Consolidation and swelling behavior of kaolinite clay containing xanthan gum biopolymer

Recently, microbial biopolymer-based soil treatment (BPST) has gained attention for its application in environmentally friendly soil stabilization, particularly for enhancing the strength and stability of fine-grained soils. However, the effects of BPST on clay’s compressibility (consolidation) and expansion (swelling) behaviors remain unclear. This study used xanthan gum, a microbially produced polysaccharide with anionic charges, to stabilize kaolinite clay. The effect of xanthan gum BPST on the consolidation and swelling behavior of cohesive kaolinite clays was assessed through a series of experimental tests, including one-dimensional consolidation tests with elastic wave measurements, swelling tests, environmental scanning electron microscopy, and unconsolidated-undrained triaxial tests. The formation of xanthan gum hydrogels induces pore-clogging, resulting in a delay in the consolidation process, increased energy dissipation, and compressibility. Furthermore, the interaction between kaolinite and xanthan gum improved the undrained shear strength of kaolinite soils, thereby reducing the consolidation time required for a specific bearing capacity. This study demonstrates the possible application of controlling hydraulic conductivity, seismic stabilization, and rapid surface stabilization. However, additional drainage is necessary for in situ applications.


XG
Xanthan gum m b Weight of biopolymer (g) m w Weight of pore fluid (g) m s Weight of kaolinite (g) m b / m s The xanthan gum-to-soil ratio in mass (%) DI Deionized water e i Initial void ratio e p Void ratio at the end of primary consolidation c v Coefficient of consolidation (cm 2 /s) k Permeability (cm/s) c ae The coefficient of secondary consolidation (cm 2 /s) C c Compression index C S Swelling index V P P-wave velocity (m/s) V S S-wave velocity (m/s)

Introduction
Ground improvement is an essential civil engineering practice to enhance the stability of civil infrastructure by increasing soil strength and stiffness, improving erosion resistance, and controlling hydraulic conductivity [42]. In antiquity, ground improvement practices commonly used bio-based organic materials such as animal blood, dung, tree pods, straw, plant stems, and leaves [40]. However, artificial chemical stabilizer (e.g., Portland cement) has become the predominant ground improvement material since the industrial revolution because of properties such as strengthening effectiveness and the high socioeconomic demand for rapid development [62,96]. However, chemical ground improvement materials, such as cement, lime, and fly ash, have several environmental concerns, including massive carbon dioxide emissions, toxic substances, and an increase in the pH of the surrounding soil and underground water [24,58]. Therefore, bio-mediated geomaterials are gaining popularity as environmentally friendly soil treatment and ground improvement binders for sustainable development. Biopolymer-based soil treatment (BPST) is being actively studied as a new approach nowadays [11,14,29,37,49,90,94,97,98].
A majority of the previous studies on the BPST focused on their application for cohesionless soils such as sand, silts, and mine tailings [1,13,18,25,33,43,61,76]. However, biopolymers electrostatically interact with charged cohesive soils, increasing the liquid limits, shear strength, and promoting clay particle aggregation, which facilitates sedimentation [28,67,85]. Because of factors such as low bearing capacity, differential settlement, and lateral movements in fine-grained soils with low shear strength and high compressibility [50,72,88], soft cohesive soils should be improved to increase shear strength and control compressibility before construction [78]. Several techniques, including replacement, densification, hydraulic modification, chemical stabilization, and electrical modifications, have been employed to enhance the hydraulic and mechanical properties of soft soils [44,52,53,75]. Among these, the biopolymer was employed in this study because this method is an ecofriendly approach for chemical stabilization for soft cohesive soils.
Previous research [71,84,111,112] analyzed the effect of biopolymers on soft soil stabilization in terms of consolidation, which is a crucial factor to consider when evaluating the potential benefits of BPST. However, the consolidation behavior of fine-grained soils for the biopolymer method is complex and variable. For instance, Latifi et al. [71] stated that biopolymer treatment (1% of soil mass) reduced the compression index (C c ) values of fine-grained soils (bentonite and kaolinite) due to the formation of hydrostatic and electrostatic bonds between kaolinite and biopolymer monomers. Other studies have also reported a decrease in collapsible potential [10,36] and compressibility [100] with biopolymer treatment. Nugent et al. [84] demonstrated that anionic biopolymers increase the compressibility of kaolinite (initial void ratio of 2-2.7) by dissipating repulsive forces between anionic biopolymer strands and kaolinite particles under high vertical loads. Another consolidation analysis of biopolymertreated cohesive soils [17,97] also reported an increase in compressibility. These contrasting mechanisms of BPST on clay compressibility may be attributable to the complex interaction between the biopolymer and clays that varied according to the soil properties (e.g., mineral type, initial void ratio) and pore fluid characteristics (i.e., biopolymer type, ionic strength, and gel rheology) [107,108]. Further, several studies have reported changes in the consolidation parameters (e.g., compressibility, coefficient of consolidation) according to the biopolymers, and a few studies have examined changes in the mechanical properties (e.g., mechanical wave, undrained shear strength) during the consolidation process. Consequently, it is necessary to analyze the alteration in fabrics [77] and mechanical waves [41] that are caused by the biopolymer during the consolidation process.
This study, therefore, assessed the effect of xanthan gum biopolymer (XG) on the consolidation of kaolinite clay with a high water content based on the microscale interaction between kaolinite clay, pore water, and XG biopolymer through consolidation and swelling stages. At constant vertical confinement of 5 kPa, the swelling pressure of XG-treated kaolinite was determined via a swelling test. A series of one-dimensional (1-D) consolidation tests were conducted on the untreated and XG-treated kaolinite specimens. The elastic wave (i.e., P-wave and S-wave) velocity of the clays was measured during the consolidation stages to obtain effective stress, energy dissipation, and small-strain stiffness variations. The possible interactions and structures between XG and kaolinite in the presence of water were analyzed using environmental scanning electron microscopy (ESEM) images. Lastly, unconsolidated-undrained (UU) triaxial tests were conducted to estimate the variation in undrained shear strength during consolidation, which is crucial for the surface stabilization of soft soils. This study demonstrates the consolidation and swelling behavior of XG-treated kaolinite, along with the changes in the material's mechanical properties during consolidation, and expands upon the foundation of BPST to improve cohesive soils.

Fine soil: kaolinite
This study used Bintang kaolinite (Belitung Island, Indonesia). The unified soil classification system (USCS) classifies Bintang kaolinite as highly plastic clay (CH) with a plastic limit of 24% and a liquid limit of 70% [6]. The average specific surface area was 22 m 2 /g, obtained through the methylene blue adsorption method [93]. The particle size distribution (Fig. 1a) of kaolinite was determined using a laser diffraction particle size analyzer (HELOS/KR-H2487) based on the ASTM International D4464-15 and B822-20 standards [3,8]. The SEM image of kaolinite (Fig. 1b) revealed that the dominant morphology of the kaolinite used was a plate, whereas lath kaolinite was also present. Before the experiments, the kaolinite was dried in an oven at 105 ± 5°C for at least 24 h to evaporate the pore water [4].

Xanthan gum biopolymer
Among various biopolymers, XG, a high molecular weight polysaccharide secreted by the bacterium Xanthomonas campestris, is known to have a minimal impact on the environment and human health [114]. XG is an anionic biopolymer with a linear backbone of 1,4-linked b-D-glucose linked to anionic trisaccharide side chains [20]. Thus, XG can absorb water at approximately 25 times its mass [38] and form electrostatic interactions with soil particles [28]. Moreover, XG possesses pseudoplastic characteristics, wherein its viscosity decreases with increasing shear rates [20]. Thus, XG is commonly used in drug delivery systems [95], food thickening agents [60], and nanoparticle stabilization [89]. In addition, it has been reported that applying XG results in an increase in the soil strength [26,81] and consistency [28] and causes a decrease in the soil permeability [18]. Other studies have demonstrated the impact of XG on the cyclic performance by offering a longer fatigue life under cyclic loading [82] and a higher damping ratio [51]. For all experimental programs, this study used research-grade XG (CAS No. 11138-66-2; Merck, USA).

Swelling tests
The swelling pressure of clays was determined using an automatic computerized consolidation test apparatus (Wykeham Farrance; 26-WF3120) with an oedometric cell of 63.5 mm in diameter and 74 mm in height (Wykeham Farrance; 26-WF0321). The porous plate and filter papers (Whatman; Grade 42 filter paper) were placed at the bottom of a specimen ring made of stainless steel with an internal diameter of 63.5 mm and a height of 20 mm. Clay specimens were prepared by mixing dry kaolinite and dry XG (i.e., XG-to-kaolinite mass ratio: m b /m s = 0%, 0.5%, 1.0%, and 2.0%). Swelling experiments were conducted under dry conditions to maximize the variation of swelling quantity with XG content. Then, the mixed biopolymerkaolinite powder was poured into the ring and compacted by tamping in 3 layers to ensure that the mixture can be placed in an oedometric ring. The initial void ratio (e i-= 2.0-2.2) was calculated as e i = (G S •A•hi-m s )/G S using the weight of the soil (m s ), the specific gravity of kaolinite (G S = 2.65), the initial height measured with Vernier calipers (h i ), and the area of the specimen ring (A = 31.67 cm 2 ). Another porous plate and filter paper were placed above the specimen, allowing deionized water (DI) to flow into the soil from the top and bottom. Before wetting, specimens were subjected to 5 kPa of vertical loading. Once the sample height was stabilized, DI was poured into the container to initiate specimen wetting. The volumetric expansion due to wetting under consistent confinement (5 kPa) was measured using a top-mounted linear variable displacement transducer (LVDT). Subsequent consolidation tests were conducted at loading increments of 12 kPa, 25 kPa, 50 kPa, 100 kPa, and 200 kPa, and each loading lasted for 24 h. The swelling pressure of the specimen was calculated as the pressure required to restore the initial sample height [9] based on the swelling and consolidation results. The experimental procedures are described in detail in Thakur and Singh [106].

Consolidation tests
1-D consolidation tests on XG-treated kaolinites (initial water content of 80%) were performed using BS 1377-5 [15] and ASTM D2435 [5]. The porous plates and Whatman Grade 42 filter papers were placed above and below the specimen to allow proper upward and downward drainage during consolidation. The P-wave (PZT plate) and S-wave (bender element) sensors were embedded on the bottom and top plates to simultaneously measure the elastic wave velocities and the specimen height during consolidation. The experimental setup is summarized in Fig. 2.
The experimental specimens were prepared by thoroughly mixing kaolinite, XG, and DI according to the desired kaolinite/XG/water ratios. The consolidation behavior of kaolinites with high water content (80%) was observed to be comparable to that of real-field clays with high water content [116]. Dry XG powder (m b = 0, 1, and 2 g) was dispersed into the target weight of DI (m w-= 160 g), and uniform XG solutions (XG-to-DI ratio by mass = 0%, 0.625%, and 1.25%) were prepared by mixing with a magnetic stirrer (DH.WMH03503; Daihan Scientific, Korea). Then, the XG solutions were hand-mixed with kaolinite (m s = 200 g) to form uniform kaolinite-XG-DI mixture (XG-to-kaolinite ratio by mass = 0%, 0.5%, and 1.0%).
The kaolinite-XG-DI mixture was then placed in an acrylic oedometer cell of diameter 74 mm, after which it was compacted to form an initial height of 45 mm to attain the desired void ratio (i.e., 2.0-2.2, in the same range as that of the swelling experiments). This technique of preparing molded specimens was adopted to avoid specimen disturbance due to cutting and fitting during trimming. Then, the cell was capped with an acrylic top cap, and the oedometer cell with the XG-treated kaolinite specimen was placed on a conventional oedometer testing device.
Vertical loading was applied to the mixture through seven incremental steps (i.e., 12.5, 25, 50, 100, 200, and 400 kPa), whereas untreated kaolinite was loaded up to 200 kPa (i.e., 12.5, 25, 50, 100, and 200 kPa). Then, the vertical stress was reduced by 200 kPa, 100 kPa, and 25 kPa. All vertical loading and unloading steps were maintained until the specimen height varied by less than 0.01 mm for 24 h. Consolidation data were analyzed based on the square-root-of-time (Taylor) method [105]; the void ratio at the end of primary consolidation (e p ) was determined based on the log-of-time (Casagrande) method [19]. The coefficient of consolidation c v , hydraulic conductivity k, and coefficient of secondary consolidation c ae at each loading step were calculated based on the time-void ratio correlation. The compressibility C c and swelling index C S were derived based on the effective stress-void ratios. For the reliability of the experiments, at least two consolidation processes were performed simultaneously for each kaolinite specimen. During the consolidation experiments, Fig. 2 1D consolidation experimental design with elastic wave measurements the displacements were measured using a dial gauge with a measurable variation of 0.01 mm.

Elastic wave measurements
The wave velocities were measured during the consolidation experiments using an oscilloscope (DSOX2014A, Keysight Technologies, USA) and a function generator (33210A, Keysight Technologies, USA). In addition, two different PZT types were embedded at the top and bottom plates of the oedometer cell: plate-type sensors for P-wave measurement and bender-element-type sensors for S-wave measurement. Detailed procedures for sensor production and oedometer cell installation can be found in Chang and Cho [23]. Figure 3 presents an example of the elastic wave signals of the 0.5% XG-treated kaolinite. Single-step signals were generated at the bottom of the PZT sensors (Fig. 3a). The input frequency and amplitude were set to 50 Hz and 10 V for the P-wave and 8 kHz and 10 V for the S-wave. After the first bump, the zero points were handpicked (Fig. 3b) as the arrival time of the S-wave to disregard near-field effects based on Lee and Santamarina [73]. The arrival time decreased with an increase in vertical loading, increased again upon unloading, and was faster than that at the same loading of virgin compression (Fig. 3c). The received raw signals showed a trend similar to a general consolidation curve. Thus, elastic wave measurements can be used to infer the consolidation process of soil.

Environmental scanning electron microscopy (ESEM)
Environmental SEM is a type of SEM during which the operator can control the water vapor pressure (10-4000 Pa) and the relative humidity in the specimen chamber. Consequently, ESEM allows observation of wet kaolinite by overcoming the shortcomings of traditional SEM, which can only be operated in a vacuum without water. This study utilized ESEM (Quattro S, FEI) to observe the effects of varying humidity on the microstructure of dry XG powder and XG-treated kaolinite. Untreated and 1% XG-treated kaolinites (with the same water content as the consolidation specimen) were sampled and air-dried at room temperature. The specimens were mounted on an ESEM mount. The surface of the specimen was then subjected to electron beams. The relative humidity in the chamber varied from 0 to 100% during observation.

Unconsolidated and undrained (UU) triaxial tests
UU triaxial compression tests were conducted on XGtreated kaolinites to analyze the effects of XG on the undrained shear strength of kaolinite clays during the consolidation at 50 kPa of vertical loading (i.e., 3.2 m depth) based on the ASTM D2850 standard [7]. The kaolinite powder (m s = 200 g) was uniformly mixed with 120 g of XG solutions containing different m b /m s (i.e., 0.0%, 0.5%, 1.0%, and 2.0%). A membrane suction stretcher wrapped the latex membrane around the soil sample using 10 kPa of suction pressure. The soil specimen was encased in a latex membrane to form a cylinder of height 100 mm and diameter 50 mm. The XG-treated kaolinite was compacted in a latex membrane to obtain the observed void ratio (1.65-1.80) during consolidation at 50 kPa vertical loading. The O-rings on the membrane's top and bottom caps sealed the samples within. The sample volume was then measured after the application of 10 kPa of vacuum pressure to the specimen. The triaxial apparatus was then positioned around the sample, and its cell was filled with de-aired water. The vacuum was slowly released from the kaolinite, while a cell pressure of 10 kPa was applied to maintain the specimen during saturation. The samples were then saturated with 5 kPa of back pressure until a sample volume (approximately 200 mL) of de-aired water flowed through the system. Lastly, Skempton's B-value was determined by measuring the pore pressure increment induced by increasing the cell pressure, and UU tests were performed on a specimen with a Skempton's B-value greater than 0.9.
Confining pressure (i.e., 50 kPa) was applied after cell assembly without water and air drainage. The specimen was then allowed to rest until a constant pore pressure was established. A motor-driven load frame (HM-5020.3F; Humboldt) sheared the specimens at 1 mm/min (i.e., 1%/ min strain) displacement rates. A linearly variable deformation transformer (LVDT) and a load cell mounted on the crosshead of the load frame monitored the axial displacement (in mm) and axial load (in N). Experiments were performed in triplicate for a given confining stress and XG content. The deviator stress at failure was defined using the maximum deviator stress from the stress-strain curve (when a peak value was found) or the deviator stress at an axial strain of 15% (when no peak value was found) while analyzing the stress-strain curves [7]. Figure 4a depicts the results of the swelling experiments conducted with a vertical loading of 5 kPa. After water intrusion, untreated kaolinite shows compaction even at 5 kPa because a 1:1 layered clay mineral has a slight swelling potential [31]. Given that the initial water content (i.e., 0%) was lower than optimum water content, the addition of DI results in a change in the clay fabrics to smaller pores [80]. Thus, compaction dominates the swelling of kaolinite following the introduction of water. The compaction behavior also occurred in 0.5% XG and was converted to the swelling phase after approximately 10 min of water flow. In contrast, kaolinite with XG [ 1.0% exhibited more significant swelling behavior. The swelling ratio of XG-treated kaolinite increased from 5% (at 0.5% XG) to 20% (at 2.0% XG) because of the fact that hydrophilic XG hydrogels swell by absorbing pore fluids penetrating kaolinite media [16,103].

Swelling behavior of XG-treated kaolinite
When the vertical loading increased, the specimen consolidated, and the volumetric strain decreased, as shown in Fig. 4b. The swelling pressures were determined as effective stress corresponding to zero volumetric strain. Given that vertical compression of 5 kPa dominates the swelling potential of pure kaolinite, XG 0.0% kaolinite exhibited a negative volumetric strain (i.e., compaction) at 5 kPa. XG treatment increased the swelling pressure from \ 5 kPa (untreated) to 11.65 kPa (0.5% of XG), 20.35 kPa (1.0% of XG), and 37.70 kPa (2.0% of XG). The final specimen height at each vertical loading was greater than that of the untreated kaolinite, and the slope of the compression curve slightly increased with an increase in XG (Fig. 4b). Typically, clays with high swelling pressure cause instability in civil infrastructure [74]. However, the swelling potentials of XG-treated kaolinite can be applied to improve barrier properties and biodegradability, remediate contaminated soils, provide a buffer for nuclear waste, and maintain borehole stability [2,65], because of their ability to resist earth pressure loads [101,102].  faces and positively charged edge surfaces [109], XG with anionic charges and kaolinite either repel or attract one another. Electrostatic repulsion between the face surface of kaolinite and anionic XG prevailed at 0.5% XG [56] because of the high face portion of kaolinite [47] and insufficient XG content to form XG-bridges between particles [70], resulting in a greater particle distance. Therefore, 0.5% XG-treated kaolinite showed a larger void ratio than the untreated kaolinite. Chang et al. [28] also noted that 0.5% XG-treated kaolinite showed a local peak liquid limit because XG increased the specific surface area of kaolinite rather than forming bridges between clay particles. In contrast, because of the bonding between kaolinite and XG, 1.0% XG-treated kaolinite showed a denser ep, even at low vertical stress. XG forms interparticle bonds directly with positively charged edge surfaces and indirectly with face surfaces via hydrogen bonds [104,117]. XG-induced particle bonding aggregates kaolinite particles, resulting in a decrease in e p . In addition, XG-adsorbed water was expelled by increased vertical loading, reducing e p with increasing XG content.

Consolidation behavior of XG-treated kaolinite
Both C C and C S increased with increasing XG content, as shown in the legend in Fig. 5. This is because the repulsion force between XG and the surface of kaolinite was overcome by the increase in vertical loading, which further resulted in a marginal increase in the rate of change of e p for XG-treated kaolinite as compression stress increased. Moreover, XG is more sensitive to volume change due to vertical load variation because it contains a large amount of water [38].
C ae is the void ratio variation over the log of time starting after the primary consolidation [80]. Secondary compression occurs by water discharge from the micropores in an adsorbed state, and the continuous skeletal deformation of soils occurs during primary consolidation [113], which is dependent on complex factors such as particle rearrangement, pre-consolidation pressure, and stress history [45]. For instance, in XG-treated kaolinite (Fig. 6), water strongly adsorbed by XG was slowly discharged during the secondary consolidation process, resulting in fabric rearrangement and a proportionally higher C ae to the XG content. Here, C ae increased with the effective stress for both untreated and 0.5% XG-treated kaolinite because a greater vertical loading accelerated the discharge of adsorbed water. In contrast, C ae of 1.0% XGtreated kaolinite gradually decreased as the effective stress increased because XG-induced bridges became compact as the vertical pressure increased [34].

Permeability of XG-treated kaolinite
The c v is related to the rate of 1D consolidation when saturated kaolinite is exposed to increased vertical pressure. Overall, c v increased as e p declined (Fig. 7a). For the same soil specimen, e p is inversely proportional to effective stress, and c v is expected to increase with effective stress [115]. Furthermore, c v decreases with an increase in the coefficient of volume change, whose value increases with e p [39]. The c v value for untreated kaolinite falls within the range of 8-30 9 10 -4 cm/s, which is consistent with the previously reported c v value for kaolinite [59,91]. XG treatment reduced the c v of kaolinite soils by 52.60% (0.5% XG at 100 kPa) to 98.87% (1.0% XG at 12.5 kPa) compared to that of untreated kaolinite at the same vertical effective stress.
The permeability (k) of kaolinite at e p was computed using the relationship between c v and k (i.e., k = c v m v c w ). The log k increases linearly with an increase in e p owing to the larger drainage paths. The k of the XG-treated kaolinite decreased exponentially during the consolidation stages, from untreated kaolinite (1.5-11.8 9 10 -7 cm/s) to 0.5% XG-treated kaolinite (0.07-3.8 9 10 -7 cm/s) and 1% XG-   Figure 8 summarizes the results of the elastic wave velocity measured during the consolidation procedures at vertical effective stresses ranging from 12.5 kPa to 200 kPa. The P-wave velocity (V P ) is typically higher than the S-wave velocity (V S ) under identical conditions (e.g., void ratio and effective stress). Both V P and V S decreased with an increase in the void ratio because kaolinite particles were initially loosely packed with a higher void ratio. Figure 8a shows no significant relationship between the V P and XG content. However, V S (Fig. 8b) decreases with increasing XG content. The V S difference with XG addition is more significant at a higher void ratio than with a lower void ratio. The parameters a and b obtained from the wave velocity and void ratio relationships are also depicted in Fig. 8, where parameter a indicates the wave velocity at a void ratio of 1 and b represents the sensitivity of wave velocity to the variation in void ratio. Both a and b tended to increase with XG treatment, whereas the S-wave velocity showed a more significant variation. The results indicate that XG has a more prominent effect on the shear stiffness than on the bulk stiffness of the kaolinites.

Wave velocity variation during consolidation
If the distance between kaolinite particles is insufficient for an XG-bridge (i.e., high void ratio), the repulsive forces between the negatively charged XG and kaolinite prevail [117], resulting in a decrease in effective stress and the V S [55]. As the void ratio decreases, XG and kaolinite form face-to-face-like fabrics through direct electrostatic bonding with the positive edge surface and hydrogen bonding with the face surface [108]. Thus, the V S of XG-treated kaolinite would be comparable to that of untreated kaolinite. However, even in such instances, kaolinite-XGkaolinite contact resulted in a slightly lower V S for XGtreated kaolinite. Figure 9 illustrates the variation in V P and V S of XGtreated kaolinite subjected to a vertical loading of 200 kPa, in terms of the velocity ratio (i.e., the wave velocity ratio to that at 0 s). The elastic wave velocity increased Fig. 7 Variation in a the coefficient of consolidation and b the hydraulic conductivity with a variation in the void ratio at the end of primary consolidation Fig. 8 The variation in a P-wave and b S-wave velocity with void ratio logarithmically with the square root of time. Although V P and V S increased slightly during the secondary consolidation, most of the V P and V S increases were completed during the primary consolidation, indicating that pore fluid dissipation during the primary consolidation causes an increase in effective stress. In contrast, the increase in effective stress during secondary consolidation is relatively modest, but it must be considered, especially for XGtreated kaolinites. The initial V P and V S increased slowly with XG treatment because XG delayed primary consolidation. Notably, XG treatment increased V P and V S more steeply during the secondary consolidation process. Figure 10 depicts the variation in V P and V S measured at the end of primary consolidation. The analysis differentiates between the loading and unloading stages because of the different stress paths and fabrics. During the loading stages, the V P was marginally affected by the XG content, whereas the V S at the same effective stress decreased gradually with XG. The V P and V S dropped during unloading but were still higher than those at the same vertical effective stress of virgin compression. Compared to untreated kaolinite, the XG treatment resulted in a minor variation in V P and V S during the unloading process.
The correlation between wave velocities and the void ratio based on Eq. 1 [21] is summarized in Table 1.
where r v 0 represents the vertical effective stress, and a and b are experimentally determined parameters. Parameter a indicates the wave velocity at the vertical effective stress of 1 kPa, and b captures the sensitivity of the kaolinite stiffness to the applied stress. Parameter a of the P-wave slightly decreased (up to 10%) with XG treatment during loading, whereas b slightly increased. However, a of the S-wave demonstrated a greater decrease (up to 30%), and b increased with XG from 0.32 to 0.39. The wave velocity and a decreased because the repulsive force between XG and kaolinite inhibited the contact between kaolinite particles [57]. In addition, the bond between XG and kaolinite produces FF-like kaolinite fabrics, resulting in wave propagation through the connection between kaolinite and XG. Previous studies by Faris et al. [42] also stated that V S traveling through hydrogel media was less than 1 m/s. A rise in b with XG indicates that XG contributes to a more significant increase in stiffness as vertical loading increases. The difference in the XG effect on P-and S-waves seems to be due to the contribution of XG to the elastic modulus (shear modulus and bulk modulus) of kaolinites [83]. The shear modulus of kaolinite (i.e., 2-37 MPa, calculated from V S in this study) is comparably lower than that of the bulk modulus of kaolinite (i.e., 180-1913 MPa, calculated from V P in this study) and water (i.e., approximately 2200 MPa [79]). Thus, the XG contribution was more pronounced for S-wave propagation. Previous studies also pointed out that the biopolymer treatment significantly affected the V S and slightly affected the V P [22,83]. During the unloading stages, the parameter a increased with the XG content because of its higher pre-consolidation stress, whereas b decreased to 60% of the untreated kaolinite. The smaller b of XG at the unloading stage suggests that XG treatment may contribute to maintaining stiffness when the upper load is removed during excavation, erosion, or other soil loss. Figure 11 depicts a remarkable reduction in the P-wave and a slight reduction in the S-wave amplitude as a result of XG treatment. Peak-to-peak amplitude values were calculated across the widowed waveforms for the first cycle. The amplitude increased as the void ratio decreased because the travel path of the waves shortened during the consolidation process. The received P-wave signals have higher amplitudes than the S-wave signals because of their lower frequencies. Signals with higher frequencies typically oscillate during wave propagation, which results in considerable energy loss [83]. The average P-wave amplitude decreased from 7.63 mV (untreated) to 4.07 mV (0.5% XG) and 2.46 mV (1.0% XG), whereas the average S-wave amplitude was 1.18 mV (untreated) to 0.87 mV (0.5% XG). The phase differences between rigid kaolinite particles and ductile XG gels result in energy dissipation at the XG-kaolinite interfaces and XG hydrogels [51]. In addition, structural disturbance (i.e., particle dispersion via repulsive forces between the kaolinite face and XG, FF-like particle bonding via attractive force between kaolinite edge and XG) occurred through XG-kaolinite interaction, resulting in higher energy dissipation during the wave propagations.

Behavior of XG-treated kaolinites during consolidation process based on microscopic observations
The ESEM observation of the XG molecule revealed a swelling characteristic of XG as relative humidity increased from 7.1% (Fig. 12a) to 100.0% (Fig. 12b). As shown, the volume of XG increased upon the absorption of adjacent water molecules. The ESEM results showed a 1.2fold increase in length following the water adsorption, which can be approximated to represent a 1.4-fold and 1.7fold increase in surface area and volume, respectively. In addition, the electrostatic interaction between kaolinite and XG affected the consolidation behavior by re-arranging kaolinite particles. XG encouraged kaolinite into FF-like fabrics via a repulsive force between the face surface and XG and via electrostatic attraction force between the edge surface and XG, as shown in Fig. 12c. With increased relative humidity (Fig. 12d), XG-adsorbed water and formed viscous hydrogels. The swelling of XG in the void space (Fig. 4a) resisted consolidation pressure. Thus, XG-treated kaolinite showed a higher void ratio in the swelling experiments (Fig. 4b) than 0.5% XG-treated kaolinite in the consolidation experiment (Fig. 5). Adsorbed water squeezed out at vertical stress higher than the swelling potential of XG. Both factors resulted in a larger C C (Fig. 5). When the applied load was removed, XG-adsorbed water and swelled again, showing a higher C S than the untreated kaolinite (Fig. 5). The volume-expanded XG clogged void spaces and inhibited water drainage, drastically lowering k and c v with XG treatment (Fig. 7). With increased relative humidity, XG surrounding the kaolinite surface formed a viscous hydrogel by absorbing pore fluids and swelling, which reduced direct kaolinite-to-kaolinite contact. Thus, V S decreased with XG content (Fig. 8b), whereas V P changed slightly with XG content (Fig. 8a). Wave propagation through the ductile XG hydrogel resulted in more significant energy dissipation (Fig. 11).  approximately 15% axial strain, the axial strain of the XGtreated specimen reached 15% without exhibiting a peak value. According to the ASTM D2850 standard [7], the deviator stress at failure was determined as the deviator stress at an axial strain of 15% for all specimens. The XG treatment caused the deviator stress at failure to increase from 14.2 kPa (untreated) to 30.1 kPa (XG 2.0%). The improvement in stress-strain behavior was comparable between 0.5% (27.8 kPa) and 1.0% (25.6 kPa) of XG, and further enhancement was observed at 2.0% of XG. Several hypotheses could account for the increase in shear resistance caused by applying XG. First, the bonding between XG and kaolinite particles improves particle contact and shear strength [36]. Moreover, the XG-induced FF particle alignment is stronger than the EF particle contact [92]. Lastly, an increase in the pore fluid viscosity due to XG enhances the resistance of soil to shear force [86]. Figure 13b depicts the improvement in s u , which is defined as half of the deviator stress at failure, as a function of the void ratio. By altering the log-log relationship between s u and the void ratio [27,66], the interactions between XG, kaolinite, and pore fluids led to a more than twofold rise in s u (from 7.43 kPa (untreated) to 15.20 kPa (2% XG) at e = 1.72), whereas s u at e = 1.72 was calculated to be 12.81 kPa for 0.5% XG and 12.13 kPa for 1.0% XG. Figure 14 compares the estimated s u derived from the log-log relationship between s u and e in Fig. 13b to the consolidation curves for a vertical loading of 50 kPa (i.e., an estimated depth of 3.2 m). Even with a higher void ratio, XG-treated kaolinite exhibited a higher s u (from 10 to 16 kPa) than untreated kaolinite (ranging from 6-9 kPa).  In other words, the XG treatment for kaolinite reduces the overall consolidation time necessary to achieve a capacity of soft soil to withstand loads applied to the ground above, including the construction equipment for soft soil stabilization (e.g., dozer, crane) [63,64]. However, the application of XG to kaolinite has both limitations and advantages in terms of the consolidation. The swelling pressure of XG and the interaction force between XG and kaolinite have the potential to resist the vertical consolidation forces. However, a thorough evaluation of XG content is required because a higher XG content resulted in a higher C C and C ae due to the squeezing out of water adsorbed by XG, and a lower C V delays the consolidation procedure. Thus, further studies should be conducted to consider additional drainage methods after obtaining a higher s u by XG treatment. Furthermore, cations in soils should be considered because they can promote XG adsorption on kaolinite and decrease soil compressibility [46].

Possible applications of XG in terms of consolidation
In addition to consolidation purposes, XG in pore spaces absorbs water, swells, and clogs pore spaces, resulting in a hindered water flow along with the pore spaces. The waterholding and pore-clogging capacity of XG increased as its content rose. Therefore, XG-treated kaolinite has the potential to be used as a hydraulic barrier, as it meets the requisite k value of less than 10 -7 cm/s [12,110], allowing the use of kaolinite, which is widely distributed compared to conventional hydraulic barrier materials such as bentonite. Lastly, an increase in P-and S-wave attenuation after XG treatment suggests that XG could be utilized for seismic stabilization of the ground.

Conclusions
This study investigated the effect of xanthan gum treatment on the swelling, compressibility, permeability, elastic wave propagation, and undrained shear strength during the consolidation of high-water-content kaolinite clays. XG biopolymer affected the consolidation and swelling behavior of soils as a result of the absorption of pore fluids, the development of XG-kaolinite bonds, and the repulsion of kaolinite particles. The XG-induced water absorption increased the swelling pressure and swelling indices of kaolinite, demonstrating its potential to provide a barrier or buffer, enable the remediation of contaminated soils, and assist in the maintenance of borehole stability. The void ratio at the end of primary consolidation varied slightly depending on the XG content. Given the dominant repulsive force between XG and kaolinite, 0.5% of XG exhibited a higher void ratio. Further, 1.0% of XG exhibited a lower void ratio because of the formation of XG-bridges between kaolinites. The compressibility and swelling index marginally increased after applying the XG treatment.
The XG-treated kaolinite, by contrast, exhibited significant energy dissipation during the propagation of an elastic wave, demonstrating the potential of XG for seismic stabilization. In addition, the XG hydrogel clogged the pore spaces and drastically reduced the hydraulic conductivity, meeting the criteria for use as a hydraulic barrier and landfill lining material. Lastly, the XG treatment increased s u at the same consolidation period, which can further minimize the consolidation time required for construction equipment to enter the soft ground. These results revealed the potential of XG application for the stabilization of finegrained soils with high water content for controlling hydraulic conductivity, seismic stabilization, and rapid surface stabilization for the trafficability of construction equipment. If additional drainage is not considered, a low XG content should be used in practical applications.
Availability of data and materials All data, models, and code generated or used during the study appear in the published article.

Declarations
Conflict of interest The authors declare that they have no conflicts of interest that could have influenced the work reported in this paper.
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