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Enhanced photoelectrocatalytic performance of ZnIn2S4 modified TiO2 nanotube array toward methylene blue

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Abstract

Environmental pollution caused by organic pollutants has been attracted more and more attention by the researchers. In this paper, ZnIn2S4 modified TiO2 nanotube array (ZnIn2S4/TiO2) composite electrodes are prepared by loading chalcogenide semiconductor material ZnIn2S4 on the surface of TiO2 nanotube array (TiO2 NTA) for the degradation of methylene blue (MB). The physicochemical properties of ZnIn2S4/TiO2 composite electrodes are analyzed by X-ray photoelectron spectroscopy, X-ray diffraction, photoluminescence spectroscopy and so on. The photoelectrocatalytic degradation rate of ZnIn2S4/TiO2 composite electrode with the concentration of ZnIn2S4 as 0.5 mmol/L (ZISTO-2) reaches 93.3% under the bias voltage of 0.7 V and simulated sunlight irradiation for 180 min against MB, which is 22.44% higher than that of pure TiO2 NTA electrode, and the degradation rate of ZISTO-2 composite electrode toward MB is maintained at 78.2% after five cycles. The radical trapping experiments indicate that h+, ·O2− and ·OH has significant contribution in the photoelectrocatalytic degradation. This paper provides a new ideal way to solve the problem of water pollution under visible light.

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Data Availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

This work was supported by Natural Science Foundation of Shandong Province (No. ZR2019BEE075), Young Science and Technology Innovation Program of Shandong Province (No. 2020KJD001), Elite Program of SDUST (No. skr21-3–051), Science and Technology Project of Qingdao West Coast New Area (2021–4), Taishan Scholars Program of Shandong Province, National Natural Science Foundation of China (Grant No. 52074175) and Shandong Provincial Natural Science Foundation (Grant No. ZR2020ME103).

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Authors and Affiliations

  1. College of Energy and Mining Engineering, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Junxiang Wang, Zhenyu Chen, Xindong Zhou & Lin Li

  2. College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Qianqian Song & Hui Yang

  3. Wanhua Chemical Group Co LTD, Yantai, 265500, People’s Republic of China

    Qingming He

  4. College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Ping Chen

  5. Weifang Baite Magnetism Technology Co LTD, Weifang, 262600, People’s Republic of China

    Jingang Wang

  6. Shandong Wosai New Materials Technology Co LTD, Weifang, 262600, People’s Republic of China

    Tao Wang

  7. Library, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Hui Yang

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  1. Junxiang Wang
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  3. Qianqian Song
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  8. Tao Wang
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  9. Hui Yang
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  10. Lin Li
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Junxiang Wang, Zhenyu Chen, Qianqian Song, Qingming He. The investigation and formal analysis were performed by Xindong Zhou, Ping Chen, Jingang Wang, Tao Wang. Fund support was provided by Junxiang Wang and Lin Li. The first draft of the manuscript was written by Hui Yang. All authors read and approved the final manuscript.

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Correspondence to Hui Yang or Lin Li.

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Wang, J., Chen, Z., Song, Q. et al. Enhanced photoelectrocatalytic performance of ZnIn2S4 modified TiO2 nanotube array toward methylene blue. J Nanopart Res 26, 34 (2024). https://doi.org/10.1007/s11051-024-05946-z

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