Abstract
Heterogenized catalysts were prepared by the immobilization of the homogeneous catalytic systems containing the rhodium complexes, copper compounds, and perfluoroorganic acids onto porous carriers. The activity of the catalysts was studied in the processes of CO oxidation and co-oxidation of CO and propane. The state of the catalyst components was determined and the possibility of their interaction was evaluated by X-ray spectroscopy (XANES and EXAFS) and electrospray mass spectrometry (ESI-MS). The oxidation of CO on the RhCl3-CuCl2-C3F7COOH/γ-Al2O3 catalyst in a flow reactor at 70–80 °C and atmospheric pressure occurs in an oscillating mode. The co-oxidation of propane and CO at 80–95 °C and a pressure of 1.0–1.5 MPa is basically possible but occurs with a low yield of propane oxygenates.
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Investigations on the preparation of the catalysts and studies of their activity were carried out in the framework of state assignment of the A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science (Russian Academy of Sciences) (theme No. 46.3).
The studies by mass spectrometry with electrospray ionization were carried out in the framework of state assignment of the Institute of Problems of Chemical Physics (Russian Academy of Sciences) (state registration No. AAAA-A19-119071190045-0).
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1489–1498, August, 2021.
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Chepaikin, E.G., Menchikova, G.N., Pomogailo, S.I. et al. Heterogenized homogeneous catalytic systems for the oxidation of carbon monoxide and propane. Russ Chem Bull 70, 1489–1498 (2021). https://doi.org/10.1007/s11172-021-3244-x
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DOI: https://doi.org/10.1007/s11172-021-3244-x