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Solar-heated melamine sponge decorated with Fe3O4 for continuous recovery of viscous crude oil

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Abstract

The offshore crude oil spill has caused serious environmental damage and affected the balance of the ecosystem. Due to the high viscosity and poor fluidity of crude oil, conventional adsorbents cannot effectively remove it. The heat converted from solar energy can reduce the viscosity of the crude oil, improved its fluidity, allowing it to be adsorbed by a porous material and then recycle, it is considered an effective approach. Herein, we have designed a melamine composite sponge decorated with Fe3O4 and modified by PDMS (MS@Fe3O4-PDMS) with good photothermal conversion performance, which can recover viscous crude oil with the assistance of solar energy. The surface temperature of MS@Fe3O4-PDMS can reach around 88.0 ℃ under the light intensity of 1 kW·m− 2, effectively heating crude oil and accelerating its absorption. In the continuous crude oil recovery experiment, the absorption rate of MS@Fe3O4-PDMS reached 52.46 kg·m− 2·h− 1. In addition, the composite sponge has good processability, facile preparation method, and practical application potential.

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References

  1. K. Yan, F. Zhao, L. Pan et al., High-throughput clean-up of viscous oil spills enabled by a gel-coated mesh filter. Nat. Sustain. 6, 1654–1662 (2023)

    Article  Google Scholar 

  2. M.G. Barron, D.N. Vivian, R.A. Heintz, U.H. Yim, Long-term ecological impacts from oil spills: comparison of Exxon Valdez, HebeiSpirit, and Deepwater Horizon. Environ. Sci. Technol. 54, 6456–6467 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. Y. Song, L.-A. Shi, H. Xing, K. Jiang, J. Ge, L. Dong, Y. Lu, S.-H. Yu, A magneto-heated ferrimagnetic sponge for continuous recovery of viscous crude oil. Adv. Mater. 33, 2100074 (2021)

    Article  CAS  Google Scholar 

  4. G. Zhang, Y. Liu, C. Chen, L. Long, J. He, D. Tian, L. Luo, G. Yang, X. Zhang, Y. Zhang, MOF-based cotton fabrics with switchable superwettability for oil–water separation. Chem. Eng. Sci. 256, 117695 (2022)

    Article  CAS  Google Scholar 

  5. X. Yan, X. Zhu, Y. Ruan, T. Xing, G. Chen, C. Zhou, Biomimetic, dopamine-modified superhydrophobic cotton fabric for oil–water sep aration. Cellulose. 27, 7873–7885 (2020)

    Article  CAS  Google Scholar 

  6. Y. Li, L. Zhu, N. Grishkewich, K.C. Tam, J. Yuan, Z. Mao, X. Sui, CO2–responsive cellulose nanofibers aerogels for switchable oil – water separation. Acs Appl. Mater. Inter. 11, 9367 – 9373 (2019)

  7. Y. Sun, W. Ye, J. Xi, Y. Chu, H. Xiao, W. Wu, Ultralight and shape recovery bio-based aerogel for oil-water separation. J. Environ. Chem. Engin. 10, 108822 (2022)

    Article  CAS  Google Scholar 

  8. L. Zhang, H. Li, X. Lai, X. Su, T. Liang, X. Zeng, Thiolated graphene-based superhydrophobic sponges for oil-water separation. Chem. Engin. Jour. 316, 736–743 (2017)

  9. N. Zhang, X. Yang, Y. Wang, Y. Qi, P. Cui, Jiang. Hierarchically porous superhydrophobic sponge for oil-water separation. J. Water Process. Eng. 46, 102590 (2022)

    Article  Google Scholar 

  10. M.Y. Combariza, A.P. Martínez-Ramírez, Blanco-Tirado, Perspectives in nanocellulose for crude oil recovery: a minireview. Energ. Fuel. 35, 15381–15397 (2021)

    Article  CAS  Google Scholar 

  11. M.-B. Wu, S. Huang, T.-Y. Liu, J. Wu, S. Agarwal, A. Greiner, Z.-K. Xu, Compressible carbon sponges from delignified wood for fast cleanup and enhanced recovery of crude oil spills by joule heat and photothermal effect. Adv. Funct. Mater. 31, 006806 (2020)

    Google Scholar 

  12. D. Liu, Y. Li, C. Wang, H. Yang, R. Wang, S. Li, X. Yang, Numerous active sites in self-supporting Co3O4 nanobelt array for boosted and stabilized 5-hydroxymethylfurfural electro-oxidation. Appl. Catal. A-Gen. 669, 119497 (2024)

    Article  CAS  Google Scholar 

  13. B. Qi, N. Wang, X. Hu, S. Cui, H. Liu, R. He, J. Lian, Y. Li, J. Lu, Y. Li, M. Bao, Melt-blown fiber felt for efficient all-weather recovery of viscous oil spills by Joule heating and photothermal effect. J. Hazard. Mater. 460, 132523 (2023)

    Article  CAS  PubMed  Google Scholar 

  14. W. Zhou, B. Zhan, G. Wang, Z. Chen, Y. Liu, Simple fabrication of superhydrophobic carbon felt with outstanding Joule heating and photothermal effects for all-weather recovery of viscous crude oil. Sep. Purif. Technol. 337, 126356 (2024)

    Article  CAS  Google Scholar 

  15. M. Anas, M.M. Mustafa, D.G. Carey, A. Sarmah, J.J. LeMonte, M.J. Green, Joule heating of carbon pixels for on-demand thermal patterning. Cabon. 174, 518–523 (2021)

    CAS  Google Scholar 

  16. C. Chen, Y. Kuang, Challenges and opportunities for solar evaporation. Joule. 3, 683–718 (2019)

    Article  CAS  Google Scholar 

  17. Y. Guan, Z. Wang, M. Bao, X. Chen, L. Dong, Y. Shen, Y. Li, Multi-energies assisted and all-weather recovery of crude oil by superhydrophobic melamine sponge. J. Hazard. Mater. 443, 130131 (2023)

    Article  CAS  PubMed  Google Scholar 

  18. Y.D. Chen, Y.J. Zhao, C. Zhang, M. Li, Q. Zhou, Y. Lin, Y. Gong, Z. Su, W. Yang, A Fe-Ni-MOF-74@bamboo photothermal evaporator for efficient solar steam generation. Desalination 57, 0117091 (2024)

  19. Y. Zhao, D. You, Y. Chen, Q. Pan, Z. Su, W. Yang, Highly efficient 3D evaporator for interfacial solar steam generation and wastewater treatment. Energy Technol. 2300586 (2023)

  20. J. Yu, C. Cao, S. Liu, Y. Pan, Eco-friendly magneto-photothermal sponge for the fast recovery of highly viscous crude oil spill. Separ Pur Tech. 298, 121668 (2022)

    Article  CAS  Google Scholar 

  21. X. Wang, D. Liu, G. Cheng, Y. Huang, Y. He, Solar heating assisted rapid cleanup of viscous crude oil spills using reduced graphene oxide-coated sponges. Sci. China Technol. Sc. 63, 1487–1496 (2020)

    Article  CAS  Google Scholar 

  22. P. Cherukupally, W. Sun, A.P.Y. Wong, D. Williams, G.A. Ozin, A.M. Bilton, C.B. Park, Surface-engineered sponges for recovery of crude oil microdroplets from wastewater. Nat. Sustain. 3, 136–143 (2020)

    Article  Google Scholar 

  23. J.L. Dong, D. Zhang, X. Chen, Y. Xue, Y. Guan, Y. Li, Mesoporous carbon spheres modified polyurethane sponge/phase change material composites: photothermal conversion, thermal storage and efficient recovery of high-viscosity crude oil. Carbon. 214, 118372 (2023)

    Article  Google Scholar 

  24. Y. Wang, L. Zhou, X. Luo, Y. Zhang, J. Sun, X. Ning, Y. Yuan, Solar-heated graphene sponge for high-efficiency clean-up of viscous crude oil spill. J. Clean. Prod. 230, 995–1002 (2019)

    Article  CAS  Google Scholar 

  25. X. Ma, K. Chen, S. Li, P. Gnanasekar, Y. Zhong, Y. An, Q. Luo, Q. Huang, J. Zhu, J. Chen, N. Yan, Degradable Ti3C2Tx MXene nanosheets containing a lignin polyurethane photothermal foam (LPUF) for rapid crude oil cleanup. ACS Appl. Nano Mater. 5, 2848–2858 (2022)

    Article  CAS  Google Scholar 

  26. R. Tang, Y. Hu, J. Yan, S. Xu, Y. Wang, J. Yan, D. Liao, H. Zhang, Z. Tong, Multifunctional carboxylated cellulose nanofibers/exfoliated bentonite/Ti3C2 aerogel for efficient oil adsorption and recovery: the dual effect of exfoliated bentonite and MXene. Chem. Eng. J. 473, 145412 (2023)

    Article  CAS  Google Scholar 

  27. J. Yang, P. Xu, Y. Yao, Y. Li, B. Shi, X. Jia, H. Song, A solar-heated Janus sponge with excellent floating stability for efficient cleanup of heavy oil. Mater. Des. 195, 108979 (2020)

    Article  CAS  Google Scholar 

  28. M. Yu, P. Xu, J. Yang, L. Ji, C. Li., Self-growth of MoS2 sponge for highly efficient photothermal cleanup of high-viscosity crude oil spills. Adv. Mater. Inter. 7, 1901671 (2020)

    Article  CAS  Google Scholar 

  29. Z. Lin, Q. Tian, X. Yue, F. Qiu, T. Zhang, Solar-heating superhydrophobic modified melamine sponge for efficient recovery of viscous crude oil. J. Hazard. Mater. 440, 12979 (2022)

    Google Scholar 

  30. M. Saeed, M.Z. Iqbal, W. Ren, Y. Xia, C. Liu, W.S. Khanac, A. Wu, Controllable synthesis of Fe3O4 nanoflowers: enhanced imaging guided cancer therapy and comparison of photothermal efficiency with black-TiO2. J. Mater. Chem. B. 6, 3800–3810 (2018)

    Article  CAS  PubMed  Google Scholar 

  31. Y. Gao, Z. Tang, X. Chen, J. Yan, Y. Jiang, J. Xu, Z. Tao, L. Wang, Z. Liu, G. Wang, Magnetically accelerated thermal energy storage within Fe3O4-anchored MXene-based phase change materials. Aggregate. 4, e248 (2023)

  32. H. Wang, T. Yang, Q. Song, H. Sun, T. Liu, H. Wang, Zeng, Plasmon mediated Fe–O in an octahedral site of cuprospinel by Cu NPs for photocatalytic hydrogen evolution. Nanoscale. 9, 15760–15765 (2017)

    Article  CAS  PubMed  Google Scholar 

  33. M. Tang, Z. Jiang, Z. Wang, Y. Qin, Y. Jiang, L. Wu, Z. Li, High-adhesion PDMS/Ag conductive composites for flexible hybrid integration. Chem. Eng. J. 451, 138730 (2023)

    Article  CAS  Google Scholar 

  34. S.J. Kashyap, R. Sankannavar, G.M. Madhu, Iron oxide (Fe2O3) synthesized via solution-combustion technique with varying fuel-to-oxidizer ratio: FT-IR, XRD, optical and dielectric characterization. Mater. Chem. Phys. 286, 126118 (2022)

    Article  CAS  Google Scholar 

  35. D.T. Phong, N.T.N. Hieu, N.D. Hai, P.M. Tu, N.M. Dat, N.T.H. Nam, C.Q. Cong, H. An, D.T.C. Minh, L.T.M. Thy, H.K.P. Ha, N. H. Hieu, Multifunctional applications of cellulose/sodium alginate aerogel material: Antibacterial, adsorption, and heat insulation. Mater. Today Sustain. 25, 100618 (2024)

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Acknowledgements

This work was funded by Hainan Province Science and Technology Special Fund (ZDYF2022SHFZ090 and ZDYF2022SHFZ298), National Natural Science Foundation of China (22061014), and the specific research fund of the Innovation Platform for Academicians of Hainan Province.

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Investigation, Y.-D.C.; methodology, Y.-J.Z.; data analysis, Y.-D.C. and Y.-J.Z.; supervision, W.-T.Y.; writing—original draft, Y.-D.C.; writing—review and editing; Y.-J.Z. and W.-T.Y., project administration and funding acquisition, W.-T.Y. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Weiting Yang.

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Chen, Y., Zhao, Y., Yang, W. et al. Solar-heated melamine sponge decorated with Fe3O4 for continuous recovery of viscous crude oil. J Porous Mater 31, 937–943 (2024). https://doi.org/10.1007/s10934-024-01569-w

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