Abstract
Dimeric phthalocyanines of a new type with a bridging 9,9,10,10-tetramethyl-9,10-dihydroanthracene fragment were synthesized. On the basis of X-ray diffraction analysis and molecular modeling of 9,9,10,10-tetramethyl-9,10-dihydroanthracene, a nearly planar structure was assumed for these phthalocyanines. The electronic absorption spectra of the obtained phthalocyanines and their monomeric and conjugated dimeric analogs were compared.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1686–1692, October, 2006.
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Makarov, S.G., Maksimova, K.N., Baranov, E.V. et al. Synthesis and electronic spectra of dimeric phthalocyanines. Russ Chem Bull 55, 1748–1754 (2006). https://doi.org/10.1007/s11172-006-0483-9
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DOI: https://doi.org/10.1007/s11172-006-0483-9