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Graphene oxide-incorporated silver-based photocatalysts for enhanced degradation of organic toxins: a review

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Abstract

Environmental contamination and scarcity of energy have been deepening over the last few decades. Heterogeneous photocatalysis plays a prominent role in environmental remediation. The failure of earlier metal oxide systems like pure TiO2 and ZnO as stable visible-light photocatalysts demanded more stable catalysts with high photodegradation efficiency. Silver-based semiconductor materials gained popularity as visible-light-responsive photocatalysts with a narrow bandgap. But their large-scale usage in natural water bodies for organic contaminant removal is minimal. The factors like self-photocorrosion and their slight solubility in water have prevented the commercial use. Various efforts have been made to improve their photocatalytic activity. This review focuses on those studies in which silver-based semiconductor materials are integrated with carbonaceous graphene oxide (GO) and reduced graphene oxide (RGO). The decoration of Ag-based semiconductor components on graphene oxide having high-surface area results in binary composites with enhanced visible-light photocatalytic activity and stability. It is found that the introduction of new efficient materials further increases the effectiveness of the system. So binary and ternary composites of GO and Ag-based materials are reviewed in this paper.

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JM contributed in the conceptualization, resources, as well as writing the original draft. NJ participated in data curation and visualization. BM contributed in the conceptualization, supervision, review, and editing of manuscript. All the authors actively participated in the reading and approval of final manuscript.

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Correspondence to Beena Mathew.

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The authors declare no competing interests.

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Mathew, J., John, N. & Mathew, B. Graphene oxide-incorporated silver-based photocatalysts for enhanced degradation of organic toxins: a review. Environ Sci Pollut Res 30, 16817–16851 (2023). https://doi.org/10.1007/s11356-022-25026-w

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  • DOI: https://doi.org/10.1007/s11356-022-25026-w

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