Characterisation of the Contaminants Generated from a Large-Scale Ex-Situ Underground Coal Gasification Study Using High-Rank Coal from the South Wales Coalfield

This paper presents an analysis of contaminants generated from large-scale, laboratory-based, underground coal gasification (UCG) experiments using a high-rank coal from the South Wales Coalfield. The experiments were performed at atmospheric and elevated pressures (30 bar) by varying the oxidants’ composition. The experiments were designed to predict the amount of produced water and contaminants generated at each stage of the operating conditions. The mass balance of water supplied and produced in the experiments was accounted for. Chemical analyses of produced water, char and ash contents were performed to quantify the inorganic and organic chemical parameters. Most of the contaminant concentrations in the produced water from the 30-bar pressure experiment were lower than the concentrations generated from the atmospheric pressure experiment. The measured concentrations of the inorganic chemical species and the inorganic parameters of the coal seam water from the South Wales Coalfield were used in theoretical calculations to predict the dominant equilibrium species concentrations in a hypothetical scenario of effluent contaminated groundwater. The biodegradation of organic contaminants such as phenol, benzene and sorbed fractions of inorganic contaminants from the produced water on iron oxide in the ash residue was predicted using existing biotransformation kinetics and surface complexation models, respectively. The biodegradation of phenol and benzene would be a slow process even at optimum conditions and the iron oxide left in the cavity can act as a sorbent for a few inorganic species. The evidence from the present study suggests future work towards (i) developing an appropriate water treatment process during gas cleaning, (ii) operational procedure (pressure and proportions of oxidant) and (iii) developing UCG-specific experimental prediction of contaminant transportation and transformation kinetics. Graphical abstract Graphical abstract


Introduction
Underground coal gasification (UCG) is a process through which gasification of coal is carried out underground within geological strata. It is similar to surface gasification, but the air, oxygen and steam are injected through boreholes to gasify the coal and the produced gas is recovered through a production well. UCG is gaining attention in many countries due to the economic and processing benefits. However, gasification of coal underground may pose a threat to groundwater. Also, treatment and disposal of effluent generated during the gas cleaning process needs to be considered. Gasification releases organic contaminants such as phenol, benzene, toluene, ethyl benzene, xylene (BTEX) and polycyclic aromatic hydrocarbons (PAH) along with inorganic metals, metalloids, non-metal and anionic compounds.
Many previous studies have been carried out to qualitatively and quantitatively measure the amount and type of contaminants produced from various coal samples (Campbell et al. 1979;Liu et al. 2007; Kapusta and Stańczyk 2011;Kapusta et al. 2013). The present work focuses on contaminants generated from a high-rank coal from the South Wales Coalfield (UK) to study the possible environmental impact of conducting UCG in geological settings hosting carbon-rich coals.
Groundwater pollution is considered to be the most serious possible negative environmental impact of UCG. It can be caused by gases escaping from the reactor through fractures and condensing in the cooler parts of the subsurface and then dissolving in groundwater (Stephens 1981;Wang et al. 1982; Dames and Moore 1996;Humenick and Novak 1978). Hence, there is a need to study contaminant generation at varying experimental conditions. Early UCG trials at Hoe Creek (Humenick and Mattox 1978) and European pilot plant studies (Creedy et al. 2001) provide limited information in the context of operational procedures related to contaminant generation. A monitoring programme at an UCG trial site in Australia reported contaminants measured in soil vapour and groundwater. Although there were significant reductions in the contaminations over the years after the site was closed, reports generated during the monitoring showed evidence for the contaminants' dispersion to the subsurface and identified unexpected levels of hydrogen in the top soils of the adjacent farm fields (Australian governments environmental protection order 2016 ;Gemmell 2016). This indicates the possibility of gas escape to the subsurface. The operational procedures of the Australian example, which was performed at shallow depth (200 m), were unknown and the example does not provide a way forward. It is assumed the UCG operations were carried out at lower pressure than the hydrostatic pressures of the surrounding strata to avoid the contaminants escape (Blinderman and Jones 2002). Despite following the best process practices, some concentrations of pollutants in groundwater have been reported (Gemmell 2016). It should be noted that the process was conducted at a relatively shallow depth (< 150 m), and the probability of groundwater contamination decreases with increasing depth of UCG.
The deepest known operation so far was Swan Hills (1400 m) trial but offers limited or no information on quantitative/qualitative measurement of groundwater or produced water quality and baseline environmental site characterisation (Swan Hills Synfuels 2012; AER 2014).The deep coal seam operations at El Tremedal, Spain (550 m), showed no impact on the groundwaters. However, the water ingression to the cavity was an issue at El Tremedal, which generated wastewater with considerable amounts of phenols, ammonia, sulphurs and conductivity, and COD and was characterised as toxic water (Sury et al. 2004). Hence, it is necessary to monitor the produced water and groundwater, and the current study is intended to study the produced water constitutions and predict the impact on an existing coal seam groundwater from 600 m depth.
Groundwater pollution studies were conducted during a UCG trial at mine Barbara, Poland, where the contaminants were monitored during the gasification process and after gasification for 200 days (Kapusta et al. 2013). A short-range and short-term impact of the UCG trial on groundwater was observed. Highly water-soluble specimens, including phenols, ammonia, cyanides and selected metal ions, were the dominant and the most mobile pollutants. It was also assumed that the possibility of naturally occurring self-restoration processes through dispersion, adsorption and degradation of the organic contaminants were the reasons for the decreasing level of contaminants measured over the monitoring period. Not only the escaping contaminants from the cavity pose a threat to groundwater but the solid ash, char and tar left in the cavity would also be leached out by the groundwater (Kapusta et al. 2013;Covell and Thomas 1996).
There are discussions to utilise un-minable coal through UCG (Geology and Regional Geophysics Commissioned Report 2013), but the technological aspects and environmental impact of performing UCG on a regional geological setting are unknown. The present study explores first-hand information on contaminants generated by a high-rank coal sample from the South Wales Coalfield in a large-scale ex situ UCG experiment. The inorganic contaminants are equilibrated with coal seam water from the South Wales Coalfield to understand the dominant species concentrations. The study also discusses the possible scenario of the post-UCG natural restoration process by biodegradation of organic contaminants such as phenol and benzene. Table 1 shows the results of proximate, ultimate and petrographic composition analyses of the coal specimen which indicates that the coal sample can be classified as high-rank semi-anthracite (ASTM D388-18a, 2018, ASTM D7582-15, 2015, ASTM D3176-15, 2015.

Experimental Aspects of Ex Situ UCG Test
The laboratory-scale UCG simulations were conducted at large-scale laboratory facilities of the Central Mining Institute's Clean Coal Technology Centre located in Mikołów, Poland. The experimental set up was as described in Stańczyk (2011), Wiatowski et al. (2019) and Zagorščak et al. (2020) (Fig. 1). Two artificial coal seams (size = 3.05 m × 0.41 m × 0.41 m, mass = 648 kg (atmospheric test) and 650 kg (30 bar pressure test) were prepared using 5 blocks of coal (Zagorščak et al. 2020). Two separate gasification experiments, one at atmospheric pressure and other at 30 bar pressure, were performed. Each experiment consisted of 6 gasification stages and one extinguishing stage. During the gasification stages, the following reagents were used: oxygen, air and oxygen enriched ear (OEA). In the extinguishing stage, nitrogen was used as inertising medium. Water was supplied to the reactor by means of a high-pressure piston pump, while its quantity was measured with a water meter installed in front of the pump (accuracy ± 2%). Gases were supplied from gas cylinders using mass flow controllers (MFC) with accuracy of ± 2%. The UCG simulation experiments were conducted for 105 h each. The experimental conditions, including the reagent supply rates, in different stages of the atmospheric and highpressure UCG experiments are presented in Table 2. The detailed interpretation of the experimental results is presented in Zagorščak et al. (2020). The UCG effluents were periodically sampled during the gasification tests from the water scrubber (see Fig. 1). The scrubber was employed to quench and clean the raw UCG gas. The water was supplied to the scrubber, at a rate of 18 kg/h. The amount of water supplied into the scrubber and the amount of water supplied into the reactor during each stage of the experiments were accounted for in the water mass balance and presented in Table 2. The total quantities of produced effluents depend on the amount of water used in the scrubber, water supplied as the gasification reagent, pyrolytic water generated in the pyrolysis zone of the reactor and water produced via combustion of hydrogen. The amounts of produced water condensates were determined by the weight method with an accuracy of ± 2 kg. The effluents from stage 1 and stage 2 were collected separately and labelled S1 and S2, respectively. The effluents produced at stage 3 to stage 6 were averaged together, labelled as 'S3 to S6' for the atmospheric test and analysed as a one sample. Similarly, the effluents collected from the highpressure test were labelled as 30S1, 30S2 and '30S3 to 30S6'. The collected water samples were filtered to remove the coal tar and undissolved residues and stored at 4°C until chemical characterisation was conducted. The solid residues from the gasification were collected at the end of the experiments for inorganic chemical analysis.
Chemical analyses of the UCG produced water were performed as described in the standard analytical chemistry methods. Electrochemical methods such as potentiometry and conductometry were employed to determine the pH and the conductivity of produced water, respectively. The biological oxygen demand (BOD) and chemical oxygen demand (COD) were The 15 polycyclic aromatic hydrocarbons (PAHs) were determined using solid-phase extraction (SPE) on ENVI-C18 cartridges purchased from Supelco (St Louis, MO, USA) followed by high-performance liquid chromatography (HPLC) using an Agilent Technologies HPLC 1200 Series. An Agilent Technologies 7890A gas chromatography coupled with a static headspace auto sampler Agilent 7697A and FID detector was used to measure the benzene and its derivatives (BTEX). The gas chromatography was configured with a DB-5MS column (30 m, 0.25 mm, 0.5 μm) and helium was used as the carrier gas at 1.0 ml/min. The split ratio was 1:30. Oven program temperature was 40°C (hold 3 min), rate 15°C/min up to 200°C (hold 9 min). Temperature of FID detector was 300°C. The post gasification residues (char and ash) were collected at different locations in the reactor. The post gasification ash specimen was  collected at approximately 0.4 m from the inlet. The char specimens were collected at approximately 1 m, 2 m and 3 m (Fig. 2c). The major and minor elemental composition analysis was carried out as per the procedure described in ISO/TS 13605: 2012 using an X-ray fluorescence spectrometry.
2.2 Analysis of Produced Water Using Geochemist's Work Bench (GWB) Geochemist's work bench (GWB), a computer application software, was used to analyse equilibrium species concentration, Monod degradation kinetics of organic contaminants and sorbed fractions of chemical species on iron oxide surface (Bethke 2007). The GWB application was employed in the study to predict the equilibrium species and trace the biodegradation reactions that happen immediately after the contaminants contact with groundwater. (i) Inorganic chemical species in produced watergroundwater system: The measured concentrations from the produced water (C1 from Table 3) and the groundwater matrix procured from a coal seam located at 600 m depth in the South Wales Coalfield were used to describe the theoretical composition of contaminated groundwater. The major ions in the coal seam aquifer; Na = 540 mg/L, K = 10.03 mg/L, Mg = 1.29 mg/L and Ca = 2.87 mg/L and dissolved oxygen = 2.25 mg/L (Sadasivam et al. 2019) and the contaminant concentrations in the sample C1 were assumed to be in 1 kg of groundwater. The React programme from GWB was used to input the above concentrations and set the temperature constrain at 20°C, as the temperature range of the coal seam water was 20-22°C around 600 m depth. The programme was run at different pH values using the 'slide pH' option of React programme to predict the equilibrium species.
(ii) Sorbed species on iron oxide surfaces: The ash produced in the cavity consist of 18% Fe and considering the temperature exposure and oxygen availability, the iron must be in haematite form. In the event of cavity flooding, the haematite in the ash reacts with the groundwater. The iron oxide left in the cavity could retain the inorganic species by surface complexation. In the calculations, it is assumed that 5 g of haematite is dispersed in 1 kg of UCG contaminant laden groundwater (C1 + coal seam water from Section 2.2 (i)). Data file FeOH+.dat from GWB dataset, which includes the surface complexation reaction dataset (Dzombak and Morel 1990), was used in the React programme to predict the sorbed fractions of the species of As, B, Co, Cr, Cu, Ni, Pb and Se at varying pH values. Surface complexation model was used in the study as the theory includes electrolytic sorption, hydrolysis, the mineral surface, electric charge on the surface and mass balance unlike the distribution coefficient (k d ) and Freundlich approach which predict that the surface can adsorb without limits. (iii) Biodegradation of phenol and benzene: the concentrations of inorganic constitutions from sample C1 (Table 3), phenol and benzene concentrations from C3 (Table 7) were used in the description of 1 kg mass of hypothetical water in the React programme. The benzene and phenol degradation by microorganisms with sufficient nutrition can be represented by reactions;  Alvarez et al. (1991) and Appelo and Postma (1993) were used to trace the biodegradation process of benzene and phenol.

Water Balance during the UCG Experiments
The amount of water fed into the system was compared with the water collected from the condensation. The raw UCG gas contains water vapour which is loaded with inorganic and organic contaminants. The water vapour condensates along with the contaminants in the cooler parts of the UCG installation. Monitoring the water balance gives insight into the amount of water produced at various stages of gasification and the overall impact on the groundwater environment and the process to treat the water used for cleaning the gas. The total mass of water supplied to the reactor was 107.5 kg (95 kg at stage 2 and 12.5 kg at stage 6). The mass of water supplied to the scrubber was 1890 kg during the entire process. Hence, the total mass of water used in each experiment was 1997.5 kg. The masses of water collected from the condenser during the atmospheric and 30 bar pressure experiments were 2002 kg and 1985 kg, respectively. Considering the ± 2 kg of measurement error, the overall water mass balances were retained during the gasification experiments. The negative values in stage 2 (S2-oxygen/water) for both experiments (Table 2) resulted from water consumption in the gasification process. The water consumption at this stage (S2) supported more methane producing reactions where oxygen and steam were used as oxidants.

Inorganic Parameters of UCG Produced Water and Ash
The results from the analysis show that the values of measured physicochemical parameters significantly varied over the time in the experiments. These variations reflected changes in the gasification conditions (temperature) and development of oxidation and pyrolysis zones during the experiments. There were considerable differences between the contaminant concentrations generated during the atmospheric and 30 bar pressure conditions (Table 3). The average pH of condensate collected during the experiment conducted under atmospheric pressure conditions was around 7. The produced water collected during the pressurised experiments showed pH ranging from acidic (pH = 4.6, 30S1, Table 3) to alkaline (pH = 8.3, 30S3 to 30S6, Table 3). The electric conductivities measured during the atmospheric conditions (3.63 mS/cm to 8.9 mS/cm) were higher than during the pressurised conditions (1.02 mS/cm to 2.76 mS/cm). The electric conductivity of the condensates has been reported as high as 19.2 mS/ cm (Kapusta and Stańczyk 2011). The produced water generated during the high pressure (30 bar) experiment exhibited comparatively lower concentrations of COD, B, Ni, As, Cl − , NH 3 (aq) , SO 4 2− and CN − than during the atmospheric conditions. The varying pH of the  condensate at high-pressure stages had an influence on the metal ions such as Zn, which is relatively higher in stage S1. Trace elements such as Sb and Se were also found in the condensates at maximum concentration levels of 0.39 mg/L. Most of the measured concentration levels exceed the legal limits for disposal. For example, the BOD, COD and ammonia nitrogen concentrations were much higher than the legal limits (BOD = 50 mg/L O 2 and 250 mg/L O 2 : Urban Wastewater Treatment (England and Wales) Regulations 1994). So appropriate treatment methods need to be explored to treat the effluent generated by cleaning the gas. The samples C1 (for atmospheric experiments) and C2 (for high-pressure experiments) in Table 3 show the calculated concentrations. The calculation was carried out by theoretically mixing the samples at appropriate mass ratios as described in Hounslow (1995). For example, S1, S2 and S3 to S6 were mixed at the proportions of 545 kg:773 kg:684 kg. The concentration levels of contamination presented in this work were measured in the produced water (water injected + water used for cleaning the gas). Under the relevant assumption that the similar level of concentrations can escape through fissures and end up in groundwater, the concentrations from the experiments were used to calculate the equilibrium species concentrations in the event of contaminants ending up in the groundwaters found in the deep coal seams. The concentrations of the species in sample C1 and a ≅ 600 m deep coal seam water from the South Wales Coalfield (concentrations of major ions in the coal seam aquifer: Na = 540 mg/L, K = 10.03 mg/L, Mg = 1.29 mg/ L and Ca = 2.87 mg/L, dissolved oxygen = 2.25 mg/L; Sadasivam et al. 2019) were used in the calculation to predict the dominant species (GWB method has been provided in the supplementary information). Table 4 shows the main aqueous species and concentrations of NH + 4 , F − , Cl − , CN − , SO 4 2− , Fe 2+ , Al 3+ , Mn 2+ , As, Ni, Pb, Sb (OH) 3 and SeO 3 2− at pH values of 3, 7 and 11. For example, most of the ammonium species would disassociate to release N 2(aq) and the toxic HCN − would be the more dominant cyanide species at neutral pH values and below. The dominant species along with the overburden  geology must be studied experimentally for their transportation and bio-geo-transformation to understand their natural restoration process. Figure 2 shows the images of both ends of the coal seam after the experiment, demonstrating that the coal has been almost entirely gasified near the inlet, while a substantial amount of unreacted char was left near the outlet of the reactor. Table 5 shows the elemental composition of the raw coal, ash and char samples taken from different locations of the reactor during the atmospheric and elevated (30 bar) pressure experiments (Fig. 2). Al, Fe, K and Ti were the major constituents of the ash and char ( Table 5). The inorganic elements, which are usually influenced by the groundwater pH, were predominant in the ash. The iron content in the ash was around 18%. The concentrations of chemical species indicate that the ash and char left in the cavity might be a source of secondary contaminations or can act as an adsorbent for the other inorganics species that have an affinity towards iron oxide surfaces. The iron left in the reactor or in the UCG cavity might be in the form of haematite due to the exposure of the elevated temperature. So, a theoretical ratio of 5 g of haematite to 1 kg of water was used to predict the sorbed fractions for the species of arsenic, boron, calcium, cobalt, chromium, copper, nickel, lead and selenium. The surface complexation reactions from Dzombak and Morel (1990) along with the extended database from GWB application software were used to predict the sorbed fractions. The sorbed fractions of chemical species on the iron hydroxide surfaces at various pH are shown in Fig. 3 (GWB method has been provided in Section 2.2 (ii) and supplementary information). The oxyanion of arsenic showed the maximum adsorption in between pH values of 6 and 9.5. The sorption behaviour of oxyanions of arsenic and selenium can be explained by the specific adsorption of the ligands at the FeOH + and FeOH 0 sites. The high sorption of oxyanions above the point of zero net proton charge of haematite (pH ≅ 8.5) can be explained by their covalent nature of the sorption. The selenite ions would be retained on the iron oxide surface as ligands by replacing the hydroxyl ions at lower pH values. Chromate ion sorption shows the pattern of chromate ions binding on the already sorbed cations and anions whereas other cations such as Cu, Ni and Pb show the pattern of specific sorption by deprotonating the surface hydroxyl group (Zelazny et al. 2018;Su and Suarez 2000;Cornell and Schwertmann 2004). Table 6 shows a quantitative evaluation of the sorption pattern showed in Fig. 3. At pH values around 4, As(OH) 4 concentration in the original fluid was 2.25 × 10 −3 moles. After equilibrating with the haematite mineral 2.17 × 10 −3 moles were adsorbed on the weak surfaces (w) as FeOHAsOH 3− (1.1 × 10 −3 moles), FeHAsO 4 − (8.9 × 10 −4 moles) and FeH 2 AsO 4 (1.7 × 10 −4 moles). The B(OH) 3 with an initial concentration of 5.5 × 10 −5 moles were adsorbed as FeH 2 BO 3 (3.39 × 10 −7 moles) at pH values around 4. Arsenic showed similar pattern at pH values around 8.3, but the boron sorption reduced (adsorbed as B(OH) 3 = 9.7 × 10 −7 moles) as the positive charge sites originated from the protonated surfaces started disappearing at pH values around 8. Similarly, nickel and copper quantitative sorbed fractions were presented in Table 1. At pH 4, 3.2 × 10 −7 moles of Ni would be retained on the strong surfaces (s) as FeONi + . The sorbed fraction increases as the pH increases to 8.3 where 1.8 × 10 −3 moles would be retained out of 2.04 × 10 −4 moles of initial nickel concentration. The copper sorption showed similar pattern as the strong surfaces increases as the pH increases.

Organic Chemical Parameters of UCG Produced Water
Organic contaminants are the major concern during the UCG operations. The phenolic compounds, benzene, toluene, ethyl benzene and polynuclear aromatic hydrocarbons (PAHs) were regularly found in the condensates collected during the trial runs. The organic contaminants generated at various stages of the experiments were presented in Table 7. The concentration levels of phenol, BTEX and PAHs in the condensate generated at high-pressure experiments were comparatively lower than the atmospheric experiments (Table 7 and Fig. 4a-d). This can be attributed to the intensification of cracking phenomena under elevated pressure which led to the formation of lower molecular weight organic compounds, e.g. aliphatic hydrocarbons. The concentrations of organic contaminants were much higher than the desirable/threshold concentration levels in the groundwater. Previous studies reported that the adsorption and biological degradation were the dominating natural restoration mechanisms of organic contaminates in the groundwater. For instance , Bekins et.al. (1998) observed in a laboratory experiment with methanogens that phenol in the groundwater degraded over a period of time. The degradation reaction can be written as C 6 H 5 OH aq ð Þ þ 13 2 H 2 O→ 7 2 CH 4 aq ð Þ þ 5 2 HCO − 3 þ 5 2 H þ and phenol dismutate as methane and bicarbonate. The data from a previous gas working site also showed that the low concentrations of BTEX have undergone the biological degradation pathway (Appelo and Postma 1993). Possible biological degradation has previously been studied and evaluated by Monod biotransformation kinetics [( dS dt ¼ −K max S k1 2 þS , Sconcentration of contaminant (mg/L), t-is time (s or days), k1 2half saturation constant (mg/L) and K maxmaximum rate constant (mg/L/s)]. The values of Monod kinetic parameters presented in the previous studies were used in the present study to predict the degradation of phenol (K max = 1.4 mg phenol/L/day, k1 2 = 1.8 mg phenol/L and molality of enzyme activity was assumed to be at 1) and benzene (K max = 5.5 × 10 −5 s −1 , k1 2 = 2.2 mol of benzene/ L and molality of enzyme activity was assumed at 0.001). (Alvarez et al. 1991;Appelo and Postma 1993). Concentrations of major ions from a ≅ 600 m deep coal seam aquifer, inorganic constitutions from sample C1 (Table 3), phenol and benzene concentrations from C3 (Table 7) were used in the calculations to develop the hypothetical groundwater (See the supplementary information for GWB method and Section 2.2 (iii)). The results show that the possible microbial enhanced natural degradation process reduces the phenol concentration exponentially in 45 days in presence of microbes (Fig. 4e). As the degradation process takes longer even at optimum conditions, the migration and transformation process without or along with enzyme activity needs to be studied. For benzene, the degradation process takes much longer and seems exponential for the literature values provided for the enzyme activity (Fig. 4f). So, the transport and natural restoration of organic contaminations must be studied experimentally at laboratory scale in the framework of UCG.

Conclusions
This study provided a comprehensive understanding of the quantitative aspects of water balance, contaminant generation at various experimental conditions and their fate in the groundwater environment in the context of UCG using high-rank coal. Based on the results obtained, the following conclusions can be made: i). UCG operational procedures play a major role in contaminants' generation. The overall water balances were maintained during the oxygen, air and OEA driven gasification experiments, both under atmospheric and high-pressure conditions. This suggests that small or negligible amount of condensate may be produced under such conditions, owing to the limited water content of the high-rank coal. Where oxygen and steam were used as oxidants under high-pressure regime, conditions that support high methane generation were established resulting in negative water balance. ii). Maintaining high operating pressure would influence and prevent high-level contaminant generation. The contaminants generated were moderately low in concentrations during the 30-bar pressure experiment (especially the inorganic contaminants and organic contaminants such as phenol and PAHs), but not applied to all kinds of contaminants produced, such as BTEX. In the event of contaminant escape, the dominant species' concentrations measured in the study would be useful to predict the contaminant spread. Notably, high concentrations of dissolved ammonia nitrogen, hydrogen cyanide and fluoride species showed dominance along with other metal and metalloid species at varying pH range. iii). Al, Fe, K and Ti were the major elements present in the residual ash and char generated at both atmospheric and elevated pressure conditions. The surface complexation calculations for the sorbed fractions of the inorganic species on iron oxide indicated the ash left in the cavity is a potential sorbent. Previously reported possible biodegradation of organic contaminants has been evaluated with the actual concentrations produced in the study which showed that the reduction in phenol concentration takes 45 days and benzene takes more than 2 years. However, the contaminant concentration levels produced in the present study must be studied at laboratory scale to reliably predict the sorption/transport/ biotransformation of the contaminations for given field conditions.
Overall, the study provided novel insights on the contaminant generation during gasification of a highrank coal and the results produced would significantly benefit the site selection in the aspect of contaminant spread and the selection of gas cleaning and water treatment options.