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Study of Eco-Friendly Organic–Inorganic Heterostructure CH3NH3SnI3 Perovskite Solar Cell via SCAPS Simulation

  • Topical Collection: International Conference on Organic Electronics 2022
  • Published:
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Abstract

Lead-based organic–inorganic perovskite (OIP) materials have shown great possibilities as absorber materials in photovoltaic devices. Despite its better power conversion efficiency (PCE), the toxicity of lead limits its application in photovoltaic organic solar cells. This limitation has encouraged researchers to find an alternative lead-free organic perovskite material that must be eco-friendly. Therefore, in this present research work, we have proposed a lead-free OIP heterostructure solar cell using CH3NH3SnI3 as the absorber layer, Cu2O as the hole transport layer (HTL), TiO2 as the electron transport layer (ETL), and FTO as a transparent conducting oxide (TCO) layer. Further, we have carried out a simulation study using SCAPS software to obtain a good performance of the proposed cell by optimizing various parameters. Thus, the obtained simulated results show that a moderate temperature of 305 K is necessary to achieve better cell efficiency. A significant decrease in efficiency is observed upon increasing the operating device temperature. Further, Gaussian energy distribution in the absorber OIP layer, CH3NH3SnI3 , shows better possibilities for obtaining a good performance from the proposed cell. On varying the Gaussian peak defect density from 1 × 1016 cm−3 to 6 × 1020 cm−3, the best-simulated result is offered at a concentration of 1.079 × 1016 cm−3. In addition, on varying the electron affinity of the active layer, we obtained the best result in its class at a value of 4.13 eV. Further, on energy band gap optimization of the active layer, we observed the maximum open-circuit voltage of 1.5 eV. Finally, all the performance parameters for the proposed OIP cell were found to be: PCE 18.27%, short-circuit current density 32.47 mA/cm2, open-circuit voltage 0.7397 V, and FF 76.06%. Thus, we can proudly say that the present analysis may open a modern doorway for attaining clean energy.

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References

  1. K.K. Markose, M. Shaji, S. Bhatia, P.R. Nair, K.J. Saji, A. Antony, and M.K. Jayaraj, Novel boron-doped p-type Cu2O thin films as a hole-selective contact in c-Si solar cells. Appl. Mater. Interfaces 12, 12972–12981 (2020).

    Article  CAS  Google Scholar 

  2. Y. Li, M.D. Cole, Y. Gao, T. Emrick, Z. Xu, Y. Liu, and T.P. Russell, High-performance perovskite solar cells with a non-doped small molecule hole transporting layer. Appl. Energy Mater. 2, 1634–1641 (2019).

    Article  CAS  Google Scholar 

  3. H.H. Huang, Y.C. Shih, L. Wang, and K.F. Lin, Boosting the ultra-stable unencapsulated perovskite solar cells by using montmorillonite/CH3NH3PbI3 nanocomposite as a photoactive layer. Energy Environ. Sci. 12, 1265–1273 (2019).

    Article  Google Scholar 

  4. W.S. Yang, B.W. Park, E.H. Jung, N.J. Jeon, Y.C. Kim, D.U. Lee, S.S. Shin, J. Seo, E.K. Kim, J.H. Noh, and S.I. Seok, Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells. Science 356, 1376–1379 (2017).

    Article  CAS  Google Scholar 

  5. Y.C. Shih, Y.B. Lan, C.S. Li, H.C. Hsieh, L. Wang, C. Wu, and K.F. Lin, Amino-acid-induced preferential orientation of perovskite crystals for enhancing interfacial charge transfer and photovoltaic performance. Small 13, 1604305–1604314 (2017).

    Article  Google Scholar 

  6. H.S. Kim, S.H. Im, and N.G. Park, Organolead halide perovskite: new horizons in solar cell research. J. Phys. Chem. C 118, 5615–5625 (2014).

    Article  CAS  Google Scholar 

  7. F. Gao, C. Li, L. Qin, L. Zhu, X. Huang, H. Liu, L. Liang, Y. Hou, Z. Lou, Y. Hu, and F. Teng, Enhanced performance of tin halide perovskite solar cell by addition of lead thiocyanate. RSC Adv. 8, 14025–14030 (2018).

    Article  CAS  Google Scholar 

  8. M. Lyu, J.H. Yun, P. Chen, M. Hao, and L. Wang, Addressing toxicity of lead: progress and applications of low-toxic metal halide perovskites and their derivatives. Adv. Energy Mater. 7, 1602512–1602537 (2017).

    Article  Google Scholar 

  9. L. Lanying, N. Chengsheng, M. Cassidya, and J.T.S. Irvine, Demonstration of high performance in a perovskite oxide supported solid oxide fuel cell based on La and Ca co-doped SrTiO3. Mater. Chem. A 4, 11708–11718 (2016).

    Article  Google Scholar 

  10. H. Kleineberg, M. Eisenacher, H. Lange, H. Strutz, and R. Palkovits, Perovskites and metal nitrides as catalysts in the base-catalyzed aldol addition of isobutyraldehyde to formaldehyde. Catal. Sci. Technol. 6, 6057–6065 (2016).

    Article  CAS  Google Scholar 

  11. S.D. Stranks, G.E. Eperon, G. Grancini, C. Menelaou, M.J.P. Alcocer, T. Leijtens, L.M. Herz, A. Petrozza, and H.J. Snaith, Electron–hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342, 341–344 (2013).

    Article  CAS  Google Scholar 

  12. A.K. Sharma, N.K. Chourasia, and R.K. Chourasia, Optical, temperature, and bulk analysis theoretically in p-Si/n-CdS heterojunction solar cell. Mater. Today: Proc. 67, 632–636 (2022).

    Google Scholar 

  13. P.K. Jha, N.K. Chourasia, A.K. Sharma, and R.K. Chourasia, Optimization of electrical properties for performance analysis of p-Si/n-CdS/ITO heterojunction photovoltaic cell. Mater. Today: Proc. 67, 620–624 (2022).

    CAS  Google Scholar 

  14. M. Weiss, J. Horn, C. Richter, and D. Schlettwein, Preparation and characterization of methylammonium tin iodide layers as photovoltaic absorbers. Phys. Status Solidi A 213, 975–981 (2016).

    Article  CAS  Google Scholar 

  15. N.K. Noel, S.D. Stranks, A. Abate, C. Wehrenfennig, S. Guarnera, A.A. Haghighirad, A. Sadhanala, G.E. Eperon, S.K. Pathak, M.B. Johnston, A. Petrozza, L.M. Herza, and H.J. Snaith, Lead-free organic–inorganic tin halide perovskites for photovoltaic applications. Energy Environ. Sci. 7, 3061–3068 (2014).

    Article  CAS  Google Scholar 

  16. M. Kumar, A. Raj, A. Kumar, and A. Anshul, An optimized lead-free formamidinium Sn-based perovskite solar cell design for high power conversion efficiency by SCAPS simulation. Opt. Mater. 108, 110213 (2020).

    Article  CAS  Google Scholar 

  17. M. Kumar, A. Raj, A. Kumar, and A. Anshul, Computational analysis of bandgap tuning, admittance and impedance spectroscopy measurements in lead-free MASnI3 perovskite solar cell device. Int. J. Energy Res. 46(8), 1–14 (2022). https://doi.org/10.1002/er.7942.

    Article  CAS  Google Scholar 

  18. Y. Guo, Y. Xue, X. Li, C. Li, H. Song, Y. Niu, H. Liu, X. Mai, J. Zhang, and Z. Guo, Effects of transition metal substituents on the interfacial and electronic structure of CH3NH3PbI3/TiO2 interface: a firstprinciples comparative study. Nanomaterials 9, 966–979 (2019).

    Article  CAS  Google Scholar 

  19. H.Y. Yang, W.Y. Rho, S.K. Lee, S.H. Kim, and Y.B. Hahn, TiO2 nanoparticles/nanotubes for efficient light harvesting in perovskite solar cells. Nanomaterials 9, 326–335 (2019).

    Article  CAS  Google Scholar 

  20. L. Lin, L. Jiang, P. Li, B. Fan, and Y. Qiu, A modelled perovskite solar cell structure with a Cu2O hole- transporting layer enabling over 20% efficiency by low-cost low-temperature processing. J. Phys. Chem. Solids 14, 205–211 (2019).

    Article  Google Scholar 

  21. S. Abdelaziz, A. Zekry, A. Shaker, and M. Abouelatta, Investigating the performance of formamidinium tin-based perovskite solar cell by SCAPS device simulation. Opt. Mater. 101, 109738 (2020).

    Article  CAS  Google Scholar 

  22. Y.H. Khattak, F. Baig, S. Ullah, B. Marí, S. Beg, and K. Khan, Effect of Cu2O hole transport layer and improved minority carrier lifetime on the efficiency enhancement of Cu2NiSnS4 based experimental solar cell. J. Renew. Sustain. Energy 10, 043502 (2018). https://doi.org/10.1063/1.5037471.

    Article  CAS  Google Scholar 

  23. W. Yu, F. Li, H. Wang, E. Alarousu, Y. Chen, B. Lin, L. Wang, M.N. Hedhili, Y. Li, K. Wu, X.W. Omar, F. Mohammedc, and T. Wu, Ultrathin Cu2O as an efficient inorganic hole transporting material for perovskite solar cells. Nanoscale 8(11), 6173–6179 (2016).

    Article  CAS  Google Scholar 

  24. Q. Qiu, S. Li, J. Jiang, D. Wang, Y. Lin, and T. Xie, Improved electron transfer between TiO2 and FTO interface by N-doped anatase TiO2 nanowires and its applications in quantum dot-sensitized solar cells. J. Phys. Chem. C 121(39), 21560–21570 (2017).

    Article  CAS  Google Scholar 

  25. H.J. Du, W.C. Wang, and J.Z. Zhu, Device simulation of lead-free CH3NH3SnI3 perovskite solar cells with high efficiency. Chin. Phys. B 25, 108802–188809 (2016).

    Article  Google Scholar 

  26. S.M. Sze, Physics of Semiconductor Devices (NewYork: John Wiley and Sons, 1981), p.264.

    Google Scholar 

  27. M.A. Green, Solar Cells (Englewood Cliffs, NJ: Prentice-Hall, 1982), p.88.

    Google Scholar 

Download references

Acknowledgments

The authors wish to acknowledge Dr. Marc Burgelman, University of Gent, Belgium, for the SCAPS-1D simulation software.

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    Authors and Affiliations

    1. University Department of Physics, Lalit Narayan Mithila University, Darbhanga, 846004, India

      Prakash Kumar Jha, Atish Kumar Sharma & Rakesh Kumar

    2. Post-Graduate Department of Physics, Samastipur College (A constituent college of L.N.M.U., Darbhanga-846004, Bihar, India), Samastipur, Bihar, 848134, India

      Prakash Kumar Jha, Ankita Srivastava, Atish Kumar Sharma, Rakesh Kumar & Ritesh Kumar Chourasia

    3. School of Physical Sciences, Jawaharlal Nehru University, New Delhi, 110067, India

      Nitesh K. Chourasia

    4. Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi, New Delhi, 110021, India

      Manish Kumar

    5. CONACyT – Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Km 107 Carretera Tijuana-Ensenada AP 14, 22860, Ensenada, BC, Mexico

      Subhash Sharma

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    Contributions

    PKJ: Writing—original draft, Formal analysis; NKC: Writing—original draft, Formal analysis; AS: Writing—original draft, Formal analysis; AKS: Formal analysis; RK: Formal analysis; SS: Formal analysis; MK: Review original draft, Formal analysis; RKC: Visualization, Supervision, Writing—original draft, Formal analysis.

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    Correspondence to Manish Kumar or Ritesh Kumar Chourasia.

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    Prakash Kumar Jha and Nitesh K. Chourasia contributed equally to this work.

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    Jha, P.K., Chourasia, N.K., Srivastava, A. et al. Study of Eco-Friendly Organic–Inorganic Heterostructure CH3NH3SnI3 Perovskite Solar Cell via SCAPS Simulation. J. Electron. Mater. 52, 4321–4329 (2023). https://doi.org/10.1007/s11664-023-10267-3

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