High-Temperature Superconducting Fiber

In this study, we demonstrated superconductivity in a fiber with an yttrium barium copper oxide core and fused silica cladding. The fibers were fabricated via a modified melt-draw technique and post-process annealing treatment in excess oxygen. The fibers maintained overall diameters ranging from 100–900 microns and core diameters of 50–700 microns. Superconductivity of this fiber design was validated via the traditional four-point probe test method in a bath of liquid nitrogen at temperatures on the order of 93 K. The high-temperature superconducting fiber provides a glimpse of its cross cutting potential in fields of electromagnetism, healthcare, optics, and energy and lends credence to the promise for superconductivity.

the field of superconductivity appeared to change in 1987 upon the discovery of "high-temperature" superconductivity in YBCO because of the higher transition temperatures, 93 K, that allowed the use of a much more cost effective cryogen: liquid nitrogen [3,4] Although the pursuit of "roomtemperature" superconductivity continues, significant effort has been dedicated to improved cable designs and manufacturing processes for these basic high-temperature superconductors [5,6]. Although the pioneering work over the past few decades has made superconductivity relevant in an increasing number of applications, superconductivity has yet to experience the revolution seen with semiconductors and fiber optics [7][8][9]. The lack of traditional cable structures has, in part, impeded mass commercialization.
To meet this need, superconductivity was demonstrated in a lead core fiber via a multidisciplinary approach akin to current research dedicated to the integration of semiconductor devices into optical fibers [10][11][12]. Unfortunately, the extremely low transition temperature, T c ≈ 7.2 K, of lead necessitated the use of liquid helium, which is both expensive and difficult to handle. Thus, a superconducting fiber with a high-temperature superconducting core material such as yttrium barium copper oxide is preferable for the majority of applications.
In this letter, we demonstrate a high-temperature Type II superconducting fiber, as seen in Fig. 1. The yttrium barium copper oxide core of these types of fibers exhibited zero resistance at temperatures of approximately 93 K.
The superconducting core fibers were prepared by the melt-draw technique on a traditional glass working lathe, as seen in Fig. 2 [10,13]. First, a fused silica substrate tube (GE214, OD = 8 mm, ID = 3 mm) was fused to a processing tube (GE214, OD = 9.5 mm, ID = 7 mm). A smaller diameter fused silica rod (GE214, 8 mm) was used to push the yttrium barium copper oxide melt into the substrate tube   forming a preform with a YBCO core. Finally, the preform was drawn into a fiber via a technique similar to the Taylor process [14,15].
The drawing temperature required for fused silica based optical fibers was on the order of 2000-2100°C, which is much higher than the melting point of YBCO (∼1010°C) [16]. As shown in Fig. 3, the rapid consolidation of the core melt upon fiberization produced a YBCO core with minimal porosity. However, the as-drawn YBCO core fibers were essentially nonsuperconducting due high-temperature phase separation, loss of oxygen upon relatively rapid cooling, possible silicon diffusion from the cladding, and thermal decomposition [17]. Thus, the as-drawn fiber was annealed in an oxygen rich environment to recover it to superconductive state. Generally, the YBCO core fibers were heated to 950°C, at a rate of 5°C/min, and held at this temperature for a period of for 12 hours, cooled to 500°C at a rate of 1°C/min and held for 12 hours, and then allowed to naturally cool to room temperature [18,19].
The fibers were fabricated on a glass working lathe, Litton Model HSJ143. The maximum achievable fiber lengths were limited by the working distance, approximately 1.2 meters, between the chuck faces, the preform length and draw rod at the tailstock end. Fiber diameters in the range of 100-900 microns were routinely fabricated to maximum lengths of 1.2 meters. Fiberization via the glass working lathe allows for the preliminary determination of feasibility prior to process implementation on a more traditional fiber drawing tower. The fundamental techniques are based on the Taylor and Taylor-Ulitovsky methods, which are employed to manufacture fiber lengths on the order of kilometers [20][21][22][23][24].
Polished fiber cross sections were characterized with a scanning electron microscope (SEM, LEO 1550). As shown previously in Fig. 1, the superconducting fiber possessed impressive core/clad concentricity and a distinct interface between the YBCO core and the fused silica glass cladding. The fused silica cladding maintained a diameter of approximately 800 µm and YBCO core diameter of 250 µm, respectively. Energy dispersive spectroscopy (EDS) chemical composition and mapping were performed with an attached IXRF system, Inc Iridium Microanalysis System, at an accelerating voltage of 20.0 kV. The EDS mapping images at the core-cladding interface can be seen in Fig. 4. A distinct transition between the cladding, SiO 2 , and the core, YBCO, exists at the interface, although cross diffusion of both yttrium and barium is evident. Preliminary EDS chemical composition analysis suggested a Y:Ba:Cu elemental ratio of approximately 1:1.96:2.57, but further investigation is required to minimize the potential measurement artifacts caused by silicon and silicon dioxide contamination of the core material upon sample preparation and analysis and the characterization methods.
The superconductivity of the YBCO core fibers was verified via the four-probe test method as shown in Fig. 5 [25]. The effects of contact resistance are eliminated via the fourprobe test method. Resistance to the flow of electrical current will produce a voltage drop measured between the two voltage probes. Conversely, a superconductor will exhibit no voltage drop below the critical temperature.

Fig. 4 X-ray dot mapping of yttrium (red), barium (green), copper (blue), oxygen (turquoise), and silicon (pink). A composite X-ray dot map image is shown in the bottom right-hand corner.
There is limited cross diffusion of the elements between the core and clad, but yttrium diffusion from the core to the clad and silicon diffusion from the clad to core is evident. A well-defined elemental transition is noted at the core-clad interface region The fused silica cladding could not be readily removed via hydrofluoric etching and/or mechanically because of the brittle nature of the YBCO material and necessitated the use of an alternative to expose the core. The YBCO core fiber was mounted into an epoxy resin mold and then carefully polished to expose the core in lengthwise fashion. The polished probe ends were placed in direct contact with the YBCO core with a custom test fixture to assure stable measurements. Furthermore, the probes were mounted in another mold at specific intervals of approximately 0.25 mm. Liquid nitrogen was used for the YBCO core fiber because the critical temperature is approximately 93 K, and the boiling point of liquid nitrogen is 77 K. A HP Hewlett-Packard Agilent, 6633A System was utilized as the direct current supply and ammeter. An Agilent, 34405A, 5 1/2 Digit Multimeter was connected to the "voltage probes" to accurately measure the voltage drop. Both Type T and E thermocouples were utilized to continuously monitor the temperate of the sample.
A baseline measurement was performed with a commercially available brass laminated high-temperature superconducting wire (thickness ≈ 0.4 mm, width ≈ 4.4 mm) in a liquid nitrogen bath to confirm the validity of the test setup. As seen in Fig. 6(a), the resistance of the commercial superconducting wire disappeared at temperatures on the order of 93 K. Although, the initial electrical resistance was considerably larger, the superconducting YBCO core fibers appeared to demonstrate a slightly higher T c of approximately 95 K. As shown in Fig. 6(b), the superconducting transition was also evaluated for a commercially bulk YBCO disk (diameter ≈ 25 mm, thickness ≈ 3.1 mm) to further confirm the performance of the superconducting fiber. The transition temperature of the bulk YBCO, T c ≈ 93 K, was lower than both the commercial wire and superconducting fiber. Although further investigation is required, the difference in T c is currently attributed to measurement errors arising due the variation in thermocouple positions, thermal electromotive forces, external electromagnetic radiation, Faraday currents, and the degradation of the electrical contacts, as well as basic errors in the experimental setup [26,27]. The critical temperature has been verified and extensively studied in the literature and is generally accepted as approximately 93 K, which is in good agreement with the measurements in this study [28].
The demonstration of a Type II superconducting fiber is one step closer to simple and cost effective superconducting cables for long haul power transmission, sensors, and devices. High-temperature superconductivity in traditional geometries such as fibers may well provide pave the way for the significant advancement of superconductivity in the landscape of emerging technologies. Fig. 6 Electrical resistance as a function of temperature upon full immersion in liquid nitrogen for (a) commercial brass laminated high--temperature superconducting wire and a YBCO core superconducting fiber with a fused silica clad and (b) a commercial bulk YBCO disk and a YBCO core superconducting fiber with the fused silica clad. The primary vertical axis is the resistance of the YBCO core samples, and the secondary vertical axis is the resistance of the commercial high--temperature superconducting samples. All samples maintain a critical temperature of approximately 90-100 K Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.