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Alkylation of catechol with cyclohexene. Novel sterically hindered o-quinones and catechols

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Abstract

A synthetic procedure for the preparation of sterically hindered catechols and o-quinones by the reaction of catechol with cyclohexene was developed. Novel cyclohexyl substituted catechols displayed remarkable stability during redox transformations and could be used as redoxactive ligands.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    T. N. Kocherova, N. O. Druzhkov, K. A. Martyanov, A. S. Shavyrin, M. V. Arsenyev, T. I. Kulikova, E. V. Baranov, V. A. Kuropatov & V. K. Cherkasov

Authors
  1. T. N. Kocherova
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  2. N. O. Druzhkov
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  3. K. A. Martyanov
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  4. A. S. Shavyrin
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  5. M. V. Arsenyev
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  6. T. I. Kulikova
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  7. E. V. Baranov
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  8. V. A. Kuropatov
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  9. V. K. Cherkasov
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Corresponding author

Correspondence to V. A. Kuropatov.

Additional information

This work was financially supported by the Russian Science Foundation (Project No. 19-13-00142). The studies were carried out using the equipment of the Center for Collective Use “Analytical Center of the IMCh RAS” at the G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences and supported by the Federal Target Program “Research and Development on Priority Directions of Scientific and Technological Complex of Russia for 2014-2020” (unique project identifier RFMEFI62120X0040).

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Kocherova, T.N., Druzhkov, N.O., Martyanov, K.A. et al. Alkylation of catechol with cyclohexene. Novel sterically hindered o-quinones and catechols. Russ Chem Bull 69, 2383–2389 (2020). https://doi.org/10.1007/s11172-020-3051-9

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  • DOI: https://doi.org/10.1007/s11172-020-3051-9

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