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Synthesis and structural characterization of a liquid polyisoprene bearing amidoxime end groups

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Abstract

Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units (1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that the structure of the end groups was governed by the steric hindrance of the initiator. Only 1,4 and 4,1 functionalized end units were evidenced, with a majority of 4,1 end units.

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Acknowledgement

Authors wish to acknowledge National Academy of Sciences of Ukraine (NASU) and French National Scientific Research Center (CNRS) for financial support. Project N°189961.

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Authors and Affiliations

  1. INSA de Rouen - UMR 6270 - FR3038 CNRS, BP08 Avenue de l’Université, 76801, Saint-Etienne du Rouvray, France

    Fabrice Burel & Claude Bunel

  2. Laboratoire de Résonance Magnétique Nucléaire, UMR 6014 CNRS, IRCOF, INSA et Université de Rouen, 76130, Mont-Saint-Aignan, France

    Hassan Oulyadi

  3. Department of Oligomers and Synthetic Rubbers, Institute of Macromolecular Chemistry, 48 Kharkivske Shaussee, Kyiv, 02160, Ukraine

    Vladimir Grishchenko, Natalya Busko, Antonina Barantsova & Vitaly Boiko

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  1. Fabrice Burel
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  2. Hassan Oulyadi
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  3. Claude Bunel
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  4. Vladimir Grishchenko
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  5. Natalya Busko
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  6. Antonina Barantsova
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  7. Vitaly Boiko
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Correspondence to Fabrice Burel.

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Burel, F., Oulyadi, H., Bunel, C. et al. Synthesis and structural characterization of a liquid polyisoprene bearing amidoxime end groups. J Polym Res 18, 2265–2273 (2011). https://doi.org/10.1007/s10965-011-9640-4

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  • DOI: https://doi.org/10.1007/s10965-011-9640-4

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