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Study on Amino-functionalized Porous Carbon Materials for MB and Cr(VI) Adsorption

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Abstract

From the perspective of environmental protection, high removal rate, reusable and degradable, amino-functionalized porous hydrogel material P-(EA-β-CD/KHA/AC) was synthesized by introducing ethylamino cyclodextrin, humic acid, and activated carbon, using polyacrylic acid as the carrier. MB and Cr (VI) are common wastewater pollutants, thus, Such contaminants must be removed from the water. The gel materials before and after adsorption were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The removal of MB and Cr(VI) showed high adsorption capacity. At 298 K and pH 8, the adsorption capacities of P-(EA-β-CD/KHA/AC) hydrogel for MB and Cr(VI) were as high as 262.31 and 170.12 mg/g, respectively, and the removal rates were 98.96% and 70.27%, respectively. The adsorption behavior follows the pseudo-second-order kinetic equation, conforming to the Langmuir model; and through intermolecular forces, π–π conjugation, chelation, and other interactions, entropy-increasing, endothermic, and spontaneous process is formed. The regeneration and degradability experiments of P-(EA-β-CD/KHA/AC) hydrogel were conducted and its recycling performance was verified.

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Abbreviations

AC :

Activated carbon

MB:

Methylene blue

SEM:

Scanning electron microscopy

XPS:

X-ray photoelectron spectroscopy

XRD:

X-ray diffraction

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Funding

This work was supported by the National Natural Science Foundation of China [No. 51803114]; Shaanxi Province Key R&D Program [No. 2022NY-195]; Xi'an City Innovation Capability Strong Foundation Plan-Agricultural Technology R&D [No. 21NYYF0025], and Shaanxi Province Key R&D Program [No. 2020SF-411].

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Authors and Affiliations

  1. Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi’an, 710021, China

    Jie Song, Lijun Chen, Yuhua Niu, Zhiqiang Wei & Yonghui Sun

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  1. Jie Song
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  2. Lijun Chen
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  3. Yuhua Niu
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  4. Zhiqiang Wei
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Contributions

JS: Reading and final approval of the version to be published. LC: Data Curation, Validation, Writing- Original draft preparation, Formal analysis,Writing-Reviewing and Editing. YN: Conceptualization; Critically reading. ZW: Methodology, Writing-Reviewing and Editing. YS: Conceptualization, Methodology.

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Correspondence to Jie Song.

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Song, J., Chen, L., Niu, Y. et al. Study on Amino-functionalized Porous Carbon Materials for MB and Cr(VI) Adsorption. J Polym Environ 31, 2999–3014 (2023). https://doi.org/10.1007/s10924-023-02781-6

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