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Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand

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Abstract

The reaction of cobalt(ii) iodide with 1,4-bis(2,4,6-trimethylphenyl)-1,4-diazabuta-1,3-diene (Mes-DAD) in anhydrous acetonitrile afforded the mononuclear complex [CoI2(Mes-DAD)] (1). The crystal structure of the complex was established by single-crystal X-ray diffraction. The phase purity was confirmed by powder X-ray diffraction. The zero-field splitting parameter (D = 17.2 cm−1) and the intermolecular exchange coupling parameter (zJ = −0.78 cm−1) were determined from magnetochemical studies of complex 1 in a direct current magnetic field of 5 kOe in the temperature range of 2–300 K. Magnetic measurements in an alternating magnetic field showed the absence of slow relaxation of the magnetization.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the state assignment of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences. This research was performed using the equipment of the JRC PMR IGIC RAS.

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  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russia

    D. S. Yambulatov, S. A. Nikolaevskii, K. A. Babeshkin, N. N. Efimov, M. A. Kiskin & I. L. Eremenko

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  1. D. S. Yambulatov
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  2. S. A. Nikolaevskii
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Correspondence to D. S. Yambulatov.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2390–2396, December, 2021.

This paper does not contain descriptions of studies on animals or humans.

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Yambulatov, D.S., Nikolaevskii, S.A., Babeshkin, K.A. et al. Synthesis, structure, and magnetic properties of the cobalt(ii) iodide complex with 1,4-diazabuta-1,3-diene ligand. Russ Chem Bull 70, 2390–2396 (2021). https://doi.org/10.1007/s11172-021-3358-1

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