, 316L Stainless Steel, Ind. Lubr. Tribol., 2003, 55(2), p 76–83
G.B. Both, A.S. Rocha, G.R. Santos, and T.K. Hirsch, An Investigation on the Suitability of Different Surface Treatments Applied to a DIN X100CrMoV8-1-1 for Cold Forming Applications, Surf. Coat. Technol., 2014, 244, p 142–150
J. Halambek, M.C. Bubalo, I.R. Redovniković, and K. Berković, Corrosion Behaviour Of Aluminium and AA5754 Alloy in 1% Acetic Acid Solution in Presence of Laurel Oil, Int. J. Electrochem. Sci., 2014, 9(10), p 5496–5506
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This work was financially supported by CONACYT México under grant number CB2015 257705.
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Díaz-Guillén, J.C., Naeem, M., Acevedo-Dávila, J.L. et al. Improved Mechanical Properties, Wear and Corrosion Resistance of 316L Steel by Homogeneous Chromium Nitride Layer Synthesis Using Plasma Nitriding. J. of Materi Eng and Perform 29, 877–889 (2020). https://doi.org/10.1007/s11665-020-04653-9
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DOI: https://doi.org/10.1007/s11665-020-04653-9