Skip to main content
SpringerLink
Log in

Synthesis and characterization of the B3-monomer and hyperbranched poly(aryl ether ketone)s

  • Research Article
  • Published:
Frontiers of Chemistry in China

Abstract

Hyperbranched poly(aryl ether ketone)s were prepared by polymerization of hydroquinone (A2) and 1,3,5-tris[4-(4-fluorobenzoyl)phenoxy]benzene (B3). The gelation of hyperbranched poly(aryl ether ketone)s was effectively avoided. Hydroxyl-term inated (HPAEK-OH) and fluoro-terminated (HPAEK-F) hyperbranched poly(aryl ether ketone)s were prepared by using different A2/B3 mass ratio. The structure of the B3 monomer was confirmed by MS, 1H NMR/IR. The glass transition temperatures of the HPAEK-F and HPAEK-OH are 114°C and 162°C respectively. Thermal stability of HPAEK-F is higher than HPAEK-OH.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Voit B. New developments in hyperbranched polymers. J Polym Sci. Part A: Polym Chem 2000;38:2505–2525.

    Article  CAS  Google Scholar 

  2. Kim YH. Hyperbranched polymers 10 years after. J Polym Sci. Polym Chem Ed 1998;36:1685–1689.

    Article  CAS  Google Scholar 

  3. Zou Jian-hua, Lin De, Shi Wen-fang. Influences of multifunctional co-monomers on UV-cure kinetics of hyperbranched acrylated polyamidester and the thermal properties of the cured films. Acta Chim Sinica 2002;60:926–930.

    CAS  Google Scholar 

  4. Miller TM, Neenan TX, Kwock EW, et al. Dendritic analogs of engineering plastics: a general one-step synthesis of dendritic polyaryl ethers. J Am Chem Soc 1993;115:356–357.

    Article  CAS  Google Scholar 

  5. Chu Fengkui, Hawker CJ. A versatile synthesis of isomeric hyperbranched polyetherketones. Polym Bull 1993;30:265–272.

    Article  CAS  Google Scholar 

  6. Hawker CJ, Fengkui Chu. Hyperbranched poly(ether ketones): manipulation of structure and physical properties. Macromolecules 1996;29:4370–4380.

    Article  CAS  Google Scholar 

  7. Shu Chingfong, Leu Chimeng. Hyperbranched poly(ether ketone) with carboxylic acid terminal groups: synthesis, characterization, and derivatization. Macromolecules 1999;32:100–105.

    Article  CAS  Google Scholar 

  8. Shu C-F, Leu C-M, Huang F-Y. Synthesis, modification, and characterization of hyperbranched poly(ether ketones). Polymer 1999;40:6591–6596.

    Article  CAS  Google Scholar 

  9. Baek J-B, Tan L-S. Linear-hyperbranched copolymerization as a tool to modulate thermal properties and crystallinity of a para-poly(ether-ketone). Polymer 2003;44:3451–3459.

    Article  CAS  Google Scholar 

  10. Hao Jianjun, Mitsutoshi Jikei, Masa-aki Kakimoto. Synthesis and comparison of hyperbranched aromatic polyimides having the same repeating unit by AB2 self-polymerization and A2 + B3 polymerization. Macromolecules 2003;36:3519–3528.

    Article  CAS  Google Scholar 

  11. Zhang, Shan-ju, Zheng, Yu-bin, Wu, Zhong-wen. Synthesis of block copolymer poly(aryl ether ketone)-poly(aryl ester). Acta Scientiarum Naturalium Universitatis Jilinensis 1997;2:106–108.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, China

    Mu Jianxin & Chen Jie

  2. College of Chemistry, JilinUniversity, Changchun, 130012, China

    Jiang Zhenhua

  3. College of Materials Science and Engineering, Jilin University, Changchun, 130012, China

    Zhang Chunling & Wang Zou

Authors
  1. Mu Jianxin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhang Chunling
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wang Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chen Jie
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jiang Zhenhua
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Mu Jianxin or Jiang Zhenhua.

Additional information

__________

Translated from Acta Scientianum Naturalium Universitatis Jilinensis, 2005, 5 (in Chinese)

About this article

Cite this article

Mu, J., Zhang, C., Wang, Z. et al. Synthesis and characterization of the B3-monomer and hyperbranched poly(aryl ether ketone)s. Front. Chem. China 1, 203–206 (2006). https://doi.org/10.1007/s11458-006-0015-z

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11458-006-0015-z

Keywords

Search

Navigation