Abstract
An eco-friendly way to improve the engineering properties of lower-strength soils becomes attractive. This study investigates the feasibility of two industrial by-products, i.e., coal gangue (CG) and calcium carbide residue (CCR), as a sustainable CG–CCR geopolymer binder for soil stabilization. The geomechanical properties, compressibility, and microstructure of marine clay stabilized using CG–CCR geopolymer with different content by mass from 0 to 30% are measured by conducting consolidated undrained (CU) triaxial compression tests, oedometer tests, X-ray diffraction, mercury intrusion porosimetry, and field-emission scanning electron microscopy. A new empirical model is proposed to predict the failure strength of stabilized soils. Results indicate that the CG–CCR geopolymer can enhance the geomechanical properties of marine clay. Increasing the geopolymer content to 15% transforms the behavior of stabilized soils from a strain-hardening response (ductile failure) into a strain-softening response (brittle failure). The failure strength increases with the geopolymer content, confining pressure, and curing time. Increasing the geopolymer content to 30% improves the cohesion and internal friction angle to 479.8 kPa and 21.1°, respectively, being approximately 96.1 and 4.9 times those of unstabilized soil. The geopolymer content of 30% is found as the optimum to achieve the lowest compressibility. Microstructural analyses show that the reaction products of CG–CCR geopolymer binder could fill the intergranular pores and densify the soil by reducing the void space between soil particles, explaining the strength improvement of marine clay. This study provides a potential strategy for enhancing the geomechanical properties of marine clay by utilizing industrial geological waste.
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References
Abdullah HH, Shahin MA, Walske ML (2019) Geo-mechanical behavior of clay soils stabilized at ambient temperature with fly-ash geopolymer-incorporated granulated slag. Soils Found 59:1906–1920
Abdullah HH, Shahin MA, Walske ML, Karrech A (2020) Systematic approach to assessing the applicability of fly-ash-based geopolymer for clay stabilization. Can Geotech J 57:1356–1368
Adam AA (2009) Strength and durability properties of alkali activated slag and fly ash-based geopolymer concrete. RMIT University Melbourne, Australia
Åhnberg H (2006) Consolidation stress effects on the strength of stabilised Swedish soils. Proc Inst Civ Eng Ground Improv 10:1–13
Åhnberg H (2007) On yield stresses and the influence of curing stresses on stress paths and strength measured in triaxial testing of stabilized soils. Can Geotech J 44:54–66
Åhnberg H, Johansson S-E, Pihl H, Carlsson T (2003) Stabilising effects of different binders in some Swedish soils. Proc Inst Civ Eng Ground Improv 7:9–23
Arulrajah A, Abdullah A, Bo MW, Bouazza A (2009) Ground improvement techniques for railway embankments. Proc Inst Civ Eng Ground Improv 162:3–14
Arulrajah A, Yaghoubi M, Disfani MM, Horpibulsuk S, Bo MW, Leong M (2018) Evaluation of fly ash-and slag-based geopolymers for the improvement of a soft marine clay by deep soil mixing. Soils Found 58:1358–1370
ASTM A (2010) D4318-10 Stardard Test Methods for Liquid Limit, Plastic Limit and Plasticity Index of Soils. ASTM Int. West Conshohocken
ASTM D A (2016.) Standard test method for unconfined compressive strength of cohesive soil. ASTM international West Conshohocken
Bergado D, Anderson L, Miura N, Balasubramaniam A (1996) Soft ground improvement in lowland and other environments. In: AsCE
Bergado D, Taechakumthorn C, Lorenzo G, Abuel-Naga HM (2006) Stress-deformation behavior under anisotropic drained triaxial consolidation of cement-treated soft Bangkok clay. Soils Found 46:629–637
Bishop AW (1971) Shear strength parameters for undisturbed and remolded soil specimens. Roscoe Memorial Symp 1971:3–58
Chen R, Congress SSC, Cai G, Zhou R, Xu J, Duan W, Liu S (2022) Evaluating the effect of active ions on the early performance of soft clay solidified by modified biomass waste-rice husk ash. Acta Geotech 18:1039–1056
Chen H, Wang Q (2006) The behaviour of organic matter in the process of soft soil stabilization using cement. Bull Eng Geol Env 65:445–448
Chen K, Wu D, Zhang Z, Pan C, Shen X, Xia L, Zang J (2022) Modeling and optimization of fly ash–slag-based geopolymer using response surface method and its application in soft soil stabilization. Constr Build Mater 315:125723
Chen R, Zhu Y, Peng LH, Bao W (2020) Stabilization of soft soil using low-carbon alkali-activated binder. Environ Earth Sci 79:1–13
Cheng Y, Hongqiang M, Hongyu C, Jiaxin W, Jing S, Zonghui L, Mingkai Y (2018) Preparation and characterization of coal gangue geopolymers. Constr Build Mater 187:318–326
Cherian C, Arnepalli DN (2015) A critical appraisal of the role of clay mineralogy in lime stabilization. Int J Geosynthet Ground Eng 1:1–20
Chew S, Kamruzzaman A, Lee F (2004) Physicochemical and engineering behavior of cement treated clays. J Geotech Geoenviron Eng 130:696–706
Chiu C, Zhu W, Zhang C (2009) Yielding and shear behaviour of cement-treated dredged materials. Eng Geol 103:1–12
Consoli NC, Párraga Morales D, Saldanha RB (2021) A new approach for stabilization of lateritic soil with Portland cement and sand: strength and durability. Acta Geotech 16:1473–1486
Coop M, Atkinson J (1993) The mechanics of cemented carbonate sands. Geotechnique 43:53–67
Criado M, Fernández-Jiménez A, De La Torre A, Aranda M, Palomo A (2007) An XRD study of the effect of the SiO2/Na2O ratio on the alkali activation of fly ash. Cem Concr Res 37:671–679
Cristelo N, Glendinning S, Fernandes L, Pinto AT (2013) Effects of alkaline-activated fly ash and Portland cement on soft soil stabilisation. Acta Geotech 8:395–405
Davidovits J (1994) Properties of geopolymer cements. In: First international conference on alkaline cements and concretes. Kiev State Technical University, Scientific Research Institute on, Ukraine, pp 131–149
Deng J, Li B, Xiao Y, Ma L, Wang C-P, Lai-wang B, Shu C-M (2017) Combustion properties of coal gangue using thermogravimetry–Fourier transform infrared spectroscopy. Appl Therm Eng 116:244–252
Du Y-J, Bo Y-L, Jin F, Liu C-Y (2016) Durability of reactive magnesia-activated slag-stabilized low plasticity clay subjected to drying–wetting cycle. Eur J Environ Civ Eng 20:215–230
Du Y-J, Yu B-W, Liu K, Jiang N-J, Liu MD (2017) Physical, hydraulic, and mechanical properties of clayey soil stabilized by lightweight alkali-activated slag geopolymer. J Mater Civ Eng 29:04016217
Duan Y-f, Wang P-m (2008) Early hydration of the material of alkali-activated coal gangue. J Mater Sci Eng 4:511–515
Gu K, Jin F, Al-Tabbaa A, Shi B, Liu C, Gao L (2015) Incorporation of reactive magnesia and quicklime in sustainable binders for soil stabilisation. Eng Geol 195:53–62
Guo Q, Wei M, Wu H, Gu Y (2020) Strength and micro-mechanism of MK-blended alkaline cement treated high plasticity clay. Constr Build Mater 236:117567
Han JY, Song XY, Gao ZH (2012) Excitation effect of soluble glass on composite system with calcined coal gangue and slag. In: Applied mechanics and materials, Trans Tech Publications, pp 30–34
Hardjito D, Rangan BV (2005) Development and properties of low-calcium fly ash-based geopolymer concrete
Head KH (1980) Manual of soil laboratory testing. Pentech Press, London
Ho T-O, Chen W-B, Yin J-H, Wu P-C, Tsang DC (2021) Stress-Strain behaviour of Cement-Stabilized Hong Kong marine deposits. Constr Build Mater 274:122103
Hoang T, Do H, Alleman J, Cetin B, Dayioglu AY (2022) Comparative evaluation of freeze and thaw effect on strength of BEICP-stabilized silty sands and cement-and fly ash-stabilized soils. Acta Geotech 18:1073–1092
Horpibulsuk S, Miura N, Bergado D (2004) Undrained shear behavior of cement admixed clay at high water content. J Geotech Geoenviron Eng 130:1096–1105
Horpibulsuk S, Rachan R, Chinkulkijniwat A, Raksachon Y, Suddeepong A (2010) Analysis of strength development in cement-stabilized silty clay from microstructural considerations. Constr Build Mater 24:2011–2021
Horpibulsuk S, Rachan R, Raksachon Y (2009) Role of fly ash on strength and microstructure development in blended cement stabilized silty clay. Soils Found 49:85–98
Huang G, Ji Y, Li J, Hou Z, Dong Z (2018) Improving strength of calcinated coal gangue geopolymer mortars via increasing calcium content. Constr Build Mater 166:760–768
Ingles OG, Metcalf JB (1972) Soil stabilization principles and practice
Ismail MA, Joer HA, Sim WH, Randolph MF (2002) Effect of cement type on shear behavior of cemented calcareous soil. J Geotech Geoenviron Eng 128:520–529
Kasama K, Zen K, Iwataki K (2006) Undrained shear strength of cement-treated soils. Soils Found 46:221–232
Kou H, Jing H, Wu C, Ni P, Wang Y, Horpibulsuk S (2022) Microstructural and mechanical properties of marine clay cemented with industrial waste residue-based binder (IWRB). Acta Geotech 17:1859–1877
Krammart P, Tangtermsirikul S (2004) Properties of cement made by partially replacing cement raw materials with municipal solid waste ashes and calcium carbide waste. Constr Build Mater 18:579–583
Latifi N, Meehan CL, Abd Majid MZ, Horpibulsuk S (2016) Strengthening montmorillonitic and kaolinitic clays using a calcium-based non-traditional additive: a micro-level study. Appl Clay Sci 132:182–193
Li Y, Li J, Cui J, Shan Y, Niu Y (2021) Experimental study on calcium carbide residue as a combined activator for coal gangue geopolymer and feasibility for soil stabilization. Constr Build Mater 312:125465
Li Y, Sun R, Liu C, Liu H, Lu C (2012) CO2 capture by carbide slag from chlor-alkali plant in calcination/carbonation cycles. Int J Greenhouse Gas Control 9:117–123
Liew Y-M, Heah C-Y, Kamarudin H (2016) Structure and properties of clay-based geopolymer cements: A review. Prog Mater Sci 83:595–629
Liew YM, Kamarudin H, Al Bakri AM, Bnhussain M, Luqman M, Nizar IK, Ruzaidi C, Heah C (2012) Optimization of solids-to-liquid and alkali activator ratios of calcined kaolin geopolymeric powder. Constr Build Mater 37:440–451
Liu Y, Chang M, Wang Q, Wang Y, Liu J, Cao C, Zheng W, Bao Y, Rocchi I (2020) Use of Sulfur-Free Lignin as a novel soil additive: a multi-scale experimental investigation. Eng Geol 269:105551
Min Y, Wu J, Li B, Zhang J (2021) Effects of Fly ash content on the strength development of soft clay stabilized by one-part geopolymer under curing stress. J Mater Civ Eng 33:04021274
Mitchell JK, Soga K (2005) Fundamentals of soil behavior. Wiley, New York
Modarres A, Nosoudy YM (2015) Clay stabilization using coal waste and lime—technical and environmental impacts. Appl Clay Sci 116:281–288
Phetchuay C, Horpibulsuk S, Arulrajah A, Suksiripattanapong C, Udomchai A (2016) Strength development in soft marine clay stabilized by fly ash and calcium carbide residue based geopolymer. Appl Clay Sci 127:134–142
Pourakbar S, Huat BB, Asadi A, Fasihnikoutalab MH (2016) Model study of alkali-activated waste binder for soil stabilization. Int J Geosynth Ground Eng 2:1–12
Quiroga AJ, Thompson ZM, Muraleetharan KK, Miller GA, Cerato AB (2017) Stress–strain behavior of cement-improved clays: testing and modeling. Acta Geotech 12:1003–1020
Salimi M, Ghorbani A (2020) Mechanical and compressibility characteristics of a soft clay stabilized by slag-based mixtures and geopolymers. Appl Clay Sci 184:105390
Sargent P, Hughes P, Rouainia M (2016) A new low carbon cementitious binder for stabilising weak ground conditions through deep soil mixing. Soils Found 56:1021–1034
Sargent P, Hughes PN, Rouainia M, White ML (2013) The use of alkali activated waste binders in enhancing the mechanical properties and durability of soft alluvial soils. Eng Geol 152:96–108
Sherwood P (1993) Soil stabilization with cement and lime
Singhi B, Laskar AI, Ahmed MA (2016) Investigation on soil–geopolymer with slag, fly ash and their blending. Arab J Sci Eng 41:393–400
Stavridakis EI, Al-Rawas A, Goosen Z (2006) Assessment of anisotropic behaviour of swelling soils on ground and construction work. In: Expansive soils: recent advances in characterization and treatment, pp 371–384
Tempest B, Sanusi O, Gergely J, Ogunro V, Weggel D (2009) Compressive strength and embodied energy optimization of fly ash based geopolymer concrete, world of coal ash (WOCA) conference, pp. 1–17
Thives LP, Ghisi E (2017) Asphalt mixtures emission and energy consumption: a review. Renew Sustain Energy Rev 72:473–484
Tong KT, Vinai R, Soutsos MN (2018) Use of Vietnamese rice husk ash for the production of sodium silicate as the activator for alkali-activated binders. J Clean Prod 201:272–286
Van Nguyen Q, Fatahi B, Hokmabadi AS (2017) Influence of size and load-bearing mechanism of piles on seismic performance of buildings considering soil–pile–structure interaction. Int J Geomech 17:04017007
Verruijt A (2001) Soil mechanics. Delft University of Technology, Delft
Vickers NJ (2017) Animal communication: when i’m calling you, will you answer too? Curr Biol 27:R713–R715
Vinod JS, Indraratna B, Mahamud MA (2010) Stabilisation of an erodible soil using a chemical admixture. Proc Inst Civ Eng Ground Improv 163:43–51
Wang D, Korkiala-Tanttu L (2020) 1-D compressibility behaviour of cement-lime stabilized soft clays. Eur J Environ Civ Eng 24:1013–1031
Wang L, Li X, Cheng Y, Bai X (2018) Effects of coal-metakaolin on the properties of cemented sandy soil and its mechanisms. Constr Build Mater 166:592–600
Wang D, Wu D, He S, Zhou J, Ouyang C (2015) Behavior of post-installed large-diameter anchors in concrete foundations. Constr Build Mater 95:124–132
Wei X, Liu H, Ku T (2020) Microscale analysis to characterize effects of water content on the strength of cement-stabilized sand–clay mixtures. Acta Geotech 15:2905–2923
Wu Z, Deng Y, Liu S, Liu Q, Chen Y, Zha F (2016) Strength and micro-structure evolution of compacted soils modified by admixtures of cement and metakaolin. Appl Clay Sci 127:44–51
Xu H, Van Deventer JS (2002) Geopolymerisation of multiple minerals. Min Eng 15:1131–1139
Xu Y, Liu X, Zhang Y, Tang B, Mukiza E (2019) Investigation on sulfate activation of electrolytic manganese residue on early activity of blast furnace slag in cement-based cementitious material. Constr Build Mater 229:116831
Xu F, Wei H, Qian W, Cai Y (2018) Composite alkaline activator on cemented soil: multiple tests and mechanism analyses. Constr Build Mater 188:433–443
Yaghoubi M, Arulrajah A, Disfani MM, Horpibulsuk S, Darmawan S, Wang J (2019) Impact of field conditions on the strength development of a geopolymer stabilized marine clay. Appl Clay Sci 167:33–42
Yi Y, Gu L, Liu S, Puppala AJ (2015) Carbide slag–activated ground granulated blastfurnace slag for soft clay stabilization. Can Geotech J 52:656–663
Yoobanpot N, Jamsawang P, Poorahong H, Jongpradist P, Likitlersuang S (2020) Multiscale laboratory investigation of the mechanical and microstructural properties of dredged sediments stabilized with cement and fly ash. Eng Geol 267:105491
Yu J, Chen Y, Chen G, Wang L (2020) Experimental study of the feasibility of using anhydrous sodium metasilicate as a geopolymer activator for soil stabilization. Eng Geol 264:105316
Zhang JX, Duan PX (2012) Chloride consolidation and penetration behavior in harden mortar of gangue added cement. In: Advanced materials research, Trans Tech Publicaion, pp 1831–1836
Zhang C-s, Fang L-m (2004) Hardening mechanisms of alkali activated burned gangue cementitious material. Mater Sci Technol 12:597–601
Zhang M, Guo H, El-Korchi T, Zhang G, Tao M (2013) Experimental feasibility study of geopolymer as the next-generation soil stabilizer. Constr Build Mater 47:1468–1478
Zheng X, Wu J (2021) Early strength development of soft clay stabilized by one-part ground granulated blast furnace slag and fly ash-based geopolymer. Front Mater 8:616430
Zhou H, Wang X, Wu Y, Zhang X (2021) Mechanical properties and micro-mechanisms of marine soft soil stabilized by different calcium content precursors based geopolymers. Constr Build Mater 305:124722
Zhu J-F, Xu R-Q, Zhao H-Y, Luo Z-Y, Pan B-J, Rao C-Y (2020) Fundamental mechanical behavior of CMMOSC-SC composite stabilized marine soft clay. Appl Clay Sci 192:105635
Acknowledgements
This research was financially supported by the National Natural Science Foundation of China (No. 52008121), the National Key Research and Development Program of China (No. 2022YFC3003601), the Key International (Regional) Joint Research Project (No. 52020105002), the Natural Science Foundation of Guangdong Province (No. 2023A1515012163), and the Open Research Fund of MOE Key Laboratory of High-speed Railway Engi-neering, Southwest Jiaotong University.
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Li, J., Shan, Y., Ni, P. et al. Multiscale experimental analysis of marine clay stabilized with coal gangue–calcium carbide residue geopolymer. Acta Geotech. 18, 5921–5939 (2023). https://doi.org/10.1007/s11440-023-02055-4
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DOI: https://doi.org/10.1007/s11440-023-02055-4