Abstract
The demand and use of dyes in modern life are increasing, and dye pollution has become a widespread concern worldwide; therefore, it is essential to develop novel environmentally friendly materials to deal with dye wastewater. Herein, a novel visible-light-driven ternary catalyst (BiOI/Bi2S3/MgIn2S4) was fabricated by employing the hydrothermal method. Compared to BiOI, the synthesized ternary catalyst exhibited better photocatalytic performance to decompose Congo red under visible light. Congo red was completely degraded after 0.5 h (0.5 g/L photocatalyst BiOI/Bi2S3/MIS-1) in the presence of visible light, which was 16.83 and 9.94 times of that of pure BiOI and MgIn2S4, respectively. A repetitive experiment showed that the BiOI/Bi2S3/MIS-1 could be reusable to degrade Congo red, demonstrating that it has excellent mechanical properties. The enhanced photocatalytic capability was due to addition of BiOI and Bi2S3, which increased the charge separation as well as suppressed the recombination of photo-induced holes and electrons. Electron paramagnetic resonance technique and free radical trapping tests were employed to determine the radicals produced in BiOI/Bi2S3/MgIn2S4 in the presence of visible light, indicating that ·O2− and h+ were major active species to decompose Congo red under photocatalytic process. Seventeen main intermediates or reaction products were identified by UPLC-MS. The tentative degradation pathway of Congo red was also proposed.
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References
Balakrishnan A, Appunni S, Chinthala M, Jacob MM, Vo D-VN, Reddy SS, Kunnel ES (2023a) Chitosan-based beads as sustainable adsorbents for wastewater remediation: a review. Environ Chem Lett 21(3):1881–1905. https://doi.org/10.1007/s10311-023-01563-9
Balakrishnan A, Appunni S, Chinthala M, Vo D-VN (2022) Biopolymer-supported TiO2 as a sustainable photocatalyst for wastewater treatment: a review. Environ Chem Lett 20(5):3071–3098. https://doi.org/10.1007/s10311-022-01443-8
Balakrishnan A, Chinthala M, Polagani RK, Vo D-VN (2023b) Removal of tetracycline from wastewater using g-C3N4 based photocatalysts: a review. Environ Res 216:114660. https://doi.org/10.1016/j.envres.2022.114660
Balakrishnan A, Gaware GJ, Chinthala M (2023c) Heterojunction photocatalysts for the removal of nitrophenol: a systematic review. Chemosphere 310:136853. https://doi.org/10.1016/j.chemosphere.2022.136853
Bariki R, Majhi D, Das K, Behera A, Mishra BG (2020) Facile synthesis and photocatalytic efficacy of UiO-66/CdIn2S4 nanocomposites with flowerlike 3D-microspheres towards aqueous phase decontamination of triclosan and H2 evolution. Appl Catal B Environ 270:118882. https://doi.org/10.1016/j.apcatb.2020.118882
Borth KW, Galdino CW, Teixeira V de C, Anaissi FJ (2021) Iron oxide nanoparticles obtained from steel waste recycling as a green alternative for Congo red dye fast adsorption. Appl Surf Sci 546:149126. https://doi.org/10.1016/j.apsusc.2021.149126
Chen D, Yang J, Zhu Y, Zhang Y, Zhu Y (2018) Fabrication of BiOI/graphene hydrogel/FTO photoelectrode with 3D porous architecture for the enhanced photoelectrocatalytic performance. Appl Catal B Environ 233:202–212. https://doi.org/10.1016/j.apcatb.2018.04.004
Chen X, Xu Z, Chen J, Yao L, Xie W, He J, Li N (2023) Continuous surface Z-Scheme and Schottky heterojunction Au/La2Ti2O7/Ag3PO4 catalyst with boosted charge separation through dual channels for excellent photocatalysis: highlight influence factors regulation and catalytic system applicability. Sep Purif Technol 312:123414. https://doi.org/10.1016/j.seppur.2023.123414
Chu Y, Miao B, Zheng X, Su H (2021) Fabrication of flower-globular Bi2WO6/BiOI@Ag3PO4 photocatalyst for the degradation of bisphenol A and cefepime under sunlight: photoelectric properties, degradation performance, mechanism and biodegradability enhancement. Sep Purif Technol 272:118866. https://doi.org/10.1016/j.seppur.2021.118866
Dolić SD, Jovanović DJ, Smits K, Babić B, Marinović-Cincović M, Porobić S, Dramićanin MD (2018) A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate. Ceram Int 44(15):17953–17961. https://doi.org/10.1016/j.ceramint.2018.06.272
Dong J, Hu J, Liu A, He J, Huang Q, Zeng Y, Gao W, Yang Z, Zhang Y, Zhou Y, Zou Z (2021) Simple fabrication of Z-scheme MgIn2S4/Bi2WO6 hierarchical heterostructures for enhancing photocatalytic reduction of Cr(VI). Catal Sci Technol 11(18):6271–6280. https://doi.org/10.1039/d1cy01178b
Guo J, Jiang L, Liang J, Xu W, Yu H, Zhang J, Ye S, Xing W, Yuan X (2021) Photocatalytic degradation of tetracycline antibiotics using delafossite silver ferrite-based Z-scheme photocatalyst: pathways and mechanism insight. Chemosphere 270:128651. https://doi.org/10.1016/j.chemosphere.2020.128651
Guo Y, Ao Y, Wang P, Wang C (2019) Mediator-free direct dual-Z-scheme Bi2S3/BiVO4/MgIn2S4 composite photocatalysts with enhanced visible-light-driven performance towards carbamazepine degradation. Appl Catal B Environ 254:479–490. https://doi.org/10.1016/j.apcatb.2019.04.031
Hamad MTMH, Saied MSS (2021) Kinetic studies of Congo red dye adsorption by immobilized Aspergillus niger on alginate. Appl Water Sci 11(2):35. https://doi.org/10.1007/s13201-021-01362-z
Han M, Wang S, Chen X, Liu H, Gao H, Zhao X, Wang F, Yang H, Yi Z, Fang L (2022) Spinel CuB2O4 (B = Fe, Cr, and Al) oxides for selective adsorption of congo red and photocatalytic removal of antibiotics. ACS Appl Nano Mater 5(8):11194–11207. https://doi.org/10.1021/acsanm.2c02349
Hu X, Wang J, Wang J, Deng Y, Zhang H, Xu T, Wang W (2022) β particles induced directional inward migration of oxygen vacancies: surface oxygen vacancies and interface oxygen vacancies synergistically activate PMS. Appl Catal B Environ 318:121879. https://doi.org/10.1016/j.apcatb.2022.121879
Huang X, Guo Q, Yan B, Liu H, Chen K, Wei S, Wu Y, Wang L (2021) Study on photocatalytic degradation of phenol by BiOI/Bi2WO6 layered heterojunction synthesized by hydrothermal method. J Mol Liq 322:114965. https://doi.org/10.1016/j.molliq.2020.114965
Iravani S (2022) Nanophotocatalysts against viruses and antibiotic-resistant bacteria: recent advances. Crit Rev Microbiol 48(1):67–82. https://doi.org/10.1080/1040841X.2021.1944053
Jabbar ZH, Okab AA, Graimed BH, Issa MA, Ammar SH (2023) Photocatalytic destruction of Congo red dye in wastewater using a novel Ag2WO4/Bi2S3 nanocomposite decorated g-C3N4 nanosheet as ternary S-scheme heterojunction: improving the charge transfer efficiency. Diam Relat Mater 133:109711. https://doi.org/10.1016/j.diamond.2023.109711
Jing L, Xu Y, Xie M, Liu J, Deng J, Huang L, Xu H, Li H (2019) Three dimensional polyaniline/MgIn2S4 nanoflower photocatalysts accelerated interfacial charge transfer for the photoreduction of Cr(VI), photodegradation of organic pollution and photocatalytic H2 production. Chem Eng J 360:1601–1612. https://doi.org/10.1016/j.cej.2018.10.214
KaviRasu K, Sakthivel P, Muthukrishnan P, PrasannaVenkatesan GKD (2021) Investigation on the structural and optical properties of Mn2+ doped MgS nanoparticles synthesized by hydrothermal method. Optik 225:165774. https://doi.org/10.1016/j.ijleo.2020.165774
Li T, Wang C, Wang T, Zhu L (2020) Highly efficient photocatalytic degradation toward perfluorooctanoic acid by bromine doped BiOI with high exposure of (001) facet. Appl Catal B Environ 268:118442. https://doi.org/10.1016/j.apcatb.2019.118442
Liang Q, Gao W, Liu C, Xu S, Li Z (2020) A novel 2D/1D core-shell heterostructures coupling MOF-derived iron oxides with ZnIn2S4 for enhanced photocatalytic activity. J Hazard Mater 392:122500. https://doi.org/10.1016/j.jhazmat.2020.122500
Lin X, Liu D, Guo X, Sun N, Zhao S, Chang L, Zhai H, Wang Q (2015) Fabrication and efficient visible light-induced photocatalytic activity of Bi2MoO6/BiPO4 composite. J Phys Chem Solids 76:170–177. https://doi.org/10.1016/j.jpcs.2014.09.002
Liu H, Niu C, Guo H, Liang C, Huang D, Zhang L, Yang Y-Y, Li L (2020a) In suit constructing 2D/1D MgIn2S4/CdS heterojunction system with enhanced photocatalytic activity towards treatment of wastewater and H2 production. J Colloid Interface Sci 576:264–279. https://doi.org/10.1016/j.jcis.2020.05.025
Liu Y, Chen P, Dai G, Su W, Sun Y, Hou J, Zhang N, Zhao G, Fang Y, Dai N (2020b) Single Bi2S3/Bi2S3-xOx nanowire photodetector with broadband response from ultraviolet to near-infrared range. Phys E Low-Dimens Syst Nanostructures 120:114041. https://doi.org/10.1016/j.physe.2020.114041
Luo J, Lin P, Zheng P, Zhou X, Ning X, Zhan L, Wu Z, Liu X, Zhou X (2022a) In suit constructing S-scheme FeOOH/MgIn2S4 heterojunction with boosted interfacial charge separation and redox activity for efficiently eliminating antibiotic pollutant. Chemosphere 298:134297. https://doi.org/10.1016/j.chemosphere.2022.134297
Luo L, Dong S, Chen H, Jin H, Huang T (2022b) Construction of MgIn2S4/ZnIn2S4 micro-flowers: efficient degradation of tetracycline hydrochloride over a wide pH range. Appl Surf Sci 581:152417. https://doi.org/10.1016/j.apsusc.2021.152417
Ma M, Lin Y, Maheskumar V, Li P, Li J, Wang Z, Zhang M, Jiang Z, Zhang R (2022) A highly efficient (Mo, N) codoped ZnIn2S4/g-C3N4 Z-scheme photocatalyst for the degradation of methylene blue. Appl Surf Sci 585:152607. https://doi.org/10.1016/j.apsusc.2022.152607
Mafa PJ, Kuvarega AT, Mamba BB, Ntsendwana B (2019) Photoelectrocatalytic degradation of sulfamethoxazole on g-C3N4/BiOI/EG p-n heterojunction photoanode under visible light irradiation. Appl Surf Sci 483:506–520. https://doi.org/10.1016/j.apsusc.2019.03.281
Mahendran V (2021) Degradation of acid scarlet 3R dye using oxidation strategies involving photocatalysis based on Fe doped TiO2 photocatalyst, ultrasound and hydrogen peroxide. Sep Purif Technol 274:119011. https://doi.org/10.1016/j.seppur.2021.119011
Meng L, Zhao C, Wang T, Chu H, Wang C-C (2023) Efficient ciprofloxacin removal over Z-scheme ZIF-67/V-BiOIO3 heterojunctions: insight into synergistic effect between adsorption and photocatalysis. Sep Purif Technol 313:123511. https://doi.org/10.1016/j.seppur.2023.123511
Monrós G, Llusar M, Badenes JA (2023) High NIR reflectance and photocatalytic ceramic pigments based on M-doped clinobisvanite BiVO4 (M = Ca, Cr) from gels. Materials 16(10):3722. https://doi.org/10.3390/ma16103722
Mulani SR, Bimli S, Choudhary E, Bunkar R, Kshirsagar UA, Devan RS (2023) Cationic and anionic cross-assisted synergistic photocatalytic removal of binary organic dye mixture using Ni-doped perovskite oxide. Chemosphere 340:139890. https://doi.org/10.1016/j.chemosphere.2023.139890
Naseem K, Farooqi ZH, Begum R, Irfan A (2018) Removal of Congo red dye from aqueous medium by its catalytic reduction using sodium borohydride in the presence of various inorganic nano-catalysts: a review. J Clean Prod 187:296–307. https://doi.org/10.1016/j.jclepro.2018.03.209
Nguyen MB, Le GH, Nguyen TD, Nguyen QK, Pham TTT, Lee T, Vu TA (2021) Bimetallic Ag-Zn-BTC/GO composite as highly efficient photocatalyst in the photocatalytic degradation of reactive yellow 145 dye in water. J Hazard Mater 420:126560. https://doi.org/10.1016/j.jhazmat.2021.126560
Qi K, Song M, Xie X, Wen Y, Wang Z, Wei B, Wang Z (2022) CQDs/biochar from reed straw modified Z-scheme MgIn2S4/BiOCl with enhanced visible-light photocatalytic performance for carbamazepine degradation in water. Chemosphere 287:132192. https://doi.org/10.1016/j.chemosphere.2021.132192
Sankararamakrishnan N, Shankhwar A, Chauhan D (2019) Mechanistic insights on immobilization and decontamination of hexavalent chromium onto nano MgS/FeS doped cellulose nanofibres. Chemosphere 228:390–397. https://doi.org/10.1016/j.chemosphere.2019.04.166
Saura-Múzquiz M, Marlton FP, Mullens BG, Liu J, Vogt T, Maynard-Casely HE, Avdeev M, Blom DA, Kennedy BJ (2023) Cation and lone pair order–disorder in the polymorphic mixed metal bismuth scheelite Bi3FeMo2O12. Chem Mater 35(1):123–135. https://doi.org/10.1021/acs.chemmater.2c02740
Shaheen N, Yousuf MA, Shakir I, Zulfiqar S, Agboola PO, Warsi MF (2020) Wet chemical route synthesis of spinel oxide nano-catalysts for photocatalytic applications. Phys B Condens Matter 580:411820. https://doi.org/10.1016/j.physb.2019.411820
Sharma G, Kumar A, Naushad Mu, Thakur B, Vo D-VN, Gao B, Al-Kahtani AA, Stadler FJ (2021) Adsorptional-photocatalytic removal of fast sulphon black dye by using chitin-cl-poly(itaconic acid-co-acrylamide)/ zirconium tungstate nanocomposite hydrogel. J Hazard Mater 416:125714. https://doi.org/10.1016/j.jhazmat.2021.125714
Sun H, Zou C, Liao Y, Tang W, Huang Y, Chen M (2023) Modulating charge transport behavior across the interface via g-C3N4 surface discrete modified BiOI and Bi2MoO6 for efficient photodegradation of glyphosate. J Alloys Compd 935:168208. https://doi.org/10.1016/j.jallcom.2022.168208
Swain G, Sultana S, Parida K (2020) Constructing a novel surfactant-free MoS2 nanosheet modified MgIn2S4 marigold microflower: an efficient visible-light driven 2D–2D p-n heterojunction photocatalyst toward HER and pH regulated NRR. ACS Sustain Chem Eng 8(12):4848–4862. https://doi.org/10.1021/acssuschemeng.9b07821
Tian L, Yang X, Cui X, Liu Q, Tang H (2019) Fabrication of dual direct Z-scheme g-C3N4/MoS2/Ag3PO4 photocatalyst and its oxygen evolution performance. Appl Surf Sci 463:9–17. https://doi.org/10.1016/j.apsusc.2018.08.209
Uddin F (2021) Environmental hazard in textile dyeing wastewater from local textile industry. Cellulose 28(17):10715–10739. https://doi.org/10.1007/s10570-021-04228-4
Wang M, Han J, Lv C, Zhang Y, You M, Liu T, Li S, Zhu T (2018a) Ag, B, and Eu tri-modified BiVO4 photocatalysts with enhanced photocatalytic performance under visible-light irradiation. J Alloys Compd 753:465–474. https://doi.org/10.1016/j.jallcom.2018.04.068
Wang P, Zhong S, Lin M, Lin C, Lin T, Gao M, Zhao C, Li X, Wu X (2022) Signally enhanced piezo-photocatalysis of Bi0.5Na0.5TiO3/MWCNTs composite for degradation of rhodamine B. Chemosphere 308:136596. https://doi.org/10.1016/j.chemosphere.2022.136596
Wang Q, Yuan Y, Li C, Zhang Z, Xia C, Pan W, Guo R (2023) Research progress on photocatalytic CO2 reduction based on perovskite oxides. Small 2301892. https://doi.org/10.1002/smll.202301892
Wang Y, Jiang S, Liu F, Zhao C, Zhao D, Li X (2019) Study on preparation and toluene removal of BiOI/Bi2WO6/ACF photocatalyst. Appl Surf Sci 488:161–169. https://doi.org/10.1016/j.apsusc.2019.05.228
Wang Y, Jin J, Chu W, Cahen D, He T (2018b) Synergistic effect of charge generation and separation in epitaxially grown BiOCl/Bi2S3 nano-heterostructure. ACS Appl Mater Interfaces 10(17):15304–15313. https://doi.org/10.1021/acsami.8b03390
Wu L, Han T, Zhang M, Gao L, Yang Z, Ding N, Jin J (2022a) Spinel-type ferrites decorated ZnO for enhanced photoelectrochemical water splitting. Opt Mater 129:112451. https://doi.org/10.1016/j.optmat.2022.112451
Wu Z, Jing J, Zhang K, Li W, Yang J, Shen J, Zhang S, Xu K, Zhang S, Zhu Y (2022b) Epitaxial BiP5O14 layer on BiOI nanosheets enhancing the photocatalytic degradation of phenol via interfacial internal-electric-field. Appl Catal B Environ 307:121153. https://doi.org/10.1016/j.apcatb.2022.121153
Xia Y, Cheng B, Fan J, Yu J, Liu G (2020) Near-infrared absorbing 2D/3D ZnIn2S4/N-doped graphene photocatalyst for highly efficient CO2 capture and photocatalytic reduction. Sci China Mater 63(4):552–565. https://doi.org/10.1007/s40843-019-1234-x
Xin S, Liu G, Ma X, Gong J, Ma B, Yan Q, Chen Q, Ma D, Zhang G, Gao M, Xin Y (2021) High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO2 for the degradation of tetracycline: economical synthesis, catalytic performance and mechanism. Appl Catal B Environ 280:119386. https://doi.org/10.1016/j.apcatb.2020.119386
Xu S, Dai J, Yang J, You J, Hao J (2018) Facile synthesis of novel CaIn2S4/ZnIn2S4 composites with efficient performance for photocatalytic reduction of Cr(VI) under simulated sunlight irradiation. Nanomaterials 8(7):472. https://doi.org/10.3390/nano8070472
Xu X, Meng L, Luo J, Zhang M, Wang Y, Dai Y, Sun C, Wang Z, Yang S, He H, Wang S (2021) Self-assembled ultrathin CoO/Bi quantum dots/defective Bi2MoO6 hollow Z-scheme heterojunction for visible light-driven degradation of diazinon in water matrix: intermediate toxicity and photocatalytic mechanism. Appl Catal B Environ 293:120231. https://doi.org/10.1016/j.apcatb.2021.120231
Yamashita H, Mori K, Kuwahara Y, Kamegawa T, Wen M, Verma P, Che M (2018) Single-site and nano-confined photocatalysts designed in porous materials for environmental uses and solar fuels. Chem Soc Rev 47(22):8072–8096. https://doi.org/10.1039/C8CS00341F
Yang B, Lv K, Li Q, Fan J, Li M (2019) Photosensitization of Bi2O2CO3 nanoplates with amorphous Bi2S3 to improve the visible photoreactivity towards NO oxidation. Appl Surf Sci 495:143561. https://doi.org/10.1016/j.apsusc.2019.143561
Yang W, Dong Y, Wang Z, Li Y, Dai C, Ma D, Jia Y, Yang Z, Zeng C (2021) Synthesis, characterization, and photocatalytic activity of stannum-doped MgIn2S4 microspheres. J Alloys Compd 860:158446. https://doi.org/10.1016/j.jallcom.2020.158446
Yin H, Fan T, Cao Y, Li P, Yao X, Liu X (2021) Construction of three-dimensional MgIn2S4 nanoflowers/two-dimensional oxygen-doped g-C3N4 nanosheets direct Z-scheme heterojunctions for efficient Cr(VI) reduction: insight into the role of superoxide radicals. J Hazard Mater 420:126567. https://doi.org/10.1016/j.jhazmat.2021.126567
Yu H, Jiang L, Wang H, Huang B, Yuan X, Huang J, Zhang J, Zeng G (2019) Modulation of Bi2MoO6‐based materials for photocatalytic water splitting and environmental application: a critical review. Small 1901008. https://doi.org/10.1002/smll.201901008
Yu J, Yan P, Chen F, Jin S, Xu X, Qian J (2023) MgIn2S4@In2O3 hierarchical tubular heterostructures with expedited photocarrier separation for efficient visible-light-driven antimicrobial activity. Chem Eng J 452:139559. https://doi.org/10.1016/j.cej.2022.139559
Zeng C, Zeng Q, Dai C, Zhang L, Hu Y (2021) Synergistic effect of surface coated and bulk doped carbon on enhancing photocatalytic CO2 reduction for MgIn2S4 microflowers. Appl Surf Sci 542:148686. https://doi.org/10.1016/j.apsusc.2020.148686
Zhang C, Fei W, Wang H, Li N, Chen D, Xu Q, Li H, He J, Lu J (2020) p-n Heterojunction of BiOI/ZnO nanorod arrays for piezo-photocatalytic degradation of bisphenol A in water. J Hazard Mater 399:123109. https://doi.org/10.1016/j.jhazmat.2020.123109
Zhang H, Liu Y, Liu H, Yin J, Shi L, Tang H (2023) Surface anchoring of nickel sulfide clusters as active sites and cocatalysts for photocatalytic antibiotic degradation and bacterial inactivation. J Colloid Interface Sci 637:421–430. https://doi.org/10.1016/j.jcis.2023.01.109
Zhang Z, Guo R, Tang J, Miao Y, Gu J, Pan W (2021) Fabrication of Bi-BiOCl/MgIn2S4 heterostructure with step-scheme mechanism for carbon dioxide photoreduction into methane. J CO2 Util 45:101453. https://doi.org/10.1016/j.jcou.2021.101453
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This work was supported by Hei Long Jiang Postdoctoral Foundation (LBH-Z21085) and the Fundamental Research Funds for the Central Universities (2572022BA09).
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Borui Li: writing — original draft, investigation; Xingze Zhao: methodology; Yajie Huang: software; Xiaohui Lu: resources; Hao Jia: validation; Ming Li: supervision, conceptualization, reviewing, and editing.
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Li, B., Zhao, X., Huang, Y. et al. Dual Z-scheme BiOI/Bi2S3/MgIn2S4 composite photocatalyst for effective photocatalytic degradation of Congo red. Environ Sci Pollut Res 30, 122537–122549 (2023). https://doi.org/10.1007/s11356-023-30909-7
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DOI: https://doi.org/10.1007/s11356-023-30909-7