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Synthesis of Fluorescent Cu-MOF and Ni-MOF Sensors for Selective and Sensitive Detection of Arginine and Hydrogen Sulfide

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Abstract

In this work, we have synthesized a vinyl functional group containing 4, 4′-bis (1, 3-diphenoxypropane) diacrylic acid organic linker, which was used in construction of novel Cu-MOF (1) and Ni-MOF (2) through a solvothermal method. The synthesized MOFs were characterized by FT-IR, PXRD, TGA, FE-SEM, and EDAX. In particular, Cu-MOF can be used as a bifunctional sensor for detection of arginine and H2S by a fluorescence “turn-off” mechanism with low limit of detection of 0.5 µM and 3.1 µM with quick response time (< 1 min) respectively. On the other hand, Ni-MOF demonstrated to have capability for selective detection of H2S only by quenching mechanism in the presence of various other biologically important analytes. The limit of detection was found to be 3.0 µM and showed rapid quenching in fluorescence intensity (< 1 min).

Graphical Abstract

Organic linker 4,4′-bis(1,3-diphenoxypropane) diacrylic acid was used to construct Cu-MOF and Ni-MOF, which are showing good selectivity and sensitivity towards arginine and H2S using turn- off quenching mechanism.

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Data Availability

Authors declare that the data supporting the findings of this research are available within the article.

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Acknowledgements

We are thankful to Mahatma Jyotiba Research Fellowship (MJRF) for the financial support. MNIT-Jaipur for FE-SEM, EDS, BET. Department of Material Science and Chemical Engineering-IITB for PXRD.

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  1. Department of Chemistry, University of Mumbai, Mumbai, 400098, India

    Chaturvedi S. Gujja & Suresh D. Pawar

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  1. Chaturvedi S. Gujja
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CSG: conceptualization, methodology, design, synthesis, and characterization of MOF, and preparation of manuscript: SDP: supervision, conceptualization, methodology, design, characterization of compounds, supervision, writing, reviewing and editing.

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Correspondence to Suresh D. Pawar.

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Gujja, C.S., Pawar, S.D. Synthesis of Fluorescent Cu-MOF and Ni-MOF Sensors for Selective and Sensitive Detection of Arginine and Hydrogen Sulfide. J Inorg Organomet Polym 33, 2636–2646 (2023). https://doi.org/10.1007/s10904-023-02669-x

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