Abstract
Preparation of a nanocatalyst (Fe3O4@SiO2@DNHCS-Tr@CuI) containing PAMAM dendrimer and trypsin enzyme supported on magnetic nanosilica on which CuI NPs were immobilized was reported in this paper. This nanocatalyst was characterized using FT-IR, FE-SEM, EDX, elemental mapping, XRD, and ICP analyses. The catalytic activity of Fe3O4@SiO2@DNHCS-Tr@CuI was evaluated by A3-coupling reaction, which indicated a highly efficient activity for the synthesis of propargylamines in green conditions, with high yields, short reaction times and easy separation and recovery of the catalyst for further use.
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The authors acknowledge the Research Council of the University of Mazandaran.
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Peiman, S., Baharfar, R. & Hosseinzadeh, R. CuI NPs immobilized on a ternary hybrid system of magnetic nanosilica, PAMAM dendrimer and trypsin, as an efficient catalyst for A3‑coupling reaction. Res Chem Intermed 48, 1365–1382 (2022). https://doi.org/10.1007/s11164-021-04654-w
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DOI: https://doi.org/10.1007/s11164-021-04654-w