Abstract
Magnesium oxide (MgO)-supported nanocatalysts are a highly insulating crystalline solid with a sodium chloride crystal structure and excellent properties including chemical inertness, high temperature stability and high thermal conductivity. Here, a ternary alloy catalyst of MgO-supported CoMoB was synthesized by means of a chemical reduction method using ethylene glycol solution. The prepared CoMoB/MgO catalysts were characterized using x-ray diffraction, scanning electron microscopy (SEM/EDX) and Fourier transform infrared spectroscopic analysis. The CoMoB/MgO nanocomposite served as the enabling platform for a range of applications including hydrogen production catalyst and hydrogen peroxide (H2O2) determination. It also showed a high hydrogen production rate (1000 mLg −1cat min−1) and low activation energy (68.319 kJ mol−1) for the hydrolysis of ammonia borane. Additionally, the electro-oxidation performance of the CoMoB/MgO for H2O2 detection was studied by cyclic voltammetry and chronoamperometry. The CoMoB/MgO sensor demonstrated a wide linear range up to 10 mM with a detection limit of 3.3 μM.
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Çelik Kazici, H., Salman, F., İzgi, M.S. et al. Synthesis of Metal-Oxide-Supported Triple Nano Catalysts and Application to H2 Production and H2O2 Oxidation. J. Electron. Mater. 49, 3634–3644 (2020). https://doi.org/10.1007/s11664-020-08061-6
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DOI: https://doi.org/10.1007/s11664-020-08061-6