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Thermal and spectroscopic behavior of glasses from P2O5–SiO2–K2O–MgO–CaO–Co2O3 system

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Abstract

Multicomponent cobalt phosphate–silicate glasses from P2O5–SiO2–K2O–MgO–CaO–Co2O3 system in which molar ratio of P2O5 to SiO2 is 41:6 and cobalt ions are gradually incorporated at the expense of magnesium and calcium ions were prepared via melt-quenched technique. The obtained amorphous solids were subjected to the thermal and spectroscopic studies and density measurements in order to gain information about the structure and physical properties. As DSC, XRD, FTIR and pycnometry techniques were applied, the glass transition temperature, specific heat change, crystallization temperature, density, molar volume, oxygen packing density and associated infrared spectra were collected for each glass. Then, the process of induced crystallization was performed on the selected glass samples. The related glass-crystalline materials were evaluated via XRD method. As a result, crystalline phases associated with crystallization temperature were identified. The alterations in determined parameters, stoichiometry of connected crystalline phases and features of infrared spectra allow to conclude the impact of cobalt ions on structure of analyzed glasses due to the direct dependence of structure, physical and thermal properties. The conducted research constitutes a basis for further analysis of cobalt phosphate–silicate glasses and makes a contribution to the knowledge concerning the phosphate glasses family.

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Acknowledgements

The work was partly supported by program "Excellence initiative—research university" for the AGH University of Science and Technology and the EU Project POWR.03.02.00-00-I004/16. Authors would also like to acknowledge PhD Piotr Jeleń from AGH University of Science and Technology, Faculty of Material Science and Ceramics for the conducting of FTIR measurements.

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Authors and Affiliations

  1. AGH University of Science and Technology, Faculty of Material Science and Ceramics, Al. Mickiewicza 30, 30-059, Cracow, Poland

    Justyna Kuczek, Magdalena Szumera & Justyna Sułowska

  2. Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Cracow, Poland

    Dorota Rutkowska-Zbik & Mariusz Gackowski

Authors
  1. Justyna Kuczek
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  2. Magdalena Szumera
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  3. Dorota Rutkowska-Zbik
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  4. Mariusz Gackowski
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  5. Justyna Sułowska
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Contributions

Material preparation, data collection and analysis were performed by JK, MS, JS, DR-Z and MG. MG conducted the 31P MAS NMR measurements and prepared the data for the analysis. JS provided the density data and performed additional analysis. The first draft of the manuscript was written by JK. MS and DR-Z commented on previous versions and the final version of the manuscript. JK and MS mainly contributed to the study conception and design. All authors participated in the process of introducing amendments into the manuscript due to revision process. All authors read and approved the final manuscript.

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Correspondence to Justyna Kuczek or Magdalena Szumera.

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Kuczek, J., Szumera, M., Rutkowska-Zbik, D. et al. Thermal and spectroscopic behavior of glasses from P2O5–SiO2–K2O–MgO–CaO–Co2O3 system. J Therm Anal Calorim 148, 1435–1444 (2023). https://doi.org/10.1007/s10973-022-11362-z

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  • DOI: https://doi.org/10.1007/s10973-022-11362-z

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