Skip to main content
SpringerLink
Log in

Construction of Snow-Cake Like NiCo2O4 Nanostructures Modified Electrode Material and Its Electrocatalytic Oxidation of Glucose

  • Research
  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Transition bimetal oxides are widely used in the field of electrochemical sensing because of their variable valence and bimetallic synergies. In this work, we demonstrate the facile synthesis of snow-cake like NiCo2O4 nanostructures and its application as a working electrode modification material in enzyme-free glucose electrochemical sensing field. In a three-electrode system, the electrocatalytic oxidation activity for glucose of NiCo2O4 nanostructures is tested. The snow-cake like NiCo2O4 nanostructures are endowed with superior electron-transfer capability, large surface area, and abundant intrinsic redox couples of Ni2+/Ni3+ and Co2+/Co3+ ions. The modified electrode exhibits excellent glucose-sensing properties, such as detection of wide range of glucose concentrations with good linearity and high sensitivity of 983 μA mM−1 cm−2 at 0.45 V operating potential. Moreover, the interference from the commonly interfering species such as ascorbic acid (AA), sodium chloride (NaCl) and uric acid (UA) can be effectively avoided.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. M. Wei, Y.X. Qiao, H.T. Zhao, J. Liang, T.S. Li, Y.L. Luo, S.Y. Lu, X.F. Shi, W.B. Lu, X.P. Sun, Chem. Commun. 56, 14553–14569 (2020)

    Article  CAS  Google Scholar 

  2. W. Song, B. Zhao, C. Wang, Y. Ozaki, X. Lu, J. Mater. Chem. B. 7, 850–875 (2019)

    Article  CAS  PubMed  Google Scholar 

  3. Y. Feng, D. Xiang, Y. Qiu, L. Li, Y. Li, K. Wu, L. Zhu, Electroanal. 32, 571–580 (2020)

    Article  CAS  Google Scholar 

  4. A. Gao, X. Zhang, X. Peng, H. Wu, L. Bai, W. Jin, G. Wu, R. Hang, P.K. Chu, Sens. Actuators B Chem. 232, 150–157 (2016)

    Article  CAS  Google Scholar 

  5. H.X. Jia, N.Z. Shang, Y. Feng, H.M. Ye, J.N. Zhao, H. Wang, C. Wang, Y.F. Zhang, J. Colloid Interface Sci. 583, 310–320 (2021)

    Article  ADS  CAS  PubMed  Google Scholar 

  6. N. Karikalan, M. Velmurugan, S.M. Chen, C. Karuppiah, A.C.S. Appl, Mater. Interfaces. 8, 22545–22553 (2016)

    Article  CAS  Google Scholar 

  7. R. Li, X. Liu, H. Wang, Y. Wu, Z. Lu, Electrochim. Acta 299, 470–478 (2019)

    Article  CAS  Google Scholar 

  8. J. Wang, Chem. Rev. 108, 814–825 (2008)

    Article  CAS  PubMed  Google Scholar 

  9. E.H. Yoo, S.Y. Lee, Sensors-Basel 10, 4558–4576 (2010)

    Article  ADS  PubMed  PubMed Central  Google Scholar 

  10. Y.T. Zhang, S.A. Liu, Y. Li, D.M. Deng, X.J. Si, Y.P. Ding, H.B. He, L.Q. Luo, Z.X. Wang, Biosens. Bioelectron 66, 308–315 (2015)

    Article  CAS  PubMed  Google Scholar 

  11. J.A. Hondred, J.C. Breger, N.T. Garland, E. Oh, K. Susumu, S.A. Walper, I.L. Medintz, J.C. Claussen, Analyst 142, 3261–3271 (2017)

    Article  ADS  CAS  PubMed  Google Scholar 

  12. G.G. Guilbault, G.J. Lubrano, Anal. Chim. Acta 3, 439–455 (1973)

    Article  Google Scholar 

  13. K. Li, G.L. Fan, L. Yang, F. Li, Sens. Actuators B Chem. 199, 175–182 (2014)

    Article  CAS  Google Scholar 

  14. J. Yu, Y. Ni, M. Zhai, J. Alloys Compds. 723, 904–911 (2017)

    Article  CAS  Google Scholar 

  15. H.Y. Yin, J.J. Zhu, J.L. Chen, J.Y. Gong, Q.L. Nie, J. Mater. Sci. 53, 11951–11961 (2018)

    Article  ADS  CAS  Google Scholar 

  16. Y.X. Qiao, Q. Liu, S.Y. Lu, G. Chen, S.Y. Gao, W.B. Lu, X.P. Sun, J. Mater. Chem. B. 8, 5411–5415 (2020)

    Article  CAS  PubMed  Google Scholar 

  17. Q. Guo, W. Zeng, Y. Li, Mater. Lett. 256, 126603 (2019)

    Article  CAS  Google Scholar 

  18. H. Zhu, L. Li, W. Zhou, Z. Shao, X.J. Chen, J. Mater. Chem. B. 4, 7333–7349 (2016)

    Article  CAS  PubMed  Google Scholar 

  19. Z.H. Ibupoto, A. Tahira, A.B. Mallah, S.A. Shahzad, M. Willander, B. Wang, C. Yu, Electroanal. 29, 213–222 (2017)

    Article  CAS  Google Scholar 

  20. L.T.H. Chung, J.S. Hur, H. Seung, Sens. Actuators B Chem. 223, 76–82 (2016)

    Article  Google Scholar 

  21. L.J. Ding, M.G. Zhao, S.S. Fan, Y. Ma, J.J. Liang, X.T. Wang, Y.W. Song, S.G. Chen, Sens. Actuators B Chem. 235, 162–169 (2016)

    Article  CAS  Google Scholar 

  22. H. Zhang, S. Liu, Sens. Actuators B Chem. 238, 788–794 (2017)

    Article  CAS  Google Scholar 

  23. C.L. Hsu, J.H. Lin, D.X. Hsu, S.H. Wang, S.Y. Lin, T.J. Hsueh, Sens. Actuators B Chem. 238, 150–159 (2017)

    Article  CAS  Google Scholar 

  24. E. Zhang, Y. Xie, S. Ci, J. Jia, Z. Wen, Biosens. Bioelectron. 81, 46–53 (2016)

    Article  CAS  PubMed  Google Scholar 

  25. R.H. Qin, L.Y. Hao, J. Li, Y.H. Wang, Z.Y. Qi, G. Liu, J. Inorg. Organomet. Polym. Mater. 30, 1744–1751 (2020)

    Article  CAS  Google Scholar 

  26. X. Xu, L. Hu, Z.R. Li, L.S. Xie, S.J. Sun, L.C. Zhang, J. Li, Y.S. Luo, X.D. Yan, M.S. Hamdy, Q.Q. Kong, X.P. Sun, Q. Liu, Sustain. Energ. Fuels 6, 4130–4136 (2022)

    Article  CAS  Google Scholar 

  27. L.F. Hu, L.M. Wu, M.Y. Liao, X.H. Hu, X.S. Fang, Adv. Funct. Mater. 22, 998–1004 (2012)

    Article  CAS  Google Scholar 

  28. Z.Q. Deng, J. Liang, Q. Liu, C.Q. Ma, L.S. Xie, L.C. Yu, Y.C. Ren, T.S. Li, Y.S. Luo, N. Li, B. Tang, A.A. Alshehri, I. Shakir, P.O. Agboola, S.H. Yan, B.Z. Zheng, J. Du, Q.Q. Kong, X.P. Sun, Chem. Eng. J. 435, 135104 (2022)

    Article  CAS  Google Scholar 

  29. Q. Liu, L.S. Xie, J. Liang, Y.C. Ren, Y.Y. Wang, L.C. Zhang, L.C. Yue, T.S. Li, Y.S. Luo, N. Li, B. Tang, Y. Liu, S.Y. Gao, A.A. Alshehri, I. Shakir, P.O. Agboola, Q.Q. Kong, Q.Y. Wang, D.W. Ma, X.P. Sun, Small 18, 2106961 (2022)

    Article  CAS  Google Scholar 

  30. J. Li, D.L. Zhao, L.C. Zhang, Y.C. Ren, L.C. Yue, Z.R. Li, S.J. Sun, Y.S. Luo, Q.Y. Chen, T.S. Li, K. Dong, Q. Liu, Q.Q. Kong, X.P. Sun, J. Colloid Interf. Sci. 629, 805–812 (2023)

    Article  ADS  CAS  Google Scholar 

  31. Z.R. Li, J. Liang, Q. Liu, L.S. Xie, L.C. Zhang, Y.C. Ren, L.C. Yue, N. Li, B. Tang, A.A. Alshehri e, M.S. Hamdy, Y.L. Luo, Q.Q. Kong, X.P. Sun, Mater. Today Phys. 23, 100619 (2022)

    Article  CAS  Google Scholar 

  32. I. Nikolov, R. Darkaoui, E. Zhecheva, R. Stoyanova, N. Dimitrov, T. Vitanov, J. Electroanal. Chem. 429, 157–168 (1997)

    Article  CAS  Google Scholar 

  33. H.L. Wang, Q.M. Gao, L. Jiang, Small 7, 2454–2459 (2011)

    Article  CAS  PubMed  Google Scholar 

  34. P.S. Bagus, C.R. Brundle, E.S. Ilton, J. Electroanal. Chem. 875, 114135 (2020)

    Article  CAS  Google Scholar 

  35. H.W. Nesbitt, D. Legrand, G.M. Bancroft, Phys. Chem. Minerals 27, 357–366 (2000)

    Article  ADS  CAS  Google Scholar 

  36. K. Sakamoto, F. Hayashi, K. Sato, M. Hirano, N. Ohtsu, Appl. Surf. Sci. 526, 146729 (2020)

    Article  CAS  Google Scholar 

  37. M. Prabu, K. Ketpang, S. Shanmugam, Nanoscale 6, 3173–3181 (2014)

    Article  ADS  CAS  PubMed  Google Scholar 

  38. W. Huang, Y. Cao, Y. Chen, J. Peng, X. Lai, J. Tu, Appl. Surf. Sci. 396, 804–811 (2017)

    Article  ADS  CAS  Google Scholar 

  39. R.H. Qin, L.Y. Hao, Q.T. Liu, J.Y. Ju, Z.Y. Qi, Inorg. Nano-Met. Chem. 52, 1441–1448 (2022)

    Article  CAS  Google Scholar 

  40. R. Ding, L. Qi, M. Jia, H. Wang, Catal. Sci. Technol. 3, 3207–3215 (2013)

    CAS  Google Scholar 

  41. Y. Zhang, F.G. Xu, Y.J. Sun, Y. Shi, Z.W. Wen, Z. Li, J. Mater. Chem. 21, 16949–16954 (2011)

    Article  CAS  Google Scholar 

  42. Y. Ni, J. Xu, H. Liu, S. Shao, Talanta 185, 335–343 (2018)

    Article  CAS  PubMed  Google Scholar 

  43. Y. Feng, D. Xiang, Y.R. Qiu, L. Li, Y.S. Li, K.Y. Wu, L.D. Zhu, Electroanalysis 32, 571–580 (2020)

    Article  CAS  Google Scholar 

  44. S.M. Babulal, S.M. Chen, R. Palani, K. Venkatesh, A.S. Haidyrah, S.K. Ramaraj, C.C. Yang, C. Karuppiah, Colloid Surface A. 621, 126600 (2021)

    Article  CAS  Google Scholar 

  45. F. Sun, J. Zhang, H. Ren, S. Wang, Y. Zhou, J. Zhang, Chin. J. Chem. Phys. 31, 799–805 (2018)

    Article  CAS  Google Scholar 

  46. H. Yin, T. Zhan, D. Qin, X. He, Q. Nie, J. Gong, Inorg. Nano-Metal Chem. 47, 1560–1567 (2017)

    Article  CAS  Google Scholar 

Download references

Funding

This research was supported by Jiangsu Province industry-university-research cooperation project (Grant No. BY2022686), Jiangsu Province College Student Innovation Program (Grant No. 202213573109Y), and the Opening Project of Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology (Grant No. ASMA201603).

Author information

Authors and Affiliations

  1. School of Materials Engineering, Jinling Institute of Technology, Nanjing, 211169, China

    Runhua Qin, Yang Zhou, Yunying Zhao & Lingyun Hao

  2. Jianagsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing, 211167, China

    Lingyun Hao

Authors
  1. Runhua Qin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yang Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yunying Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lingyun Hao
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

RHQ, YZ, YYZ: Investigation, Methodology, Formal analysis. RHQ, YZ, LYH: Funding acquisition. RHQ: Writing original draft. RHQ, LYH: Writing-review and editing. All authors reviewed the manuscript.

Corresponding authors

Correspondence to Runhua Qin or Lingyun Hao.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Qin, R., Zhou, Y., Zhao, Y. et al. Construction of Snow-Cake Like NiCo2O4 Nanostructures Modified Electrode Material and Its Electrocatalytic Oxidation of Glucose. J Inorg Organomet Polym 34, 712–721 (2024). https://doi.org/10.1007/s10904-023-02855-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-023-02855-x

Keywords

Search

Navigation